Assessing catchment-scale spatial and temporal patterns of groundwater and stream salinity     

David L. Poulsen  Craig T. Simmons  Corinne Le Galle La Salle  Jim W. Cox 《Hydrogeology Journal》2006,14(7):1339-1359

Understanding catchment-scale patterns of groundwater and stream salinity are important in land- and water-salinity management. A large-scale assessment of groundwater and stream data was undertaken in the eastern Mt Lofty Ranges of South Australia using geographical information systems (GIS), regional scale hydrologic data, hydrograph separation and hydrochemical techniques. Results of the study show: (1) salts were mostly of marine origin (75%), while sulfate and bicarbonate from mineral weathering comprised most of the remainder, (2) elevated groundwater salinities and stable water isotopic compositions similar to mean rainfall indicated that plant transpiration was the primary salt accumulation mechanism, (3) key factors explaining groundwater salinity were geology and rainfall, with overall catchment salinity inversely proportional to average annual rainfall, and groundwater salinity ‘hotspots’ (EC >8 mS/cm) associated with geological formations comprising sulfidic marine siltstones and shales, (4) shallow groundwater correlated with elevated stream salinity, implying that baseflow contributed to stream salt loads, with most of the annual salt load (estimated to be 24,500 tonnes) occurring in winter when baseflow volume was highest. Salt-load analysis using stream data could be a practical, low-cost technique to rapidly target the investigation of problem areas within a catchment.  相似文献   

Testing the genetic relationship between fluid alteration and brecciation in CM chondrites     

Maximilien J. Verdier‐Paoletti  Yves Marrocchi  Lionel G. Vacher  Jrme Gattacceca  Andrey Gurenko  Corinne Sonzogni  Matthieu Gounelle 《Meteoritics & planetary science》2019,54(8):1692-1709

Boriskino is a poorly studied CM chondrite with numerous millimeter‐ to centimeter‐scale clasts exhibiting sharp boundaries. Clast textures and mineralogies attest to diverse geological histories with various degrees of aqueous alteration. We conducted a petrographic, chemical, and isotopic study on each clast type of the breccia to investigate if there exists a genetic link between brecciation and aqueous alteration, and to determine the controlling parameter of the extent of alteration. Boriskino is dominated by CM2 clasts for which no specific petrographic type could be assigned based on the chemical compositions and modal abundances of constituents. One clast stands out and is identified as a CM1 lithology, owing to its lack of anhydrous silicates and its overall abundance of dolomite‐like carbonates and acicular iron sulfides. We observe that alteration phases near clast boundaries exhibit foliation features, suggesting that brecciation postdated aqueous alteration. We measured the O‐isotopic composition of Ca‐carbonates and dolomite‐like carbonates to determine their precipitation temperatures following the methodology of Verdier‐Paoletti et al. (2017). Both types of carbonates yield similar ranges of precipitation temperatures independent of clast lithology, ranging from ?13.9 ± 22.4 (2σ) to 166.5 ± 47.3 °C, precluding that temperature alone accounts for the differences between the CM1 and CM2 lithologies. Instead, we suggest that initial water/rock ratios of 0.75 and 0.61 for the CM1 and CM2 clasts, respectively, might control the extent of aqueous alteration. Based on these estimates, we suggest that Boriskino clasts originated from a single parent body with heterogeneous distribution of water either due to local differences in the material permeability or in the initial content of ice available. These conditions would have produced microenvironments with differing geochemical conditions thus leading to a range of degrees of aqueous alteration.  相似文献   

Ground motion prediction with the empirical Green's function technique: an assessment of uncertainties and confidence level     

Ronan Pavic  Martin G. Koller  Pierre-Yves Bard  Corinne Lacave-Lachet 《Journal of Seismology》2000,4(1):59-77

An assessment of uncertainties for ground motion predictions with the aid of the empirical Green's function (EGF) technique is presented. The main input parameters were identified, and their respective uncertainties were assessed by means of an international expert inquiry. The repercussion of these input uncertainties on the final ground motion estimates were investigated by means of the Latin Hypercube Sampling technique. The mean ground motion estimates (response spectra) and their standard deviations were compared with results obtained from empirical attenuation laws. The most sensitive input parameter turned out to be the seismic moment corresponding to the EGF. In general, if the source parameters are well determined, equivalent uncertainties, statistically speaking, can be expected from the EGF technique and from the application of attenuation laws. Therefore, if EGFs with well known source parameters are available, the EGF technique seems to be preferable: site effects are automatically taken into account, and physically realistic acceleration time histories can be obtained. However, further investigations on the reliability of the EGF technique should be performed, and finally, it is recalled that the EGF technique is based on the assumption of linearity. If conditions are such that this assumption cannot be maintained, the EGF technique should be combined with non-linear geotechnical methods.  相似文献   

New mass increase beneath Askja volcano,Iceland – a precursor to renewed activity?     

Hazel Rymer  Corinne Locke  Benedikt G. Ófeigsson  Páll Einarsson  Erik Sturkell 《地学学报》2010,22(4):309-313

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Inter-laboratory comparison of oxygen isotope compositions from biogenic silica     

Bernhard Chapligin  Melanie J. Leng  Anne Alexandre  Akira Ijiri  Aldo Shemesh  Ulrike Herzschuh  Hanno Meyer  Yusuke Okazaki  Zachary D. Sharp  Corinne Sonzogni  Florence Sylvestre  Ruth Yam 《Geochimica et cosmochimica acta》2011,75(22):7242-7256

Several techniques have been introduced in the last decades for the dehydration and release of O₂ from biogenic silica (opal-A) for oxygen-isotope analysis. However, only one silica standard is universally available: a quartz standard (NBS28) distributed by the IAEA, Vienna. Hence, there is a need for biogenic silica working standards. This paper compares the existing methods of oxygen-isotope analyses of opal-A and aims to characterize additional possible working standards to calibrate the δ¹⁸O values of biogenic silica. For this purpose, an inter-laboratory comparison was organized. Six potential working standard materials were analysed repeatedly against NBS28 by eight participating laboratories using their specific analytical methods. The materials cover a wide range of δ¹⁸O values (+23 to +43‰) and include diatoms (marine, lacustrine), phytoliths and synthetically-produced hydrous silica. To characterize the proposed standards, chemical analyses and imaging by scanning electron microscopy (SEM) were also performed. Despite procedural differences at each laboratory, all methods are in reasonable agreement with a standard deviation (SD) for δ¹⁸O values between 0.3‰ and 0.9‰ (1σ). Based on the results, we propose four additional biogenic silica working standards (PS1772-8: 42.8‰; BFC: 29.0‰; MSG60: 37.0‰; G95-25-CL leaves: 36.6‰) for δ¹⁸O analyses, available on request through the relevant laboratories.  相似文献   

Seasonal dripwater Mg/Ca and Sr/Ca variations driven by cave ventilation: Implications for and modeling of speleothem paleoclimate records   总被引：1，自引：0，他引：1  

Corinne I. Wong  Jay L. Banner 《Geochimica et cosmochimica acta》2011,75(12):3514-4950

A 4-year study in a central Texas cave quantifies multiple mechanisms that control dripwater composition and how these mechanisms vary at different drip sites. We monitored cave-air compositions, in situ calcite growth, dripwater composition and drip rate every 4-6 weeks. Three groups of drip sites are delineated (Groups 1-3) based on geochemical variations in dripwater composition. Quantitative modeling of mineral-solution reactions within the host carbonate rock and cave environments is used to identify mechanisms that can account for variations in dripwater compositions. The covariation of Mg/Ca (and Sr/Ca) and Sr isotopes is key in delineating whether Mg/Ca and Sr/Ca variations are dictated by water-rock interaction (i.e., calcite or dolomite recrystallization) or prior calcite precipitation (PCP). Group 1 dripwater compositions reflects a narrow range of the extent of water-rock interaction followed by varying amounts of prior calcite precipitation (PCP). Group 2 dripwater compositions are controlled by varying amounts of water-rock interaction with little to no PCP influence. Group 3 dripwater compositions are dictated by variable extents of both water-rock interaction and PCP. Group 1 drip sites show seasonal variations in dripwater Mg/Ca and Sr/Ca, whereas the other drip sites do not. In contrast to the findings of most previous dripwater Mg/Ca-Sr/Ca studies, these seasonal variations (at Group 1 drip sites) are independent of changes in water flux (i.e., rainfall and/or drip rate), and instead significantly correlate with changes in cave-air CO₂ concentrations. These results are consistent with lower cave-air CO₂, related to cool season ventilation of the cave atmosphere, enhancing calcite precipitation and leading to dripwater geochemical evolution via PCP. Group 1 dripwater Mg/Ca and Sr/Ca seasonality and evidence for PCP as a mechanism that can account for that seasonality, have two implications for many other regions where seasonal ventilation of caves is likely: (1) speleothem trace-element records may provide seasonal signals, and (2) such records may be biased toward recording climate conditions during the season when calcite is depositing. Additionally, we use our results to construct a forward model that illustrates the types of speleothem Mg/Ca and Sr/Ca variations that would result from varying controls on dripwater compositions. The model provides a basis for interpreting paleo-dripwater controls from high frequency Mg/Ca and Sr/Ca variations for speleothems from caves at which long term monitoring studies are not feasible.  相似文献   

Major, trace element and oxygen isotope study of glass cosmic spherules of chondritic composition: The record of their source material and atmospheric entry heating     

Carole Cordier  Luigi Folco  Corinne Sonzogni 《Geochimica et cosmochimica acta》2011,75(18):5203-6210

New geochemical data on cosmic spherules (187 major element, 76 trace element, and 10 oxygen isotope compositions) and 273 analyses from the literature were used to assess the chemical diversity observed among glass cosmic spherules with chondritic composition. Three chemical groups of glass spherules are identified: normal chondritic spherules, CAT-like spherules (where CAT refers to Ca-Al-Ti-rich spherules), and high Ca-Al spherules. The transition from normal to high Ca-Al spherules occurs through a progressive enrichment in refractory major elements (on average from 2.3 wt.% to 7.0 wt.% for CaO, 2.8 wt.% to 7.2 wt.% for Al₂O₃, and 0.14 wt.% to 0.31 wt.% for TiO₂) and refractory trace elements (from 6.2 μg/g to 19.3 μg/g for Zr and 1.6CI-4.3CI for Rare Earth Elements-REEs) relative to moderately refractory elements (Mg, Si) and volatile elements (Rb, Na, Zn, Pb). Based on a comparison with experimental works from the literature, these chemical groups are thought to record progressive heating and evaporation during atmospheric entry. The evaporative mass losses evaluated for the high Ca-Al group (80-90%) supersede those of the CAT spherules which up to now have been considered as the most heated class of stony cosmic spherules. However, glass cosmic spherules still retain isotopic and elemental evidence of their source and precursor mineralogy. Four out of the 10 normal and high Ca-Al spherules analysed for oxygen isotopes are related to ordinary chondrites (δ¹⁸O = 13.2-17.3‰ and δ¹⁷O = 7.6-9.2‰). They are systematically enriched in Ni and Co (Ni = 24-500 μg/g) with respect to spherules related to carbonaceous chondrites (Ni < 1.2 μg/g, δ¹⁸O = 13.1-28.0‰ and δ¹⁷O = 5.1-14.0‰). REE abundances in cosmic spherules, which are not fractionated according to parent body or atmospheric entry heating, can then be used to unravel the precursor mineralogy. Spherules with flat REE pattern close to unity when normalized to CI are the most abundant in our dataset (54%) and likely derive from homogeneous, fine-grained chondritic precursors. Other REE patterns fall into no more than five categories, a surprising reproducibility in view of the mineralogical heterogeneity of chondritic lithologies at the micrometeorite scale.  相似文献   

Northwest Africa 5958: A weakly altered CM‐related ungrouped chondrite,not a CI3          下载免费PDF全文

Emmanuel Jacquet  Jean‐Alix Barrat  Pierre Beck  Florent Caste  Jérôme Gattacceca  Corinne Sonzogni  Matthieu Gounelle 《Meteoritics & planetary science》2016,51(5):851-869

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Integrating epidemiological and engineering approaches in the assessment of human casualties in earthquakes   总被引：1，自引：1，他引：0  

Stav Shapira  Limor Aharonson-Daniel  Igal M. Shohet  Corinne Peek-Asa  Yaron Bar-Dayan 《Natural Hazards》2015,78(2):1447-1462

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Simplified non-linear seismic displacement demand prediction for low period structures   总被引：1，自引：0，他引：1  

Clotaire Michel  Pierino Lestuzzi  Corinne Lacave 《Bulletin of Earthquake Engineering》2014,12(4):1563-1581

The prediction of non-linear seismic demand using linear elastic behavior for the determination of peak non-linear response is widely used for seismic design as well as for vulnerability assessment. Existing methods use either linear response based on initial period and damping ratio, eventually corrected with factors, or linear response based on increased equivalent period and damping ratio. Improvements to the original EC8 procedure for displacement demand prediction are proposed in this study. Both propositions may be graphically approximated, which is a significant advantage for practical application. A comparison with several other methods (equal displacement rule, EC8 procedure, secant stiffness and empirical equivalent period methods) is performed. The study is based on non-linear SDOF systems subjected to recorded earthquakes, modified to match design response spectra of different ground types, and focuses on the low frequency range that is of interest for most European buildings. All results are represented in the spectral displacement/fundamental period plane that highlights the predominant effect of the fundamental period on the displacement demand. This study shows that linearized methods perform well at low strength reduction factors but may strongly underestimate the displacement demand at strength reduction factors greater than 2. This underestimation is an important issue, especially for assessment of existing buildings, which are often related with low lateral strength. In such cases, the corresponding strength reduction factors are therefore much larger than 2. The new proposals significantly improve the reliability of displacement demand prediction for values of strength reduction factors greater than 2 compared to the original EC8 procedure. As a consequence, for the seismic assessment of existing structures, such as unreinforced masonry low-rise buildings, the current procedure of EC8 should be modified in order to provide accurate predictions of the displacement demand in the domain of the response spectrum plateau.  相似文献