Mathematical models for petroleum-forming processes: carbon isotope fractionation     

Douglas W Waples  Leonard Tornheim 《Geochimica et cosmochimica acta》1978,42(5):467-472

A mathematical model has been developed in which carbon isotope fractionation during thermal cracking of n-paraffins can be simulated. The model has been calibrated based on data from laboratory cracking experiments carried out on n-octadecane. Relative rate constants for cleavage of C¹²-C¹², C¹²-C¹³ and C¹³-C¹³ bonds agree with the experimental values obtained by other workers.Application of this model to the process of petroleum formation gives good agreement with some existing experimental data, but suggests that a review of our understanding of isotope fractionation during thermal cracking may be necessary. The relative importance of the degree to which the organic material has been cracked and of the type of the organic material in influencing δC¹³ values is discussed.The present model predicts that cracking of n-paraffin distributions having initial odd or even carbon number predominances can induce isotopic inhomogeneity among the homologs of the resulting distribution. The model exhibits some deficiencies in explaining or predicting the δC¹³ values of ethane and propane in relation to methane in gases and of oils and associated methane. Explanations for these discrepancies may lie in the simplicity of our mathematical model, in our assumption of initial isotopic homogeneity within molecules and in our use of only n-paraffins as the source molecules for the cracking reactions.  相似文献   

Mathematical models for petroleum-forming processes: n-paraffins and isoprenoid hydrocarbons     

Douglas W Waples  Leonard Tornheim 《Geochimica et cosmochimica acta》1978,42(5):457-465

Mathematical models have been developed which simulate both random and nonrandom thermal cracking of branched and straight-chain hydrocarbons. Application of these models to n-paraffins suggests that thermal cracking alone cannot be the dominant mechanism in formation of the n-paraffin distributions present in crude oils. Application to isoprenoid hydrocarbons indicates that nonrandom cracking could be important in producing the isoprenoid distributions found in oils.Results of the mathematical modeling show that methane formation should, as predicted from energy considerations, be kinetically disfavored. It therefore is likely that substantial quantities of methane are produced from saturated hydrocarbons only under thermal conditions more severe than those under which oil is produced.The mathematical models employed are adaptable for other geochemical applications, such as isotope fractionation.  相似文献   

A maximal background spectrum of gravitational radiation     

Leonard A. Rosi  Robert L. Zimmerman 《Astrophysics and Space Science》1976,45(2):447-466

A maximal spectrum of gravitational radiation from sources outside our galaxy is calculated. The sources are galaxies, quasars and events that occur in the early history of the universe. The major contribution is from galaxies whose effect extends over the frequency region 10^–810⁺⁴Hz, peaking at 10^–110 Hz, with a spectral flux of 10 erg cm^–2, s^–1. The main processes of gravitational radiation in the galaxies are stellar collapse into a black hole and dying binary systems. In the region 10^–410⁴ Hz the background spectrum is well above the detection levels of currently proposed detectors. FromMinimal considerations of this spectrum it is determined that the density of gravitational radiation is 10^–39g cm^–3. This background spectrum is sensitive to galactic evolution and especially sensitive to the upper mass limits and mass distribution of stars in galactic models. Therefore, the spectrum could provide information about galactic evolution complementary to that obtained by electromagnetic investigations.  相似文献   

New specimens of a fossil ostrich from the Miocene of Kenya   总被引：1，自引：0，他引：1  

Leona M. Leonard  Gareth J. Dyke  Cyril A. Walker 《Journal of African Earth Sciences》2006,45(4-5):391-394

Fossilised hind limb bones from the late Middle Miocene (approximately 14 million-year-old [MYA]) Fort Ternan, Kadianga West and Ngorora localities in Western Kenya indicate the presence of a new representative of the ostrich genus Struthio. These new fossils represent some of the oldest known records for Struthio yet described, slightly younger than Struthio coppensi, from the Lower Miocene of Namibia. Because the four sub-species of the modern-day ostrich (Struthio camelus camelus, Struthio camelus australis, Struthio camelus massaicus, and Struthio camelus molybdophanes) inhabit the plains of Africa, and as recently as the 1940s, a fifth sub-species was also present in the Middle East and Saudi Arabia (Struthio camelus syriacus), records of Struthio from Kenya and Namibia testify to the much wider distribution of these cursorial birds in the relatively recent past. This is further supported by the very high frequency of ostrich eggshell fragments found across Africa and Eurasia, which vastly outweighs the amount of skeletal material uncovered over the last century.  相似文献   

Assessment of mercury mobility and bioavailability by fractionation method in sediments from coastal zone inundated by the 26 December 2004 tsunami in Thailand     

Leonard Boszke  Artur Kowalski  Witold Szczuciński  Grzegorz Rachlewicz  Stanisław Lorenc  Jerzy Siepak 《Environmental Geology》2006,51(4):527-536

The 26 December 2004 tsunami covered significant portion of a coastal zone with a blanket of potentially contaminated sediments. In this report are presented results on mercury concentrations in sediments deposited by the tsunami in a coastal zone of Thailand. Since the total mercury concentrations are insufficient to assess mercury mobility and bioavailability in sediment, its fractionation was applied. Sediments were sampled within 50 days after the event and analyzed by sequential extraction method. The procedure of sequential extraction involved five subsequent stages performed with solutions of chloroform, deionized water, 0.5 M HCl, 0.2 M NaOH, and aqua regia. The mean concentration of total mercury in sediments was 119 ± 50 ng g⁻¹ dry mass (range 66–230). The fractionation revealed that mercury is mainly bound to the least bioavailable sulphides 75 ± 6% (range 62–86), organomercury compounds 14 ± 7% (range 4–26), and humic matter 9 ± 7% (range 1–27). The lowest contributions bring fractions of water-soluble mercury 0.8 ± 1.0% (range 0.1–3.6) and acid soluble mercury 0.9 ± 0.5% (range 0.2–2.1). Although, the total mercury content is similar in a reference sample and in the tsunami sediments, the highly toxic organomercury fraction contribution is higher in the latter. The results were compared with chemical and sedimentological properties of the sediments but no significant correlations were obtained between them.  相似文献   

Small-scale vegetation dynamics in semi-arid steppe in Inner Mongolia     

Wei Zhang  Christina Skarpe 《Journal of Arid Environments》1996,34(4):421-439

Small-scale vegetation dynamics were followed for ecotones and in uniform stands inArtemisia-dominated steppe vegetation under grazing and when recovering from heavy grazing. Species composition was followed annually for 5 years in 1 m²and 0·25 m²plots for (1) presence–absence; (2) density; and (3) biomass.More rapid vegetation dynamics, in terms of change of type of vegetation and distance moved in DCA species space between sampling occasions, were observed in smaller plots and in early seral stages, where species were few and alpha diversity low. Only the plots recently protected from grazing showed a directional vegetation change; those protected for more than 3 years and those under continued grazing showed, at this scale, non-directional dynamics.  相似文献   

Ambiguity in Measuring Matrix Diffusion with Single-Well Injection/Recovery Tracer Tests   总被引：2，自引：0，他引：2  

Steven C. Lessoff  Leonard F. Konikow 《Ground water》1997,35(1):166-176

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A Local Example of Land‐Use Change: Southern Illinois—1807, 1938, and 1993*     

Leslie A. Duram  Jon Bathgate  Christina Ray 《The Professional geographer》2004,56(1):127-140

This article provides an analysis of a wetland site in southern Illinois from presettlement to the present. The study area is part of the Cache River‐Cypress Creek Wetland, which has international importance, as recognized by the Ramsar Convention on Wetlands. Land‐cover data for 1807, 1938, and 1993 were created and analyzed with a geographic information system (GIS). Land‐use change by topographic setting (uplands, transitional, and bottomlands) and soil productivity was quantified and studied. Interviews with local experts informed this analysis. Results illustrate the complexity of environmental change and its driving forces. First, notable forest and swamp acreage was converted to cropland between 1807 and 1938 and, to a lesser degree, from 1938 to 1993. Second, there were land‐use variations by topographic region. Between 1807 and 1938, the largest transformation occurred in the uplands, with substantial acreage converted from forest to cropland. Between 1938 and 1993, however, agriculture decreased in the upland areas as hilly areas reverted to forest cover. At the same time, agriculture expanded in the bottomlands as this land was drained for farming. Third, there are interesting patterns within these categories of land‐use change, as soil productivity is an indicator of what lands were taken out of cropland and converted back to grassland and forest.  相似文献   

A Preliminary Survey of the Level of Microbiological Pollution of Major Rivers in Northern Greece     

Panagiotis Karanis  Ioannis Chronis  George Zakas  Christina Kourenti  Isaia Sotiriadou  Chrissanthy Papadopoulou 《洁净——土壤、空气、水》2005,33(4):346-354

The objective of the present survey was to assess the microbiological quality of river waters used mainly to irrigate the large plains of Macedonia and Thessaly in Northern Greece. Five rivers (Aliakmonas, Axios, Loudias, Mavroneri and Pineios) were sampled during a 10‐month period (June 2002 – March 2003) for Total Microbial Flora (TMF) at 22 °C and 37 °C, Total Coliforms (TC), Fecal Coliforms (FC), enterococci, staphylococci, Pseudomonas, fungi, Giardia spp. and Cryptosporidium spp. The results indicate moderate to high microbiological pollution, with the highest levels of microbial pollution found in Mavroneri and Pineios Rivers, and moderate pollution levels in Aliakmonas, Axios and Loudias Rivers. The extent of microbiological pollution is accentuated by the fact that Giardia‐ and/or Cryptosporidium cysts were detected in nine out of eleven samples collected in June 2002 with excessive Giardia counts demonstrated for Pineios River. The microbiological pollution of the surveyed rivers is attributed to various degrees of human interference and to lack of ample pollution monitoring systems, which emphasize the need for implementation of the EU Water Framework Directive.  相似文献   

Groundwater depletion: A global problem   总被引：19，自引：6，他引：19  

Leonard F. Konikow  Eloise Kendy 《Hydrogeology Journal》2005,13(1):317-320

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