Mineralogical and chemical evolution of ochreous precipitates from the Libiola Fe–Cu-sulfide mine (Eastern Liguria,Italy)     

Pietro Marescotti  Cristina Carbone  Paola Comodi  Francesco Frondini  Gabriella Lucchetti 《Applied Geochemistry》2012

The mineralogical and chemical evolution of ochreous precipitates forming from acid mine drainage (AMD) from the abandoned Libiola Fe–Cu-sulfide mine (Eastern Liguria, Italy) was followed through a multianalytical approach (XRD, TEM, XRF, ICP) applied to surface precipitates and associated waters collected from several mine adits. The mineralogy of the precipitates changed significantly as a consequence of the variations of the chemical parameters of the circulating solutions (mainly pH, Eh, and sulfate concentrations) which, in turn, were mainly controlled by mixing with unpolluted stream and rill waters of the mining area. A progressive transition from jarosite-, to schwertmannite-, to goethite-, to ferrihydrite-, to amorphous-dominated precipitates was observed, mainly as a consequence of an increase in the pH of the associated solutions. This mineralogical evolution agrees well with the aqueous speciation and Eh–pH stability calculations performed on the waters associated with the different precipitate types. Furthermore, TEM analysis indicated that metastable pristine phases (schwertmannite) tend to transform progressively to well-crystallized more stable species, here represented by goethite. The comparison of the water chemistry and the crystal chemistry of the different precipitates showed a significant decrease in the Zn, Cu, Ni, Co contents in waters where the coexisting precipitates were almost exclusively composed of goethite. The distribution of V, Sr, As concentrations within the different precipitates showed that the most efficient scavenging phase for these elements was jarosite, whereas ferrihydrite efficiently took up Pb ions, and schwermannite acted as a natural sink for Cr.  相似文献   

http://www.sciencedirect.com/science/article/pii/S1674987112000837   总被引：1，自引：1，他引：0  

Julio Cezar Mendes  Cristina M.P.De Campos 《地学前缘(英文版)》2012,3(6):789-800

The Venda Nova Pluton(VNP) is a zoned ring structure emplaced in the southern portion of the Neoproterozoic Aracuai Belt,in Espirito Santo.Brazil.It is a slightly westward tilted cylinder-like intrusion,with an almost circular horizontal section.In the center of this structure,an off-centered gabbro-noritic core,surrounded by syeno-monzonitic rocks,intrudes an outer ring of charnockites and norite.These envelop the syeno-monzonitic and gabbro-noritic center,as a narrow discontinuous belt. While,in the core intrusion,mingling and mixing processes are widespread and well documented in the literature,in the outer ring,the norite and charnockite layers show predominantly homogeneous and isotropic internal structures.Nevertheless,smaller interaction zones between charnockites and norite denote a comparatively more restricted mingling process.The norite is a fine-grained rock with hypidiomorphic granular to intergranular texture.The charnockites are medium-grained and made up of: (a) orthopyroxene-tonalite.(b) orthopyroxene-quartz-diorite,and(c) orthopyroxene-granodiorite with hypidiomorphic granular to porphyritic textures.In all lithotypes both ortho- and clinopyroxene are replaced by hornblende and biotite.Two contrasting compositional sequences have been recognized,based on whole rock geochemistry:(1) a basic,with tholeiitic affinities(norite) and,(2) an intermediate. medium-K calc-alkaline,comprising the charnockites.Estimated crystallization temperatures,which have been calculated from micro-probe analysis of pyroxenes,range from 915±25℃to 960±50℃.Re-equilibration temperature(ilmenite-magnetite calibration) is around 600±50℃.This indicates oxygen fugacities four order of magnitude below the FMQ-buffer and a reduced environment. Coeval pressure conditions estimated from the Al-content in hornblende range from 5.5±0.6 kbar.Data obtained for the norite point toward an evolution from the partial melting of an anhydrous tholeiitic mantle magma.The charnockites may correspond to the differentiation of a calc-alkaline parental magma.The later could be the hybrid product from the contamination and mixing between the anhydrous tholeiitic magma with other deeper crustal sources.Further the magmatic system evolved through fractionation of orthopyroxene.clinopyroxene.plagioclase and ilmenite.Our results support the hypothesis for the evolution of the Venda Nova Pluton through a mantle-crust delamination process probably related to the collapse of the Aracuai orogeny.  相似文献   

Accelerated erosion in a watershed in the southeastern region of Brazil     

Mariana Dorici  Carlos Wilmer Costa  Mayra Cristina Prado de Moraes  Fabiola Geovanna Piga  Reinaldo Lorandi  José Augusto de Lollo  Luiz Eduardo Moschini 《Environmental Earth Sciences》2016,75(19):1301

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Statistical and spatial analysis of landslide susceptibility maps with different classification systems     

Cristina Baeza  Nieves Lantada  Samuel Amorim 《Environmental Earth Sciences》2016,75(19):1318

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A unified assessment of marine Mediterranean assemblages: a lesson from benthic hydroids          下载免费PDF全文

Manuel M. González‐Duarte  Cesar Megina  Doris De Vito  Cristina Goia Di Camillo  Stefania Puce  Stefano Piraino 《Marine Ecology》2016,37(1):155-163

Hydroids are important components of the communities of rocky bottom shallow coastal areas. The hydrozoan fauna of the Mediterranean Sea is probably one of most investigated in the world, with lots of faunistic and biogeographical studies. However, quantitative studies using the same sampling methodology and controlled sampling effort have been restricted to areas in the Western and Central Mediterranean. We compared hydroid assemblages in four areas of the Mediterranean Sea, from the Gulf of Cádiz to the South Adriatic Sea, following the same sampling and quantification methodology. Our analysis showed the dominant Atlantic character of the assemblages of the Gulf of Cádiz and the South Alboran Sea because of the influence of the inflowing Atlantic waters. Conversely, the hydroid assemblages of the North Alboran Sea were more similar to the assemblages in the Ligurian and in the South Adriatic, and with a number of species ranking between the observed in these two Mediterranean zones. Fourteen species were identified as making the most significant contributions to characterizing the Mediterranean hydroid species pool from a quantitative point of view. These taxa include species previously named as typical components of the Mediterranean hydroid fauna as well as those only recently recorded in the region (Eudendrium moulouyensis) and invaders such as Clytia hummelincki.  相似文献   

Influence of friction on erosion and accretion processes in the Yavaros Bay,Gulf of California     

Noel Carbajal  Juan A. Dworak  Yovani Montaño-Ley  Cristina Noyola-Medrano 《Environmental Earth Sciences》2014,72(2):429-440

A two-dimensional, vertically integrated, nonlinear numerical model was applied to investigate the tide-driven bed load transport of sediments and morphodynamics in the shallow coastal lagoon of Yavaros, located in the southeastern part of the Gulf of California, Mexico. Satellite imagery exposes strong sediment dynamics in this coastal region. The dynamics in the lagoon were forced by 13 tidal constituents at the open boundary. Tides are of a mixed character and they are predominantly semidiurnal. The calculations showed areas of intense tidal currents and considerable water exchange with the Gulf of California. Numerical experiments revealed an ebb-dominant tidal distortion and a net export of sediment from the lagoon to the Gulf of California. A simulation of 20 years showed that the lagoon exported about 1,600 m³ of sediment; however, the daily oscillating exchange of sediment reached values of around 8 m³. The daily averaged flux of export–import sediments oscillates principally with semiannual, monthly and fortnightly periods. By applying a threshold velocity, a variable friction coefficient and the calculated amplitude of tidal velocities, it was possible to determine that morphological changes occur in zones of sharp topographic gradients and to explain the effect of friction on the export–import process of sediments. A 10-year simulation revealed that accumulation of sediment (~20 cm) occurred in small areas, whereas erosion occurred in larger areas but with less intensity (~8 cm). Besides the importance for the morphodynamics, these kinds of erosion–accretion processes may be relevant for the marine ecology.  相似文献   

Ordinary chondrite-like colors in small Koronis family members     

Andrew S. Rivkin  Cristina A. Thomas  David E. Trilling  Marie-therese Enga  Jennifer A. Grier 《Icarus》2011,211(2):1294-1297

A survey of small (<5-10 km diameter) members of the Koronis family shows some objects with visible-wavelength broadband colors consistent with membership in the Q-class (Tholen, D.J. [1984]. Asteroid taxonomy from cluster analysis of photometry. Ph.D. Dissertation, University of Arizona, Tucson, AZ; Bus, S.J., Binzel, R.P. [2002]. Icarus 158, 146-177). This agrees with an ordinary chondritic composition for this family and suggests the timescale for changing Q-class to S-class spectra in the main belt is roughly comparable to the regolith refresh time in the 2-5 km size range.  相似文献   

Validation and evaluation of two multivariate statistical models for predictive shallow landslide susceptibility mapping of the Eastern Pyrenees (Spain)   总被引：2，自引：2，他引：0  

Cristina Baeza  Nieves Lantada  Jose Moya 《Environmental Earth Sciences》2010,61(3):507-523

This paper deals with the quality of two multivariate statistical models based on the Geographical Information System for shallow landslide susceptibility assessment in a test area at La Pobla de Lillet (Eastern Pyrenees, Spain). The quality, which was guaranteed by a rigorous methodology based on a suitable diagnosis, validation, and evaluation of the models, ensured a reliable contrast of the final susceptibility maps. This enables us to transfer the best results to the end user. Landslide susceptibility models were carried out by logistic regression and discriminant analysis of the significant conditioning factors related to the characteristics of the slope and the upslope contributing area captured from the digital elevation model and landslide distribution. The explanatory variables were tested (KS test, principal components and one-way and T-test) to select the most statistically significant ones before being introduced into the logistic and discriminant analyses. Accuracy statistics and the receiver operating characteristic curve used for diagnosis and validation showed similar prediction skills and a good fit to the data with more than 85% of unfailed cells properly classified for the two models. The evaluation of the study area and the correlation function (R ² = 0.83) between the models revealed that the discriminant model overestimated the susceptibility of the most stable zones with respect to the logistic model. Different methods of producing susceptibility maps showed marked differences in matching the models. Substantial spatial agreement (Kappa = 0.741) between binary maps produced by the standard cut-off value descended moderately (Kappa = 0.540) as a result of superimposing maps with five susceptibility levels defined by landslide percentage. Despite the fact that the two statistical models are similar in assessing susceptibility in the study area, the implications for hazard and risk management can be different because of the conservative nature of the discriminant model.  相似文献   

Lateglacial and Holocene palaeoenvironments at Sierra La Madera,northwestern Mexico: Sharp signals of Younger Dryas and North American monsoon     

Carlos Alberto Galaz-Samaniego  M. Cristina Peñalba  Francisco Abraham Paz-Moreno  Iván Rosario Espinoza-Encinas  Kinardo Flores-Castro  Rogelio Monreal  Carlos Lizárraga-Celaya 《第四纪科学杂志》2023,38(1):76-91

During the last glacial termination, the climate system experienced intense global variations whose causes and impacts are not fully defined, particularly for low latitudes. The northwestern Mexico Sky Islands present a climate-sensitive ideal setting to record palaeoecological and palaeoclimatic changes due to their physiographic complexity and location in the ecotone between temperate and tropical ecosystems. High-resolution pollen analysis and a detailed sedimentological study were conducted at the Ciénega Tonibabi tropical thorn scrub site. The 15 540–0 cal a bp nearly continuous record shows that the North Atlantic Ocean did have a cold and humid climatic influence during the glacial stages of the end of the Pleistocene, including a sharp pulse during the Younger Dryas. However, a shift to the Pacific Ocean influence occurred during the Holocene, which led to the development of the El Niño conditions prevailing today. Colder and warmer phases follow one another with higher or lower winter precipitation, including a sharp Bølling–Allerød and development and intensification of the North American monsoon. They are reflected in hydrological changes as well as in the advances, retreats and intermingling of coniferous forests and tropical thorn scrub.  相似文献