The origin of young mare basalts inferred from lunar meteorites Northwest Africa 4734, 032, and LaPaz Icefield 02205     

Stephen M. Elardo  Charles K. Shearer Jr.  Amy L. Fagan  Lars E. Borg  Amy M. Gaffney  Paul V. Burger  Clive R. Neal  Vera A. Fernandes  Francis M. McCubbin 《Meteoritics & planetary science》2014,49(2):261-291

Northwest Africa (NWA) 4734 is an unbrecciated basaltic lunar meteorite that is nearly identical in chemical composition to basaltic lunar meteorites NWA 032 and LaPaz Icefield (LAP) 02205. We have conducted a geochemical, petrologic, mineralogic, and Sm‐Nd, Rb‐Sr, and Ar‐Ar isotopic study of these meteorites to constrain their petrologic relationships and the origin of young mare basalts. NWA 4734 is a low‐Ti mare basalt with a low Mg* (36.5) and elevated abundances of incompatible trace elements (e.g., 2.00 ppm Th). The Sm‐Nd isotope system dates NWA 4734 with an isochron age of 3024 ± 27 Ma, an initial ε_Nd of +0.88 ± 0.20, and a source region ¹⁴⁷Sm/¹⁴⁴Nd of 0.201 ± 0.001. The crystallization age of NWA 4734 is concordant with those of LAP 02205 and NWA 032. NWA 4734 and LAP 02205 have very similar bulk compositions, mineral compositions, textures, and ages. Their source region ¹⁴⁷Sm/¹⁴⁴Nd values indicate that they are derived from similar, but distinct, source materials. They probably do not sample the same lava flow, but rather are similarly sourced, but isotopically distinct, lavas that probably originate from the same volcanic complex. They may have experienced slightly different assimilation histories in route to eruption, but can be source‐crater paired. NWA 032 remains enigmatic, as its source region ¹⁴⁷Sm/¹⁴⁴Nd definitively precludes a simple relationship with NWA 4734 and LAP 02205, despite a similar bulk composition. Their high Ti/Sm, low (La/Yb)_N, and Cl‐poor apatite compositions rule out the direct involvement of KREEP. Rather, they are consistent with low‐degree partial melting of late‐formed LMO cumulates, and indicate that the geochemical characteristics attributed to urKREEP are not unique to that reservoir. These and other basaltic meteorites indicate that the youngest mare basalts originate from multiple sources, and suggest that KREEP is not a prerequisite for the most recent known melting in the Moon.  相似文献   

UD-SV: Urban data services and visualization framework for sharing multidisciplinary research     

John Samuel  Vincent Jaillot  Clément Colin  Diego Vinasco Alvarez  Eric Boix  Sylvie Servigne  Gilles Gesquière 《Transactions in GIS》2023,27(3):841-858

With the widespread availability of a large volume of urban data, stakeholders from different domains require advanced tools to manage, visualize and understand cities and their evolution. During the last few years, researchers have proposed numerous research works and applications to illustrate the cities of the past and possible scenarios of the future under different conditions. However, many of these approaches are one-time solutions and not based on standards, making them obsolete and unusable for reproducible research. In this article, we present UD-SV: an Urban data-Services and Visualization open-source framework for multidisciplinary research to handle complex processing, analysis, and visualization of urban data. However, our goal is not to present a one-time monolithic software solution for urban data management and analysis, but we demonstrate the design and development of an open and interoperable software framework driven by use cases from diverse users to solve applied research challenges. The main contribution of UD-SV is that it uses open standards and open data with documented and reproducible processes with a particular emphasis on the reuse of existing open-source software components. We also show an enhanced use of standards to enable a shift toward components that are interchangeable or composable with other existing components in the GIS community.  相似文献   

Timescales of mixing and mobilisation in the Bishop Tuff magma body: perspectives from diffusion chronometry     

Katy?J.?ChamberlainEmail author  Daniel?J.?Morgan  Colin?J.?N.?Wilson 《Contributions to Mineralogy and Petrology》2014,168(1):1034

We present two-feldspar thermometry and diffusion chronometry from sanidine, orthopyroxene and quartz from multiple samples of the Bishop Tuff, California, to constrain the temperature stratification within the pre-eruptive magma body and the timescales of magma mixing prior to its evacuation. Two-feldspar thermometry yields estimates that agree well with previous Fe–Ti oxide thermometry and gives a ~80 °C temperature difference between the earlier- and later-erupted regions of the magma chamber. Using the thermometry results, we model diffusion of Ti in quartz, and Ba and Sr in sanidine as well as Fe–Mg interdiffusion in orthopyroxene to yield timescales for the formation of overgrowth rims on these crystal phases. Diffusion profiles of Ti in quartz and Fe–Mg in orthopyroxene both yield timescales of <150 years for the formation of overgrowth rims. In contrast, both Ba and Sr diffusion in sanidine yield nominal timescales 1–2 orders of magnitude longer than these two methods. The main cause for this discrepancy is inferred to be an incorrect assumption for the initial profile shape for Ba and Sr diffusion modelling (i.e. growth zoning exists). Utilising the divergent diffusion behaviour of Ba and Sr, we place constraints on the initial width of the interface and can refine our initial conditions considerably, bringing Ba and Sr data into alignment, and yielding timescales closer to 500 years, the majority of which are then within uncertainty of timescales modelled from Ti diffusion in quartz. Care must be thus taken when using Ba in sanidine geospeedometry in evolved magmatic systems where no other phases or elements are available for comparative diffusion profiling. Our diffusion modelling reveals piecemeal rejuvenation of the lower parts of the Bishop Tuff magma chamber at least 500 years prior to eruption. Timescales from our mineral profiling imply either that diffusion coefficients currently used are uncertain by 1–2 orders of magnitude, or that the minerals concerned did not experience a common history, despite being extracted from the same single pumice clasts. Introduction of the magma initiating crystallisation of the contrasting rims on sanidine, quartz, orthopyroxene and zircon was prolonged, and may be a marker of other processes that initiated the Bishop Tuff eruption rather than the trigger itself.  相似文献   

Corrosion of metal roof materials related to volcanic ash interactions     

Christopher Oze  Jim Cole  Allan Scott  Thomas Wilson  Grant Wilson  Sally Gaw  Samuel Hampton  Colin Doyle  Zhengwei Li 《Natural Hazards》2014,71(1):785-802

Metal roofing material is commonly used for residential and industrial roofs in volcanically active areas. Increased corrosion of metal roofing from chemically reactive volcanic ash following ash deposition post-eruption is a major concern due to decreasing the function and stability of roofs. Currently, assessment of ash-induced corrosion is anecdotal, and quantitative data are lacking. Here, we systematically evaluate the corrosive effects of volcanic ash, specifically ash leachates, on a variety of metal roofing materials (i.e. weathered steel, zinc, galvanized steel, and Colorsteel©) utilizing weathering chamber experiments and direct acid treatments. Weathering chamber tests were carried out for up to 30 days, and visual, chemical, and surface analyses did not definitively identify significant corrosion in any of the test roofing metal samples. Direct concentrated acid treatments with hydrochloric (HCl), sulphuric (H₂SO₄), and hydrofluoric (HF) acids demonstrate that roofing materials are chemically resilient. Our experimental results suggest that ash-leachate-related corrosion is a longer-term process (>1 month), potentially related to a multitude of factors including increased ash leachate concentrations, the dissolution of the glass matrix of the ash, moisture retention at the ash-surface boundary, and potential reactions involving photo-oxidation. Overall, corrosion is not a simple process related to the short-term release of acid and/or salt leachates from the ash surface, but a product of dynamic interactions involving ash and water at the surface of metal roofing material for extended periods.  相似文献   

The effects of biological fouling control at coastal and estuarine power stations   总被引：3，自引：0，他引：3  

Taylor CJ 《Marine pollution bulletin》2006,53(1-4):30-48

The use of low levels of oxidants as antifouling agents in coastal and estuarine power station cooling water circuits can give rise to concerns over the likely production of chlorination byproducts (CBPs) including organohalogens, of largely cryptic identity, loading and impact. In order to review the current understanding of the degree of impact involved this paper describes a recent collaborative programme of work on CBPs within the wider context of a number of allied studies on power station cooling water entrainment and discharge effects. Bromoform was the single most important CBP found in coastal power station effluents. Although bromoform was found to accumulate in the liver of the sea bass Dicentrarchus labrax (L.) continuously exposed to a chlorinated effluent stream, no otherwise untoward impact on continuously exposed individuals was discerned. Populations of the common blue mussel Mytilus edulis L., likewise exposed, exhibited two responses: a high degree of genoplasticity and the evolution of stress proteins--although both may have been due to thermal rather than toxic stress. Experiments on plankton that simulated the conditions of entrainment within cooling water systems isolated the influence of oxidant usage, with mortality varying between taxa and life stage. The results suggest a very limited impact of oxidant use and the associated CBPs on receiving waters both in terms of plume toxicity or any more widespread ecotoxicological influence. Instead, it is in combination with applied temperature (DeltaT), pressure and the other stressors involved in entrainment within the power station cooling water circuits themselves that an impact is most marked.  相似文献   

A cascade of magmatic events during the assembly and eruption of a super-sized magma body     

Aidan.?S.?R.?Allan  Simon?J.?Barker  Marc-Alban?Millet  Daniel?J.?Morgan  Shane?M.?Rooyakkers  C.?Ian?Schipper  Colin?J.?N.?WilsonEmail authorView author&#;s OrcID profile 《Contributions to Mineralogy and Petrology》2017,172(7):49

We use comprehensive geochemical and petrological records from whole-rock samples, crystals, matrix glasses and melt inclusions to derive an integrated picture of the generation, accumulation and evacuation of 530 km³ of crystal-poor rhyolite in the 25.4 ka Oruanui supereruption (New Zealand). New data from plagioclase, orthopyroxene, amphibole, quartz, Fe–Ti oxides, matrix glasses, and plagioclase- and quartz-hosted melt inclusions, in samples spanning different phases of the eruption, are integrated with existing data to build a history of the magma system prior to and during eruption. A thermally and compositionally zoned, parental crystal-rich (mush) body was developed during two periods of intensive crystallisation, 70 and 10–15 kyr before the eruption. The mush top was quartz-bearing and as shallow as ~3.5 km deep, and the roots quartz-free and extending to >10 km depth. Less than 600 year prior to the eruption, extraction of large volumes of ~840 °C low-silica rhyolite melt with some crystal cargo (between 1 and 10%), began from this mush to form a melt-dominant (eruptible) body that eventually extended from 3.5 to 6 km depth. Crystals from all levels of the mush were entrained into the eruptible magma, as seen in mineral zonation and amphibole model pressures. Rapid translation of crystals from the mush to the eruptible magma is reflected in textural and compositional diversity in crystal cores and melt inclusion compositions, versus uniformity in the outermost rims. Prior to eruption the assembled eruptible magma body was not thermally or compositionally zoned and at temperatures of ~790 °C, reflecting rapid cooling from the ~840 °C low-silica rhyolite feedstock magma. A subordinate but significant volume (3–5 km³) of contrasting tholeiitic and calc-alkaline mafic material was co-erupted with the dominant rhyolite. These mafic clasts host crystals with compositions which demonstrate that there was some limited pre-eruptive physical interaction of mafic magmas with the mush and melt-dominant body. However, the mafic magmas do not appear to have triggered the eruption or controlled magmatic temperatures in the erupted rhyolite. Integration of textural and compositional data from all available crystal types, across all dominant and subordinate magmatic components, allow the history of the Oruanui magma body to be reconstructed over a wide range of temporal scales using multiple techniques. This history spans the tens of millennia required to grow the parental magma system (U–Th disequilibrium dating in zircon), through the centuries and decades required to assemble the eruptible magma body (textural and diffusion modelling in orthopyroxene), to the months, days, hours and minutes over which individual phases of the eruption occurred, identified through field observations tied to diffusion modelling in magnetite, olivine, quartz and feldspar. Tectonic processes, rather than any inherent characteristics of the magmatic system, were a principal factor acting to drive the rapid accumulation of magma and control its release episodically during the eruption. This work highlights the richness of information that can be gained by integrating multiple lines of petrologic evidence into a holistic timeline of field-verifiable processes.  相似文献   

Nonnative Species in British Columbia Eelgrass Beds Spread via Shellfish Aquaculture and Stay for the Mild Climate     

Megan E. Mach  Colin D. Levings  Kai M. A. Chan 《Estuaries and Coasts》2017,40(1):187-199

Nonnative species cause economic and ecological impacts in habitats they invade, but there is little information on how they spread and become abundant. This is especially true for nonnative species in native Zostera marina eelgrass beds in coastal British Columbia, Canada, which play a vital role in estuarine ecosystems. We tested how nonnative species richness and abundance were related to both arrival vectors and environmental factors in northeast Pacific eelgrass. Using correlation tests and generalized linear models, we examined how nonnative macroinvertebrates (benthic, epifaunal, and large mobile) and some algae species were related to arrival vectors (shipping and aquaculture) and environmental factors (climate variables, human population density, and native richness and abundance). We found 12 nonnative species, 50 % with known negative impacts within eelgrass habitats. For benthic organisms, both nonnative richness and abundance were strongly correlated with shellfish aquaculture activities, and not with shipping activity. For epifaunal nonnative richness and abundance, neither vector was significantly correlated. Climate (temperature and salinity) helped explain nonnative richness but not abundance; there was no relationship of nonnative richness or abundance to native species richness and abundance or population density. Results suggest that aquaculture activities are responsible for many primary introductions of benthic nonnative species, and that temperature and salinity tolerances are responsible for post-introduction invasion success. While aquaculture and shipping vectors are becoming increasingly regulated to prevent further international spread of nonnative species, it will be important when managing nonnatives to consider secondary spread from intraregional transport through local shellfish aquaculture and shipping.  相似文献   

A dating intercomparison study on Late Stone Age coastal midden deposits,South Africa     

Mark D. Bateman  Andrew S. Carr  Colin V. Murray‐Wallace  David L. Roberts  Peter J. Holmes 《Geoarchaeology》2008,23(6):715-741

The southern and western coastlines of South Africa have an extensive archaeological record with many sites associated with widespread eolian deposits. While much of this rich archaeological record is based on cave sites, evidence of Late Stone Age occupation is additionally preserved in the form of open‐site shell middens. We present here a comparative study of the application of amino acid racemization (AAR), optically stimulated luminescence (OSL), and radiocarbon analyses to three Late Stone Age (LSA) midden sites found within dunes on the southern coastline of South Africa. Preliminary geochronological analyses suggest that middens offer opportunity to fill in gaps in what is still a fragmentary archaeological record. Results show OSL and radiocarbon ages in good agreement, illustrating the potential to date not only the middens but also the surrounding dunes that constituted the dwelling sites. AAR results show increasing ratios with age and also that the application of paired shell and “whole rock” AAR can provide insights into the degree of biogenic sediment recycling at buried midden sites. However, the work also highlights that caution is required when OSL sampling sediment associated with middens which may have undergone human disturbance and that further work is required to improve the regional marine reservoir correction for radiocarbon dating in this part of South Africa. The study also illustrates that AAR will only provide useful data provided that middens have been sufficiently deeply buried to overcome fluctuations in environmental variables that affect the racemization rate and that inter‐genus comparisons should be avoided. © 2008 Wiley Periodicals, Inc.  相似文献   

Use of archaeology to date liquefaction features and seismic events in the New Madrid seismic zone,Central United States     

Martitia P. Tuttle  Robert H. Lafferty  Margaret J. Guccione  Eugene S. Schweig  Neal Lopinot  Robert F. Cande  Kathleen Dyer-Williams  Marion Haynes 《Geoarchaeology》1996,11(6):451-480

Prehistoric earthquake-induced liquefaction features occur in association with Native American occupation horizons in the New Madrid seismic zone. Age control of these liquefaction features, including sand-blow deposits, sand-blow craters, and sand dikes, can be accomplished by extensive sampling and flotation processing of datable materials as well as archaeobotanical analysis of associated archaeological horizons and pits. This approach increases both the amount of carbon for radiocarbon dating and the precision dating of artifact assemblages. Using this approach, we dated liquefaction features at four sites northwest of Blytheville, Arkansas, and found that at least one significant earthquake occurred in the New Madrid seismic zone between A.D. 1180 and 1400, probably about A.D. 1300 ± 100 yr. In addition, we found three buried sand blows that formed between 3340 B.C. and A.D. 780. In this region where very large to great earthquakes appear to be closely timed, archaeology is helping to develop a paleoearthquake chronology for the New Madrid seismic zone. © 1996 John Wiley & Sons, Inc.  相似文献