Aliphatic and aromatic hydrocarbons in coastal Caspian Sea sediments   总被引：17，自引：0，他引：17  

Tolosa I  de Mora S  Sheikholeslami MR  Villeneuve JP  Bartocci J  Cattini C 《Marine pollution bulletin》2004,48(1-2):44-60

This investigation represents the first extensive study of the spatial distribution and sources of aliphatic (n-alkanes and unresolved complex mixture of fossil hydrocarbons) and polycyclic aromatic hydrocarbons (PAHs) in coastal sediments from the Caspian Sea. PAH concentrations, n-alkanes and biomarker profiles all suggested that there was limited petrogenic contamination in the shallow North Caspian Sea sediments, which are coarse with a low total organic carbon content. In contrast, moderate to high petrogenic contamination was found in the South Caspian Sea, in particular in the offshore oil fields near Baku, Azerbaijan. Contaminant patterns indicated that the PAHs were mainly from fossil sources, with higher contributions of pyrolytic only near industrialized and urban areas. A high contribution of perylene, a geochemically derived PAH, to the total PAHs was found in the west and south at sites influenced by the Kura, Safid Rud, Terek, Sulak and Samur Rivers.  相似文献   

Temporal trends of solar EUV and UV full-disk fluxes     

Richard F. Donnelly 《Solar physics》1987,109(1):37-58

Several progressions in the temporal characteristics of full-disk solar UV and EUV fluxes have been identified that raise many questions about the solar physics involved. The collective effect of numerous enhancements smaller than scaled plages contribute significantly to the solar cycle variations, especially for emissions from the cooler portions of the corona and the chromosphere. Active-region remnants are suggested to have a strong role even in solar-rotation induced variations late in an episode of major activity. Although cool coronal EUV emissions are long lasting, the persistence of the solar-rotation induced variations is even greater at photospheric UV wavelengths. Gyroresonance and possibly nonthermal radio emission at centimeter wavelengths are suggested to be particularly important during the first solar rotation of an episode of major activity.  相似文献   

Chlorinated hydrocarbons in marine biota and coastal sediments from the Gulf and Gulf of Oman     

de Mora S  Fowler SW  Tolosa I  Villeneuve JP  Cattini C 《Marine pollution bulletin》2005,50(8):835-849

The spatial distribution of various organochlorinated compounds was investigated in the Gulf and Gulf of Oman based on marine biota (fish and various bivalves) and coastal sediment collected in Bahrain, Oman, Qatar and the United Arab Emirates (UAE) during 2000-2001. Several potential organic contaminants from agricultural (e.g., DDT and its breakdown products, lindane, endrin, dieldrin, endosulfan) and industrial (PCBs) sources were measured. Sediment burdens for all compounds, even for an apparent hot spot near a refinery in Bahrain, were amongst the lowest reported for surface sediments from other seas. Concentrations of DDTs were low in the muscle and liver of all fish (orange spotted grouper and the spangled emperor) analysed. Similarly, the levels of chlorinated hydrocarbons were low in the various bivalve species, notably rock oysters and pearl oysters. These results contribute to the sparse regional database for organochlorinated compounds in the marine environment. Moreover, they can be used as the most recent end point for elucidating temporal trends. Whereas the levels, albeit relatively low, SigmaDDTs in the rock oysters from the Gulf of Oman have remained uniform, there has been an irregular but generally decreasing trend in concentrations of summation SigmaPCBs during the last two decades.  相似文献   

Donnees experimentales sur la diffusion des elements majeurs entre verres ou liquides de compositions basaltique,rhyolitique et phonolitique,entre 900°C et 1300°C,a pression ordinaire     

Chantal Alibert  Jean-Paul Carron 《Earth and Planetary Science Letters》1980,47(2):294-306

Diffusion coefficients for Si, Ti, Al, Na, K, Ca, Mg and Fe between pairs of glasses of basaltic, rhyolitic or phonolitic compositions have been determinated experimentally. This method involves the heating of coaxial cylinders of paired glasses under atmospheric conditions, over a range of temperatures from 900 to 1300°C, followed by microprobe analysis determination of the concentration gradients across the interface.The measured diffusivities are similar for all cations and range from 10^?13 cm²/s at 900°C to 5 × 10^?9 cm²/s at 1300°C. Depending mainly on the composition contrast, the diffusion is characterized by asymmetrical concentration profiles. This peculiar feature increases with temperature and chemical gradients across the contact surface of the glasses and leads to higher diffusion coefficients (D) in the more “basic” glass of a given pair. In the case of the rhyolite-basalt couple, this variation increases by a factor of about 10 at 1300°C. Diffusion dependence on temperature follows an Arrhenius equation which gives activation energies ranging from 65 to 85 kcal/mole. Assuming a constant and overall D for the two glasses we have attempted to apply our results to some geological examples such as exchanges between molten enclaves and liquids of contrasting composition.  相似文献   

Organochlorinated compounds in Caspian Sea sediments   总被引：2，自引：0，他引：2  

de Mora S  Villeneuve JP  Sheikholeslami MR  Cattini C  Tolosa I 《Marine pollution bulletin》2004,48(1-2):30-43

Several organochlorinated contaminants, including numerous pesticides, were determined in coastal sediments from the Caspian Sea. The most important contaminants were p,p'-DDT (up to 7400 pg g(-1)) and its breakdown products, p,p'-DDD (up to 3400 pg g(-1)) and p,p'-DDE (up to 1300 pg g(-1)). Although the contamination was most severe in Azerbaijan, the sediment concentrations and percentage distribution of the three DDT-related compounds indicated that such contamination constitutes a contemporary and ubiquitous problem in the Caspian Sea. Lindane represented the second most significant contaminant, particularly in the Russian Federation, with concentrations up to 609 pg g(-1). The concentrations of HCB and other chlorinated pesticides (cis- and trans-chlordane, methoxychlor, heptachlor, heptachlor epoxide, aldrin, endrin, and endosulfans) were lower and not generally of concern, but the pesticides did demonstrate markedly different distributions reflecting differing agricultural usage in the region. The concentrations of Sigma PCBs were also quite low and ranged from 0.03 to 6.4 ng g(-1), with the highest amounts in the Russian Federation and Azerbaijan.  相似文献   

Perturbations of a twisted solar coronal loop: The relation between surface waves and instabilities     

N. F. Cramer  I. J. Donnelly 《Solar physics》1985,99(1-2):119-132

The spectrum of propagating waves and instabilities on a current-carrying, zero gas pressure, twisted magnetic flux loop is analysed for several models of the magnetic field structure. A surface wave mode of the fast Alfvén wave is found to exist, with damping of the wave when Alfvén resonance absorption occurs. If the loop is surrounded by a uniform, purely axial magnetic field, then the surface wave is always stable. If the loop is surrounded by a nonuniform field which is continuous with the loop's field, then the surface wave may connect to the unstable external kink mode.  相似文献   

New evidence for high discharge to the Chukchi shelf since the Last Glacial Maximum     

Jenna C. Hill  Neal W. Driscoll  Jeffrey P. Donnelly  Lloyd Keigwin 《Quaternary Research》2007,68(2):271-279

Using CHIRP subbottom profiling across the Chukchi shelf, offshore NW Alaska, we observed a large incised valley that measures tens of kilometers in width. The valley appears to have been repeatedly excavated during sea level lowering; however, the two most recent incisions appear to have been downcut during the last sea level rise, suggesting an increase in the volume of discharge. Modern drainage from the northwestern Alaskan margin is dominated by small, low-discharge rivers that do not appear to be large enough to have carved the offshore drainage. The renewed downcutting and incision during the deglaciation and consequent base level rise implies there must have been an additional source of discharge. Paleoprecipitation during deglaciation is predicted to be at least 10% less than modern precipitation and thus cannot account for the higher discharge to the shelf. Glacial meltwater is the most likely source for the increased discharge.  相似文献   

Apport d'informations qualitatives pour l'estimation des teneurs en milieux hétérogènes : cas d'une pollution de sols par des hydrocarbures aromatiques polycycliques (HAP)     

Nicolas Jeannée  Chantal de Fouquet 《Comptes Rendus Geoscience》2003,335(5):441-449

Grade estimates are often of weak precision in the case of heterogeneous media, due to their high variability, even at small scale. Qualitative information is then useful to improve the quality of the estimates, without prohibitive additional costs. How can we sample such variables, and detect the ones that are of interest for the estimation of grades? The general methodology is presented and then illustrated for the estimation of the benzo(a)pyren (a polycyclic aromatic hydrocarbon, PAH) concentration in soils, sampled on a former coking plant. To cite this article: N. Jeannée, C. de Fouquet, C. R. Geoscience 335 (2003).To cite this article: N. Jeannée, C. de Fouquet, C. R. Geoscience 335 (2003).  相似文献   

A backbarrier overwash record of intense storms from Brigantine, New Jersey     

Jeffrey P. Donnelly  Jessica Butler  Stuart Roll  Micah Wengren  Thompson Webb  III 《Marine Geology》2004,210(1-4):107-121

Analysis of aerial photographs and historic charts indicates that the barrier beach at Brigantine, NJ has migrated landward 300 to 400 m since 1869, primarily as a result of overwash during hurricanes and winter storms. A series of vibracores from the backbarrier salt marsh reveals a millennial-scale stratigraphic record of overwash deposition. Carbon-14 (C-14) and Cesium-137 (Cs-137) radioisotopic methods were used to date overwash deposits (washovers). The ages of recent washovers are consistent with deposition during intense storms in 1938, 1944, 1950, and 1962. An additional overwash deposit recovered in five of the sediment cores was likely deposited by an intense hurricane strike in 1821 or possibly in 1788. Two prehistoric overwash fans were likely deposited by intense storms striking the New Jersey Coast in the 7th to 14th centuries and 6th to 7th centuries A.D. The landward barrier migration indicates that the older overwash sediments were likely transported a considerably greater distance than the more recent overwash fans. The greater distance of transport may indicate that the prehistoric storms that deposited overwash fans across the study site were more intense than the most intense storm to strike this coast in the historic period, the hurricane of 1821. The spatially variable occurrence of overwash deposition at this site points to a need for multisite stratigraphic surveys of extensive stretches of the coast in order to develop reliable records of past intense storm frequency from backbarrier environments.  相似文献   

Subsidence analysis on the Sardinian margin and the central Tyrrhenian Basin: Thermal modelling and heat flow control; deep structure implications     

Jean-Pierre Rehault  Chantal Tisseau  Marie-Franoise Brunet  Keith E Louden 《Journal of Geodynamics》1990,12(2-4)

The subsidence of the Tyrrhenian Basin is analysed based on numerous MCS reflection data and related seismic velocities, and calibrated using subsidence curves versus time at ODP Leg 107 sites 654 and 652 on the Sardinian margin. Two main phases of rifting are clearly defined for the margin-basin evolution: the first, beginning at 7 Ma, split the Sardinian-Calabrian margins, the second, beginning at 5 Ma formed the Central oceanic subbasins.Thermal models, based on thinned crust geometry from reflection-refraction data, are used which consider both vertical and horizontal conduction over time along a NW-SE transect across the entire Tyrrhenian Basin from Sardinia to Calabria. In general, there is a close agrrement between the predicted and the observed surface heat flow and the rate of subsidence over time. However, within the oceanic domain an initial subsidence must be chosen about 1000 m greater than observed on typical spreading centers, i.e., at about 3500 m as postulated in numerous back-arc basins.Thermal models, constrained by subsidence analysis and gravity observations, imply a large difference for the Moho depth beneath the Sardinian margin as determined after refraction seismic experiments. The upper mantle, hot but with high density, would be situated much higher than is postulated by seismic data and probably includes 7.3–7.4 km/s velocity layers previously interpreted as deep crustal layers.  相似文献