Thermochemistry of jarosite-alunite and natrojarosite-natroalunite solid solutions     

Christophe Drouet  Dirk Baron  Alexandra Navrotsky 《Geochimica et cosmochimica acta》2004,68(10):2197-2205

The thermochemistry of jarosite-alunite and natrojarosite-natroalunite solid solutions was investigated. Members of these series were either coprecipitated or synthesized hydrothermally and were characterized by XRD, FTIR, electron microprobe analysis, ICP-MS, and thermal analysis. Partial alkali substitution and vacancies on the Fe/Al sites were observed in all cases, and the solids studied can be described by the general formula K_1-x-yNa_y(H₃O)_xFe_zAl_w(SO₄)₂(OH)_6-3(3-z-w)(H₂O)_3(3-z-w). A strong preferential incorporation of Fe over Al in the jarosite/alunite structure was observed. Heats of formation from the elements, ΔH°_f, were determined by high-temperature oxide melt solution calorimetry. The solid solutions deviate slightly from thermodynamic ideality by exhibiting positive enthalpies of mixing in the range 0 to +11 kJ/mol. The heats of formation of the end members of both solid solutions were derived. The values ΔH°_f = −3773.6 ± 9.4 kJ/mol, ΔH°_f = −4912.2 ± 24.2 kJ/mol, ΔH°_f = −3734.6 ± 9.7 kJ/mol and ΔH°_f = −4979.7 ± 7.5kJ/mol were found for K_0.85(H₃O)_0.15Fe_2.5(SO₄)₂(OH)_4.5(H₂O)_1.5, K_0.85(H₃O)_0.15Al_2.5(SO₄)₂(OH)_4.5(H₂O)_1.5, Na_0.7(H₃O)_0.3Fe_2.7(SO₄)₂(OH)_5.1(H₂O)_0.9, and Na_0.7(H₃O)_0.3Al_2.7(SO₄)₂(OH)_5.1(H₂O)_0.9 respectively. To our knowledge, this is the first experimentally-based report of ΔH°_f for such nonstoichiometric alunite and natroalunite samples. These thermodynamic data should prove helpful to study, under given conditions, the partitioning of Fe and Al between the solids and aqueous solution.  相似文献   

Oxygen isotope compositions of phosphate from arvicoline teeth and Quaternary climatic changes, Gigny, French Jura     

Nicolas Navarro  Christophe Lécuyer  Sophie Montuire  Cyril Langlois 《Quaternary Research》2004,62(2):172-182

Oxygen isotope compositions of biogenic phosphates from mammals are widely used as proxies of the isotopic compositions of meteoric waters that are roughly linearly related to the air temperature at high- and mid-latitudes. An oxygen isotope fractionation equation was determined by using present-day European arvicoline (rodents) tooth phosphate: δ¹⁸O_p = 20.98(±0.59) + 0.572(±0.065) δ¹⁸O_w. This fractionation equation was applied to the Late Pleistocene karstic sequence of Gigny, French Jura. Comparison between the oxygen isotope compositions of arvicoline tooth phosphate and Greenland ice core records suggests to reconsider the previously established hypothetical chronology of the sequence. According to the δ¹⁸O value of meteoric water-mean air temperature relationships, the δ¹⁸O value of arvicoline teeth records variations in mean air temperatures that range from 0° to 15°C.  相似文献   

Flow behaviour and runout modelling of a complex debris flow in a clay‐shale basin     

Alexandre Remaître  Jean‐Philippe Malet  Olivier Maquaire  Christophe Ancey  Jacques Locat 《地球表面变化过程与地形》2005,30(4):479-488

Identification of debris‐flow hazard areas necessitates the knowledge of the flow thickness and the runout distance. Both have been investigated using a numerical runout model. On the Faucon stream (South French Alps), representative of clay‐shale basins, results of various rheological tests and numerical experiments are presented and discussed. The calibration of the model was undertaken using the results of both geomorphological surveys and sedimentological analyses. Rheological tests using either a parallel‐plate rheometer, a coaxial rheometer, slump tests, and an inclined plane were carried out on several samples. Results have shown that the flow behaviour could be described by an Herschel‐Bulkley constitutive equation. The rheological responses of several natural suspensions collected from surficial deposits (sandstones, moraines, weathered black marls) were also investigated. In order to model the runout of the flow, the model BING was used. The model describes well the influence of each type of sediment on the behaviour (runout distance, deposit thickness) of the flow, although the velocities were significantly overestimated. Different risk scenarios are tested and discussed. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Frontal advance of turf-banked solifluction lobes, Kluane Range, Yukon Territory, Canada     

Christophe Kinnard  Antoni G. Lewkowicz 《Geomorphology》2006,73(3-4):261-276

Humus horizons associated with thirteen solifluction lobes on a single slope were radiocarbon dated at fixed distances behind the risers, as well as ahead of the lobes. The dated horizons, together with stratigraphic observations of planar discontinuities inside the lobes and shallow burial of vegetation ahead of the lobes, all suggest rapid advance of lobe fronts. We infer that lobe advance at this site results from slow accumulation of soliflucted material behind a relatively rigid riser, progressive steepening of the riser and build-up of stress, and finally rupture of the front and its collapse onto the slope. Rebuilding of the lobe usually then takes place. The time for a full cycle of development is estimated to be in the order of a few hundred years. Long-term frontal movement appears inversely related to lobe size, and is mainly controlled by soil moisture and sediment characteristics. These findings call into question the usefulness of solifluction lobe advance rates for paleoclimate reconstructions, at least at this site.  相似文献   

A climatic control on the accretion of meteoric and super-chondritic iridium–platinum to the Antarctic ice cap     

Paolo Gabrielli  John M.C. Plane  Claude F. Boutron  Sungmin Hong  Giulio Cozzi  Paolo Cescon  Christophe Ferrari  Paul J. Crutzen  Jean Robert Petit  Vladimir Y. Lipenkov  Carlo Barbante   《Earth and Planetary Science Letters》2006,250(3-4):459-469

Meteoric smoke particles (MSPs) form through the vaporization of meteoroids and the subsequent re-condensation of metallic species in the mesosphere. Recently, iridium and platinum enrichments have been identified in Greenland ice layers and attributed to the fallout of MSPs supplying polar latitudes with cosmic matter during the Holocene. However, the MSP fallout to Antarctica during the Earth's climatic history remains essentially unknown.

We have determined iridium and platinum in deep Antarctic ice from Dome C and Vostok dated back to 240 kyrs BP. We find high super-chondritic fluxes during warm periods and low meteoric accretion during glacial times, a pattern that is opposite to any known climatic variation in dust fallout to polar regions. The proposed explanation of this accretion regime is a weaker polar vortex during warm periods, allowing peripheral air masses enriched in volcanic iridium and platinum to penetrate inland to Antarctica. The MSP signal emerges only during cold phases and is four times lower than in the Greenland ice cap where more snow accumulates. This suggests that wet deposition is an important route of cosmic material to the Earth's surface.  相似文献   

Fluid inclusion and stable isotope (O, H, C, and S) constraints on the genesis of the Serrinha gold deposit, Gurupi Belt, northern Brazil   总被引：1，自引：0，他引：1  

Evandro L. Klein  Chris Harris  Christophe Renac  André Giret  Candido A. V. Moura  Kazuo Fuzikawa 《Mineralium Deposita》2006,41(2):160-178

The Serrinha gold deposit of the Gurupi Belt, northern Brazil, belongs to the class of orogenic gold deposits. The deposit is hosted in highly strained graphitic schist belonging to a Paleoproterozoic (∼2,160 Ma) metavolcano-sedimentary sequence. The ore-zones are up to 11 m thick, parallel to the regional NW–SE schistosity, and characterized by quartz-carbonate-sulfide veinlets and minor disseminations. Textural and structural data indicate that mineralization was syn- to late-tectonic and postmetamorphic. Fluid inclusion studies identified early CO₂ (CH₄-N₂) and CO₂ (CH₄-N₂)-H₂O-NaCl inclusions that show highly variable phase ratios, CO₂ homogenization, and total homogenization temperatures both to liquid and vapor, interpreted as the product of fluid immiscibility under fluctuating pressure conditions, more or less associated with postentrapment modifications. The ore-bearing fluid typically has 18–33mol% of CO₂, up to 4mol% of N₂, and less than 2mol% of CH₄ and displays moderate to high densities with salinity around 4.5wt% NaCl equiv. Mineralization occurred around 310 to 335°C and 1.3 to 3.0 kbar, based on fluid inclusion homogenization temperatures and oxygen isotope thermometry with estimated oxygen fugacity indicating relatively reduced conditions. Stable isotope data on quartz, carbonate, and fluid inclusions suggest that veins formed from fluids with δ¹⁸O_H2O and δD_H2O (310–335°C) values of +6.2 to +8.4‰ and −19 to −80‰, respectively, which might be metamorphic and/or magmatic and/or mantle-derived. The carbon isotope composition (δ¹³C) varies from −14.2 to −15.7‰ in carbonates; it is −17.6‰ in fluid inclusion CO₂ and −23.6‰ in graphite from the host rock. The δ³⁴S values of pyrite are −2.6 to −7.9‰. The strongly to moderately negative carbon isotope composition of the carbonates and inclusion fluid CO₂ reflects variable contribution of organic carbon to an originally heavier fluid (magmatic, metamorphic, or mantle-derived) at the site of deposition and sulfur isotopes indicate some oxidation of the originally reduced fluid. The deposition of gold is interpreted to have occurred mainly in response to phase separation and fluid-rock interactions such as CO₂ removal and desulfidation reactions that provoked variations in the fluid pH and redox conditions.  相似文献   

Comparison between tomographic structures and models of convection in the upper mantle   总被引：1，自引：0，他引：1  

Pierre Vacher  Antoine Mocquet  Christophe Sotin 《Geophysical Journal International》1996,124(1):45-56

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The aging of gypsum in underground mines   总被引：1，自引：0，他引：1  

Christophe Auvray  Franoise Homand  Claudia Sorgi 《Engineering Geology》2004,74(3-4):183-196

The aging properties of gypsum extracted from two underground mines in France (Livry–Gargan and Grozon) have been highlighted by means of observation performed using scanning electron microscopy on samples taken along horizontal boreholes drilled through to the middle of several pillars. The aging process is exhibited by the presence of traces of dissolution (edges of the dissolved crystals, corroded crystalline surfaces, important intra- and intercrystalline space). These dissolution figures decrease in number and in intensity from the wall heading towards the middle of the pillar. The “older” pillars display a greater number of dissolution traces than the “more recent” pillars. Then, the role of the aging has been assessed by determining various physical and mechanical parameters on cylindrical samples of 38 mm in diameter and 76 mm in height, machined from the set of drilled boreholes. The following parameters have been quantified: density, grains density, total porosity, porosity accessible to water, intrinsic permeability to nitrogen, velocity of ultrasonic compression and shear waves, dynamic Young's modulus, dynamic Poisson's ratio, uniaxial compressive strength and static Young's modulus. Significant variations in parameter values between the wall and the middle of the pillar were recorded and recognized as being strongly correlated with the intensity of dissolution traces, and hence with gypsum aging.  相似文献   

Variability of the ice export through Fram Strait in 1993–98: the winter 1994/95 anomaly     

Marie-Noëlle Houssais  Christophe Herbaut 《Polar research》2003,22(1):99-106

The origin of the large positive anomaly of the Fram Strait sea ice export which occurred in winter 1994/95 is analysed on the basis of a model simulation of the Arctic sea ice cover over the period 1993-98. The overall intra-annual and interannual variability in the model is in good agreement with observational estimates and the 1994/95 anomaly is well reproduced with an amplitude amounting to half of the mean winter value. Model results suggest that, concomitant to anomalous export velocities, larger than usual ice thickness in the strait contributes to the outstanding amplitude of the anomaly. Analysis on the ice thickness evolution in the strait indicates that the thick ice advected in Fram Strait at the end of the fall of 1994 originates in the anomalous cyclonic wind stress which prevailed during the preceding summer. This anomalous wind stress resulted in persistent convergence of the ice flow against the northern coasts of Canada and Greenland and in the formation of a large thickness anomaly north of Greenland. The anomaly then feeds the Fram Strait ice flow during those following winter months when the local wind forcing in the strait favours ice drift from the north-west. Our results suggest that short-term wind stress variations resulting in local thickness changes to the north of Fram Strait can lead to substantial variability of the Fram Strait ice export.  相似文献   

Traceurs sédimentaires des variations du niveau marin et de la mousson sud-est asiatique depuis 450 ka en mer de Chine du Sud     

Sbastien Boulay  Christophe Colin  Alain Trentesaux 《Comptes Rendus Geoscience》2008,340(6):367-378

In order to reconstruct the past variations of the Southeast Asian monsoon intensity and estimate the sedimentary system reactivity to climatic changes in Southeast Asia over the last 450 kyr, mineralogical and sedimentological analyses have been performed on the terrigenous fraction of the South China Sea sediment. End-member modelling coupled with grain size data discriminates three end-members that determine the nature and intensity of the main sediment transport vectors. Low sea-level stands are characterized by sediment reworking that allows transportation of a coarse end-member (20–40 μm) to the deep-basin. By contrast, the other end-members (4–6 μm; 9–13 μm) are controlled by the shoreline position (sea level) and/or by changes of the rivers capacity transport (monsoon). Finally, aeolian input to the northern margin of the South China Sea can be considered negligible compared to the massive fluvial input and the reworking of the sediments.  相似文献