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21.
Large pyroclastic rhyolites are snapshots of evolving magma bodies, and preserved in their eruptive pyroclasts is a record of evolution up to the time of eruption. Here we focus on the conditions and processes in the Oruanui magma that erupted at 26.5 ka from Taupo Volcano, New Zealand. The 530 km3 (void-free) of material erupted in the Oruanui event is comparable in size to the Bishop Tuff in California, but differs in that rhyolitic pumice and glass compositions, although variable, did not change systematically with eruption order. We measured the concentrations of H2O, CO2 and major and trace elements in zoned phenocrysts and melt inclusions from individual pumice clasts covering the range from early to late erupted units. We also used cathodoluminescence imaging to infer growth histories of quartz phenocrysts. For quartz-hosted inclusions, we studied both fully enclosed melt inclusions and reentrants (connecting to host melt through a small opening). The textures and compositions of inclusions and phenocrysts reflect complex pre-eruptive processes of incomplete assimilation/partial melting, crystallization differentiation, magma mixing and gas saturation. ‘Restitic’ quartz occurs in seven of eight pumice clasts studied. Variations in dissolved H2O and CO2 in quartz-hosted melt inclusions reflect gas saturation in the Oruanui magma and crystallization depths of ∼3.5–7 km. Based on variations of dissolved H2O and CO2 in reentrants, the amount of exsolved gas at the beginning of eruption increased with depth, corresponding to decreasing density with depth. Pre-eruptive mixing of magma with varying gas content implies variations in magma bulk density that would have driven convective mixing. Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorized users.  相似文献   
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A stochastic channel embedded in a background facies is conditioned to data observed at wells. The background facies is a fixed rectangular box. The model parameters consist of geometric parameters that describe the shape, size, and location of the channel, and permeability and porosity in the channel and nonchannel facies. We extend methodology previously developed to condition a stochastic channel to well-test pressure data, and well observations of the channel thickness and the depth of the top of the channel. The main objective of this work is to characterize the reduction in uncertainty in channel model parameters and predicted reservoir performance that can be achieved by conditioning to well-test pressure data at one or more wells. Multiple conditional realizations of the geometric parameters and rock properties are generated to evaluate the uncertainty in model parameters. The ensemble of predictions of reservoir performance generated from the suite of realizations provides a Monte Carlo estimate of the uncertainty in future performance predictions. In addition, we provide some insight on how prior variances, data measurement errors, and sensitivity coefficients interact to determine the reduction in model parameters obtained by conditioning to pressure data and examine the value of active and observation well data in resolving model parameters.  相似文献   
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The southern Andes plate boundary zone records a protracted history of bulk transpressional deformation during the Cenozoic, which has been causally related to either oblique subduction or ridge collision. However, few structural and chronological studies of regional deformation are available to support one hypothesis or the other. We address along- and across-strike variations in the nature and timing of plate boundary deformation to better understand the Cenozoic tectonics of the southern Andes.Two east–west structural transects were mapped at Puyuhuapi and Aysén, immediately north of the Nazca–South America–Antarctica triple junction. At Puyuhuapi (44°S), north–south striking, high-angle contractional and strike-slip ductile shear zones developed from plutons coexist with moderately dipping dextral-oblique shear zones in the wallrocks. In Aysén (45–46°), top to the southwest, oblique thrusting predominates to the west of the Cenozoic magmatic arc, whereas dextral strike-slip shear zones develop within it.New 40Ar–39Ar data from mylonites and undeformed rocks from the two transects suggest that dextral strike-slip, oblique-slip and contractional deformation occurred at nearly the same time but within different structural domains along and across the orogen. Similar ages were obtained on both high strain pelitic schists with dextral strike-slip kinematics (4.4±0.3 Ma, laser on muscovite–biotite aggregates, Aysén transect, 45°S) and on mylonitic plutonic rocks with contractional deformation (3.8±0.2 to 4.2±0.2 Ma, fine-grained, recrystallized biotite, Puyuhuapi transect). Oblique-slip, dextral reverse kinematics of uncertain age is documented at the Canal Costa shear zone (45°S) and at the Queulat shear zone at 44°S. Published dates for the undeformed protholiths suggest both shear zones are likely Late Miocene or Pliocene, coeval with contractional and strike-slip shear zones farther north. Coeval strike-slip, oblique-slip and contractional deformation on ductile shear zones of the southern Andes suggest different degrees of along- and across-strike deformation partitioning of bulk transpressional deformation.The long-term dextral transpressional regime appears to be driven by oblique subduction. The short-term deformation is in turn controlled by ridge collision from 6 Ma to present day. This is indicated by most deformation ages and by a southward increase in the contractional component of deformation. Oblique-slip to contractional shear zones at both western and eastern margins of the Miocene belt of the Patagonian batholith define a large-scale pop-up structure by which deeper levels of the crust have been differentially exhumed since the Pliocene at a rate in excess of 1.7 mm/year.  相似文献   
24.
To validate a resuspension model of particulate material (salmonid farm wastes), a UV fluorescent particle tracer was selected with similar settling characteristics. Tracer was introduced to the seabed (water depth ≈30 m) and sediment samples taken on days 0, 3, 10, 17 and 30 to measure the horizontal and vertical distribution of tracer in sediments. A concentric sampling grid was established at radii of 25, 50, 100, 150, 200, 400, 700 and 1, 000 m from the source on transects 30° apart. The bulk of the deployed tracer was initially concentrated in an area 25 m radius from the release point; tracer was observed to steadily decrease to zero over a period of 30 days. In a 200 m region measured from the release point in the direction of the residual current, the redeposition of tracer was low. A Lagrangian particle tracking model was validated using these observed data by varying resuspension model parameters within limits to obtain the best agreement between spatial and temporal distributions. The validated model generally gave good predictions of total mass budgets (±7% of total tracer released), particulary where tracer concentrations were high near the release point. Best fit model parameters (critical erosion shear stress=0.018 N m−2, erodibility constan=60 g m−2 d−1) are at the low end of reported parameters for coastal resuspension models. Such a low critical erosion shear stress indicates that the frequency of resuspension and deposition events for freshly deposited material is high.  相似文献   
25.
Eco-epidemiology: On the Need to Measure Health Effects from Global Change   总被引:1,自引:0,他引:1  
To prevent harm to human health from degrading ecosystems, epidemiologists need useful indicators that are sensitive to those shifts in health status that might parallel these declines. Traditional measures of health (e.g., life expectancy, infant mortality) are intuitively linkable to effects from environmental degradation but, in fact, they do not appear to provide early warning indications of negative ecological impacts on health. Alternative health measures, such as social well-being, may be needed for epidemiological research. New measures must combine those factors having policy relevance, including sensitive measures of well-being and of health, with models of those human behaviours that contribute to ecological declines. Exposure factors (e.g., pollution) made worse by ecosystem changes (e.g., global warming) also are relevant. In addition, epidemiologists must be able to relate health outcomes not only to the traditional base of geo-political boundaries (e.g., census tracts or countries), but more appropriately to eco-regions (e.g., climate regions). Only then could direct comparisons of effect be made between areas that have eco-region as the common base for defining both denominators and numerator events for rate calculations and comparisons. In conclusion, administrative infrastructure is needed so that meaningful eco-epidemiology can be conducted. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
26.
This study examines the spatial and temporal variability of chemical denudation rates in Kärkevagge, northern Sweden. The chemical flux rates within the valley are strongly influenced by the local geology. Chemical denudation rates determined for the study period are more than double those previously reported in the literature for this valley. Rates of greater than 46t km−2 a−1 were measured at the valley mouth over the course of the melt season. This difference is likely due to differences in measurement technique compared to that used by past researchers. This rate is also much higher than for other arctic and alpine watersheds. Chemical denudation in Kärkevagge is comparable to larger temperate rivers. The rapid chemical denudation in Kärkevagge is likely due to sulfide weathering creating acid solutions.  相似文献   
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The second marvel to catch the eye of the visitor to Kärkevagge, after the impressive boulder deposit on the floor of the valley, is the series of prominent white stripes running down the valley's dark cliffs. Streams and springs descending the eastern flank of Kärkevagge are marked by the presence of whitish coatings on the black rock surfaces and on cobbles lining ephemeral waterways. These were referred to as 'lime crusts' by early investigators, but they are not reactive to HCl. We believe that they are a precipitate resulting from acid attack on the local rocks. Pyrite is common in many of the rocks in the valley and its oxidation produces sulfuric acid. As the dissolved mineral elements are carried in the drainage water, efflorescence forms on the surfaces where the water flows due to evaporation or to changes in temperature. The exact mineralogy of the white crusts is unknown, but the crusts are dominated by Al, S, and O, and in some cases by Ca, depending on the substrate and local conditions. Gypsum, illite, and chlorite have been identified by X–ray diffraction of some scrapings of white–coated rocks. However, we believe that some unidentified oxy–hydroxy aluminum sulfates make up the bulk of the precipitates.  相似文献   
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