Unravelling the effects of melt depletion and secondary infiltration on mantle Re-Os isotopes beneath the French Massif Central     

J. Harvey  A. Gannoun  K.W. Burton  P. Schiano  O. Alard 《Geochimica et cosmochimica acta》2010,74(1):293-6182

Spinel lherzolite xenoliths from Mont Briançon, French Massif Central, retain evidence for multiple episodes of melt depletion and melt/fluid infiltration (metasomatism). Evidence for primary melt depletion is still preserved in the co-variation of bulk-rock major elements (MgO 38.7-46.1 wt.%; CaO 0.9-3.6 wt.%), and many samples yield unradiogenic bulk-rock Os isotope ratios (¹⁸⁷Os/¹⁸⁸Os = 0.11541-0.12626). However, many individual xenoliths contain interstitial glasses and melt inclusions that are not in equilibrium with the major primary minerals. Incompatible trace element mass balance calculations demonstrate that metasomatic components comprise a significant proportion of the bulk-rock budget for these elements in some rocks, ranging to as much as 25% of Nd and 40% of Sr Critically, for Re-Os geochronology, melt/fluid infiltration is accompanied by the mobilisation of sulfide. Consequently, bulk-rock isotope measurements, whether using lithophile (e.g. Rb-Sr, Sm-Nd) or siderophile (Re-Os) based isotope systems, may only yield a perturbed and/or homogenised average of these multiple events.Osmium mass balance calculations demonstrate that bulk-rock Os in peridotite is dominated by contributions from two populations of sulfide grain: (i) interstitial, metasomatic sulfide with low [Os] and radiogenic ¹⁸⁷Os/¹⁸⁸Os, and (ii) primary sulfides with high [Os] and unradiogenic ¹⁸⁷Os/¹⁸⁸Os, which have been preserved within host silicate grains and shielded from interaction with transient melts and fluid. The latter can account for >97% of bulk-rock Os and preserve geochronological information of the melt from which they originally precipitated as an immiscible liquid. The Re-depletion model ages of individual primary sulfide grains preserve evidence for melt depletion beneath the Massif Central from at least 1.8 Gyr ago despite the more recent metasomatic event(s).  相似文献   

Evidence from the Historical Record to Support Projection of Future Wind Regimes: An Application to Canada     

Chad Shouquan Cheng 《大气与海洋》2014,52(3):232-241

In the field of climate change impact analysis, bidirectional changes in projections of future wind regimes varying among studies, locations, and models have been described in the literature, which is understandable from a global perspective. However, we should attempt to find evidence in the historical record to support these projections. This paper attempts to address this issue by analyzing historical wind gust observations for up to 57 years (1953–2009) over Canada. Two wind gust analysis techniques were used: the speed of daily wind gust events ≥50?km?h^?1 was compared with (1) the climatological daily temperature anomaly and (2) the climatological daily sea level air pressure anomaly. In addition, the frequency of daily wind gust events ≥90?km?h^?1 was compared with both daily temperature and pressure anomalies. The results indicate that during the past five decades gust wind speed over Canada increased significantly as the daily temperature anomaly increased and the daily pressure anomaly decreased. About 50–60% of daily wind gust events ≥90?km?h^?1 occurred with positive daily temperature anomalies and negative daily pressure anomalies. One major conclusion is that the methods used in and results derived from this study might be applied to climate change impact analysis to support projections of future wind regimes.  相似文献   

Building zoned ignimbrites by recycling silicic cumulates: insight from the 1,000 km<Superscript>3</Superscript> Carpenter Ridge Tuff,CO     

Olivier?BachmannEmail author  Chad?D.?Deering  Peter?W.?Lipman  Charles?Plummer 《Contributions to Mineralogy and Petrology》2014,167(6):1025

The ~1,000 km³ Carpenter Ridge Tuff (CRT), erupted at 27.55 Ma during the mid-tertiary ignimbrite flare-up in the western USA, is among the largest known strongly zoned ash-flow tuffs. It consists primarily of densely welded crystal-poor rhyolite with a pronounced, highly evolved chemical signature (high Rb/Sr, low Ba, Zr, Eu), but thickly ponded intracaldera CRT is capped by a more crystal-rich, less silicic facies. In the outflow ignimbrite, this upper zone is defined mainly by densely welded crystal-rich juvenile clasts of trachydacite composition, with higher Fe–Ti oxide temperatures, and is characterized by extremely high Ba (to 7,500 ppm), Zr, Sr, and positive Eu anomalies. Rare mafic clasts (51–53 wt% SiO₂) with Ba contents to 4,000–5,000 ppm and positive Eu anomalies are also present. Much of the major and trace-element variations in the CRT juvenile clasts can be reproduced via in situ differentiation by interstitial melt extraction from a crystal-rich, upper-crustal mush zone, with the trachydacite, crystal-rich clasts representing the remobilized crystal cumulate left behind by the melt extraction process. Late recharge events, represented by the rare mafic clasts and high-Al amphiboles in some samples, mixed in with parts of the crystal cumulate and generated additional scatter in the whole-rock data. Recharge was important in thermally remobilizing the silicic crystal cumulate by partially melting the near-solidus phases, as supported by: (1) ubiquitous wormy/sieve textures and reverse zoning patterns in feldspars and biotites, (2) absence of quartz in this very silicic unit stored at depths of >4–5 km, and (3) heterogeneous melt compositions in the trachydacite fiamme and mafic clasts, particularly in Ba, indicating local enrichment of this element due mostly to sanidine and biotite melting. The injection of hot, juvenile magma into the upper-crustal cumulate also imparted the observed thermal gradient to the deposits and the mixing overprint that partly masks the in situ differentiation process. The CRT provides a particularly clear perspective on processes of in situ crystal-liquid separation into a lower crystal-rich zone and an upper eruptible cap, which appears common in incrementally built upper-crustal magma reservoirs of high-flux magmatic provinces.  相似文献   

Molecular modeling of Al and benzene interactions with Suwannee fulvic acid     

Chad C. Trout 《Geochimica et cosmochimica acta》2007,71(15):3859-3871

The effects that Al³⁺ and benzene interactions exhibit on a model fulvic acid were investigated. Energy minimizations of the structures mimicking the interactions of Al³⁺-Suwannee fulvic acid (SFA), benzene-SFA and Al³⁺-benzene-SFA were run with a solvation sphere of 60 H₂O molecules with the semi-empirical methods PM3 and PM5. The semi-empirical method PM3 was run with Gaussian 98 and CAChe Workstation Pro 6.1.1 to compare the results of the energy minimization algorithms in the two programs. PM5 calculations were run with CAChe Workstation Pro 6.1.1. Molecular dynamics (MD) simulations were run in Cerius² (Accelrys Inc., San Diego, CA) using the Universal Force Field (UFF) 1.02 [Rappé A. K., Casewit C., Colwell K., Goddard W., and Skiff W. (1992) UFF, a full periodic-table force-field for molecular mechanics and molecular dynamics simulations. J. Am. Chem. Soc.114(25), 10024-10035] and COMPASS force field [Sun H. (1998) COMPASS: an ab initio force-field optimized for condensed-phase applications—overview with details on alkane and benzene compounds. J. Phys. Chem. B102, 7338-7364]. Single point calculations were run on the minimized structures at the B3LYP/6-31G(d) level to obtain more accurate estimates of the energy on the minimized structures derived from the PM3, PM5, and UFF methods and to normalize energies to the same reference state. This methodology was used as the standard of comparison for all the models to assess whether or not a given configuration was reasonably stable.The PM3/G03 energy minimizations predicted the lowest B3LYP/6-31G(d) potential energies of the methodologies examined in this study. Thus, this method is considered the most reliable of those tested. The PM3/G03 method predicted that there would be aromatic-aromatic interactions between benzene and SFA. The presence of Al³⁺ was predicted not to interfere with aromatic-aromatic interactions between benzene and SFA, but benzene may influence the location of metal complexation to SFA.  相似文献   

Activity-composition relations in the system CaCO₃-MgCO₃ predicted from static structure energy calculations and Monte Carlo simulations     

Victor L. Vinograd  Benjamin P. Burton  Neil L. Allan 《Geochimica et cosmochimica acta》2007,71(4):974-983

Thermodynamic mixing properties and subsolidus phase relations of the rhombohedral carbonate system, (1 − x) · CaCO₃ − x · MgCO₃, were modelled in the temperature range of 623-2023 K with static structure energy calculations based on well-parameterised empirical interatomic potentials. Relaxed static structure energies of a large set of randomly varied structures in a 4 × 4 × 1 supercell of calcite (a = 19.952 Å, c = 17.061 Å) were calculated with the General Utility Lattice Program (GULP). These energies were cluster expanded in a basis set of 12 pair-wise effective interactions. Temperature-dependent enthalpies of mixing were calculated by the Monte Carlo method. Free energies of mixing were obtained by thermodynamic integration of the Monte Carlo results. The calculated phase diagram is in good agreement with experimental phase boundaries.  相似文献   

Forgotten coast,forgotten people: sustainable development and disproportionate impacts from Hurricane Michael in Gulf County,Florida     

Boda  Chad S.  Scown  Murray W.  Faran  Turaj 《Natural Hazards》2022,111(1):877-899

Natural Hazards - A central challenge for sustainable development is how societies are to avoid, minimize or address impacts from anthropogenic climate change. However, competing perspectives on...  相似文献   

Mineralogy,petrology, chronology,and exposure history of the Chelyabinsk meteorite and parent body          下载免费PDF全文

K. Righter  P. Abell  D. Agresti  E. L. Berger  A. S. Burton  J. S. Delaney  M. D. Fries  E. K. Gibson  M. K. Haba  R. Harrington  G. F. Herzog  L. P. Keller  D. Locke  F. N. Lindsay  T. J. McCoy  R. V. Morris  K. Nagao  K. Nakamura‐Messenger  P. B. Niles  L. E. Nyquist  J. Park  Z. X. Peng  C.‐Y. Shih  J. I. Simon  C. C. Swisher III  M. J. Tappa  B. D. Turrin  R. A. Zeigler 《Meteoritics & planetary science》2015,50(10):1790-1819

Three masses of the Chelyabinsk meteorite have been studied with a wide range of analytical techniques to understand the mineralogical variation and thermal history of the Chelyabinsk parent body. The samples exhibit little to no postentry oxidation via Mössbauer and Raman spectroscopy indicating their fresh character, but despite the rapid collection and care of handling some low levels of terrestrial contamination did nonetheless result. Detailed studies show three distinct lithologies, indicative of a genomict breccia. A light‐colored lithology is LL5 material that has experienced thermal metamorphism and subsequent shock at levels near S4. The second lithology is a shock‐darkened LL5 material in which the darkening is caused by melt and metal‐troilite veins along grain boundaries. The third lithology is an impact melt breccia that formed at high temperatures (~1600 °C), and it experienced rapid cooling and degassing of S₂ gas. Portions of light and dark lithologies from Chel‐101, and the impact melt breccias (Chel‐102 and Chel‐103) were prepared and analyzed for Rb‐Sr, Sm‐Nd, and Ar‐Ar dating. When combined with results from other studies and chronometers, at least eight impact events (e.g., ~4.53 Ga, ~4.45 Ga, ~3.73 Ga, ~2.81 Ga, ~1.46 Ga, ~852 Ma, ~312 Ma, and ~27 Ma) are clearly identified for Chelyabinsk, indicating a complex history of impacts and heating events. Finally, noble gases yield young cosmic ray exposure ages, near 1 Ma. These young ages, together with the absence of measurable cosmogenic derived Sm and Cr, indicate that Chelyabinsk may have been derived from a recent breakup event on an NEO of LL chondrite composition.  相似文献   

Similarity Scaling Over a Steep Alpine Slope   总被引：5，自引：5，他引：0  

Daniel F. Nadeau  Eric R. Pardyjak  Chad W. Higgins  Marc B. Parlange 《Boundary-Layer Meteorology》2013,147(3):401-419

In this study, we investigate the validity of similarity scaling over a steep mountain slope (30–41 $^\circ $ ). The results are based on eddy-covariance data collected during the Slope Experiment near La Fouly (SELF-2010); a field campaign conducted in a narrow valley of the Swiss Alps during summer 2010. The turbulent fluxes of heat and momentum are found to vary significantly with height in the first few metres above the inclined surface. These variations exceed by an order of magnitude the well-accepted maximum 10 % required for the applicability of Monin–Obukhov similarity theory in the surface layer. This could be due to a surface layer that is too thin to be detected or to the presence of advective fluxes. It is shown that local scaling can be a useful tool in these cases when surface-layer theory breaks down. Under convective conditions and after removing the effects of self-correlation, the normalized standard deviations of slope-normal wind velocity, temperature and humidity scale relatively well with $z/\varLambda $ , where $z$ is the measurement height and $\varLambda (z)$ the local Obukhov length. However, the horizontal velocity fluctuations are not correlated with $z/\varLambda $ under all stability regimes. The non-dimensional gradients of wind velocity and temperature are also investigated. For those, the local scaling appears inappropriate, particularly at night when shallow drainage flows prevail and lead to negative wind-speed gradients close to the surface.  相似文献   

The amino acid composition of the Sutter's Mill CM2 carbonaceous chondrite     

Aaron S. Burton  Daniel P. Glavin  Jamie E. Elsila  Jason P. Dworkin  Peter Jenniskens  Qing‐Zhu Yin 《Meteoritics & planetary science》2014,49(11):2074-2086

We determined the abundances and enantiomeric compositions of amino acids in Sutter's Mill fragment #2 (designated SM2) recovered prior to heavy rains that fell April 25–26, 2012, and two other meteorite fragments, SM12 and SM51, that were recovered postrain. We also determined the abundance, enantiomeric, and isotopic compositions of amino acids in soil from the recovery site of fragment SM51. The three meteorite stones experienced terrestrial amino acid contamination, as evidenced by the low d/l ratios of several proteinogenic amino acids. The d/l ratios were higher in SM2 than in SM12 and SM51, consistent with rain introducing additional l‐ amino acid contaminants to SM12 and SM51. Higher percentages of glycine, β‐alanine, and γ‐amino‐n‐butyric acid were observed in free form in SM2 and SM51 compared with the soil, suggesting that these free amino acids may be indigenous. Trace levels of d +l‐ β‐aminoisobutyric acid (β‐AIB) observed in all three meteorites are not easily explained as terrestrial contamination, as β‐AIB is rare on Earth and was not detected in the soil. Bulk carbon and nitrogen and isotopic ratios of the SM samples and the soil also indicate terrestrial contamination, as does compound‐specific isotopic analysis of the amino acids in the soil. The amino acid abundances in SM2, the most pristine SM meteorite analyzed here, are approximately 20‐fold lower than in the Murchison CM2 carbonaceous chondrite. This may be due to thermal metamorphism in the Sutter's Mill parent body at temperatures greater than observed for other aqueously altered CM2 meteorites.  相似文献   

A CH₃CN and HCO⁺ survey towards southern methanol masers associated with star formation     

C. R. Purcell  R. Balasubramanyam  M. G. Burton  A. J. Walsh  V. Minier  M. R. Hunt-Cunningham  L. L. Kedziora-Chudczer  S. N. Longmore  T. Hill  I. Bains  P. J. Barnes  A. L. Busfield  P. Calisse  N. H. M. Crighton  S. J. Curran  T. M. Davis  J. T. Dempsey  G. Derragopian  B. Fulton  M. G. Hidas  M. G. Hoare  J.-K. Lee  E. F. Ladd  S. L. Lumsden  T. J. T. Moore  M. T. Murphy  R. D. Oudmaijer  M. B. Pracy  J. Rathborne  S. Robertson  A. S. B. Schultz  J. Shobbrook  P. A. Sparks  J. Storey  T. Travouillion 《Monthly notices of the Royal Astronomical Society》2006,367(2):553-576

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