Tropospheric methane in the mid-latitudes of the Southern Hemisphere     

P. J. Fraser  M. A. K. Khalil  R. A. Rasmussen  L. P. Steele 《Journal of Atmospheric Chemistry》1984,1(2):125-135

Results of more than 800 new measurements of methane (CH₄) concentrations in the Southern Hemisphere troposphere (34–41° S, 130–150° E) are reported. These were obtained between September 1980 and March 1983 from the surface at Cape Grim, Tasmania, through the middle (3.5–5.5 km) to the upper troposphere (7–10 km). The concentration of CH₄ increased throughout the entire troposphere over the measurement period, adding further support to the view that CH₄ concentrations are currently increasing on a global scale. For data averaged vertically through the troposphere the rate of increase found was 20 ppbv/yr or 1.3%/yr at December 1981. In the surface CH₄ data a seasonal cycle with a peak to peak amplitude of approximately 28 ppbv is seen, with the minimum concentration occurring in March and the maximum in September–October. A cycle with the same phase as that seen at the surface, but with a significantly decreased amplitude, is apparent in the mid troposphere but no cycle is detected in the upper tropospheric data. The phase and amplitude of the cycle are qualitatively in agreement with the concept that the major sink for methane is oxidation by hydroxyl radicals. Also presented is evidence of a positive vertical gradient in methane, with a suggestion that the magnitude of this gradient has changed over the period of measurements.  相似文献   

The global distribution of methane in the troposphere   总被引：6，自引：0，他引：6  

L. P. Steele  P. J. Fraser  R. A. Rasmussen  M. A. K. Khalil  T. J. Conway  A. J. Crawford  R. H. Gammon  K. A. Masarie  K. W. Thoning 《Journal of Atmospheric Chemistry》1987,5(2):125-171

Methane has been measured in air samples collected at approximately weekly intervals at 23 globally distributed sites in the NOAA/GMCC cooperative flask sampling network. Sites range in latitude from 90° S to 76° N, and at most of these we report 2 years of data beginning in early 1983. All measurements have been made by gas chromatography with a flame ionization detector at the NOAA/GMCC laboratory in Boulder, Colorado. All air samples have been referenced to a single secondary standard of methane-in-air, ensuring a high degree of internal consistency in the data. The precision of measurements is estimated from replicate determinations on each sample as 0.2%. The latitudinal distribution of methane and the seasonal variation of this distribution in the marine boundary layer has been defined in great detail, including a remarkable uniformity in background levels of methane in the Southern Hemisphere. We report for the first time the observation of a complete seasonal cycle of methane at the South Pole. A significant vertical gradient is observed between a sea level and a high altitude site in Hawaii. Globally averaged background concentrations in the marine boundary layer have been calculated for the 2 year-period May 1983–April 1985 inclusive, from which we find an average increase of 12.8 ppb per year, or 0.78% per year when referenced to the globally averaged concentration (1625 ppb) at the mid-point of this period. We present evidence that there has been a slowing down in the methane growth rate.Presented at the Conference on the Scientific Application of Baseline Observations of Atmospheric Composition (SABOAC), Aspendale, Australia, 7–9 November 1984.  相似文献   

Preface     

Gordon McBean  Erik Rasmussen 《Dynamics of Atmospheres and Oceans》1987,10(4)

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Termites and global methane—another assessment     

P. J. Fraser  R. A. Rasmussen  J. W. Creffield  J. R. French  M. A. K. Khalil 《Journal of Atmospheric Chemistry》1986,4(3):295-310

New CH₄ emission data from a number of Northern and Southern Hemispheric, tropical and temperate termites, are reported, which indicate that the annual global CH₄ source due to termites is probably less than 15 Tg. The major uncertainties in this estimate are identified and found to be substantial. Nevertheless, our results suggest that termites probably account for less than 5% of global CH₄ emissions.  相似文献   

Sources of magnetic susceptibility in a slate     

Graham Borradaile  John Mothersill  Don Tarling  Craig Alford 《Earth and Planetary Science Letters》1986,76(3-4)

Magnetic susceptibility and its anisotropy in the Borrowdale Volcanic slates at Kentmere in the English Lake District are attributed largely to preferred orientation of a paramagnetic chlorite of diabantite-ripidolite composition. In units of 10⁻⁶ cgs/g, the principal susceptibilities for the slates are 9.61; 9.42; 8.69 and for the chlorite grains the minimum anisotropy is represented by principal susceptibilities of 11.57; 11.22 and 9.15. Because the magnetic susceptibility is carried by a tightly packed, matrix-forming mineral that has recrystallised during the deformation it is not possible to imagine simple grain rotation as being responsible for the anisotropy of susceptibility.  相似文献   

GEOSECS AtlanticSi profiles     

B.L.K. Somayajulu  R. Rengarajan  D. Lal  R.F. Weiss  H. Craig 《Earth and Planetary Science Letters》1987,85(4)

Measurements of five cosmogenic³²Si vertical profiles in Atlantic waters (27°N to 60°S) are presented. The amounts of dissolved SiO₂ extracted range from 2 to 54 g; the amounts of water from which SiO₂ was extracted range between 540 kg and 270, 000 kg. In additon, SiO₂ recovered from four surface particulate composites (64°N to 61°S) were also analyzed for³²Si.³²Si measurements were made by milking and counting the daughter activity, ³²P. The net³²P activities range from 0.7 to 6.8 cph; typical errors in measurements of the³²P activities are 20–30%.The³²Si concentrations vary from 0.6 dpm/10⁶ kg of water in the North Atlantic surface waters to 235 dpm/10⁶ kg at 400 m depth in the circumpolar waters. The vertical profiles of³²Si at the five Atlantic stations approximately follow the Si profiles but the depth gradients are different. This would be expected also considering the in-situ release mechanisms due to dissolution and advection/diffusion from the bottom waters. Except for the circumpolar station 89, where the Si and³²Si profiles show the effect of marked vertical mixing (nearly depth independent profiles), the profiles show the following features: (1) specific activities of³²Si (³²Si/SiO₂ ratios) are lowest at intermediate depths, and (2) on an average the surface specific activities are higher, by 2–4 times, than the bottom water values. These data are consistent with generation of the highest specific activity³²Si waters at the surface, where Si concentrations are lowest and precipitation adds cosmogenic³²Si scavenged from the troposphere. Rapid removal of biogenic silica to the water-sediment interface, without much dissolution during transit, leads to the second regime of high³²Si specific activities.The³²Si inventories in the water column in the latitude belt 27°N-27°S are in the range (1–1.4) × 10⁻² dpm³²Si/cm², which is consistent with the expected fallout of cosmogenic³²Si. However, the³²Si column inventories south of 40°S are higher by a factor of 5–7, whereas the corresponding Si inventories increase by only a factor of 3. This excess³²Si in the Southern Ocean cannot be explained by direct fallout from the stratosphere or by melting of Antarctic snow and ice. Instead, this excess is maintained primarily by the southward deep-water transport of³²Si dissolved from sinking particulates.  相似文献   

A numerical study of the heat transfer through a fluid layer with recirculating flow between concentric and eccentric spheres     

R. M. Rasmussen  V. Levizzani  H. R. Pruppacher 《Pure and Applied Geophysics》1982,120(4):702-720

A numerical study has been made of the heat transfer through a fluid layer with recirculating flow. The outer fluid surface was assumed to be spherical, while the inner surface consisted of a sphere concentrically or eccentrically located with respect to the outer spherical surface. The recirculating flow was assumed to be driven by a gas flow creating stress on the fluid's outer surface so that creeping (low Reynolds number) flow developed in its interior. The present study solves the Stokes equation of motion and the convective diffusion equation in bispherical coordinates and presents the streamline and isotherm patterns.Nomenclature a _i inner sphere radius - a _d outer sphere radius - A ₁ defined by equation (5) - A ₂ defined by equation (6) - B ₁ defined by equation (7) - B ₂ defined by equation (8) - c dimensional factor for bispherical coordinates - C constant in equation (4) - d narrowest distance between the two eccentric spheres - E ² operator defined by equation (1) in spherical coordinates and by equation (21) in bispherical coordinates - G modified vorticity, defined in equation (22) - G ^* non-dimensional modified vorticity, defined in equation (28) - h metric coefficient of bispherical coordinate system, defined in equation (18) - k _w thermal conductivity of water - K ₁ defined by equation (9) - K ₂ defined by equation (10) - N _Re Reynolds number=2a _dU/gn - N _Pe,h Peclet number=2a _dU/ - n integer counter - q heat flux - r radius - r ^* non-dimensional radius=r/a _d - S surface area - t time - t ^* non-dimensional time=t/a _d ² - T temperature - T _o temperature at inner sphere surface - T _a temperature at outer sphere surface - T ^* non-dimensional temperature;=(T–T _o)/(T_a–T_o) - u velocity - u _r radial velocity in spherical coordinates - u angular velocity in spherical coordinates - u radial velocity in bispherical coordinates - u angular velocity in bispherical coordinates - U free stream velocity - u _r ^* =u _r/U - u ^* =u /U - u ^* =u /U - u ^* =u /U Greek symbols a ₁ small displacement - vorticity, defined in equation (17) - ^* non-dimensional vorticity, defined in equation (27) - radial bispherical coordinates - _o bispherical coordinate of inner sphere - _a bispherical coordinate of outer sphere - angular coordinate in spherical coordinates - thermal diffusivity - _w thermal diffusivity of water - kinematic viscosity - angular bispherical coordinate - spherical coordinate - streamfunction - non-dimensional streamfunction for spherical coordinates, = /(U a _d ² ) - ^* non-dimensional streamfunction for bispherical coordinates, defined in equation (26)  相似文献   

Helium isotopes and mantle volatiles in Loihi Seamount and Hawaiian Island basalts and xenoliths     

W. Rison  H. Craig 《Earth and Planetary Science Letters》1983

We examine in this paper the use of helium isotope ratios for the study of hotspot volcanism along age-progressive island volcanic chains. The Hawaiian Islands are the original “high ³He” hotspot, with ³He/⁴He ratios as high as 32 × the atmospheric ratio; in the Pacific they stand out against the surrounding sea of MORB (rather uniformly 8 × atmospheric) which fills the entire Pacific with the exception of the Macdonald-Mehetia-Samoa axis in the South Pacific. The recent availability of a variety of alkalic and tholeiitic glasses from the U.S. Geological Survey and our own dredge hauls has prompted us to look first at isotopic variability within a single fresh and new volcano which is probably sitting directly atop a mantle plume. Thus we have looked in some detail at the total helium in glass pillow rims, at He in the enclosed vesicles, and at He in the glass itself, in both tholeiitic and alkalic lavas, and also at helium in associated phenocrysts and xenoliths. The measured ³He/⁴He ratios range from atmospheric to 30 × atmospheric, but we see clear evidence that the highly vesiculated lavas suffer exchange of He between the thin glass walls of vesicles and ambient seawater, so that we observe a post-eruptive isotopic disequilibrium between glass and gas phases. The primary effect is the very large loss of initial He content during eruptive vesiculation, which results in quite large isotopic effects from small additions of ambient He (of the order of 0.02 μcc He per gram of basalt; corresponding to a “water/rock ratio” of 0.5). Phenocrystic He in olivines verifies that the gas-phase He is not affected by vesicularities up to about 5%. Alkali basalt He appears to be independent of vesicularity up to values as high as 35%; this He is somewhat lower in ³He/⁴He ratio, but matches precisely the associated xenolithic He. However, from the present data we cannot exclude the possibility that diffusive exchange with seawater has affected the He ratio in alkalic vesicles.On the large scale, along the 10% of the Hawaiian chain available for subaerial sampling, we find high ³He/⁴He ratios (24 × atmospheric) in 5.5 × 10⁶-year-old lavas on Kauai. Maximum values of the ratio so far observed are in the pre-erosional Kula basalts on Maui, confirming the previous results of Kaneoka and Takaoka. Hawaii, where these high values were first observed is now seen to range from MORB ratios at Mauna Loa to only 15 × R_A at Kilauea fumaroles. Most xenolithic He so far measured is MORB He, but Loihi xenoliths have high values and are quite different in this respect. Finally, we discuss also the hydrogen and carbon isotope results on Loihi lavas, and show that these elements resemble MORB and appear not to show a distinctive plume signature.  相似文献   

²¹⁰Pb in the Pacific: the GEOSECS measurements of particulate and dissolved concentrations     

Y. Chung  H. Craig 《Earth and Planetary Science Letters》1983,65(2):406-432

We report here on particulate and dissolved²¹⁰Pb profiles at 16 stations, and on total²¹⁰Pb profiles at 3 stations, all occupied during the Pacific GEOSECS expedition. Comparison with measurements at Yale on GEOSECS library samples indicates that during separation of particulate lead from dissolved lead, our filtered water samples suffered some loss of²¹⁰Pb in the filtration system; this effect appears to have reduced the dissolved²¹⁰Pb activities by ～ 20% in stations where the water was filtered. However, for these first Pacific data on the²¹⁰Pb distribution between the two phases, this effect does not significantly interfere with our recognition of the major features of both particulate and dissolved²¹⁰Pb distributions.The dissolved²¹⁰Pb profiles in general vary geographically, following the²²⁶Ra profiles. In deep water,²²⁶Ra increases northward and eastward from the southwest Pacific, from ～ 22dpm/100kg, to over 40 dpm/100 kg in the northeast Pacific. Our dissolved²¹⁰Pb profiles show a similar increase in deep water, varying from about 10 to 20 dpm/100 kg along this line, and are commonly characterized by a mid-depth maximum. This²¹⁰Pb maximum reflects the mid-depth²²⁶Ra maximum of the Pacific Deep Water observed along the western boundary current.In surface water at low latitudes there is a significant²¹⁰Pb flux from the atmosphere, which produces a²¹⁰Pb/²²⁶Ra activity ratio generally greater than unity. This flux penetrates as deep as 600 m, as indicated by an “induced”²¹⁰Pb minimum caused by the surface maximum. The surface water²¹⁰Pb excess decreases toward high southern latitudes and vanishes in the Circumpolar region.The particulate²¹⁰Pb profiles show a general increase with depth, from ～ 0.3dpm/100kg in subsurface water to ～ 1.5dpm/100kg in bottom water, with or without a mid-depth maximum that reflects the²²⁶Ra or dissolved²¹⁰Pb maximum. The particulate²¹⁰Pb normally comprises about 2% of the total²¹⁰Pb in subsurface water, and this fraction increases to about 10% near the bottom. As the filtration loss is not taken into account, the fraction of particulate²¹⁰Pb quoted here is an upper limit. Since the particulate matter concentrations are quite uniform in the water column below a few hundred meters, the²¹⁰Pb activity of the particulate matter also increases with depth. The particulate matter has a²¹⁰Pb concentration of ～ 100dpm/g in subsurface water, but the concentration increases to ～ 500dpm/g or more toward the bottom. This indicates that there is a cumulative adsorption of Pb onto the suspended particles as they are sinking through the water column.  相似文献   

Total mercury,methyl mercury and sulphide in river carron sediments     

P.J. Craig  P.A. Moreton 《Marine pollution bulletin》1983,14(11):408-411

Total mercury, methyl mercury and sulphide contents of River Carron sediments (Lothian, Scotland) have been determined. Total mercury concentrations are comparable to other mercury polluted estuaries in the UK, but the methyl mercury values for low-sulphide Carron sediments are generally higher. It has been found that methyl mercury levels are initially in direct proportion to the sulphide concentrations of the sediments but beyond sulphide concentrations of 1.8 mg g^?1 the methyl mercury levels decline sharply.  相似文献