DMSP and DMS in coastal fast ice and under-ice water of Lützow-Holm Bay, eastern Antarctica     

Daiki Nomura  Nobue Kasamatsu  Kazu TateyamaSakae Kudoh  Mitsuo Fukuchi 《Continental Shelf Research》2011,31(13):1377-1383

The combined concentration of total dimethylsulfoniopropionate and dimethylsulfide (DMSP+DMS) were measured in Antarctic fast ice on the coast of Lützow-Holm Bay, eastern Antarctica. High bulk-ice DMSP+DMS and chlorophyll a concentrations were found at the bottom of the sea ice, and these concentrations were higher than those in the under-ice water. The bulk-ice DMSP+DMS and chlorophyll a concentrations were highly correlated (r²=0.68, P<0.001), suggesting that the high bulk-ice DMSP+DMS concentrations were caused mainly by the presence of algae assemblages in the ice. The calculated brine DMSP+DMS concentrations were as high as 1100 nM in the bottom ice layer, and the vertical profile patterns of brine DMSP+DMS concentrations were almost the same as for the bulk ice, mainly because of the small amount of variability in the vertical brine volume fraction. DMSP+DMS and chlorophyll a concentrations in the under-ice water increased, whereas the salinity of the under-ice water decreased, during the sampling period. These results reflect the supply of freshwater containing high levels of DMSP+DMS to the water just under the ice as the ice melted. These results suggest that sea-ice melting could be important to sulfur cycling in coastal ice-covered regions of the polar oceans.  相似文献   

Flux of low salinity water from Aniva Bay (Sakhalin Island) to the southern Okhotsk Sea     

Sachiko Oguma  Tsuneo Ono  Yutaka W. Watanabe  Hiromi Kasai  Shuichi Watanabe  Daiki Nomura  Humio Mitsudera 《Estuarine, Coastal and Shelf Science》2011

In this study, we examined the relationship between the low salinity water in the shelf region of the southern Okhotsk Sea which was seasonally sampled (0–200 m), and fluxes of low salinity water from Aniva Bay. To express the source of freshwater mixing in the surface layer, we applied normalized total alkalinity (NTA) and stable isotopes of seawater as chemical tracers. NTA-S diagrams indicate that NTA of low salinity water in the upper 30 m layer just off the Soya Warm Current is clearly higher than in the far offshore region in summer and autumn. Using NTA-S regression lines, we could deduce that the low salinity and high NTA water in the upper layer originates from Aniva Bay. For convenience, we defined this water as the Aniva Surface Water (ASW) with values S < 32, NTA > 2450 μmol kg⁻¹. Formation and transport processes of ASW are discussed using historical data. The interaction between the maximum core of high NTA water on the bottom slope of eastern Aniva Bay and an anticyclonic eddy at the mouth of Aniva Bay are concluded to control ASW formation. Upwelling of the Cold Water Belt water at the tip of Cape Krillion is considered to cause ASW outflow from Aniva Bay.  相似文献   

Geologic age of the lower Josoji Formation,Shimane Peninsula,Southwest Honshu,Japan: Implications for an abrupt change to deep-water during the earlier opening stage of the Japan Sea     

Ritsuo Nomura 《Island Arc》2021,30(1):e12421

The lower part of the Josoji Formation, Shimane Peninsula, contains clues for figuring out changes in deep-water characteristics during the opening of the Japan Sea. The foraminiferal assemblage includes early to middle Miocene biostratigraphic index taxa such as planktonic foraminiferal Globorotalia zealandica and Globorotaloides suteri. The occurrence of these two species, together with the absence of praeorbulinids, suggests that the lower part of the Josoji Formation is assigned to the top of planktonic foraminiferal Zone N7/M4 (16.39 Ma). The benthic foraminiferal assemblage, which is characterized by Cyclammina cancellata and Martinottiella communis, clearly suggests that the lower Josoji Formation was deposited at bathyal depths, and that it developed in association with the abrupt appearance of deep-sea calcareous forms. Such bathyal taxa are the main constituents of the Spirosigmoilinella compressa–Globobulimina auriculata Zone of the Josoji Formation and also of the Gyrodina–Gyroidinoides Zone at Ocean Drilling Program Site 797 in the Japan Sea. The base of these benthic foraminiferal zones can be correlated with the base of the nannofossil Sphenolithus heteromorphus Base Zone (= CNM6/CN3); thus, its estimated age is 17.65 Ma. This biostratigraphic information suggests that the lower Josoji Formation was deposited from shortly before 17.65–16.39 Ma in upper limit age. Evidence that fresh to brackish and shallow-water basins formed in the rifting interval of 20–18 Ma in the Japan Sea borderland suggests that the abrupt appearance of deep-sea calcareous foraminifera occurred about 1 my earlier in this area than in other sedimentary basins and suggests that a significant paleoceanographic change occurred in the proto-Japan Sea at 17.65 Ma.  相似文献   

Rapid physically driven inversion of the air–sea ice CO₂ flux in the seasonal landfast ice off Barrow,Alaska after onset of surface melt     

Daiki Nomura  Hajo Eicken  Rolf Gradinger  Kunio Shirasawa 《Continental Shelf Research》2010

The air–sea ice CO₂ flux was measured over landfast sea ice in the Chukchi Sea, off Barrow, Alaska in late May 2008 with a chamber technique. The ice cover transitioned from a cold early spring to a warm late spring state, with an increase in air temperature and incipient surface melt. During melt, brine salinity and brine dissolved inorganic carbon concentration (DIC) decreased from 67.3 to 18.7 and 3977.6 to 1163.5 μmol kg⁻¹, respectively. In contrast, the salinity and DIC of under-ice water at depths of 3 and 5 m below the ice surface remained almost constant with average values of 32.4±0.3 (standard deviation) and 2163.1±16.8 μmol kg⁻¹, respectively. The air–sea ice CO₂ flux decreased from +0.7 to −1.0 mmol m⁻² day⁻¹ (where a positive value indicates CO₂ being released to the atmosphere from the ice surface). During this early to late spring transition, brought on by surface melt, sea ice shifted from a source to a sink for atmospheric CO₂, with a rapid decrease of brine DIC likely associated with a decrease in the partial pressure of CO₂ of brine from a supersaturated to an undersaturated state compared to the atmosphere. Formation of superimposed ice coincident with melt was not sufficient to shut down ice–air gas exchange.  相似文献   

Linkage of deep sea rapid acidification process and extinction of benthic foraminifera in the deep sea at the Paleocene/Eocene transition          下载免费PDF全文

Hodaka Kawahata  Ritsuo Nomura  Katsumi Matsumoto  Hiroshi Nishi 《Island Arc》2015,24(3):301-316

Ocean Drilling Program Leg 199 Site 1220 provides a continuous sedimentary section across the Paleocene/Eocene (P/E) transition in the carbonate‐bearing sediments on 56–57 Ma oceanic crust. The large negative δ¹³C shift in seawater is likely due to the disintegration of methane hydrate, which is expected to be rapidly changed to carbon dioxide in the atmosphere and well‐oxygenated seawater, leading to a reduction in deep‐sea pH. A pH decrease was very likely responsible for the emergence of agglutinated foraminiferal fauna as calcareous fauna was eliminated by acidification at the P/E transition at Site 1220. The absence of the more resistant calcareous benthic foraminifera and the presence of the planktonic foraminifera at Site 1220 is interesting and unique, which indicates that calcareous benthic foraminifera suffered greatly from living on the seafloor. Box model calculation demonstrates that, assuming the same mean alkalinity as today, pCO₂ must increase from 280 ppm to about 410 ppm for the calcite undersaturation in the deep ocean and for the oversaturation in the surface ocean during the P/E transition. The calculated increased pCO₂ coincides with paleo‐botanical evidence. The current global emission rate (～7.3 peta (10¹⁵) gC/y) of anthropogenic carbon input is approximately 30 times of the estimate at the P/E transition. The results at the P/E transition give an implication that the deep sea benthic fauna will be threatened in future in combination with ocean acidification, increased sea surface temperature and more stratified surface water.  相似文献   

Two-dimensional models of proto planetary disk chemistry     

T.J. Millar  H. Nomura  A.J. Markwick 《Astrophysics and Space Science》2003,285(3-4):761-768

We have developed a two-dimensional model of a flared protoplanetary disk (PPD) incorporating a self-consistent treatment of gas and dust temperature, and a detailed treatment of the gas-phase chemistry as well as the freeze-out and desorption of material from dust grains. The results show that, in the inner 10 AU of the disk, the gas-phase abundances are dominated by material evaporated from dust grains. The surface layer of the disk shows many of the characteristics of photon-dominated regions. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Study of ionospheric disturbances during solar flare events using the SuperDARN Hokkaido radar     

Daiki Watanabe  Nozomu Nishitani 《极地研究(英文版)》2013,24(1)

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Eutrophication-induced changes in Lake Nakaumi,southwest Japan     

Kota Katsuki  Yasushi Miyamoto  Kazuyoshi Yamada  Hiroyuki Takata  Keiko Yamaguchi  Daisuke Nakayama  Hugo Coops  Hidenobu Kunii  Ritsuo Nomura  Boo-Keun Khim 《Journal of Paleolimnology》2008,40(4):1115-1125

Lake Nakaumi, southwest Japan, is an enclosed lagoon characterized by polyhaline and halocline conditions. Since the last century, its ecological state has been altered by eutrophication. We used a paleolimnological approach and studied multiple proxies, including chemical compounds, diatoms, foraminifera and molluscs, to infer the eutrophication history of the ecosystem. Eutrophication in Lake Nakaumi was associated with several factors, including increased nutrient loading, input of herbicides, and dike building since the 1920s. The ecological condition of this lake was divided into several stages that reflect the eutrophication process after the 1940s. A catastrophic “regime shift” from a clear state with aquatic vegetation to a turbid one with phytoplankton occurred in the early 1950s. Environmental degradation in the Honjo area, a part of Lake Nakaumi, was attributed primarily to physical changes caused by the construction of an enclosing dike. Eutrophication occurred almost simultaneously with the physical changes to the Honjo area in the 1970s. Until recently, no regime shift was observed in this area, though the core-top sediments show possible symptoms of incipient change.  相似文献   

Alteration of the equal settling ratio of fine particles by vertically-oscillating water     

Tatsuya Oki  Mikio Kobayashi  Shuji Owada  Daiki Matsuura 《International Journal of Mineral Processing》2007

An equal settling ratio is an important factor in estimating particle separation accuracy. However, this factor is often calculated using the settling velocity in stationary water, there are no examples of calculation of the equal settling ratio in an actual separator. This is difficult because particle movement in a separator is very complicated, and even simple periodic motions, such as the oscillation field used with many separators, are ignored in many cases. The authors have previously reported on the relation between the equal settling ratio and the oscillation frequency by analysis of particle movement in vertically oscillating water, using spherical particles of glass (average size 435 μm) and zirconia (202 μm) which have the same settling velocity in stationary water. In this study, the influence of particle diameter on the change in the settling velocity in oscillating water was experimentally investigated for three pairs of glass and zirconia particles having different sizes under 0.5 mm, which have the same settling velocity in stationary water. The settling velocities of different-sized particles decreased at different rates in oscillating water, indicating that the equal settling ratio is reduced by water oscillation. We conclude that water oscillation improves the accuracy of size separation for glass particles over 300 μm and zirconia particles over 150 μm when glass and zirconia particles are separated from each other with the difference of these settling velocities.  相似文献   

Twin formation in hematite during dehydration of goethite     

Genki Saito  Yuji Kunisada  Takahiro Nomura  Norihito Sakaguchi  Tomohiro Akiyama 《Physics and Chemistry of Minerals》2016,43(10):749-757

Twin formation in hematite during dehydration was investigated using X-ray diffraction, electron diffraction, and high-resolution transmission electron microscopy (TEM). When synthetic goethite was heated at different temperatures between 100 and 800 °C, a phase transformation occurred at temperatures above 250 °C. The electron diffraction patterns showed that the single-crystalline goethite with a growth direction of [001]_G was transformed into hematite with a growth direction of [100]_H. Two non-equivalent structures emerged in hematite after dehydration, with twin boundaries at the interface between the two variants. As the temperature was increased, crystal growth occurred. At 800 °C, the majority of the twin boundaries disappeared; however, some hematite particles remained in the twinned variant. The electron diffraction patterns and high-resolution TEM observations indicated that the twin boundaries consisted of crystallographically equivalent prismatic (100) (010), and (1\(\bar{1}\)0) planes. According to the total energy calculations based on spin-polarized density functional theory, the twin boundary of prismatic (100) screw had small interfacial energy (0.24 J/m²). Owing to this low interfacial energy, the prismatic (100) screw interface remained after higher-temperature treatment at 800 °C.  相似文献