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The effect of pH and Gibbs energy on the dissolution rate of a synthetic Na-montmorillonite was investigated by means of flow-through experiments at 25 and 80 °C at pH of 7 and 9. The dissolution reaction took place stoichiometrically at 80 °C, whereas at 25 °C preferential release of Mg over Si and Al was observed. The TEM-EDX analyses (transmission electronic microscopy with quantitative chemical analysis) of the dissolved synthetic phase at 25 °C showed the presence of newly formed Si-rich phases, which accounts for the Si deficit. At low temperature, depletion of Si concentration was attributed to incongruent clay dissolution with the formation of detached Si tetrahedral sheets (i.e., alteration product) whereas the Al behaviour remains uncertain (e.g., possible incorporation into Al-rich phases). Hence, steady-state rates were based on the release of Mg. Ex situ AFM measurements were used to investigate the variations in reactive surface area. Accordingly, steady-state rates were normalized to the initial edge surface area (11.2 m2 g−1) and used to propose the dissolution rate law for the dissolution reactions as a function of ΔGr at 25 °C and pH∼9:
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133.
The Bay of Fundy in eastern Canada has the highest tides in the world. Harnessing the tidal energy in the region has long been considered. In this study, the effects of tidal in-stream energy extraction in the Minas Passage on the three-dimensional (3D) tidal circulation in the Bay of Fundy (BoF) and the Gulf of Maine (GoM) are examined using a nested-grid coastal ocean circulation model based on the Princeton Ocean Model (POM). The nested-grid model consists of a coarse-resolution (~4.5 km) parent sub-model for the GoM and a high-resolution (~1.5 km) child sub-model for the BoF. The tidal in-stream energy extraction in the model is parameterized in terms of nonlinear Rayleigh friction in the momentum equation. A suite of numerical experiments are conducted to determine the ranges of extractable tidal in-stream energy and resulting effects on the 3D tidal circulation over the Bay of Fundy and the Gulf of Maine (BoF-GoM) in terms of the Rayleigh friction coefficients. The 3D model results suggest that the maximum energy extraction in the Minas Passage increases tidal elevations and tidal currents throughout the GoM and reduces tidal elevations and circulation in the upper BoF, especially in the Minas Basin. The far-field effect of tidal energy extraction in the Passage on the 3D tidal circulation in the BoF-GoM is examined in two cases of harnessing tidal in-stream energy from (a) the entire water column and (b) the lower water column within 20 m above the bottom in the Passage. The 3D model results demonstrate that tidal in-stream energy extraction from the lower water column has less impact on the tidal elevations and circulation in the BoF-GoM than the energy extraction from the whole water column in the Minas Passage.  相似文献   
134.
We have investigated the high-pressure behavior of cristobalite in helium by powder X-ray diffraction. Cristobalite transformed to a new phase at about 8 GPa. This phase is supposed to have a molar volume of about 30 % larger than cristobalite, suggesting the dissolution of helium atoms in its interstitial voids. On further compression, the new phase transformed to a different phase which showed an X-ray diffraction pattern similar to cristobalite X-I at about 21 GPa. On the other hand, when the new phase was decompressed, it transformed to another new phase at about 7 GPa, which is also supposed to have a molar volume of about 25 % larger than cristobalite. On further decompression, the second new phase transformed to cristobalite II at about 2 GPa. In contrast to cristobalite, quartz did not show anomalous behavior in helium. The behavior of cristobalite in helium was also consistent with that in other mediums up to about 8 GPa, where the volume of cristobalite became close to that of quartz. These results suggest that dissolution of helium may be controlled not only by the density (amount of voids) but also by the network structure of SiO4 tetrahedra (topology of voids).  相似文献   
135.
The knowledge from the compression behavior of densified SiO2 glass suggests that SiO2 melt may behave as a single phase having a densified network structure (intermediate-range order) at the pressure condition of the Earth’s deep upper mantle, including the transition zone. A simple and easy-to-use equation of state of silicate melts which is applicable to a wide range of chemical composition at the pressure condition of the deep upper mantle is proposed based on the assumption that SiO2 component is in its densified state (or phase). The equation of state proposed in this study is consistent with all the available density data of silicate melts with an SiO2 content of about 35–55 mol% measured with large-volume presses at pressures between 8 and 22 GPa. The equations of state in previous studies differ considerably from each other. The main reason for the discrepancies seems to be that the compression behavior of multiple states (or phases) of silicate melts has been described in most cases with a single equation of state. It is necessary to consider that silicate melts are in their densified states (or phases) in the deep upper mantle.  相似文献   
136.
We develop an automatic system for the sampling of ash fall particles, to be used for continuous monitoring of magma ascent and eruptive dynamics at active volcanoes. The system consists of a sampling apparatus and cameras to monitor surface phenomena during eruptions. The Sampling Apparatus for Time Series Unmanned Monitoring of Ash (SATSUMA-I and SATSUMA-II) is less than 10 kg in weight and works automatically for more than a month with a 10-kg lead battery to obtain a total of 30 to 36 samples in one cycle of operation. The time range covered in one cycle varies from less than an hour to several months, depending on the aims of observation, allowing researchers to target minute-scale fluctuations in a single eruptive event, as well as daily to weekly trends in persistent volcanic activity. The latest version, SATSUMA-II, also enables control of sampling parameters remotely by e-mail commands. Durability of the apparatus is high: our prototypes worked for several months, in rainy and typhoon seasons, at windy and humid locations, and under strong sunlight. We have been successful in collecting ash samples emitted from Showa crater almost everyday for more than 4 years (2008–2012) at Sakurajima volcano in southwest Japan.  相似文献   
137.
A post-tsunami field survey following the 2011 Tohoku-oki Earthquake Tsunami was carried out to asses inundated area in Sendai Plain, Northeast Japan. The type of inundation was classified into two categories (major and minor) according to the amount of accumulated debris, garbage and sediment. Major and minor inundations were identified up to 4 and 5 km from the coastline, respectively. Many artificial geomorphological features, such as roadway embankments and canals, were believed to have affected the run-up process of the tsunami. The inundation area of the 2011 tsunami on the Sendai Plain is compared with that of the 869 Jogan tsunami, which was reconstructed using numerical modeling based on available historical and geological records. The inundation area of the 2011 Tohoku-oki tsunami is comparable to that of the 869 Jogan tsunami, although a direct comparison is difficult due to differences in geomorphological contexts between the paleo period and the present.  相似文献   
138.
We report the result of our near-infrared observations ( JHK s) for type II Cepheids (including possible RV Tau stars) in galactic globular clusters. We detected variations of 46 variables in 26 clusters (10 new discoveries in seven clusters) and present their light curves. Their periods range from 1.2 d to over 80 d. They show a well-defined period–luminosity relation at each wavelength. Two type II Cepheids in NGC 6441 also obey the relation if we assume the horizontal branch stars in NGC 6441 are as bright as those in metal-poor globular clusters in spite of the high metallicity of the cluster. This result supports the high luminosity which has been suggested for the RR Lyr variables in this cluster. The period–luminosity relation can be reproduced using the pulsation equation     assuming that all the stars have the same mass. Cluster RR Lyr variables were found to lie on an extrapolation of the period–luminosity relation. These results provide important constraints on the parameters of the variable stars.
Using Two Micron All-Sky Survey (2MASS) data, we show that the type II Cepheids in the Large Magellanic Cloud (LMC) fit our period–luminosity relation within the expected scatter at the shorter periods. However, at long periods (   P > 40  d, i.e. in the RV Tau star range) the LMC field variables are brighter by about one magnitude than those of similar periods in galactic globular clusters. The long-period cluster stars also differ from both these LMC stars and galactic field RV Tau stars in a colour–colour diagram. The reasons for these differences are discussed.  相似文献   
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