A basalt-trachyte-phonolite series from Ua Pu,Marquesas Islands,Pacific Ocean     

Arthur Clive Bishop  Alan Robert Woolley 《Contributions to Mineralogy and Petrology》1973,39(4):309-326

The paper describes a suite of volcanic and intrusive rocks from Ua Pu, one of the Marquesas Islands, situated in the central Pacific Ocean. The rocks comprise alkali olivine basalts, hawaiites, mugearites, trachytes, and phonolites. Their petrographic characters are briefly described and 24 new chemical analyses presented. The rocks fall into a sodic and a potassic series, since some rocks are richer in K₂O than Na₂O, whilst the phonolites have exceptionally high total alkali contents.The differentiation of the series is discussed and special attention is paid to the phonolites in which icositetrahedral pseudomorphs occur. It is concluded that these pseudomorphs are probably after analcime rather than leucite.  相似文献   

Comment on “Trace-element crystal chemistry of mantle eclogites” by F.A. Caporuscio and J.R. Smyth     

Lawrence A. Taylor  Clive R. Neal 《Contributions to Mineralogy and Petrology》1993,113(2):280-284

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Plate tectonics and the fusion of Asia     

Clive F. Burrett 《Earth and Planetary Science Letters》1974,21(2):181-189

The coincidence of orogenic belts containing zones of high pressure metamorphism, ophiolites and deepwater sediments with faunal province boundaries leads to the postulation of several sutural zones within Asia. About nine blocks are defined and it is suggested on the basis of palaeogeographical, palaeontological and tectonic evidence that Asia did not fuse completely until well into the Mesozoic.  相似文献   

Size-Resolved Characterisation of Soluble Ions in the Particles in the Tropospheric Plume of Masaya Volcano, Nicaragua: Origins and Plume Processing   总被引：2，自引：0，他引：2  

T. A. Mather  A. G. Allen  C. Oppenheimer  D. M. Pyle  A. J. S. McGonigle 《Journal of Atmospheric Chemistry》2003,46(3):207-237

We present the first application of a multi-stage impactor to study volcanic particle emissions to the troposphere from Masaya volcano, Nicaragua. Concentrations of soluble SO₄ ^2–,Cl^–, F^–, NO₃ ^–, K⁺, Na⁺,NH₄ ⁺, Ca²⁺ and Mg²⁺ were determined in 11 size bins from 0.07 m to >25.5 m. The near-source size distributions showed major modes at 0.5m (SO₄ ^2–, H⁺,NH₄ ⁺); 0.2 m and 5.0 m (Cl^–) and 2.0–5.0 m(F^–). K⁺ and Na⁺ mirrored the SO₄ ^2– size-resolvedconcentrations closely, suggesting that these were transported primarily asK₂SO₄ and Na₂SO₄ in acidic solution, while Mg²⁺ andCa²⁺ presented modes in both <1 m and >1 m particles. Changes in relative humidity were studied by comparing daytime (transparent plume) and night-time (condensed plume) results. Enhanced particle growth rates were observed in the night-time plume as well as preferential scavenging of soluble gases, such as HCl, by condensed water. Neutralisation of the acidic aerosol by background ammonia was observed at the crater rim and to a greater extent approximately 15 km downwind of the active crater. We report measurements of re-suspended near-source volcanic dust, which may form a component of the plume downwind. Elevated levels ofSO₄ ^2–, Cl^–, F^–,H⁺, Na⁺, K⁺ and Mg²⁺ were observed around the 10 m particle diameter in this dust. The volcanic SO₄ ^2– flux leaving the craterwas 0.07 kg s^–1.  相似文献   

Automated,high time-resolution measurements of SO<Subscript>2</Subscript> flux at Soufrière Hills Volcano,Montserrat   总被引：2，自引：0，他引：2  

M.?EdmondsEmail author  R.?A.?Herd  B.?Galle  C.?M.?Oppenheimer 《Bulletin of Volcanology》2003,65(8):578-586

We report here the first results from an automated, telemetered UV scanning spectrometer system for monitoring SO ₂ emission rates at Soufrière Hills Volcano, Montserrat. Two spectrometers receive light by way of a motor-driven stepping prism and telescope in order to make vertical scans of the volcanic plume. Spectral data from these spectrometers, situated 2,800 m apart and 4,500 m from the volcano, are relayed back to the observatory every 4–5 s via radio modems. A full scan of the plume is accomplished every 1–6 min by the (time-synchronised) spectrometers and a SO ₂ emission rate is calculated using the SO ₂ slant concentrations, scan angles and plume speeds estimated from the wind speed from a telemetered weather station near to the volcano. The plume's position and dimensions are calculated using the angular data from the two spectrometers. The plume height varies significantly diurnally and seasonally and is important in order to minimise the error on SO ₂ emission rates. The new scanning system (Scanspec) provides SO ₂ emission rates from 08:00 to 16:00 h local time every day. Preliminary results highlight a number of features of the SO ₂ time series and plume dynamics and give our first indications of the errors and limits of detection of this system. SO ₂ emission rates vary widely on all time scales (minutes, days, months). This new system has already provided the first real and consistent indication that SO ₂ emission rates vary on a minutes to hours basis, which can be correlated with volcanic activity (for example, rockfall and pyroclastic flow activity). It is anticipated that this system at Soufrière Hills will yield information on shallow processes occurring on short time scales (periods of minutes to hours) as well as deep processes relating to magma supply rates, which will be associated with longer wavelength SO ₂ signals of weeks to months.  相似文献   

Velocities of compressional and shear waves in limestones   总被引：2，自引：1，他引：2  

Solomon Assefa  Clive McCann  Jeremy Sothcott 《Geophysical Prospecting》2003,51(1):1-13

Carbonate rocks are important hydrocarbon reservoir rocks with complex textures and petrophysical properties (porosity and permeability) mainly resulting from various diagenetic processes (compaction, dissolution, precipitation, cementation, etc.). These complexities make prediction of reservoir characteristics (e.g. porosity and permeability) from their seismic properties very difficult. To explore the relationship between the seismic, petrophysical and geological properties, ultrasonic compressional‐ and shear‐wave velocity measurements were made under a simulated in situ condition of pressure (50 MPa hydrostatic effective pressure) at frequencies of approximately 0.85 MHz and 0.7 MHz, respectively, using a pulse‐echo method. The measurements were made both in vacuum‐dry and fully saturated conditions in oolitic limestones of the Great Oolite Formation of southern England. Some of the rocks were fully saturated with oil. The acoustic measurements were supplemented by porosity and permeability measurements, petrological and pore geometry studies of resin‐impregnated polished thin sections, X‐ray diffraction analyses and scanning electron microscope studies to investigate submicroscopic textures and micropores. It is shown that the compressional‐ and shear‐wave velocities (V_p and V_s, respectively) decrease with increasing porosity and that V_p decreases approximately twice as fast as V_s. The systematic differences in pore structures (e.g. the aspect ratio) of the limestones produce large residuals in the velocity versus porosity relationship. It is demonstrated that the velocity versus porosity relationship can be improved by removing the pore‐structure‐dependent variations from the residuals. The introduction of water into the pore space decreases the shear moduli of the rocks by about 2 GPa, suggesting that there exists a fluid/matrix interaction at grain contacts, which reduces the rigidity. The predicted Biot–Gassmann velocity values are greater than the measured velocity values due to the rock–fluid interaction. This is not accounted for in the Biot–Gassmann velocity models and velocity dispersion due to a local flow mechanism. The velocities predicted by the Raymer and time‐average relationships overestimated the measured velocities even more than the Biot model.  相似文献   

The acoustic signature of fluid flow in complex porous media   总被引：2，自引：0，他引：2  

Morten Jakobsen  Tor Arne Johansen  Clive McCann   《Journal of Applied Geophysics》2003,54(3-4):219

Effective medium approximations for the frequency-dependent and complex-valued effective stiffness tensors of cracked/porous rocks with multiple solid constituents are developed on the basis of the T-matrix approach (based on integral equation methods for quasi-static composites), the elastic–viscoelastic correspondence principle, and a unified treatment of the local and global flow mechanisms, which is consistent with the principle of fluid mass conservation. The main advantage of using the T-matrix approach, rather than the first-order approach of Eshelby or the second-order approach of Hudson, is that it produces physically plausible results even when the volume concentrations of inclusions or cavities are no longer small. The new formulae, which operates with an arbitrary homogeneous (anisotropic) reference medium and contains terms of all order in the volume concentrations of solid particles and communicating cavities, take explicitly account of inclusion shape and spatial distribution independently. We show analytically that an expansion of the T-matrix formulae to first order in the volume concentration of cavities (in agreement with the dilute estimate of Eshelby) has the correct dependence on the properties of the saturating fluid, in the sense that it is consistent with the Brown–Korringa relation, when the frequency is sufficiently low. We present numerical results for the (anisotropic) effective viscoelastic properties of a cracked permeable medium with finite storage porosity, indicating that the complete T-matrix formulae (including the higher-order terms) are generally consistent with the Brown–Korringa relation, at least if we assume the spatial distribution of cavities to be the same for all cavity pairs. We have found an efficient way to treat statistical correlations in the shapes and orientations of the communicating cavities, and also obtained a reasonable match between theoretical predictions (based on a dual porosity model for quartz–clay mixtures, involving relatively flat clay-related pores and more rounded quartz-related pores) and laboratory results for the ultrasonic velocity and attenuation spectra of a suite of typical reservoir rocks.  相似文献   

Three-Dimensional Geopositioning Accuracy of Ikonos Imagery   总被引：3，自引：0，他引：3  

Clive Fraser  Harry Hanley  & Takeshi Yamakawa 《The Photogrammetric Record》2002,17(99):465-479

An investigation of the accuracy potential of Ikonos 1m satellite imagery is reported. Three sensor orientation/triangulation models are applied to stereo- and three-image configurations of "Geo" imagery with the aim of achieving 3D geopositioning to sub-metre accuracy. The models considered comprise rational functions with bias compensation, affine projection and the direct linear transformation. Test results from the Melbourne Ikonos Testfield are reported and these show that with modest provision of good quality ground control, Ikonos "Geo" imagery can yield 3D object-point determination to an accuracy of 0.5m in planimetry and 0.7m in height. The accuracy achieved is not only consistent with expectations for rigorous sensor orientation models, but is also readily attainable in practice with only a small number of ground control points being required  相似文献   

Modelling the seismic attributes of overpressured siliciclastic rocks, with a genetic annealing (GAN) algorithm     

Patricia Domnesteanu  Robert Domnesteanu  Clive McCann 《Geophysical Prospecting》2002,50(2):169-182

ABSTRACT A genetic annealing (GAN) algorithm is used to derive an empirical model which predicts compressional-wave velocity values for overpressured siliciclastic rocks. The algorithm involves non-linear random searching and mutation techniques and its annealing component imposes a very strict control over the rate of convergence of the search. This technique provides an alternative to the standard calculations involving the effective stress coefficient ( n ). The pore pressure is introduced into the model as an explicit variable and as part of an overpressure coefficient, ( P _p/ P _c) − the ratio of pore to confining pressure. Empirical model-derived data and known laboratory data are compared and their differences are shown to be within statistically acceptable error limits. The empirical equation fits all under- and overpressured data simultaneously, irrespective of pore fluid pressure level, with the same parameters. It is used to predict seismic velocities very accurately for extreme levels of overpressure, starting from normally pressured experimental data. The model highlights the effect of pore pressure on the compressional-wave velocity of fully saturated samples with different clay contents. It can be used when the experimental data available are sparse and particularly when a prediction of material behaviour is necessary at specific pore fluid pressure and depth conditions.  相似文献   

The influence of sampling design on spatial data quality in a geographic citizen science project     

Greg Brown  Jonathan Rhodes  Daniel Lunney  Ross Goldingay  Kelly Fielding  Nicole Garofano  Scott Hetherington  Marama Hopkins  Jo Green  Skye McNamara  Angie Brace  Lorraine Vass  Linda Swankie  Clive McAlpine 《Transactions in GIS》2019,23(6):1184-1203

Geographic citizen science has much potential to assist in wildlife research and conservation, but the quality of observation data is a key concern. We examined the effects of sampling design on the quality of spatial data collected for a koala citizen science project in Australia. Data were collected from three samples—volunteers (n = 454), an Internet panel (n = 103), and landowners (n = 35)—to assess spatial data quality, a dimension of citizen science projects rarely considered. The locational accuracy of koala observations among the samples was similar when benchmarked against authoritative data (i.e., an expert‐derived koala distribution model), but there were differences in the quantity of data generated. Fewer koala location data were generated per participant by the Internet panel sample than the volunteer or landowner samples. Spatial preferences for land uses affecting koala conservation were also mapped, with landowners more likely to map locations for residential and tourism development and volunteers less likely. These spatial preferences have the potential to influence the social acceptability of future koala conservation proposals. With careful sampling design, both citizen observations and land use preferences can be included within the same project to augment scientific assessments and identify conservation opportunities and constraints.  相似文献