Geochemical constraints on the origin of the Permian Baimazhai mafic–ultramafic intrusion,SW China     

Christina?Yan?WangEmail author  Mei-Fu?Zhou  Reid?R.?Keays 《Contributions to Mineralogy and Petrology》2006,152(3):309-321

The ∼260 Ma Baimazhai mafic–ultramafic intrusion is considered to be part of the Emeishan large igneous province and consists of orthopyroxenite surrounded by websterite and gabbro. The intrusion is variably mineralized with a massive sulfide ore body (∼20 vol.%) in the core of the intrusion. Silicate rocks have Ni/Cu ratios ranging from 0.3 to 46 with majority less than 7 and are rich in LREE relative to HREE and show Nb and Ta anomalies in primitive mantle-normalized trace element patterns, with low Nb/Th (1.0–4.5) and Nb/La (0.3–1.0) ratios. Their ɛ Nd(t) values range from −3.3 to −8.4. Uniform Pd/Pt (0.7–3.5) and Cu/Pd (100,000–400,000) ratios throughout the intrusion indicate that all the sulfides in the rocks were formed in a single sulfide-saturation event. Modeling suggests that the Baimazhai rocks were formed when an Mg-rich magma became crustally contaminated in a deep-seated staging chamber. Crustal contamination (up to ∼35%) drove the magma to S-saturation and forced orthopyroxene (Opx) onto the liquidus. The crystal-bearing magma forced out of the staging chamber was migrated by flow differentiation and consequently, the denser sulfide melt and the Opx crystals became centrally disposed in the flowing magma to form the Baimazhai intrusion.Electronic Supplementary Material Supplementary material is available to authorised users in the online version of this article at .  相似文献   

Northern African climate at the end of the twenty-first century: an integrated application of regional and global climate models   总被引：1，自引：1，他引：0  

Christina M. Patricola  Kerry H. Cook 《Climate Dynamics》2010,35(1):193-212

A method for simulating future climate on regional space scales is developed and applied to northern Africa. Simulation with a regional model allows for the horizontal resolution needed to resolve the region’s strong meridional gradients and the optimization of parameterizations and land-surface model. The control simulation is constrained by reanalysis data, and realistically represents the present day climate. Atmosphere–ocean general circulation model (AOGCM) output provides SST and lateral boundary condition anomalies for 2081–2100 under a business-as-usual emissions scenario, and the atmospheric CO₂ concentration is increased to 757 ppmv. A nine-member ensemble of future climate projections is generated by using output from nine AOGCMs. The consistency of precipitation projections for the end of the twenty-first century is much greater for the regional model ensemble than among the AOGCMs. More than 77% of ensemble members produce the same sign rainfall anomaly over much of northern Africa. For West Africa, the regional model projects wetter conditions in spring, but a mid-summer drought develops during June and July, and the heat stoke risk increases across the Sahel. Wetter conditions resume in late summer, and the likelihood of flooding increases. The regional model generally projects wetter conditions over eastern Central Africa in June and drying during August through September. Severe drought impacts parts of East Africa in late summer. Conditions become wetter in October, but the enhanced rainfall does not compensate for the summertime deficit. The risk of heat stroke increases over this region, although the threat is not projected to be as great as in the Sahel.  相似文献   

A study of weather types at Athens and Thessaloniki and their relationship to circulation types for the cold-wet period, part I: two-step cluster analysis     

C. Michailidou  P. Maheras  A. Arseni-Papadimititriou  F. Kolyva-Machera  C. Anagnostopoulou 《Theoretical and Applied Climatology》2009,97(1-2):163-177

This paper presents a method for grouping weather types that occur over an area, which combines meteorological parameters, reflecting air mass characteristics at the surface, with synoptic conditions prevailing over an area. Five quantitative meteorological parameters are used in the procedure: temperature, precipitation, relative humidity, wind velocity and sunshine duration. In addition, two qualitative variables related to the prevailing circulation type and whether it is cyclonic or anticyclonic are also included. The study period is 43 years (1958–2000) and is restricted to the cold and wet sub-period of the year, December–March. Weather types are defined using a relatively new method of cluster analysis, two-step cluster analysis, which allows the simultaneous use of both quantitative and qualitative variables. The aim of the present study is to distinguish primary weather patterns so that the investigation into the relationship between weather patterns and circulation types will be more effective. For Athens, six weather types are created, whereas for Thessaloniki five are produced. For both stations, only two weather types are related to anticyclonic situations. The majority of the identified weather types correspond to a distinctive and well-defined synoptic situation. Each weather type differs from the others, not only in terms of the circulation conditions referring to it, but also with reference to meteorological variables such as temperature and precipitation. The results of the evaluation of the aforementioned procedure are considered to be highly satisfactory.  相似文献   

PM2.5 co-benefits of climate change legislation part 1: California’s AB 32     

Christina Zapata  Nicholas Muller  Michael J. Kleeman 《Climatic change》2013,117(1-2):377-397

The Scoping Plan for compliance with California Assembly Bill 32 (Global Warming Solutions Act of 2006; AB 32) proposes a substantial reduction in 2020 greenhouse gas (GHG) emissions from all economic sectors through energy efficiency, renewable energy, and other technological measures. Most of the AB 32 Scoping Plan measures will simultaneously reduce emissions of traditional criteria pollutants along with GHGs leading to a co-benefit of improved air quality in California. The present study quantifies the airborne particulate matter (PM_2.5) co-benefits of AB 32 by comparing future air quality under a Business as Usual (BAU) scenario (without AB 32) to AB 32 implementation by sector. AB 32 measures were divided into five levels defined by sector as follows: 1) industrial sources, 2) electric utility and natural gas sources, 3) agricultural sources, 4) on-road mobile sources and 5) other mobile sources. Air quality throughout California was simulated using the UCD source-oriented air quality model during 12 days of severe air pollution and over 108 days of typical meteorology representing an annual average period in the year 2030 (10 years after the AB 32 adoption deadline). The net effect of all AB 32 measures reduced statewide primary PM and NO_x emissions by ~1 % and ~15 %, respectively. Air quality simulations predict that these emissions reductions lower population-weighted PM_2.5 concentrations by ~6 % for California. The South Coast Air Basin (SoCAB) experienced the greatest reductions in PM_2.5 concentrations due to the AB 32 transportation measures while the San Joaquin Valley (SJV) experiences the smallest reductions or even slight increases in PM_2.5 concentrations due to the AB 32 measures that called for increased use of dairy biogas for electricity generation. The ~6 % reduction in PM_2.5 exposure associated with AB 32 predicted in the current study reduced air pollution mortality in California by 6.2 %, avoiding 880 (560–1100) premature deaths per year for the conditions in 2030. The monetary benefit from this avoided mortality was estimated at $5.4B/yr with a weighted average benefit per tonne of $35 k/tonne ($23 k/tonne–$45 k/tonne) of PM, NO_x, SO_x, and NH₃ emissions reduction.  相似文献   

Shifting post production patterns: exploring changes in New Zealand's seafood processing industry     

Stringer C  Simmons G  Rees E 《New Zealand geographer》2011,67(3):161-173

This paper examines the changing nature of New Zealand's seafood companies' production practices. The past 15 years has seen the offshore outsourcing of post-harvest fish gain unprecedented momentum. The growth in offshore processing is a further stage in an increasingly globalised fisheries value chain. Fish is head and gutted, frozen and then transported to processing sites in China where it is thawed, value-added processed and refrozen for export to the original sourcing country or third country markets. Reasons advanced by the industry for this shift in production practices include quota reductions, increasing production costs and the sale of trawlers.  相似文献   

Vulnerability of water supply from the Oregon Cascades to changing climate: Linking science to users and policy   总被引：1，自引：0，他引：1  

Kathleen A. Farley  Christina Tague  Gordon E. Grant   《Global Environmental Change》2011,21(1):110-122

Despite improvements in understanding biophysical response to climate change, a better understanding of how such changes will affect societies is still needed. We evaluated effects of climate change on the coupled human-environmental system of the McKenzie River watershed in the Oregon Cascades in order to assess its vulnerability. Published empirical and modeling results indicate that climate change will alter both the timing and quantity of streamflow, but understanding how these changes will impact different water users is essential to facilitate adaptation to changing conditions. In order to better understand the vulnerability of four water use sectors to changing streamflow, we conducted a series of semi-structured interviews with representatives of each sector, in which we presented projected changes in streamflow and asked respondents to assess how changing water availability would impact their activities. In the McKenzie River watershed, there are distinct spatial and temporal patterns associated with sensitivity of water resources to climate change. This research illustrates that the implications of changing streamflow vary substantially among different water users, with vulnerabilities being determined in part by the spatial scale and timing of water use and the flexibility of those uses in time and space. Furthermore, institutions within some sectors were found to be better positioned to effectively respond to changes in water resources associated with climate change, while others have substantial barriers to the flexibility needed to manage for new conditions. A clearer understanding of these opportunities and constraints across water use sectors can provide a basis for improving response capacity and potentially reducing vulnerability to changing water resources in the region.  相似文献   

The silicon isotopic composition of surface waters in the Atlantic and Indian sectors of the Southern Ocean     

Christina L. De La Rocha  Pierre Bescont  Emmanuel Ponzevera 《Geochimica et cosmochimica acta》2011,75(18):5283-5295

We report here the silicon isotopic composition (δ³⁰Si) of dissolved silicon (DSi) from 42 surface water samples from the Drake Passage, the Weddell Gyre, other areas south of the Southern Boundary of the Antarctic Circumpolar Current (ACC), and the ACC near the Kerguelen Plateau, taken between the beginning of February and the end of March 2007. From the beginning to end of the cruise (ANTXXIII/9), DSi diminished in the Antarctic by 50 μmol L⁻¹ while concentrations of nitrate + nitrite and phosphate showed no net decline, indicating that the high seasonal Si/N removal ratios well known for the Southern Ocean may be more related to the strength of the silicate pump in the Southern Ocean than to the instantaneous Si/N uptake ratio of diatoms. The δ³⁰Si of DSi in samples containing more than 20 μM DSi were strongly negatively correlated to DSi concentrations, supporting the use of δ³⁰Si as a proxy for DSi removal. The “open system” fractionation observed, ε = −1.2 ± 0.11‰, agrees well with results from previous work in other areas, and the estimate of the initial δ³⁰Si of DSi of +1.4‰ is not far off observations of the δ³⁰Si of DSi in Winter Water (WW) in this area. Results were used to model DSi draw down in the past from the δ³⁰Si of sediment cores, although isotopic fractionation during silica dissolution appeared to influence the δ³⁰Si of some surface water samples, inviting further study of this phenomenon.  相似文献   

Experimental study of the aragonite to calcite transition in aqueous solution     

Christina Perdikouri  Thorsten Geisler  Burkhard C. Schmidt 《Geochimica et cosmochimica acta》2011,75(20):6211-6224

The experimental replacement of aragonite by calcite was studied under hydrothermal conditions at temperatures between 160 and 200 °C using single inorganic aragonite crystals as a starting material. The initial saturation state and the total [Ca²⁺]:[CO₃²⁻] ratio of the experimental solutions was found to have a determining effect on the amount and abundance of calcite overgrowths as well as the extent of replacement observed within the crystals. The replacement process was accompanied by progressive formation of cracks and pores within the calcite, which led to extended fracturing of the initial aragonite. The overall shape and morphology of the parent aragonite crystal were preserved. The replaced regions were identified with scanning electron microscopy and Raman spectroscopy.Experiments using carbonate solutions prepared with water enriched in ¹⁸O (97%) were also performed in order to trace the course of this replacement process. The incorporation of the heavier oxygen isotope in the carbonate molecule within the calcite replacements was monitored with Raman spectroscopy. The heterogeneous distribution of ¹⁸O in the reaction products required a separate study of the kinetics of isotopic equilibration within the fluid to obtain a better understanding of the ¹⁸O distribution in the calcite replacement. An activation energy of 109 kJ/mol was calculated for the exchange of oxygen isotopes between [C¹⁶O₃²⁻]_aq and [H₂¹⁸O] and the time for oxygen isotope exchange in the fluid at 200 °C was estimated at ∼0.9 s. Given the exchange rate, analyses of the run products imply that the oxygen isotope composition in the calcite product is partly inherited from the oxygen isotope composition of the aragonite parent during the replacement process and is dependent on access of the fluid to the reaction interface rather than equilibration time. The aragonite to calcite fluid-mediated transformation is described by a coupled dissolution-reprecipitation mechanism, where aragonite dissolution is coupled to the precipitation of calcite at an inwardly moving reaction interface.  相似文献   

Growth rate of the preserved continental crust: II. Constraints from Hf and O isotopes in detrital zircons from Greater Russian Rivers   总被引：1，自引：0，他引：1  

Christina Yan Wang  Ian H. Campbell  Aleksandr S. Stepanov 《Geochimica et cosmochimica acta》2011,75(5):1308-1345

Detrital zircons from the Ob, Yenisey, Lena, Amur, Volga, Dnieper, Don and Pechora rivers have been analyzed for U-Th-Pb, O and Lu-Hf isotopes to constrain the growth rate of the preserved continental crust in Greater Russia. Four major periods of zircon crystallization, 0.1-0.55, 0.95-1.3, 1.45-2.0 and 2.5-2.9 Ga, were resolved from a compilation of 1366 zircon U/Pb ages. The Archean zircons have δ¹⁸O values lying between 4.53‰ and 7.33‰, whereas Proterozoic and Phanerozoic zircons have a larger range of δ¹⁸O values in each of the recognized U/Pb time intervals with maximum δ¹⁸O values up to 12‰. We interpret the zircons with δ¹⁸O between 4.5‰ and 6.5‰ to have been derived from a magmatic precursor that contains little or no sedimentary component. The variable δ¹⁸O values of the zircons were used to constrain the ¹⁷⁶Lu/¹⁷⁷Hf ratios of the crustal source region of the zircons, which, in turn, were used to calculate Hf model ages (T_DM^V). The crustal incubation time, the time difference between primitive crust formation (dated by T_DM^V) and crustal melting (dated by zircon U/Pb age), varies between 300 to 1000 Myr for the majority of analyzed zircon grains, but can be up to 2500 Myr. The average T_DM^V Hf model age weighted by the fraction of zircons in the river load is 2.12 Ga, which is in reasonable agreement with the area-weighted average of 2.25 Ga. The T_DM^V Hf model age crustal growth curve for zircons with mantle-like δ¹⁸O values (4.5-6.5‰), weighted by area, shows that growth of the Great Russian continental crust started at 4.2 Ga, and that there are two principal periods of crustal growth, 3.6-3.3 Ga and 0.8-0.6 Ga, which are separated by an interval of low but more or less continuous growth. An alternative interpretation, in which the average ¹⁷⁶Lu/¹⁷⁷Hf ratio (0.0115) of the continental crust is used for the Paleoproterozoic zircons from the Lena River, lowers the average T_DM^V age of these grains by about 500 Myr and delays the onset of significant crustal growth to 3.5 Ga.The two principal growth periods recognized in Greater Russia differ from those identified from the Gondwana and the Mississippi river basin, which show peaks at 1.7-1.9 and 2.9-3.1 Ga (Hawkesworth and Kemp, 2006a) and 1.6-2.2 and 2.9-3.4 Ga (Wang et al., 2009), respectively. The older 3.6-3.3 Ga or 3.5-3.3 Ga peak for Greater Russia is slightly older than the older Gondwana-Mississippi peaks, whereas the younger 0.8-0.6 Ga peak is distinctly younger than the youngest peak in either Gondwana or the Mississippi river basin. This suggests that the two major peaks of crustal growth identified in Gondwana and the Mississippi river basin may not be global periods of enhanced continental growth and that the major periods of crustal growth may differ from continent to continent.  相似文献   

    

Ute Christina Herzfeld 《Mathematical Geology》1996,28(2):137-160

In 1963, Gandin published a monograph on optimum interpolation for the objective analysis of meteorological fields, ≓ a method that is similar mathematically to geodetical least-squares prediction and collocation, simple kriging, and spectral interpolation. The common problem is the interpolation or extrapolation or estimation of a continuous spatial property from finitely many observations. Gandin 's method is presented in an inverse-theoretical context with focus on a methodological comparison with related methods. Underlying mathematical assumptions as well as geological implications are discussed. An introductory overview of inverse methods in the earth sciences is given, with emphasis on methods with a structure analysis step.  相似文献