This paper presents the results of a detailed structural analysis of the northern Nijar and southern Vera basins with special emphasis on the evolution of the regional stress field and the associated timing of movement of the Serrata, Gafarillos and Palomares strike-slip fault zones. These major fault zones control the Neogene deformation of the SE Internal Betic Cordilleras in Spain. Detailed stress analysis on Neogene sediments of the Vera and Nijar basins shows a strike-slip regime with NW–SE-oriented subhorizontal maximum principal stress (σ1) during Tortonian and earliest Messinian times. Under the influence of this stress field, dextral displacement along the N090E-trending Gafarillos fault zone resulted in deformation of the sediments of the southern Sorbas and northeastern Nijar basins. During the early Messinian a clock-wise rotation of the stress field occurred. Stress analysis in rocks with late–early Messinian up to Quaternary ages in the Nijar and Vera basins indicates a strike-slip regime with N–S-oriented subhorizontal maximum principal stress (σ1). Under the influence of this stress field the main activity along the N010E-striking Palomares strike-slip fault zone took place, resulting in deformation of the Neogene sediments of the southeastern Vera basin and culminating in a maximum sinistral displacement of more than 20 km. At the same time the stress field was not suitably oriented to exert a large shear component on the Gafarillos fault zone, which activity ended after the earliest Messinian. Fault and outcrop patterns of syntectonic Neogene sediments in the Vera basin show that displacement along the Palomares fault zone decreased at the end of the Middle Miocene although minor displacement phases may still have occurred during the Late Miocene and possibly even Pliocene. From the Middle Miocene onward, deformation in the Nijar basin was controlled by sinistral displacement along the N040E-trending Serrata strike-slip fault zone. 相似文献
The Menderes massif consists of a Precambrian Core Series that preserves evidence for a polymetamorphic history and a Paleozoic/Mesozoic Cover Series that experienced only the Alpine tectonometamorphic evolution. Structural, petrographic, and geochronologic investigations in the central Menderes massif demonstrate that (a) part of the metamorphic and structural evolution of the Precambrian basement is older than the undeformed 551±1.4-Ma-old Birgi metagranite, and (b) inferred Alpine fabrics overprinting the Cover Series largely have the same attitudes as the old structures in the much older Core Series. The inferred Alpine fabrics include both contractional and extensional structures. Contraction under greenschist to amphibolite facies conditions resulted in the imbrication of the Core and Cover Series and generated an inverted metamorphic sequence by north-directed thrusting. During Alpine extension, most of the south-dipping thrust faults were reactivated as extensional shear zones under decreasing greenschist facies conditions. 相似文献
Information on the particle size and reactive surface area of natural samples and its interaction with natural organic matter (NOM) is essential for the understanding bioavailability, toxicity, and transport of elements in the natural environment. In part I of this series (Hiemstra et al., 2010), a method is presented that allows the determination of the effective reactive surface area (A, m2/g soil) of the oxide particles of natural samples which uses a native probe ion (phosphate) and a model oxide (goethite) as proxy. In soils, the natural oxide particles are generally embedded in a matrix of natural organic matter (NOM) and this will affect the ion binding properties of the oxide fraction. A remarkably high variation in the natural phosphate loading of the oxide surfaces (Γ, μmol/m2) is observed in our soils and the present paper shows that it is due to surface complexation of NOM, acting as a competitor via site competition and electrostatic interaction. The competitive interaction of NOM can be described with the charge distribution (CD) model by defining a ≡NOM surface species. The interfacial charge distribution of this ≡NOM surface species can be rationalized based on calculations done with an evolved surface complexation model, known as the ligand and charge distribution (LCD) model. An adequate choice is the presence of a charge of −1 v.u. at the 1-plane and −0.5 v.u. at the 2-plane of the electrical double layer used (Extended Stern layer model).The effective interfacial NOM adsorption can be quantified by comparing the experimental phosphate concentration, measured under standardized field conditions (e.g. 0.01 M CaCl2), with a prediction that uses the experimentally derived surface area (A) and the reversibly bound phosphate loading (Γ, μmol/m2) of the sample (part I) as input in the CD model. Ignoring the competitive action of adsorbed NOM leads to a severe under-prediction of the phosphate concentration by a factor ∼10 to 1000. The calculated effective loading of NOM is low at a high phosphate loading (Γ) and vice versa, showing the mutual competition of both constituents. Both constituents in combination usually dominate the surface loading of natural oxide fraction of samples and form the backbone in modeling the fate of other (minor) ions in the natural environment.Empirically, the effective NOM adsorption is found to correlate well to the organic carbon content (OC) of the samples. The effective NOM adsorption can also be linked to DOC. For this, a Non-Ideal Competitive adsorption (NICA) model is used. DOC is found to be a major explaining factor for the interfacial loading of NOM as well as phosphate. The empirical NOM-OC relation or the parameterized NICA model can be used as an alternative for estimating the effective NOM adsorption to be implemented in the CD model for calculation of the surface complexation of field samples. The biogeochemical impact of the NOM-PO4 interaction is discussed. 相似文献
Two harbor porpoises in a floating pen were subjected to five pure tone underwater signals of 70 or 120kHz with different signal durations, amplitudes and duty cycles (% of time sound is produced). Some signals were continuous, others were intermittent (duty cycles varied between 8% and 100%). The effect of each signal was judged by comparing the animals' surfacing locations and number of surfacings (i.e. number of respirations) during test periods with those during baseline periods. In all cases, both porpoises moved away from the sound source, but the effect of the signals on respiration rates was negligible. Pulsed 70kHz signals with a source level (SL) of 137dB had a similar effect as a continuous 70kHz signal with an SL of 148dB (re 1muPa, rms). Also, a pulsed 70kHz signal with an SL of 147dB had a much stronger deterring effect than a continuous 70kHz signal with a similar SL. For pulsed 70kHz signals (2s pulse duration, 4s pulse interval, SL 147dB re 1muPa, rms), the avoidance threshold sound pressure level (SPL), in the context of the present study, was estimated to be around 130dB (re 1muPa, rms) for porpoise 064 and around 124dB (re 1muPa, rms) for porpoise 047. This study shows that ultrasonic pingers (70kHz) can deter harbor porpoises. Such ultrasonic pingers have the advantage that they do not have a "dinner bell" effect on pinnipeds, and probably have no, or less, effect on other marine fauna, which are often sensitive to low frequency sounds. 相似文献
Backward erosion piping (BEP) is a form of internal erosion which can lead to failure of levees and dams. Most research focused on the critical head difference at which piping failure occurs. Two aspects have received less attention, namely (1) the temporal evolution of piping and (2) the local hydraulic conditions in the pipe and at the pipe tip. We present small-scale experiments with local pressure measurements in the pipe during equilibrium and pipe progression for different sands and degrees of hydraulic loading. The experiments confirm a positive relation between progression rate and grain size as well as the degree of hydraulic overloading. Furthermore, the analysis of local hydraulic conditions shows that the rate of BEP progression can be better explained by the bed shear stress and sediment transport in the pipe than by the seepage velocity at the pipe tip. The experiments show how different processes contribute to the piping process and these insights provide a first empirical basis for modeling pipe development using coupled seepage-sediment transport equations.
Human activities affect the impact of the nitrogen cycle on both the environment and climate. The rate of anthropogenic nitrogen fixation from atmospheric N2 may serve as an indicator to the magnitude of this impact, acknowledging that relationship to be effect-dependent and non-linear. Building on the set of Representative Concentration Pathway (RCP) scenarios developed for climate change research, we estimate anthropogenic industrial nitrogen fixation throughout the 21st century. Assigning characteristic key drivers to the four underlying scenarios we arrive at nitrogen fixation rates for agricultural use of 80 to 172 Tg N/yr by 2100, which is slightly less to almost twice as much compared with the fixation rate for the year 2000. We use the following key drivers of change, varying between scenarios: population growth, consumption of animal protein, agricultural efficiency improvement and additional biofuel production. Further anthropogenic nitrogen fixation for production of materials such as explosives or plastics and from combustion are projected to remain considerably smaller than that related to agriculture. While variation among the four scenarios is considerable, our interpretation of scenarios constrains the option space: several of the factors enhancing the anthropogenic impact on the nitrogen cycle may occur concurrently, but never all of them. A scenario that is specifically targeted towards limiting greenhouse gas emissions ends up as the potentially largest contributor to nitrogen fixation, as a result of large amounts of biofuels required and the fertilizer used to produce it. Other published data on nitrogen fixation towards 2100 indicate that our high estimates based on the RCP approach are rather conservative. Even the most optimistic scenario estimates that nitrogen fixation rate will remain substantially in excess of an estimate of sustainable boundaries by 2100. 相似文献