Anthropogenic Pb in settling particulate matter in the Northwestern Pacific examined using stable isotopes of Pb     

Daisuke Nagaoka  Masahito Shigemitsu  Masao Minagawa  Shinichiro Noriki 《Journal of Oceanography》2010,66(1):117-132

We have investigated Pb concentrations and isotopic compositions in settling particles collected by sediment traps experiments over a period of two years, from May 2005 to April 2007, at two depths, 770 and 5100 m, at station KNOT in the Northwestern Pacific Ocean (44°N, 155°E). To the identify provenances of Pb, the samples were separated into two fractions by chemical leaching techniques, with the leachate expected to contain Pb of anthropogenic origin. Isotopic compositions of Pb and concentrations of Pb, Sc, Mn, La, Yb, and Th were measured by quadrupole ICP-MS. The isotope ratios of leachable Pb in settling particles were ²⁰⁷Pb/²⁰⁶Pb = 0.860 ± 0.001; ²⁰⁸Pb/²⁰⁶Pb = 2.116 ± 0.002 (mean ± 95% confidence intervals), which are similar to those of aerosols in China that are greatly affected by pollution from coal combustion. We estimated the mean contribution from anthropogenic Pb sources to the Pb in settling particles, using the conventional binary (anthropogenic and natural Pb) mixing equation for Pb isotopes, as 90% in the upper trap and 78% in the lower trap. Furthermore, we found a significant negative correlation between the isotope ratios of Pb and concentrations of leachable Mn, normalized to those of leachable Pb, suggesting that manganese oxides play an important role in transporting Pb from the upper layers of the ocean to the deeper layers. Our results support the speculation published in a previous study that Pb might be scavenged by Mn oxides in the Northwestern Pacific Ocean.  相似文献   

Intermineral oxygen three‐isotope systematics of silicate minerals in equilibrated ordinary chondrites          下载免费PDF全文

David McDougal  Daisuke Nakashima  Travis J. Tenner  Noriko T. Kita  John W. Valley  Takaaki Noguchi 《Meteoritics & planetary science》2017,52(11):2322-2342

High‐precision oxygen three‐isotope ratios were measured for four mineral phases (olivine, low‐Ca and high‐Ca pyroxene, and plagioclase) in equilibrated ordinary chondrites (EOCs) using a secondary ion mass spectrometer. Eleven EOCs were studied that cover all groups (H, L, LL) and petrologic types (4, 5, 6), including S1–S4 shock stages, as well as unbrecciated and brecciated meteorites. SIMS analyses of multiple minerals were made in close proximity (mostly <100 μm) from several areas in each meteorite thin section, to evaluate isotope exchange among minerals. Oxygen isotope ratios in each mineral become more homogenized as petrologic type increases with the notable exception of brecciated samples. In type 4 chondrites, oxygen isotope ratios of olivine and low‐Ca pyroxene are heterogeneous in both δ¹⁸O and Δ¹⁷O, showing similar systematics to those in type 3 chondrites. In type 5 and 6 chondrites, oxygen isotope ratios of the four mineral phases plot along mass‐dependent fractionation lines that are consistent with the bulk average Δ¹⁷O of each chondrite group. The δ¹⁸O of three minerals, low‐Ca and high‐Ca pyroxene and plagioclase, are consistent with equilibrium fractionation at temperatures of 700–1000 °C. In most cases the δ¹⁸O values of olivine are higher than those expected from pyroxene and plagioclase, suggesting partial retention of premetamorphic values due to slower oxygen isotope diffusion in olivine than pyroxene during thermal metamorphism in ordinary chondrite parent bodies.  相似文献   

Noble gases in angrites Northwest Africa 1296, 2999/4931, 4590, and 4801: Evolution history inferred from noble gas signatures     

Daisuke Nakashima  Keisuke Nagao  Anthony J. Irving 《Meteoritics & planetary science》2018,53(5):952-972

Noble gases in the five angrites Northwest Africa (NWA) 1296, 2999, 4590, 4801, and 4931 were analyzed with total melting and stepwise heating methods. The noble gases consist of in situ components: spallogenic, radiogenic, nucleogenic, and fission. Cosmic-ray exposure ages of the angrites (including literature data) spread uniformly from <0.2 to 56 Ma, and coarse-grained angrites have longer exposure ages than fine-grained angrites. It is implied that the parent bodies from which the two subgroups of angrites were ejected are different and have distinct orbital elements. The ²⁴⁴Pu-¹³⁶Xe relative ages of the angrites obtained by using ²⁴⁴Pu/¹⁵⁰Nd ratios are as old as that of Angra dos Reis, reflecting their early formation. On the other hand, another method to obtain ²⁴⁴Pu-¹³⁶Xe relative ages, using fission ¹³⁶Xe, spallogenic ¹²⁶Xe, and Ba/REE ratios, yields systematically older ²⁴⁴Pu-¹³⁶Xe ages than those obtained by using ²⁴⁴Pu/¹⁵⁰Nd ratios, which is explained by apparently high Ba/REE ratios caused by Ba contamination during terrestrial weathering. The ²⁴⁴Pu/²³⁸U ratio at 4.56 Ga of angrites is estimated as 0.0061 ± 0.0028, which is consistent with those for chondrules, chondrites, achondrites, and a terrestrial zircon. It is suggested that initial ²⁴⁴Pu/²³⁸U ratio has been spatially homogeneous at least in the inner part of the early solar system.  相似文献   

Open Ocean Originated Phosphorus and Nitrogen in the Seto Inland Sea,Japan     

Tetsuo?YanagiEmail author  Daisuke?Ishii 《Journal of Oceanography》2004,60(6):1001-1005

The ratios of phosphorus and nitrogen originating from land and the open ocean in the Seto Inland Sea, which is the largest semi-enclosed coastal sea in Japan, have been estimated from data on total phosphorus and nitrogen loads and observed concentrations of total phosphorus and nitrogen. The ratios of land-origin and open-ocean-origin total phosphorus and nitrogen in the Seto Inland Sea are 0.28:0.72 and 0.19:0.81, respectively.  相似文献   

Alkylbenzenesulfonate (ABS) in the bottom muds of the inner part of Tokyo Bay     

Yoshinari Ambe 《Journal of Oceanography》1973,29(1):1-7

The contents of alkylbenzenesulfonate (ABS) in the bottom sediments were analyzed for the inner part of Tokyo Bay and five inflowing rivers. Methylene blue active substances (MBAS) was extracted from the dired sample with methanol-benzene mixture.After the concentration of MBAS was determined by colorimetry, the ratio ABS/MBAS was estimated by an infrared spectrum of MBAS-MB complex. The net content of ABS was calculated from these two values.The ABS contents in the surface of the bottom sediments of the rivers and sea ranged 1.959g/g and 014.1g/g dry weight, respectively. The contents of ABS in the river sediments reflected the degree of pollution of each river by urban waste waters. From the results of the analysis of the core samples of sea sediment at two points containing ABS only in the upper layer, the average rate of sedimentation of the bottom muds in the inner part of Tokyo Bay since the usage of ABS began was estimated as 3 cm/year and 7 cm/year respectively.  相似文献   

Zonally asymmetric response of the Japan Sea to synoptic pressure forcing     

Daisuke Inazu  Naoki Hirose  Shoichi Kizu  Kimio Hanawa 《Journal of Oceanography》2006,62(6):909-916

We investigated the sea level response of the Japan Sea to changes in atmospheric pressure using barotropic shallow water models driven by idealized synoptic pressure forcing. The regional response lags behind the synoptic pressure forcing because the adjustment is slowly established by water exchange through narrow, shallow straits. The sea level response of the realistic Japan Sea to the idealized forcing varies with geographical location and shows zonally asymmetric variations in amplitude and phase. The simulated response is in good agreement with the observed response of sea level recorded at Japanese coastal tide gauges. The results of a simple one-dimensional model indicate that the zonally asymmetric pattern, with an eastward-propagating pressure system, is essentially caused by bottom friction in shallow straits. This asymmetry arises if the typical wavelength of the synoptic pressure system is slightly larger than the spatial scale of the Japan Sea.  相似文献   

Gully erosion in the Siwalik Hills,Nepal: estimation of sediment production from active ephemeral gullies     

Sohan K. Ghimire  Daisuke Higaki  Tara P. Bhattarai 《地球表面变化过程与地形》2006,31(2):155-165

A simple field‐based monitoring programme was established in a small catchment (area 4·6 km²) to find the rates of gully erosion in the Siwalik Hills, Nepal. The rates are used to estimate the amount of sediment produced by gully erosion in the catchment. Three large and active gullies were selected with areas ranging from 0·44 to 0·78 ha. Aerial photographs taken in 1964, 1978 and 1992 were ortho‐rectified and used to study the dynamics of gully heads. The same gullies were also monitored manually using an orthogonal reference system fixed by erosion pins around the gully heads. Results from the aerial photos indicated that the gullies expanded remarkably over the period from 1964 to 1992, by 34 to 58 per cent. Head‐retreat rates during that period were 0·48, 0·55 and 0·73 m a^?1 and average annual sediment evacuation was estimated as 2534 ± 171, 959 ± 60 and 2783 ± 118 m³ a^?1 for the three gullies respectively. From the field measurement, estimated volumes were found to vary from 731 ± 57 to 2793 ± 201 m³ a^?1 over the monitoring period of two years. It was also found that the gullies produce sediment which accounts for up to 59 per cent of the sediment produced from surface erosion in the headwater catchment. The findings are useful for planning and executing appropriate control measures and constructing a sediment hazard map at the catchment scale. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Fe-Mg interdiffusion in magnesiowüstite up to 35 GPa     

Daisuke Yamazaki  Tetsuo Irifune 《Earth and Planetary Science Letters》2003,216(3):301-311

Fe-Mg interdiffusivities in (Fe,Mg)O magnesiowüstite have been measured in experiments conducted at pressures of 7-35 GPa and temperatures of 1573-1973 K using a Kawai-type high-pressure apparatus. The diffusion profiles were measured across the interface between MgO and (Fe_0.5,Mg_0.5)O samples by electron microprobe analysis, and the Fe-Mg interdiffusivities were determined as D_Fe-Mg=D₀exp{−E*(1+PV*_Mg/E*_Mg)/RT}, where D₀=4.1(^+16.1_−3.3)×10⁻⁷ m²/s, E*=(1−C_Mg)E*_Fe+C_MgE*_Mg (activation energy for the concentration of Mg, where E*_Fe=113(±74) kJ/mol and E*_Mg=226(±32) kJ/mol), the activation volume V*_Mg=1.8(±1.2)×10⁻⁶ m³/mol. By extrapolating these results to the P-T conditions of the core-mantle boundary, we conclude that the interdiffusivity of Fe-Mg in magnesiowüstite at the bottom of the lower mantle is at least one order of magnitude larger than that at the top of the lower mantle.  相似文献   

Dark inclusions in CO3 chondrites: new indicators of parent-body processes     

Daisuke Itoh 《Geochimica et cosmochimica acta》2003,67(1):153-169

A petrographic and scanning electron microscopic study of the four CO3 chondrites Kainsaz, Ornans, Lancé, and Warrenton reveals for the first time that dark inclusions (DIs) occur in all the meteorites. DIs are mostly smaller in size than those reported from CV3 chondrites. They show evidence suggesting that they were formed by aqueous alteration and subsequent dehydration of a chondritic precursor and so probably have a formation history similar to that of DIs in CV3 chondrites. DIs in the CO3 chondrites consist mostly of fine-grained, Fe-rich olivine and can be divided into two types on the basis of texture. Type I DIs contain rounded, porous aggregates of fine grains in a fine-grained matrix and have textures suggesting that they are fragments of chondrule pseudomorphs. Veins filled with Fe-rich olivine are common in type I DIs, providing evidence that they experienced aqueous alteration on the parent body. Type II DIs lack rounded porous aggregates and have a matrix-like, featureless texture. Bulk chemical compositions of DIs and mineralogical characteristics of olivine grains in DIs suggest that these two types of DIs have a close genetic relationship.The DIs are probably clasts that have undergone aqueous alteration and subsequent dehydration at a location different from the present location in the meteorites. The major element compositions, the mineralogy of metallic phases, and the widely dispersed nature of the DIs suggest that their precursor was CO chondrite material. The CO parent body has been commonly regarded to have been dry, homogeneous, and unprocessed. However, the DIs suggest that the CO parent body was a heterogeneous conglomerate consisting of water-bearing regions and water-free regions and that during asteroidal heating, the water-bearing regions were aqueously altered and subsequently dehydrated. Brecciation may also have been active in the parent body.The DIs and the matrices are similarly affected by thermal metamorphism in their own host CO3 chondrites (petrologic subtypes 3.1 to 3.6), but the degree of the secondary processing (aqueous alteration and subsequent dehydration) of the DIs has no apparent correlation with the petrologic grades of the host chondrites. These observations suggest that the DIs had been incorporated into the host chondrites before the thermal metamorphism took place and that the secondary processes that affected the DIs largely occurred before the thermal metamorphism.  相似文献   

A global barotropic ocean model driven by synoptic atmospheric disturbances for detecting seafloor vertical displacements from in situ ocean bottom pressure measurements     

Daisuke Inazu  Ryota Hino  Hiromi Fujimoto 《Marine Geophysical Researches》2012,33(2):127-148

A global barotropic ocean model forced by atmospheric disturbances is developed for the detection of seafloor vertical displacements from in situ ocean bottom pressure (OBP) data. The model accuracy is validated by deep-sea OBP data at more than 100 sites obtained over the global ocean. Parameters and boundary conditions including the horizontal resolution incorporated in the ocean model are tested in order to accurately simulate the nontidal (>2 days) OBP variations. The horizontal resolution is found to the factor that most significantly affects the simulated result. The finer the horizontal resolution applied, the smaller the model variability is. The model accuracy is highest when the horizontal resolution is 1/12°, but deteriorates when the horizontal resolution is finer than 1/12°. This may indicate a failure of the energy dissipation parameterization in the barotropic ocean model. Using the developed 1/12° model, the root-mean-square of the observed nontidal OBP component can be reduced by 18 % as an average of all the OBP data used. It is found that the 1/12° model is useful for the detection of a slow seafloor vertical displacement of centimeters related to the 2011 Tohoku-Oki earthquake from in situ OBP records near the hypocenter of the earthquake.  相似文献