Plio-Pleistocene evolution of the north Alpine drainage system: new constraints from detrital thermochronology of foreland deposits     

Wolfgang Reiter  Simon Elfert  Christoph Glotzbach  Cornelia Spiegel 《International Journal of Earth Sciences》2015,104(3):891-907

  相似文献   

Whole-watershed mercury balance at Sagehen Creek, Sierra Nevada, CA     

Xavier Faïn  Daniel Obrist  Cornelia Barth  Douglas P. Boyle 《Geochimica et cosmochimica acta》2011,75(9):2379-2392

Few data are available on mercury (Hg) dynamics at high-elevation mountain sites. In this project, a whole-watershed approach was used to quantify major fluxes and pools of Hg in Sagehen basin, a closed basin in the Sierra Nevada mountains in California. Over a period spanning 9 months (January-September 2009), we estimated wet deposition inputs to the watershed at 3.8 μg m⁻². Dry deposition added additional Hg in the range of 0.30-2.45 μg m⁻² during this time period, and was the dominant deposition process during summer time. Seasonal snowpack accounted for only half of the Hg deposited by wet deposition. We suggest that photo-induced reduction of Hg(II) in snow and subsequent volatilization was responsible for this loss. Thus, snowpacks in the Sierra Nevada mountains likely reduce the effective atmospheric mercury flux via wet deposition due to significant emission fluxes prior to snowmelt. As such, wet Hg deposition could be of lesser importance as a Hg source in snow-dominated systems. Finally, stream runoff collected at the outlet of the watershed could account for only 4% of total Hg wet deposition suggesting that a large fraction of mercury deposition was sequestered in the ecosystem, specifically in the soils.  相似文献   

澳大利亚黄土磁学性质及环境意义   总被引：4，自引：3，他引：1  

刘秀铭  马明明  P.Hesse  吕镔  汤德平  郭雪莲  陈家胜 《第四纪研究》2011,31(5):837-848

澳大利亚内陆广大而干旱,发育着大面积沙漠,却没有多少黄土的报道.本文对惟一报道的黄土,新南威尔士州Mackenzie地区Waterholes Creek剖面进行了详细的采样和磁学参数测量,并与中国黄土高原洛川和西峰经典剖面进行了对比.结果表明该剖面磁学性质与中国黄土高原有许多异同.它成土特征强,百分比频率磁化率较高,但...  相似文献   

An Evaluation of the Inter‐Method Discrepancies in Ferromanganese Nodule Proficiency Test GeoPT 23A     

Cornelia Kriete 《Geostandards and Geoanalytical Research》2011,35(3):319-340

Round 23 of the GeoPT international proficiency testing scheme included the ferromanganese nodule powder FeMn‐1 which was distributed as an additional sample (23A). The aim of this initiative was to assess overall analytical performance for such a challenging oxide matrix with a view to the possible certification of such a material in accordance with ISO Guide requirements. To investigate inter‐method discrepancies, precision data and the method means for the most frequently used analytical methods (XRF, ICP‐MS and ICP‐AES) and sample preparation techniques were calculated and then compared using statistical tests of equivalence. For most major elements, XRF and ICP‐AES data dominated and these were found to give equivalent results. In contrast, for most trace elements significant discrepancies were detected between data obtained by different analytical methods. Possible causes are discussed with a view to attributing their origin to calibration strategy, sensitivity or interferences. It is assumed that the unusual oxide matrix generated unexpected interferences and thus method bias. Discrepancies observed between data from different analytical methods provide valuable information for the participating analysts, helping them to avoid systematic errors and thus minimising bias. They also suggest actions necessary to improve results for any future certification of such a material.  相似文献   

Metasomatism of the Pan-African lithospheric mantle beneath the Damara Belt,Namibia, by the Tristan mantle plume: geochemical evidence from mantle xenoliths     

Anton?le?RoexEmail author  Cornelia?Class 《Contributions to Mineralogy and Petrology》2014,168(2):1046

In situ trace element analyses of constituent minerals in mantle xenoliths occurring in an alnöite diatreme and in nephelinite plugs emplaced within the central zone of the Damara Belt have been determined by laser ablation ICP-MS. Primitive mantle-normalized trace element patterns of clinopyroxene and amphibole indicate the presence of both depleted MORB-like mantle and variably enriched mantle beneath this region. Clinopyroxenes showing geochemical depletion have low La/Sm_n ratios (0.02–0.2), whereas those showing variable enrichment have La/Sm_n ranging up to 3.8 and La/Yb_n to 9.1. The most enriched clinopyroxenes coexist with amphibole showing similar REE patterns (La/Sm_n = 1.3–4.1; La/Yb_n = 4.5–9). Primitive mantle-normalized trace element patterns allow further groups to be distinguished amongst the variably enriched clinopyroxenes: one having strong relative depletion in Rb–Ba, Ta–Nb and relative enrichment in Th–U; another with similar characteristics but with additional strong relative depletion in Zr–Hf; and one showing no significant anomalies. Amphiboles show similar normalized trace element patterns to co-existing clinopyroxene. Clinopyroxene and amphiboles showing LREE_N enrichment have high Sr and low Nd isotope ratios compared to clinopyroxene with LREE-depleted patterns. Numerical simulation of melt percolation through the mantle via reactive porous flow is used to show that the chromatographic affect associated with such a melt migration process is able to account for the fractionation seen in La–Ce–Nd in cryptically metasomatized clinopyroxenes in Type 1 xenoliths, where melt–matrix interactions occur near the percolation front, whereas REE patterns in clinopyroxenes proximal to the source of metasomatic melt/fluid match those found in modally metasomatized Type 2 xenoliths. The strong fractionation between Rb–Ba, Th–U and Ta–Nb shown by some cryptically metasomatized xenoliths can be also accounted for by reactive porous flow, provided amphibole crystallizes from the percolating melt/fluid close to its source. The presence of amphibole in vein-like structures in some xenoliths is consistent with this interpretation. The strong depletion in Zr–Hf in clinopyroxene and amphibole in some xenoliths cannot be accounted for by melt migration processes and requires metasomatism by a separate carbonate-rich melt/fluid. When taken together with published isotope data on these same xenoliths, the source of metasomatic enrichment of the previously depleted (MORB-like) sub-Damaran lithospheric mantle is attributed to the upwelling Tristan plume head at the time of continental breakup.  相似文献   

Relations between denudation,glaciation, and sediment deposition: implications from the Plio‐Pleistocene Central Alps     

Wolfgang Reiter  Simon Elfert  Christoph Glotzbach  Matthias Bernet  Cornelia Spiegel 《Basin Research》2013,25(6):659-674

Despite abundant data on the early evolution of the Central Alps, the latest stage exhumation history, potentially related to relief formation, is still poorly constrained. We aim for a better understanding of the relation between glaciation, erosion and sediment deposition. Addressing both topics, we analysed late Pliocene to recent deposits from the Upper Rhine Graben and two modern river sands by apatite fission‐track and (U‐Th‐Sm)/He thermochronology. From the observed age patterns we extracted the sediment provenance and paleo‐erosion history of the Alpine‐derived detritus. Due to their pollen and fossil record, the Rhine Graben deposits also provide information on climatic evolution, so that the erosion history can be related to glacial evolution during the Plio‐Pleistocene. Our data show that Rhine Graben deposits were derived from Variscan basement, Hegau volcanics, Swiss Molasse Basin, and the Central Alps. The relations between glaciation, Alpine erosion, and thermochronological age signals in sedimentary rocks are more complex than assumed. The first Alpine glaciation during the early Pleistocene did not disturb the long‐term exhumational equilibrium of the Alps. Recent findings indicate that main Alpine glaciation occurred at ca. 1 Ma. If true, then main Alpine glaciation was coeval with an apparent decrease of hinterland erosion rates, contrary to the expected trend. We suggest that glaciers effectively sealed the landscape, thus reducing the surface exposed to erosion and shifting the area of main erosion north toward the Molasse basin, causing sediment recycling. At around 0.4 Ma, erosion rates increased again, which seems to be a delayed response to main glaciation. The present‐day erosion regime seems to be dominated by mass‐wasting processes. Generally, glacial erosion rates did not exceed the pre‐glacial long‐term erosion rates of the Central Alps.  相似文献   

A methodology for dealing with regional change in integrated water resources management     

Jochen Schanze  Johanna Trümper  Cornelia Burmeister  Dirk Pavlik  Ivan Kruhlov 《Environmental Earth Sciences》2012,65(5):1405-1414

The paper presents a methodology on how to consistently deal with the future change and management options in integrated water resources management (IWRM). It is based on a conceptual framework with a five step procedure for the formulation and analysis of a so-called ‘parameterised regional futures’. Developing and testing the approach for IWRM is realised for the upper part of the Western Bug River catchment (Ukraine). Special attention is paid to scenarios of change covering climate and land use. The future regional climate is downscaled with the model CCLM. Land cover is projected after retrospective change detection and the derivation of prospective algorithms. Parameters of the interrelations between land use and the water cycle are tackled through using the concept of the model PWF-LU. The methodology is currently being tested to analyse the impacts of mid-term regional change and management options on the water cycle of the catchment.  相似文献   

Origins of yttrium and rare earth element distributions in metamorphic garnet   总被引：1，自引：0，他引：1  

S. J. Moore  W. D. Carlson  M. A. Hesse 《Journal of Metamorphic Geology》2013,31(6):663-689

Highly variable distributions of yttrium and rare earth elements (Y+REEs) are documented in pelitic garnet from the Picuris Mountains, New Mexico, and from Passo del Sole, Switzerland, and in mafic garnet from the Franciscan Complex, California. The wide variety of these Y+REE zoning patterns, and those described previously in other occurrences, imply diverse origins linked to differing degrees of mobility of these elements through the intergranular medium during garnet growth. In the Picuris Mountains, large, early‐nucleating crystals have radial profiles of Y+REE dominated by central peaks and annular maxima, in patterns that vary systematically with atomic number. Superimposed on these features are narrow spikes in HREEs and MREEs, located progressively rimward with decreasing atomic number. In contrast, profiles in small, late‐nucleating crystals contain only broad central maxima for all Y+REEs. In garnet from Passo del Sole, Y+REE zoning varies radically from sample to sample: in some rocks, crystals of all sizes display only central peaks for all Y+REEs; in others, profiles exhibit irregular fluctuations in Y+REE contents that match up with small‐scale patchy zoning in Y and Ca X‐ray maps. In the Franciscan Complex, Y+REE in garnet cores fluctuate unsystematically, but mantles and rims display concentric oscillatory zoning for both major elements and Y+REEs. Our interpretation of the complexity of Y+REE distributions in metamorphic garnet centres on the concept that these distributions vary primarily in response to the length scales over which these elements can equilibrate during garnet growth. Very short length scales of equilibration, due to low intergranular mobility, produce overprint zoning characterized by small‐scale irregularities. Higher but still restricted mobility yields diffusion‐controlled uptake, characterized by patterns of central peaks and annular maxima that vary with atomic number and are strongly influenced by T–t paths during garnet growth. Still greater mobility permits progressively greater, potentially rock‐wide, equilibration with major‐ and accessory‐phase assemblages, leading to mineralogical controls: an unchanging mineral assemblage during garnet growth produces bell‐shaped profiles resembling those produced by Rayleigh fractionation, whereas changes in major‐ and/or accessory‐phase assemblages produce profiles with distinct annuli and sharp discontinuities in concentration. The very high mobility associated with influxes of Y+REE‐bearing fluids can cause these element distributions to be dominated by factors external to the rock, yielding profiles characterized by abrupt shifts or oscillations that are not correlated to changes in mineral assemblages.  相似文献   

Using remote sensing to quantify aeolian transport and estimate the age of the terminal dune field Dunas Pampa Blanca in southern Peru     

Ralf Hesse   《Quaternary Research》2009,71(3):426-436

Aeolian dunes are widely used to reconstruct paleoenvironmental conditions. However, terminal dune fields (ergs) in the coastal desert of southern Peru – where information regarding Quaternary paleoenvironmental conditions is very limited – have until now not been used for paleoenvironmental reconstructions and the time depth of their accumulation is unknown. Here, different estimates are derived to constrain the time depth recorded in the Dunas Pampa Blanca, a terminal dune field in coastal southern Peru. Dune field age is calculated using the volume of the Dunas Pampa Blanca and (i) recent aeolian transport rate in migrating transverse dunes feeding the Dunas Pampa Blanca (derived from digital processing of sequential Landsat and Quickbird images) and (ii) limitations posed by recent fluvial sediment supply to the source of aeolian transport. The resulting maximum age estimate of 70 ± 8 ka (from aeolian transport) compares with a minimum age estimate of 4–75 ka (from sediment supply). However, a minimum age estimate of 110–450 ka is deduced from the tectonic and topographic evolution of the region. This discrepancy contradicts the hypothesis of late Quaternary stability in the Peruvian coastal desert and indicates that recent conditions of aeolian sediment supply and transport are not representative for the late Quaternary.  相似文献   

Can pyrolysis-GC/MS be used to estimate the degree of thermal alteration of black carbon?     

Joeri Kaal  Cornelia Rumpel 《Organic Geochemistry》2009,40(12):1179-1187

Very little is known about the macromolecular properties of biomass combustion residues referred to as black carbon (BC). Pyrolysis-gas chromatography–mass spectrometry (Py-GC/MS) was performed on: (i) peat from Spain at 400–1200 °C to investigate the effect of charring on pyrolysis fingerprint and (ii) natural charcoal from Laos in order to link molecular information to published chemical and reactivity parameters. Confirming earlier Py-GC/MS studies, the BC in the artificially charred peat and the natural charcoal produced predominantly benzene, toluene, C₂-benzenes, PAHs and benzonitriles. Furthermore, some charcoal samples produced significant amounts of phenols, methoxyphenols, carbohydrate markers, n-alkanes and n-alkenes upon pyrolysis, reflecting non-charred and weakly charred biomass. A series of pyrolysis product ratios related to the degree of dealkylation of the pyrolysis products (benzene/toluene, naphthalene/C₁-naphthalenes, C₁-naphthalenes/C₂-naphthalenes, benzofuran/C₁-benzofurans and benzonitrile/C₁-benzonitrile) increased with increasing artificial charring (peat) and, for the natural charcoal, these ratios were in accordance with established chemical and reactivity parameters related to charring intensity from other methods: proportion of aromatic C obtained from solid state ¹³C nuclear magnetic resonance spectroscopy (NMR), the proportion of charred material as estimated from NMR in conjunction with a molecular mixing model (NMR–MMM) and the resistance to acid dichromate oxidation. The alkyl side chains of aromatic pyrolysis products are probably inherited from short chain aliphatic C chains that cross link the predominantly aromatic building blocks of BC, and these linkages seem to disappear with increasing charring intensity. Thus, the degree of thermal alteration of BC can be discerned from the pyrolysis fragmentation pattern.  相似文献