Iron porphyrins in the Permian Kupferschiefer of the lower Rhine Basin, N.W. Germany     

C. B. Eckardt  M. Wolf  J. R. Maxwell 《Organic Geochemistry》1989,14(6)

Immature samples of the Permian Kupferschiefer from the Lower Rhine Basin in N.W. Germany were analysed for tetrapyrrole pigment type and abundance. The sediment, thought to have been deposited in a marine regime with enhanced salinity, was found to contain high concentrations of metalloporphyrins. The porphyrins are complexed to nickel (Ni) and oxovanadium (V=0), but high abundances of iron (Fe) porphyrins were also detected using UV/visible spectroscopy and mass spectrometry. The presence in the latter of series of aetioporphyrins, cycloalkanoporphyrins, di-cycloalkanoporphyrins and benz-cycloalkanoporphyrins was confirmed by accurate mass measurements; HPLC co-injection of deoxophylloerythroetioporphyrin (C₃₂ DPEP) with the demetallated iron porphyrins indicated its presence in the sediment as an iron complex. The study provides the first evidence for the occurrence of Fe porphyrins in geological samples other than coals and lignites, and reports the highest concentrations in sedimentary organic matter to date.  相似文献   

Organic matter of the Mulhouse Basin, France: a synthesis     

P. Hofmann  A.Y. Huc  B. Carpentier  P. Schaeffer  P. Albrecht  B. Kelly  J.R. Maxwell  J.S.Sinninghe Damst  J.W. de Leeuw  D. Leythaeuser 《Organic Geochemistry》1993,20(8)

The lower Oligocene evaporite sequence of the Mulhouse Basin (France) contains organic matter-rich marl deposits. These marls display an overall cyclic variation of sedimentation rate, organic carbon content, hydrogen index and selected molecular parameters over a 30 m thick stratigraphic interval. The integration of all sedimentological and geochemical parameters has allowed the reconstruction and characterization of the paleoenvironment of deposition. The marls were deposited in a perennial lake that was at times connected to the sea. Two organic facies end members could be assigned to a lake stage with a marine connection and a lake stage that received dominantly continental water input. The overall stratigraphic variation in the organic matter content is interpreted to reflect the adaptation of the Oligocene flora to the changing paleoclimate and environmental conditions.  相似文献   

Evidence of an early alteration process driven by magmatic fluid in Mururoa volcano     

Christine Destrigneville  Jacques Schott  Yves Caristan  Pierre Agrinier 《Earth and Planetary Science Letters》1991,104(2-4)

Evidence for a deuteric alteration process induced by a magmatic fluid has been found in the feeder zone of the Mururoa volcano (French Polynesia). Within the dikes, where basaltic glass does not show any evidence of pervasive alteration, vesicles are filled with dioctahedral smectites and calcite, while olivine phenocrysts are replaced by dioctahedral smectites, ankerite and calcite.The ¹³C signature of carbonates, the carbon and H₂O content of the whole rocks and their impoverishment in deuterium are compatible with the presence of magmatic CO₂ during the crystallization of intruding lavas and exclude contamination by seawater. Mass balance calculations on selected thin sections photographs of partly filled up vesicles and replaced olivine crystals, constrain, assuming a closed system interaction, the chemical composition of the initial fluid and the respective amounts of the initial solid phases involved in the alteration process. Thermodynamic modelings using the EQ3/6 software package correctly predict the mineralogic, chemical and isotopic exchanges accompanying alteration, thus validating the closed system assumption. The model which allows prediction of the influence of CO₂ on the alteration products, shows that, above a 0.25 CO₂ mole fraction in the initial fluid, the alteration is entirely controlled by the chemical composition of the initial solid phases. The presence of CO₂ implies the precipitation of dioctahedral smectites and carbonates instead of the magnesian smectites commonly observed in CO₂-free systems.The Mururoa feeder zone shows alteration features typical of a closed system interaction between the basaltic rock and a magmatic fluid in which seawater did not take part.  相似文献   

The effect of maturation on the configurations of acyclic isoprenoid acids in sediments     

A.S. Mackenzie  R.L. Patience  D.A. Yon  J.R. Maxwell 《Geochimica et cosmochimica acta》1982,46(5):783-792

Within a variety of sedimentary rocks of differing maturity, the configurations of a suite of acyclic isoprenoid acids have been examined by gas Chromatographic (in a few cases also by combined gas chromatography-mass spectrometry) analysis of their diastereoisomeric methyl and (?)-menthyl esters. The samples include the Eocene Messel (Germany) and Green River (U.S.) shales, the Permian Irati shale (Brazil) and a number of Lower Toarcian shales from the Paris Basin. The isomer distributions show that isomerisation occurs at the chiral centres with increasing maturation (to increase the number of isomers) and that the rate of isomerisation increases for centres (C-2,C-3) closest to the carboxyl group. These results suggest that adsorption of the carboxyl group to a catalyst surface may control the isomerisation rates by way of access to the catalyst.  相似文献   

Efficiency of heavy liquid separation to concentrate magnetic particles     

Christine Franke  Thomas Frederichs  Mark J. Dekkers 《Geophysical Journal International》2007,170(3):1053-1066

Low-temperature rock magnetic measurements have distinct diagnostic value. However, in most bulk marine sediments the concentration of ferrimagnetic and antiferromagnetic minerals is extremely low, so even sensitive instrumentation often responds to the paramagnetic contribution of the silicate matrix in the residual field of the magnetometer. Analysis of magnetic extracts is usually performed to solve the problems raised by low magnetic concentrations. Additionally magnetic extracts can be used for several other analyses, for example electron microscopy or X-ray diffraction. The magnetic extraction technique is generally sufficient for sediments dominated by magnetite. In this study however, we show that high-coercivity components are rather underrepresented in magnetic extracts of sediments with a more complex magnetic mineralogy. We test heavy liquid separation, using hydrophilic sodium polytungstenate solution Na₆[H₂W₁₂O₄₀], to demonstrate the efficiencies of both concentration techniques. Low-temperature cycling of zero-field-cooled, field-cooled and saturation isothermal remanent magnetization acquired at room temperature was performed on dry bulk sediments, magnetic extracts, and heavy liquid separates of clay-rich pelagic sediments originating from the Equatorial Atlantic. The results of the thermomagnetic measurements clarify that magnetic extraction favours components with high spontaneous magnetization, such as magnetite and titanomagnetite. The heavy liquid separation is unbiased with respect to high- and low-coercive minerals, thus it represents the entire magnetic assemblage.  相似文献   

Early diagenetic greigite as a recorder of the palaeomagnetic signal in Miocene–Pliocene sedimentary rocks of the Carpathian foredeep (Romania)     

Iuliana Vasiliev  Mark J. Dekkers  Wout Krijgsman  Christine Franke  Cor G. Langereis  Tom A. T. Mullender 《Geophysical Journal International》2007,171(2):613-629

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Slip rates variability and sediment mobilization on a shallow landslide in the northern Swiss Alps     

Marco Schwab  Christine Läderach  Dirk Rieke-Zapp  Fritz Schlunegger 《Swiss Journal of Geoscience》2007,100(2):281-292

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Exploring the influence of the non-dipole field on magnetic records for field reversals and excursions     

Maxwell C. Brown  Richard Holme  Alistair Bargery 《Geophysical Journal International》2007,168(2):541-550

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Slowness-backazimuth weighted migration: A new array approach to a high-resolution image     

Tadashi Kito  reas Rietbrock  Christine Thomas 《Geophysical Journal International》2007,169(3):1201-1209

We have developed a new array method combining conventional migration with a slowness-backazimuth deviation weighting scheme. All seismic traces are shifted based on the theoretical traveltime of the scattered wave from specific gridpoints in a 3-D volume. Observed slowness and backazimuth are calculated for each raypath and compared with theoretical values in order to estimate slowness and backazimuth deviations. Subsequently, stacked energy calculated by a conventional migration method is weighted by the slowness and backazimuth deviations to suppress any arrival energy whose slowness and backazimuth are inconsistent with the expected theoretical values. This new method was applied to two P- wave data sets which comprise (1) underside reflections at the 410 and 660 km mantle discontinuities and (2) D" reflections as well as their corresponding synthetic data sets. The results show that the weighting scheme dramatically increases the resolution of the migrated images and enables us to obtain well-constrained, focused images, making upper-mantle discontinuities and D" reflections more distinct by reducing their surrounding energy.  相似文献   

New insights into the P- and S-wave velocity structure of the D" discontinuity beneath the Cocos plate     

Tadashi Kito  Sebastian Rost  Christine Thomas  Edward J. Garnero 《Geophysical Journal International》2007,169(2):631-645

Broad-band P - and S -waves from earthquakes in South America recorded at Californian network stations are analysed to image lateral variations of the D"-discontinuity beneath the Cocos plate. We apply two array processing methods to the data set: a simplified migration method to the P -wave data set and a double-array method to both the P - and S -wave data sets, allowing us to compare results from the two methods. The double-array method images a dipping reflector at a depth range from 2650 to 2700 km in the southern part of the study area. We observe a step-like topography of 100 km to a shallower reflector at about 2600 km depth to the north, as well as evidence for a second (deeper) reflector at a depth range from 2700 to 2750 km in the north. Results from the simplified migration agree well with those from the double-array method, similarly locating a large step in reflector depth in a similar location (about 2650 km depth in the south and about 2550 km in the north) as well as the additional deeper reflector at the depth of about 2750 km in the north. Waveform modelling of the reflected waves from both methods suggests a positive velocity contrast for S waves, but a negative velocity contrast for P waves for the upper reflector in agreement with predictions from mineral physical calculations for a post-perovskite phase transition. The data also show some evidence for the existence of another deeper reflector that could indicate a double intersection of the geotherm with the post-perovskite stability field, that is, the back-transformation of post-perovskite to perovskite close to the core–mantle boundary.  相似文献