High-pressure Raman spectroscopic study of Mn2GeO4, Ca2GeO4, Ca2SiO4, and CaMgGeO4 olivines     

Bruno Reynard  Corinne Remy  Fouzia Takir 《Physics and Chemistry of Minerals》1997,24(2):77-84

We present a Raman spectroscopic study of the structural modifications of several olivines at high pressures and ambient temperature. At high pressures, the following modifications in the Raman spectra are observed: 1)?in Mn₂GeO₄, between 6.7 and 8.6?GPa the appearance of weak bands at 560 and 860?cm^?1; between 10.6 and 23?GPa, the progressive replacement of the olivine spectrum by the spectrum of a crystalline high pressure phase; upon decompression, the inverse sequence of transformations is observed with some hysteresis in the transformation pressures; this sequence may be interpreted as the progressive transformation of the olivine to a spinelloid where Ge tetrahedra are polymerized, and then to a partially inverse spinel; 2)?in Ca₂SiO₄, the olivine transforms to larnite between 1.9 and 2.1?GPa; larnite is observed up to the maximum pressure of 24?GPa and it can partially back-transform to olivine during decompression; 3)?in Ca₂GeO₄, the olivine transforms to a new structure between 6.8 and 8?GPa; the vibrational frequencies of the new phase suggest that the phase transition involves an increase of the Ca coordination number and that Ge tetrahedra are isolated; this high pressure phase is observed up to the maximum pressure of 11?GPa; during decompression, it transforms to a disordered phase below 5?GPa; 4)?in CaMgGeO₄, no significant modification of the olivine spectrum is observed up to 15?GPa; between 16 and 26?GPa, broadening of some peaks and the appearance of a weak broad feature at 700–900?cm^?1 suggests a progressive amorphization of the structure; near 27?GPa, amorphization is complete and an amorphous phase is quenched down to ambient pressure; this unique behaviour is interpreted as the result of the incompatibilities in the high pressure behaviour of the Ca and Mg sublattices in the olivine structure.  相似文献   

Low Ozone Episodes at Amphitrite Point Marine Boundary Layer Observatory,British Columbia,Canada     

Ian McKendry  Eric Christensen  Corinne Schiller  Roxanne Vingarzan  Anne Marie Macdonald  Yimei Li 《大气与海洋》2014,52(3):271-280

At Amphitrite Point, ozone (O₃) mixing ratios are observed to drop steadily to 5–15?ppb over a period of 12 hours or less with a frequency approaching one event per week (with highest frequencies occurring in summer and fall). Analysis of 47 such O₃ depletion events reveals that low O₃ episodes are a predominantly nocturnal phenomenon associated with anticyclonic conditions characterized by light onshore or alongshore winds and an absence of fog and mist. Back-trajectories show air carried to the Amphitrite Point Observatory (APO) during depletion events remains in the marine boundary layer and is not brought to the surface from aloft. There is no strong correlation with other “criteria” pollutants (CO, NO_x, SO₂, PM_2.5) that might be indicative of a mechanism for O₃ destruction linked to human, terrestrial, or marine pollutant sources. However, CO₂ mixing ratios are observed to increase, coincident with O₃ depletion. Together, these results point to a natural marine boundary layer phenomenon in which O₃ destruction dominates O₃ production and/or replenishment by vertical mixing. While there are several candidate mechanisms, the conditions for O₃ depletion (and CO₂ buildup) to occur are set by meteorology and, in particular, development of a stable marine boundary layer in which vertical mixing is suppressed. Support for this interpretation is provided by simultaneous increases in CO₂ in the stable marine boundary that are indicative of an important role played by marine biogenic processes (respiration). Future research should be directed at elucidating the chemical mechanisms responsible for O₃ destruction in the coastal zone, which means that there would be a need for a much broader range of measurements at APO (including halogenated species) as well as offshore measurements of both chemical and marine boundary layer meteorological variables.  相似文献   

The extremely reduced silicate‐bearing iron meteorite Northwest Africa 6583: Implications on the variety of the impact melt rocks of the IAB‐complex parent body     

Agnese Fazio  Massimo D'Orazio  Luigi Folco  Jérôme Gattacceca  Corinne Sonzogni 《Meteoritics & planetary science》2013,48(12):2451-2468

Northwest Africa (NWA) 6583 is a silicate‐bearing iron meteorite with Ni = 18 wt%. The oxygen isotope composition of the silicates (?′¹⁷O = ?0.439 ‰) indicates a genetic link with the IAB‐complex. Other chemical, mineralogical, and textural features of NWA 6583 are consistent with classification as a new member of the IAB‐complex. However, some unique features, e.g., the low Au content (1.13 μg g^?1) and the extremely reducing conditions of formation (approximately ?3.5 ?IW), distinguish NWA 6583 from the known IAB‐complex irons and extend the properties of this group of meteorites. The chemical and textural features of NWA 6583 can be ascribed to a genesis by impact melting on a parent body of chondritic composition. This model is also consistent with one of the most recent models for the genesis of the IAB‐complex. Northwest Africa 6583 provides a further example of the wide lithological and mineralogical variety that impact melting could produce on the surface of a single asteroid, especially if characterized by an important compositional heterogeneity in space and time like a regolith.  相似文献   

Oxygen isotope analyses of fine silica grains using laser-extraction technique: Comparison with oxygen isotope data obtained from ion microprobe analyses and application to quartzite and silcrete cement investigation   总被引：1，自引：0，他引：1  

Anne Alexandre  Isabelle Basile-Doelsch  Corinne Sonzogni  Claude Parron  Fabrice Colin 《Geochimica et cosmochimica acta》2006,70(11):2827-2835

The laser fluorination technique reported here for analyzing the oxygen isotope composition (δ¹⁸O) of fine quartz size fractions 50-20, 20-10, 10-5, 5-2, 2-1 and <1 μm has been validated by comparison with the ion microprobe technique. It yields accurate δ¹⁸O data with an external precision better than 0.15‰. This is a significant methodological improvement for isotopic studies dealing with materials such as soil or biogenic oxides and silicates: particles are often too small and recovered in insufficient amount to be easily handled for ion microprobe analysis. Both techniques were used to investigate δ¹⁸O composition of a Cretaceous quartzite and silcrete sequence from the South-East of France. Quartzite cements average 31.04 ± 1.93‰. They formed from Mid-Cretaceous seawater. Higher in the series, silcretes cements average 26.66 ± 1.36‰. They formed from Upper- or post-Upper-Cretaceous soil water and groundwater. Oxygen isotope data show that the silicification steps from one mineralogical phase to another and from one layer to another (including from an upper pedogenic silcrete to a lower groundwater silcrete) occurred in a closed or weakly evaporating hydrological system.  相似文献   

Domains of spit evolution in the Goro area, Po Delta, Italy   总被引：2，自引：0，他引：2  

Umberto Simeoni  Giorgio Fontolan  Umberto Tessari  Corinne Corbau 《Geomorphology》2007,86(3-4):332-348

Goro lagoon was formed during the 19th century in the southern part of the Po Delta. Its origin is related to the growth of a spit system, which progressively occluded the southernmost interdistributary bay from the sea. The development of the spits is due to the morphological prominence of the Po Delta which causes a divergent littoral drift, enhanced by wave refraction over the delta front. During the last century the spit was abandoned, destroyed, and re-constructed several times because of the development of newer spits seawards. Using historical maps and aerial photographs, three different periods are recognised, featuring distinctive spit growth styles: parallel, fan-shaped and branched. The different domains of spit evolution are related to several factors, mainly to the mutual influence of sediment discharge, sand mining along the Po river, wave action over the delta front, human-induced subsidence and direct human interventions along the spits and for flood-control.  相似文献   

Ceilometer observations of aerosol layer structure above the Petit Lubéron during ESCOMPTE's IOP 2     

Marcel Zphoris  Hubert Holin  Franck Lavie  Nadine Cenac  Michel Cluzeau  Olivier Delas  Franoise Eideliman  Jacqueline Gagneux  Alain Gander  Corinne Thibord 《Atmospheric Research》2005,74(1-4):581-595

A modified ceilometer has been used during the second Intensive Observation Period (IOP) of the “Expérience sur Site pour COntraindre les Modèles de Pollution atmosphériques et de Transport d'Émission” (ESCOMPTE) to perform continuous remote observations of aerosol accumulations in the first 3 km of the atmosphere. These observations encompassed an episode of intense particulate and photochemical pollution. The submicronic particles density, measured at an altitude of 600 m, went from a very low point of a few tens of particles per cubic centimeter (at the end of a Mistral episode in the free atmosphere) to a high point of more than 4500 particles per cubic centimeter (when pollutants were trapped by thermal inversions).The main result is that this instrument enables a fine documentation of the mixing layer height and of aerosol particles stratifications and circulation. Airborne aerosol measurements have been made above the mountainous region of Mérindol in order to validate in situ the remote sensing measurements. Ozone measurements near the summit of the mountains as well as in the valley were performed in order to correlate aerosol accumulation and ozone concentration. As a notable example, the two-layer aerosol stratification seen in the first 2 days of IOP 2b in that part of the ESCOMPTE domain confirms the results of another team which used backtrajectories. The low-altitude pollution for this timeframe had a local origin (the Fos industrial area), whereas above 500 m, the air masses had undergone regional-scale transport (from north-eastern Spain).The second major result is the highlighting of a pattern, in sea breeze conditions and in this part of the ESCOMPTE experiment zone, of nocturnal aerosol accumulation at an altitude of between 500 and 2000 m, followed by high ozone concentration the next day.  相似文献   

Compartmentalization of physical and chemical properties in hard-rock aquifers deduced from chemical and groundwater age analyses     

Virginie Ayraud  Luc Aquilina  Thierry Labasque  Hélène Pauwels  Jérôme Molenat  Anne-Catherine Pierson-Wickmann  Véronique Durand  Olivier Bour  Corinne Tarits  Pierre Le Corre  Elise Fourre  Philippe Merot  Philippe Davy 《Applied Geochemistry》2008

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Tropical sea-surface temperatures during the last glacial period: a view based on alkenones in Indian Ocean sediments     

Corinne Sonzogni  Edouard Bard  Frauke Rostek 《Quaternary Science Reviews》1998,17(12):1185-1201

The qualitification of tropical temperatures during the last glacial cycle (0-150 kyr BP) is a controversial issue since different proxies seem to provide conflicting informations. To obtain a complementary point of view, we use the alkenone method to estimate sea-surface temperatures and focus our work on deep-sea sediments recovered from the tropical Indian Ocean. We present alkenone data obtained in two cores which cover in detail the last deglaciation and in about twenty cores distributed between 20°S and 20°N that were chosen to evaluate the temperature contrast of the last glacial-interglacial transition. Our results indicate that Indian Ocean tropical temperatures remained an average within 1.5-2.5°C of their present values during the last glaciation. At 10°N the last deglaciation is characterized by two warming steps which is similar to the classical deglacial chronology observed in the North Atlantic area. At 20°S the deglacial warming occurred at ca. 15 cal kyr BP, lagging significantly (5-4 kyr) behind the Antarctic warming, but in phase with northern hemisphere time series.  相似文献   

Highly magnetised and differentiated basalts at the 18–19° S propagating spreading centre in the North Fiji Basin     

Horen  Hélène  Fleutelot  Corinne 《Marine Geophysical Researches》1998,20(2):129-137

Geochemical and magnetic properties of basalts dredged along a propagating spreading centre (central part of the North Fiji Basin) have been analysed. Two phenomena appear to be important in controlling variations of natural remanent magnetisation (NRM): 1) an extensive magma differentiation to Fe-Ti basalts increases with the intensity of NRM; and both increase towards the propagator tip, 2) low temperature oxidation (maghemitisation) seems to have already occurred along the ridge axis for the zero age basalts. This paper shows that despite the apparent lack of correlation between NRM and the maghemitisation process (masked by the effect of extensive magma differentiation), the latter involves a change of the domain state of magnetic carriers, from pseudo single-domain to single-domain. We separated the NRM into 4 partial NRMs (pNRM) depending on the coercivity of grains. This analysis showed that the contribution to the remanence of grains with high coercivity increases with maghemitisation, whereas the contribution of grains with weak coercivity decreases.Despite the relatively high degree of maghemitisation, the variations of natural remanent magnetisation intensity principally reflect the variations of magmatic processes. This joint work on magnetic and magmatic properties of basalts collected on the NS-propagating spreading centre from the North Fiji Basin reinforces the magnetic telechemistry hypothesis of Vogt (1979).  相似文献   

A novel nuclear forensic tool involving deposit type normalized rare earth element signatures   总被引：1，自引：0，他引：1       下载免费PDF全文

Tyler L. Spano  Antonio Simonetti  Thomas Wheeler  Grace Carpenter  Devonee Freet  Enrica Balboni  Corinne Dorais  Peter C. Burns 《地学学报》2017,29(5):294-305

Identifying the provenance of uranium‐rich materials is a critical objective of nuclear forensic analysis. Rare earth element (REE) distributions within uranium ores are well‐established forensic indicators, but quantifying and correlating trace element signatures for U ores to known deposits has thus far involved intricate statistical analyses. This study reports average chondrite normalized (CN)‐REE signatures for important U deposit types worldwide, which are then employed to evaluate U ore paragenesis using a simple linear regression analysis. This technique provides a straightforward method that can aid in determining the deposit type of U ores based on their REE abundances, and combined with other forensic indicators (e.g. radiogenic isotope signatures) can provide essential provenance information for nuclear materials.  相似文献