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21.
PCBs were analysed in surficial sediments and selected sediment cores collected between 2002 and 2008 in Central Vietnam coastal lagoons. The aim was to determine contamination levels and trends, and to evaluate the effects of anthropogenic pressures and natural events. Samples were mostly fine-grained with low total PCB concentrations (0.367-44.7 μg kg−1). Atmospheric transport and post depositional processes modify to some degree the fingerprint of PCB inputs to the environment favouring the predominance of 3, 4 and 5 chlorinated congeners. The similarity of congener distributions in contemporary surficial samples also suggests the presence of a unique source over the entire study area, probably connected to mobilisation and long range transports from land-based stocks. The removal of consistent sediment layers is hypothesised based on repeated samplings of the same area. Natural meteorological events (such as typhoons) are suspected to be responsible for these sediment losses.  相似文献   
22.
Perfluorinated compounds (PFCs) have emerged as significant global environmental pollutants with persistent, bioaccumulative and toxic properties. The aim of this study was to determine the occurrence of PFCs in water (wastewater, submarine emissaries and port-waters), sediment and transplanted mussels in estuarine areas of high urban and industrial impact from Northern Spain. Five PFCs of industrial use were studied: perfluorooctanesulfonate, perfluorohexanesulfonate, perfluorobutanesulfonate, perfluorooctanoate acid and perfluorononanoate acid. After selective extraction, samples were analyzed by Ultra Performance Liquid Chromatography coupled to tandem mass spectrometry. ΣPFCs ranged from 0.06 to 10.9 ng/L in water, with higher levels in wastewater treatment plants effluents and port waters than in submarine emissaries. Little accumulation was observed in sediments and mussels with ΣPFCs ranging from 0.01-0.13 ng/g dw and 0.01-0.06 ng/g ww, respectively. Most ubiquitous compounds were PFOS and PFOA. Mass fluxes of PFCs to the Cantabrian Sea are estimated and the impact to the coastal ecosystem is discussed.  相似文献   
23.
As a result of their morphological complexity, large macroalgae show intra-thallus variations in their nutritional composition and secondary metabolite content, which influences the trophic ecology of herbivorous invertebrates, and ultimately their fitness. In this study, we evaluated for the first time the variability in nutritional quality (protein content, carbohydrates, lipids, and total organic matter), secondary metabolites (phlorotannins), and structure (shape and toughness) between blades and stipes of the macroalgae Durvillaea Antarctica. Specifically, we looked at their effect on feeding preference, rate of consumption, absorption efficiency, and growth rate of the amphipod Orchestoidea tuberculata, one of the most abundant organisms on Chilean sandy beaches. Proteins, carbohydrates, total organic matter and phlorotannin contents were significantly higher in blades than in stipes. Preference experiments revealed that the amphipods preferred blades when fresh pieces of blades and stipes were offered at the same time. Similar results were found when artificial food (in which structures of both parts of the alga were standardized) was offered, suggesting that shape and toughness of the two different parts of the alga did not influence preference patterns of O. tuberculata. Absorption efficiency of O. tuberculata was higher on blades compared to stipes. When the amphipods were kept with each of the algal parts separately (i.e. no choice), they consumed a significantly higher amount of stipe, which suggests that O. tuberculata used food quantity to compensate for the lower nutritional quality of stipes. The higher nutritional values of blades compared to stipes appears to explain observed preference patterns by O. tuberculata. Phlorotannin content did not appear to inhibit blade consumption, suggesting that the nutritional quality of the food could be more important than chemical defense in determining food choice in O. tuberculata. Growth did not differ between the amphipods maintained with either blades or stipes (i.e. no choice), which is consistent with the hypothesis of compensatory feeding. To conclude, O. tuberculata can actively select specific parts of an alga and this selection appears to be based on nutritional quality. The capacity for using different feeding strategies allow O. tuberculata, in some cases, to successfully exploit food types with different nutritional qualities.  相似文献   
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We studied the occurrence of large high frequency temperature fluctuations and their potential association with settlement of intertidal invertebrates during the spring/summer period 1999/2000 at Las Cruces, on the coast of central Chile. Our results showed the existence of internal tidal bores, characterized by sharp drops in water temperature at the surface and near the bottom, and subsequent temperature increases, which occurred with a semidiurnal periodicity. Measured currents support the hypothesis of alternating onshore and offshore movement of warm-water fronts. The frequency of the events varied through the summer and their amplitude seems to be modulated by onshore winds. The strongest events were observed when strong onshore winds occurred in late afternoon hours and the entire water column showed a semidiurnal temperature signal. Highest values of chlorophyll concentration in the intertidal zone and daily settlement of bivalves, gastropods and crustaceans were observed at times when conditions were favorable for occurrence of internal tidal bores. Results suggest that internal tidal bore warm fronts could play an important role in the transport of neustonic larval invertebrates and the delivery of phytoplankton to at least some intertidal sites along the coast of Chile.  相似文献   
27.
In the present study, the dynamic response of a coupled SPM-feeder-cage system under irregular waves and shear currents is analyzed. A numerical model is developed by using the commercial software Orca Flex. Hydrodynamics coefficients of the vessel are calculated by using a 3D diffraction/radiation panel program. First- and second-order wave forces are included in the calculations. Morison equation is used to compute the drag force on line elements representing the net. Drag coefficients are determined at every time step in the simulation considering the relative normal velocity between the structural elements and the fluid flow. The dynamic response of the coupled system is analyzed for various environments and net materials. The results of the study show the effects of solidity ratio of the net and vertical positions of the cage on the overall dynamic response of the system, confirming the viability of this type of configuration for future development of offshore aquaculture in deep waters.  相似文献   
28.
The use of groundwater as water supply has increased dramatically in Santiago, Chile, during the last decades, and there is a need for accurately estimating the actual groundwater supply capacity in the upper Santiago Valley aquifer. The behavior of this aquifer was studied in order to determine the availability of water and the long-range sustainable extraction rate.Water-table depths were simulated using a numerical model with information on recharge from the last 48 years under different extraction policies. With this series of groundwater level data, groundwater level probability distribution functions were determined and extraction statistics were estimated by fitting time series models and by using the crossing theory. With this information, it has been possible to calculate the risk of being unable to supply groundwater demand because the results verify that only 67% of the water rights granted are able to be extracted on a sustained basis with a 90% exceedance probability. Furthermore, the results obtained demonstrate that the method is adequate for determining exceedance probabilities of groundwater flow.
Resumen El uso de las aguas subterráneas como fuente de abastecimiento se ha incrementado enormemente en Santiago de Chile durante las últimas décadas, por lo que se necesita estimar de forma adecuada la capacidad actual de suministro del acuífero superior del Valle de Santiago. Se ha estudiado el comportamiento de este acuífero para determinar la disponibilidad de recursos y la tasa de extracción sustentable a largo plazo.Se ha simulado los niveles freáticos del acuífero utilizando un modelo numérico con información de la recarga en los últimos 48 años bajo diferentes regímenes de extracción. Con esta serie de datos de los niveles en el acuífero, se ha determinado la distribución de probabilidad de los niveles de las aguas subterráneas y se ha estimado las estadísticas de las extracciones mediante el ajuste de modelos de series temporales y la teoría de cruce. Con esta información, se ha podido calcular el riego de no satisfacer la demanda de abastecimiento, puesto que los resultados verifican que sólo se podría extraer el 67% de las concesiones de agua existentes de manera sustentable con un 90% de probabilidad de excedencia. Aún más, los resultados obtenidos demuestran que el método es adecuado para determinar las probabilidades de excedencia del flujo de las aguas subterráneas.

Resumé Lutilisation de leau souterraine pour leau potable sest considérablement accrue à Santiago (Chili) au cours des derniers lustres; cest pourquoi il est maintenant nécessaire destimer avec précision la capacité réelle dalimentation de la nappe de laquifère supérieur de la vallée de Santiago. Le fonctionnement de cet aquifère a été étudié afin de déterminer la disponibilité en eau et le taux dextraction durable à long terme.Les niveaux de la nappe ont été simulés avec un modèle numérique à partir dinformation sur la recharge au cours des 48 dernières années pour différentes politiques dextraction. A partir de cette série de données piézométriques, des fonctions de distribution de probabilité des niveaux de la nappe ont été déterminées et des statistiques dextraction ont été estimées par ajustement de modèles de séries chronologiques en utilisant la théorie du croisement. Avec ces informations, il a été possible de calculer le risque de ne pas pouvoir satisfaire la demande deau souterraine, puisque les résultats vérifient que seulement 67% des droits deau attribués peuvent être extraits sur une base durable avec une probabilité de dépassement de 90%. En outre, les résultats obtenus démontrent que la méthode est adaptée à la détermination des probabilités de dépassement de lécoulement souterrain.
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29.
This work presents the preliminary results of the first field calibration campaign performed in the Atacama Desert, Chile, between the 18 and 22 August 2014, called the Atacama Field Campaign (ATAFIC 2014). In situ measurements were performed in order to spectrally characterize the surface reflectance spectra between 0.3 and 2.5?µm, radiometric temperature (8.0–14.0?µm) and atmospheric measurements. A soil sample was collected and analyzed using Fourier Transform Infrared Spectroscopy and X-Ray Diffraction techniques to characterize the surface reflectance spectra and mineralogical composition, respectively. ASTER land surface emissivity in addition to GOES, MODIS and Landsat-8 land surface temperature (LST) were also used. Results showed that the spectral features of the Atacama soil and the characteristics of this geographical zone, which is featured as the most hyper-arid and cloudless place in the world, make this area a potential target for surface reflectance characterization. Day and night LST comparison between field and remote sensing data are lower than 2?K and the Root Mean Square Error for land surface emissivity is close to 2%. This work opens the possibilities to consider the Atacama Desert as a reference target for calibration and validation activities for earth observation missions’ purposes.  相似文献   
30.
Natural Hazards - Empirical relationships between MSK macroseismic intensity and several engineering ground motion parameters are developed using the macroseismic and instrumental data available...  相似文献   
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