Hydrochemistry and hydrogen sulfide generating processes in the Malm aquifer,Bavarian Molasse Basin,Germany     

Christina Mayrhofer  Reinhard Niessner  Thomas Baumann 《Hydrogeology Journal》2014,22(1):151-162

Knowledge about the hydrochemical conditions of deep groundwater is crucial for the design and operation of geothermal facilities. In this study, the hydrochemical heterogeneity of the groundwaters in the Malm aquifer, Germany, is assessed, and reasons for the extraordinarily high H₂S concentrations in the central part of the Bavarian Molasse Basin are proposed. Samples were taken at 16 sites, for a total of 37 individual wells, to analyze cations, anions, gas loading and composition. The hydrochemical characteristics of the Malm groundwater in the center of the Molasse Basin are rather heterogeneous. Although the groundwater in the central basin is dominated by meteoric waters, there is a significant infiltration of saline water from higher strata. Care has to be taken in the interpretation of data from geothermal sites, as effects of chemical stimulation of the boreholes may not be fully removed before the final analyses. The distribution of H₂S in the gas phase is correlated to the gas loading of the water which increases in the central basin. Temperatures, isotopic data and the sulfur mass balance indicate that H₂S in the central basin is related to thermochemical sulfate reduction (south of Munich) and bacterial sulfate reduction (north of Munich).  相似文献   

Re–Os isotope and platinum-group element geochemistry of the Pobei Ni–Cu sulfide-bearing mafic–ultramafic complex in the northeastern part of the Tarim Craton     

Sheng-Hong Yang  Mei-Fu Zhou  Peter C. Lightfoot  Ji-Feng Xu  Christina Yan Wang  Chang-Yi Jiang  Wen-Jun Qu 《Mineralium Deposita》2014,49(3):381-397

A number of mafic–ultramafic intrusions that host Ni–Cu sulfide mineralization occur in the northeastern Tarim Craton and the eastern Tianshan Orogenic Belt (NW China). The sulfide-mineralized Pobei mafic–ultramafic complex is located in the northeastern part of the Tarim Craton. The complex is composed of gabbro and olivine gabbro, cut by dunite, wehrlite, and melatroctolite of the Poyi and Poshi intrusions. Disseminated Ni–Cu sulfide mineralization is present towards the base of the ultramafic bodies. The sulfide mineralization is typically low grade (<0.5 wt.% Ni and <2 wt.% S) with low platinum-group element (PGE) concentrations (<24.5 ppb Pt and <69 ppb Pd); the abundance of Cu in 100 % sulfide is 1–8 wt.%, and Ni abundance in 100 % sulfide is typically >4 wt.%. Samples from the Pobei complex have εNd (at 280 Ma) values up to +8.1, consistent with the derivation of the magma from an asthenospheric mantle source. Fo 89.5 mol.% olivine from the ultramafic bodies is consistent with a primitive parental magma. Sulfide-bearing dunite and wehrlite have high Cu/Pd ratios ranging from 24,000 to 218,000, indicating a magma that evolved under conditions of sulfide saturation. The grades of Ni, Cu, and PGE in 100 % sulfide show a strong positive correlation. A model for these variations is proposed where the mantle source of the Pobei magma retained ~0.033 wt.% sulfide during the production of a PGE-depleted parental magma. The parental magma migrated from the mantle to the crust and underwent further S saturation to generate the observed mineralization along with its high Cu/Pd ratio at an R-factor varying from 100 to 1,200. The mineralization at Poshi and Poyi has very high γOs (at 280 Ma) values (+30 to +292) that are negatively correlated with the abundance of Os in 100 % sulfide (5.81–271 ppb) and positively correlated with the Re/Os ratios; this indicates that sulfide saturation was triggered by the assimilation of crustal sulfide with both high γOs and Re/Os ratios. When compared to other Permian mafic–ultramafic intrusions with sulfide mineralization in the East Tianshan, the Poyi and Poshi ultramafic bodies were formed from more primitive magmas, and this helps to explain why the sulfide mineralization has high Ni tenor.  相似文献   

Microtopography,water storage and flow patterns in a fine‐textured soil under agricultural use     

Christina Bogner  Mohammadreza Mirzaei  Stéphane Ruy  Bernd Huwe 《水文研究》2013,27(12):1797-1806

Agricultural use of soils implies tillage and often compaction and therefore influences processes on soil surface and affects infiltration of water into the subsoil. Although many studies on soil surface processes or flow patterns in soils exist, works relating both are rare in literature. We did two tracer experiments with Brilliant Blue FCF on a tilled and compacted plot and a non‐tilled one to investigate water storage on the soil surface during simulated rainfall and changes of soil microtopography, to analyse the associated flow patterns in the soil and to relate both to tillage and compaction. Our results show that storage was larger on the tilled and compacted plot than on the non‐tilled one. After tillage, transport processes above the plough pan were partly disconnected from those underneath because macropores were disrupted and buried by the tillage operation. However, preferential flow along cracks occurred on both plots and the macropores buried below the tillage pan still functioned as preferential flow paths. Therefore, we conclude that the studied soil is susceptible to deep vertical solute propagation at dry conditions when cracks are open, irrespective of tillage and compaction. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Till‐forming processes beneath parts of the Cordilleran Ice Sheet,British Columbia,Canada: macroscale and microscale evidence and a new statistical technique for analysing microstructure data     

Christina M. Neudorf  Tracy A. Brennand  Olav B. Lian 《Boreas: An International Journal of Quaternary Research》2013,42(4):848-875

This paper presents the first integrated macroscale and microscale examination of subglacial till associated with the last‐glacial (Fraser Glaciation) Cordilleran Ice Sheet (CIS). A new statistical approach to quantifying till micromorphology (multivariate hierarchical cluster analysis for compositional data) is also described and implemented. Till macrostructures, macrofabrics and microstructures support previous assertions that primary till in this region formed through a combination of lodgement and deformation processes in a temperate subglacial environment. Macroscale observations suggest that subglacial environments below the CIS were probably influenced by topography, whereby poor drainage of the substrate in topographically constricted areas, or on slopes adverse to the ice‐flow direction at glacial maximum, facilitated ductile deformation of the glacier bed. Microscale observations suggest that subglacial till below the CIS experienced both ductile and brittle deformation, including grain rotation and squeeze flow of sediment between grains under moist conditions, and microshearing, grain stacking and grain fracturing under well‐drained conditions. Macroscale observations suggest that ductile deformation events were probably followed by brittle deformation events as the substrate subsequently drained. The prevalence of ductile‐type microstructures in most till exposures investigated in this study suggests that ductile deformation signatures can be preserved at the microscale after brittle deformation events that result in larger‐scale fractures and shear structures. It is likely that microscale ductile deformation can also occur within distributed shear zones during lodgement processes. Cluster analysis of microstructure data and qualitative observations made from thin sections suggest that the relative frequency of countable microstructures in this till is influenced by topography in relation to ice‐flow direction (bed drainage conditions) as well as by the frequency and distribution of voids in the till matrix and skeletal grain shapes.  相似文献   

Swedish coastal fisheries—From conflict mitigation to participatory management     

Karl Bruckmeier  Christina Höj Larsen 《Marine Policy》2008

Several research projects have studied Swedish coastal fishery to investigate the conflict between seals and fishery. In recent years, a strategy of participation by means of co-management has been unfolding. Realising that maintaining the coastal fishery requires societal support and knowledge integration, attempts have been made to introduce the principle of participatory management into the centralised Swedish fisheries management system. However, this co-management approach, presently implemented in six pilot projects, will take a long time to develop through a sustained process of experimentation and improvement.  相似文献   

PM2.5 co-benefits of climate change legislation part 2: California governor’s executive order S-3-05 applied to the transportation sector     

Michael J. Kleeman  Christina Zapata  John Stilley  Mark Hixson 《Climatic change》2013,117(1-2):399-414

California Governor’s Executive Order (CGEO) S-3-05 requires that California greenhouse gas (GHG) emissions be reduced to 80 % below 1990 levels by the year 2050. Meeting this target will require drastic changes in transportation technology, fuel, and behavior which will reduce criteria pollutant emissions as well as GHG emissions. The improvement to local air quality caused by the reduced criteria pollutant emissions must be calculated to fully evaluate the overall benefits and costs of CGEO S-3-05. In the present study, seven different transportation scenarios that move towards the goals of CGEO S-3-05 in the transportation sector were examined to determine how they would affect future airborne particulate matter (PM_2.5) concentrations in California: (1) hydrogen fuel cells, (2) electric vehicles, (3) high efficiency vehicles, (4) public mass transit, (5) biofuels, (6) biofuels + hybrid electric vehicles, and (7) hydrogen fuel cells + electric vehicles. The air quality implications of each scenario were evaluated using a chemical transport model applied during a wintertime stagnation episode representing future climate in California. Scenarios (6) and (7) reduced population-weighted PM_2.5 mass concentrations by ~9 % and PM_2.5 elemental carbon (EC) concentrations by ~30 % relative to base-case predictions.  相似文献   

Hydrogeologic controls on summer stream temperatures in the McKenzie River basin,Oregon     

Christina Tague  Michael Farrell  Gordon Grant  Sarah Lewis  Serge Rey 《水文研究》2007,21(24):3288-3300

Stream temperature is a complex function of energy inputs including solar radiation and latent and sensible heat transfer. In streams where groundwater inputs are significant, energy input through advection can also be an important control on stream temperature. For an individual stream reach, models of stream temperature can take advantage of direct measurement or estimation of these energy inputs for a given river channel environment. Understanding spatial patterns of stream temperature at a landscape scale requires predicting how this environment varies through space, and under different atmospheric conditions. At the landscape scale, air temperature is often used as a surrogate for the dominant controls on stream temperature. In this study we show that, in regions where groundwater inputs are key controls and the degree of groundwater input varies in space, air temperature alone is unlikely to explain within-landscape stream temperature patterns. We illustrate how a geologic template can offer insight into landscape-scale patterns of stream temperature and its predictability from air temperature relationships. We focus on variation in stream temperature within headwater streams within the McKenzie River basin in western Oregon. In this region, as in other areas of the Pacific Northwest, fish sensitivity to summer stream temperatures continues to be a pressing environmental issue. We show that, within the McKenzie, streams which are sourced from deeper groundwater reservoirs versus shallow subsurface flow systems have distinct summer temperature regimes. Groundwater streams are colder, less variable and less sensitive to air temperature variation. We use these results from the western Oregon Cascade hydroclimatic regime to illustrate a conceptual framework for developing regional-scale indicators of stream temperature variation that considers the underlying geologic controls on spatial variation, and the relative roles played by energy and water inputs. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Delgada Fan: Preliminary interpretation of channel development     

William R. Normark  Christina E. Gutmacher 《Geo-Marine Letters》1984,3(2-4):79-83

The Delgada Fan, an irregularly shaped turbidite deposit extending more than 350 km offshore from northern California, consists of two large leveed-valley units each fed by a separate complex of coalescing submarine canyons and slope gullies. Although the leveed-valley units head within 25 km of each other, both appear to have developed independently during fan growth. The larger southern leveed-valley system has not developed middle-fan distributary channels and appears to illustrate a period of progressive valley abandonment. Although the lower-fan area is underlain by sandy sediments, little sand has been recovered in piston cores from the leveed-valley unit. Margin setting represents fan and/or source area  相似文献   

Volcanic risk ranking for Auckland, New Zealand. I: Methodology and hazard investigation     

Christina Magill  Russell Blong 《Bulletin of Volcanology》2005,67(4):331-339

Volcanic eruptions typically produce a number of hazards, and many regions are at risk from more than one volcano or volcanic field. So that detailed risk assessments can be carried out, it is necessary to rank potential volcanic hazards and events in terms of risk. As it is often difficult to make accurate predictions regarding the characteristics of future eruptions, a method for ranking hazards and events has been developed that does not rely on precise values. Risk is calculated individually for each hazard from each source as the product of likelihood, extent and effect, based on the parameters order of magnitude. So that multiple events and outcomes can be considered, risk is further multiplied by the relative probability of the event occurring (probability_e) and the relative importance of the outcome (importance_o). By adding the values obtained, total risk is calculated and a ranking can be carried out.This method was used to rank volcanic hazards and events that may impact the Auckland Region, New Zealand. Auckland is at risk from the Auckland volcanic field, Okataina volcanic centre, Taupo volcano, Tuhua volcano, Tongariro volcanic centre, and Mt. Taranaki volcano. Relative probabilities were determined for each event, with the highest given to Mt. Taranaki. Hazards considered were, for local events: tephra fall, scoria fall and ballistic impacts, lava flow, base surge and associated shock waves, tsunami, volcanic gases and acid rain, earthquakes and ground deformation, mudflows and mudfills, lightning and flooding; and for distal events: tephra fall, pyroclastic flows, poisonous gases and acid rain, mudflows and mudfills, climate variations and earthquakes. Hazards from each source were assigned values for likelihood, with the largest for tephra fall from all sources, earthquakes and ground deformation, lava flows, scoria fall and base surge for an Auckland eruption on land, and earthquakes and ground deformation from an Auckland eruption in the ocean. The largest values for extent were for tephra fall and climate variation from each of the distal centres. However, these parameters do not give a true indication of risk. In a companion paper the effect of each hazard is fully investigated and the risk ranking completed.  相似文献   

Tectonic evolution of the Brian?onnais units along a transect (ECORS-CROP) through the Italian-French Western Alps     

Stefan Bucher  Christina Ulardic  Romain Bousquet  Stefano Ceriani  Bernhard Fügenschuh  Yves Gouffon  Stefan M. Schmid 《Eclogae Geologicae Helvetiae》2004,97(3):321-345

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