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Late Quaternary paleotemperatures and paleosalinities of surface waters of the Gulf of Mexico were estimated using a multivariate statistical analysis of census data of planktonic foraminifera. Two climatic extremes were selected for detailed basinwide study, the climatic optimum 125,000 yr ago and the glacial maximum 18,000 yr ago. In addition, patterns of climatic change were examined in seven piston cores from 127,000 yr ago to the present day. During the climatic optimum 125,000 yr ago temperature distributions in surface waters were similar to those of the present. The 22°C winter isotherm trended northeastward across the central basin and paleotemperatures decreased northward. Summer distributions were nearly homogeneous and ranged between 28° and 29°C. Winter salinities were 1‰ fresher than present values in the northmost Gulf and 0.4‰ fresher in the central basin. Summer salinities were similar during both times. In contrast, during the last glacial maximum temperatures were 1° to 2°C cooler in winter and 1°C cooler in summer, and isotherms formed a circular pattern in the Gulf during both seasons. Salinity was 0.3‰ fresher in winter than at present but 0.6‰ saltier in summer. Conditions deteriorated from the climatic optimum to the glacial maximum. In the Mexico Basin, winter temperatures were 2°C cooler from 75,000 to 45,000 yr ago (Y6 to Y3 Subzones), summer temperatures reached a minimum (3°C cooler) 32,000 yr ago (Y2–Y3 boundary), and seasonality reached minimal values (5°C) from 45,000 to 15,000 yr ago. All three parameters became similar in value to those in the Straits of Florida from 45,000 to 15,000 yr ago, suggesting that the exchange of surface waters was enhanced at this time between the two regions. Summer salinities remained similar to present conditions in the Mexico Basin, whereas, winter salinities increased 2‰ by 32,000 yr ago and then fell 0.5‰ until the glacial maximum ended. The Westerlies may have migrated southward over the Mexico Basin in winter from 32,000 to 15,000 yr ago.  相似文献   
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The Lesser Qinling carbonatite dykes are mainly composed of calcites. They are characterized by unusually high heavy rare earth element concentrations (HREE; e.g. Yb > 30 ppm) and flat to weakly light rare earth element (LREE) enriched chondrite-normalized patterns (La/Ybn = 1.0–5.5), which is in marked contrast with all other published carbonatite data. The trace element contents of calcite crystals were measured in situ by laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS). Some crystals show reduced LREE from core to rim, whereas their HREE compositions are relatively constant. The total REE contents and chondrite-normalized REE patterns from the cores of carbonate crystals are similar to those of the whole rock. The carbon and oxygen isotopic compositions of calcites fall within the range of primary, mantle-derived carbonatites. The initial Sr isotopic compositions (0.70480–0.70557) of calcites are consistent with an EM1 source or mixing between HIMU and EM1 mantle sources. However these sources cannot produce carbonatite parental magmas with a flat or slightly LREE enrichment pattern by low degrees of partial melting. Analyses of carbonates from other carbonatites show that carbonates have nearly flat REE pattern if they crystallize from a LREE enriched carbonatite melt. This implies that when carbonates crystallize from a carbonatite melt the calcite/melt partition coefficients (D) for HREE are much greater than the D for the LREE. The nearly flat REE patterns of the Lesser Qinling carbonatites can be explained if they are carbonate cumulates that contain little trapped carbonatite melt. Strong enrichment of HREE in the carbonatites may require their derivation by small degrees of melting from a garnet-poor source.  相似文献   
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The Malino Metamorphic Complex (MMC) is located at the western end of the north arm of Sulawesi. It consists of mica schists and gneisses (derived from proximal turbidite and granitoid protoliths), with intercalations of greenschist, amphibolite, marble, and quartzite, forming an E-W elongated dome-like structure bounded on all sides by faults. The age of the MMC is constrained between Devonian and Early Carboniferous. This Paleozoic age, the presence of Archean and Proterozoic inherited zircons, and the isotopic signature of the mica schists and gneisses indicate that the terrane was derived from the New Guinea-Australian margin of Gondwana. Similarities with basement rocks in the Bird’s Head suggests a common origin. Greenschists forming a discontinuous selvage (metamorphic carapace) around the complex were derived from adjacent autochthonous Paleogene formations. The rocks of the MMC show a Barrovian-type progression from greenschist through epidote-amphibolite to amphibolite facies. P–T estimations suggest a depth of burial of up to 27–30 km. K/Ar and 40Ar/39Ar cooling ages of 23–11 Ma, and a 7 Ma age for unconformably overlying volcanic rocks, indicate that the complex was exhumed during the Miocene. Two tectonic scenarios are considered: 1. the continental fragment docked with Sulawesi during the Mesozoic and was exhumed as a metamorphic core complex during the Miocene; 2. it was subducted beneath the north arm during the late Oligocene and then rapidly returned back to the surface.  相似文献   
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Modelling and extracting 3D geographical data presents numerous challenges that require continual research to attempt to evolve an efficient, reliable and accurate solution. LiDAR data capture and analysis has become a preferred acquisition choice for elevation data because the resulting quality and level of detail far exceeds traditional methods for large survey areas. As with any data collection system, LiDAR is prone to errors. Analysing these errors, ascertaining causes and producing error correction strategies is vital if accurate and confident results are to be obtained. Eight years of LiDAR datasets (from 1998 to 2005) have been closely analysed for a large coastal area of South Wales. This article provides a detailed and accurate summary of the identified LiDAR data issues and subsequent errors which affect the accuracy of end products such as Digital Surface Models (DSMs).  相似文献   
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Williamson  Daniel  Blaker  Adam T.  Hampton  Charlotte  Salter  James 《Climate Dynamics》2015,45(5-6):1299-1324
Climate Dynamics - We describe the method of history matching, a method currently used to help quantify parametric uncertainty in climate models, and argue for its use in identifying and removing...  相似文献   
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The role of sulfur in two hydrothermal vent systems, the Logatchev hydrothermal field at 14°45′N/44°58′W and several different vent sites along the southern Mid-Atlantic Ridge (SMAR) between 4°48′S and 9°33′S and between 12°22′W and 13°12′W, is examined by utilizing multiple sulfur isotope and sulfur concentration data. Isotope compositions for sulfide minerals and vent H2S from different SMAR sites range from + 1.5 to + 8.9‰ in δ34S and from + 0.001 to + 0.051‰ in Δ33S. These data indicate mixing of mantle sulfur with sulfur from seawater sulfate. Combined δ34S and Δ33S systematics reveal that vent sulfide from SMAR is characterized by a sulfur contribution from seawater sulfate between 25 and 33%. This higher contribution, compared with EPR sulfide, indicates increased seawater sulfate reduction at MAR, because of a deeper seated magma chamber and longer fluid upflow path length, and points to fundamental differences with respect to subsurface structures and fluid evolution at slow and fast spreading mid-ocean ridges.Additionally, isotope data uncover non-equilibrium isotopic exchange between dissolved sulfide and sulfate in an anhydrite bearing zone below the vent systems at fluid temperatures between 335 and 400 °C. δ34S values between + 0.2 to + 8.8‰ for dissolved and precipitated sulfide from Logatchev point to the same mixing process between mantle sulfur and sulfur from seawater sulfate as at SMAR. δ34S values between ? 24.5 and + 6.5‰ and Δ33S values between + 0.001 and + 0.125‰ for sulfide-bearing sediments and mafic/ultramafic host rocks from drill cores taken in the region of Logatchev indicate a clear contribution of biogenic sulfides formed via bacterial sulfate reduction. Basalts and basaltic glass from SMAR sites with Δ33S = ? 0.008‰ reveal lower Δ33S lower values than suggested on the basis of previously published isotopic measurements of terrestrial materials.We conclude that the combined use of both δ34S and Δ33S provides a more detailed picture of the sulfur cycling in hydrothermal systems at the Mid-Atlantic Ridge and uncovers systematic differences to hydrothermal sites at different mid-ocean ridge sites. Multiple sulfur isotope measurements allow identification of incomplete isotope exchange in addition to isotope mixing as a second important factor influencing the isotopic composition of dissolved sulfide during fluid upflow. Furthermore, based on Δ33S we are able to clearly distinguish biogenic from hydrothermal sulfides in sediments even when δ34S were identical.  相似文献   
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Drawing upon theory from the field of urban political ecology, we analyse a major strategic water plan for Melbourne, Australia—the Sustainable water strategy for the Central Region, published in 2006. We assess the extent to which the strategy identified and addressed ecological sustainability in terms of: cultural frames; ecological context; social equity; and engagement processes. We identify that the strategy's framing of water was largely separate from its social and ecological context. This framing resulted in the importance of issues such as environmental flows, social equity and cultural values being diminished, thus avoiding the inevitable confrontation with environmental limits needed to ensure long-term ecological sustainability. Our analysis shows that the discursive dominance of economics limited the response to persuasive scientific arguments for greater ecological consideration in the strategy. Our findings suggest that broadening engagement with the diverse ways in which water is valued is likely to contribute to more equitable and ecologically sustainable water futures.  相似文献   
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