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Several laboratory studies have recently demonstrated the utility of geophysical methods for the investigation of microbial-induced changes over contaminated sites. However, it remains difficult to distinguish the effects due to the new physical properties imparted by microbial processes, to bacterial growth, or to the development of bacterial biofilm. We chose to study the influence of biofilm formation on geophysical response using complex conductivity measurements (0.1-1000 Hz) in phenanthrene-contaminated media. Biotic assays were conducted with two phenanthrene (PHE) degrading bacterial strains: Burkholderia sp (NAH1), which produced biofilm and Stenophomonas maltophilia (MATE10), which did not, and an abiotic control. Results showed that bacterial densities for NAH1 and MATE10 strains continuously increased at the same rate during the experiment. However, the complex conductivity signature showed noticeable differences between the two bacteria, with a phase shift of 50 mrad at 4 Hz for NAH1, which produced biofilm. Biofilm volume was quantified by Scanning Confocal Laser Microscopy (SCLM). Significant correlations were established between phase shift decrease and biofilm volume for NAH1 assays. Results suggest that complex conductivity measurements, specifically phase shift, can be a useful indicator of biofilm formation inside the overall signal of microbial activity on contaminated sites.  相似文献   
53.
The inorganic manufactured nanoparticles as TiO2, Ag°, the iron oxides and CeO2 are more and more present in various manufactured products and in the aqueous media (TiO2). Their dispersion in the ecosystems during their life cycle will be associated with interactions with biota (plants, bacteria, fishes). The present work shows strong relations between particular physical chemical properties of very small nanoparticles (size < 30 nm) and biological activity perturbations. It is shown that Ag° and CeO2 act at very low concentrations. TiO2 act via the ROS production due to their photo-reactivity.  相似文献   
54.
This overview features the chemical background on condensation phenomena of the aluminum cation in aqueous solution. The formation of polycationic molecular clusters and nanosized solid phases of aluminum oxy(hydroxi)des is interpreted with illustrative mechanisms, building a bridge between solution chemistry and solid-state chemistry. The formation of the main structural types of aluminosilicates (zeolites, clays, imogolite) is also illustrated through the aqueous chemistry of aluminum and silicates.  相似文献   
55.
We present a Raman spectroscopic study of the structural modifications of several olivines at high pressures and ambient temperature. At high pressures, the following modifications in the Raman spectra are observed: 1)?in Mn2GeO4, between 6.7 and 8.6?GPa the appearance of weak bands at 560 and 860?cm?1; between 10.6 and 23?GPa, the progressive replacement of the olivine spectrum by the spectrum of a crystalline high pressure phase; upon decompression, the inverse sequence of transformations is observed with some hysteresis in the transformation pressures; this sequence may be interpreted as the progressive transformation of the olivine to a spinelloid where Ge tetrahedra are polymerized, and then to a partially inverse spinel; 2)?in Ca2SiO4, the olivine transforms to larnite between 1.9 and 2.1?GPa; larnite is observed up to the maximum pressure of 24?GPa and it can partially back-transform to olivine during decompression; 3)?in Ca2GeO4, the olivine transforms to a new structure between 6.8 and 8?GPa; the vibrational frequencies of the new phase suggest that the phase transition involves an increase of the Ca coordination number and that Ge tetrahedra are isolated; this high pressure phase is observed up to the maximum pressure of 11?GPa; during decompression, it transforms to a disordered phase below 5?GPa; 4)?in CaMgGeO4, no significant modification of the olivine spectrum is observed up to 15?GPa; between 16 and 26?GPa, broadening of some peaks and the appearance of a weak broad feature at 700–900?cm?1 suggests a progressive amorphization of the structure; near 27?GPa, amorphization is complete and an amorphous phase is quenched down to ambient pressure; this unique behaviour is interpreted as the result of the incompatibilities in the high pressure behaviour of the Ca and Mg sublattices in the olivine structure.  相似文献   
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At Amphitrite Point, ozone (O3) mixing ratios are observed to drop steadily to 5–15?ppb over a period of 12 hours or less with a frequency approaching one event per week (with highest frequencies occurring in summer and fall). Analysis of 47 such O3 depletion events reveals that low O3 episodes are a predominantly nocturnal phenomenon associated with anticyclonic conditions characterized by light onshore or alongshore winds and an absence of fog and mist. Back-trajectories show air carried to the Amphitrite Point Observatory (APO) during depletion events remains in the marine boundary layer and is not brought to the surface from aloft. There is no strong correlation with other “criteria” pollutants (CO, NOx, SO2, PM2.5) that might be indicative of a mechanism for O3 destruction linked to human, terrestrial, or marine pollutant sources. However, CO2 mixing ratios are observed to increase, coincident with O3 depletion. Together, these results point to a natural marine boundary layer phenomenon in which O3 destruction dominates O3 production and/or replenishment by vertical mixing. While there are several candidate mechanisms, the conditions for O3 depletion (and CO2 buildup) to occur are set by meteorology and, in particular, development of a stable marine boundary layer in which vertical mixing is suppressed. Support for this interpretation is provided by simultaneous increases in CO2 in the stable marine boundary that are indicative of an important role played by marine biogenic processes (respiration). Future research should be directed at elucidating the chemical mechanisms responsible for O3 destruction in the coastal zone, which means that there would be a need for a much broader range of measurements at APO (including halogenated species) as well as offshore measurements of both chemical and marine boundary layer meteorological variables.  相似文献   
58.
Northwest Africa (NWA) 6583 is a silicate‐bearing iron meteorite with Ni = 18 wt%. The oxygen isotope composition of the silicates (?′17O = ?0.439 ‰) indicates a genetic link with the IAB‐complex. Other chemical, mineralogical, and textural features of NWA 6583 are consistent with classification as a new member of the IAB‐complex. However, some unique features, e.g., the low Au content (1.13 μg g?1) and the extremely reducing conditions of formation (approximately ?3.5 ?IW), distinguish NWA 6583 from the known IAB‐complex irons and extend the properties of this group of meteorites. The chemical and textural features of NWA 6583 can be ascribed to a genesis by impact melting on a parent body of chondritic composition. This model is also consistent with one of the most recent models for the genesis of the IAB‐complex. Northwest Africa 6583 provides a further example of the wide lithological and mineralogical variety that impact melting could produce on the surface of a single asteroid, especially if characterized by an important compositional heterogeneity in space and time like a regolith.  相似文献   
59.
The laser fluorination technique reported here for analyzing the oxygen isotope composition (δ18O) of fine quartz size fractions 50-20, 20-10, 10-5, 5-2, 2-1 and <1 μm has been validated by comparison with the ion microprobe technique. It yields accurate δ18O data with an external precision better than 0.15‰. This is a significant methodological improvement for isotopic studies dealing with materials such as soil or biogenic oxides and silicates: particles are often too small and recovered in insufficient amount to be easily handled for ion microprobe analysis. Both techniques were used to investigate δ18O composition of a Cretaceous quartzite and silcrete sequence from the South-East of France. Quartzite cements average 31.04 ± 1.93‰. They formed from Mid-Cretaceous seawater. Higher in the series, silcretes cements average 26.66 ± 1.36‰. They formed from Upper- or post-Upper-Cretaceous soil water and groundwater. Oxygen isotope data show that the silicification steps from one mineralogical phase to another and from one layer to another (including from an upper pedogenic silcrete to a lower groundwater silcrete) occurred in a closed or weakly evaporating hydrological system.  相似文献   
60.
Domains of spit evolution in the Goro area, Po Delta, Italy   总被引:2,自引:0,他引:2  
Goro lagoon was formed during the 19th century in the southern part of the Po Delta. Its origin is related to the growth of a spit system, which progressively occluded the southernmost interdistributary bay from the sea. The development of the spits is due to the morphological prominence of the Po Delta which causes a divergent littoral drift, enhanced by wave refraction over the delta front. During the last century the spit was abandoned, destroyed, and re-constructed several times because of the development of newer spits seawards. Using historical maps and aerial photographs, three different periods are recognised, featuring distinctive spit growth styles: parallel, fan-shaped and branched. The different domains of spit evolution are related to several factors, mainly to the mutual influence of sediment discharge, sand mining along the Po river, wave action over the delta front, human-induced subsidence and direct human interventions along the spits and for flood-control.  相似文献   
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