Domoic acid excretion in dungeness crabs, razor clams and mussels     

Schultz IR  Skillman A  Woodruff D 《Marine environmental research》2008,66(1):21-23

Domoic acid (DA) is a neurotoxic amino acid produced by several marine algal species of the Pseudo-nitzschia (PN) genus. We studied the elimination of DA from hemolymph after intravascular (IV) injection in razor clams (Siliqua patula), mussels (Mytilus edulis) and Dungeness crabs (Cancer magister). Crabs were also injected with two other organic acids, dichloroacetic acid (DCAA) and kainic acid (KA). For IV dosing, hemolymph was repetitively sampled and DA concentrations measured by HPLC-UV. Toxicokinetic analysis of DA in crabs suggested most of the injected dose remained within hemolymph compartment with little extravascular distribution. This observation is in sharp contrast to results obtained from clams and mussels which exhibited similarly large apparent volumes of distribution despite large differences in overall clearance. These findings suggest fundamentally different storage and elimination processes are occurring for DA between bivalves and crabs.  相似文献   

Variability of stream extents controlled by flow regime and network hydraulic scaling     

Dana A. Lapides  Christine D. Leclerc  Hana Moidu  David N. Dralle  W. Jesse Hahm 《水文研究》2021,35(3):e14079

Stream networks expand and contract through time, impacting chemical export, aquatic habitat, and water quality. Although recent advances improve prediction of the extent of the wetted channel network (L ) based on discharge at the catchment outlet (Q ), controls on the temporal variability of L remain poorly understood and unquantified. Here we develop a quantitative, conceptual framework to explore how flow regime and stream network hydraulic scaling factors co-determine the relative temporal variability in L (denoted here as the total wetted channel drainage density). Network hydraulic scaling determines how much L changes for a change in Q , while the flow regime describes how Q changes in time. We compiled datasets of co-located dynamic stream extent mapping and discharge to analyze all globally available empirical data using the presented framework. We found that although variability in L is universally damped relative to variability in Q (i.e., streamflow is relatively more variable in time than network extent), the relationship is elastic, meaning that for a given increase in the variability in Q , headwater catchments will experience greater-than-proportional increases in the variability of L . Thus, under anticipated climatic shifts towards more volatile precipitation, relative variability in headwater stream network extents can be expected to increase even more than the relative variability of discharge itself. Comparison between network extents inferred from the L -Q relationship and blue lines on USGS topographic maps shows widespread underestimation of the wetted channel network by the blue line network.  相似文献   

The distribution of iron in the Northwest Atlantic     

James L Symes  Dana R Kester 《Marine Chemistry》1985,17(1):57-74

Samples from eleven stations in the Sargasso Sea, Slope Water, and continental shelf water of the Northwest Atlantic have been analyzed for total iron by atomic absorption spectrophotometry. Vertical profiles for iron and associated temperature and nutrient data were obtained at the five open-ocean stations. Data from six stations provided a transect across the continental shelf into the apex of the New York Bight.At open-ocean stations, iron was depleted near the surface to levels of about 1–2 nmol kg^?1 and increased to levels of about 4–7 nmol kg^?1 in the vicinity of the oxygen minimum. A characteristic bottom-water maximum was observed at stations where closely spaced, near-bottom sampling was conducted. This feature was due at least partially to resuspension of particulate iron associated with the nepheloid layer.Comparison of total iron concentrations (available upon digestion in concentrated nitric acid) to those of filtered samples (0.4 μm) at one Slope Water station indicated that about 40% of the available iron in the water column was associated with the particulate phase. Near the surface, in the vicinity of the chlorophyll maximum, iron was present almost totally in particulate form. The dissolved fraction increased to approximately 50% at the nutrient maximum and approached 100% in the mid-portion of the water column. In deeper waters, the particulate fraction again became important, increasing to approximately 80% of the total iron in the near-bottom maximum.In the apex of the New York Bight, iron levels in excess of 200 and 500 nmol kg^?1 were observed in surface and bottom waters, respectively. In the mid-continental shelf region, the iron distribution does not appear to be greatly influenced by coastal sources; within 65 km of the coastline, iron levels approached open-ocean values.  相似文献   

The infrared colors of main sequence stars: how much circumstellar debris is normal?     

Robert E. Stencel  Dana E. Backman 《Astrophysics and Space Science》1995,224(1-2):401-404

We have been awarded NASA Key Project observing time on ISO, in order to establish the true frequency of far-infrared excesses in a volume-limited sample of main sequence and related stars, and address the relative success or failure of single stars in processes related to the forming of planetary systems. For a volume-limited subset of main sequence and related stars, PHT03 measurements at 3.6, 11.5, 20 and 60 micron will be obtained, using a 120 arsec aperture in all cases to eliminate possible companion confusion with differing apertures, to ascertain spectral energy distributions. For the M dwarfs, 100 micron observations will also be obtained. For some, brighter sources, more extensive wavelength coverage and improved spatial resolution will be attempted, using CAM and SWS. Spatially over-sampled PHOT observations will be made at 60 micron of the brightest and nearest Vega-like sources to measure the characteristic sizes of the emitting regions and obtain some information regarding their shapes and orientations. The goal is not a map, but scan profiles along 3 position angles which can be deconvolved to find the intrinsic size and shape of the half-maximum contour of the emitting region. Photometry of selected lines of sight through the zodiacal dust will also be carried out to look for outer solar system (Kuiper Belt) material. Observation at a range of wavelengths, ecliptic latitudes and at 2 epochs is designed to help untangle foreground Zodiacal from background Kuiper flux, not necessarily to look for individual macroscopic objects.  相似文献   

The effects of tributyltin within aThalassia seagrass ecosystem     

John R. Kelly  Suzanne N. Levine  Linda A. Buttel  Kelly A. Carr  David T. Rudnick  R. Dana Morton 《Estuaries and Coasts》1990,13(3):301-310

Flow-through seagrass core microcosms were used to examine responses of species and processes to a logarithmic gradient of dosing with¹⁴C-labeled tributyltin-chloride (TBT-CI). Experiments involved delivery of TBT-CI to the water column of replicate cores of a treatment (n=16) once per week; one-half of the cores were sacrificed after 3 wk of dosing, the others were dosed for 6 wk. Initial water column concentrations for the three treatments averaged 0.205, 2.23, and 22.21 μg I^?1, expressed as the TBT⁺ cation, but these concentrations dropped rapidly. Retained¹⁴C tracer, an estimate of total organotin species, was distributed to sediments, plants, and other biological tissues, all of whose tracer concentrations increased with time. Measures to indicate responses of both autotrophic and heterotrophic organisms were made; in general, treatment effects were demonstrable statistically only at the highest dose level. Accumulation of chlorophyll and biomass on glass slides was highest when suspended for the entire experiment in the water of the highest treatment; this unexpected result was perhaps an indirect effect related to reduced grazing activity in the microcosms. The highest dose of TBT-CI resulted in virtual population mortality of a few macrobenthic species and decreased loss of plant material in litter bags, both demonstrated within the first 3 wk of dosing. Reduced litter loss was coincident with mortality of an amphipod (Cymadusa compta) capable of shredding plant material, and a causal relation between the two effects is plausible. Thus, if concentrated to similar levels in aThalassia bed, TBT⁺ may have direct species-level effects and process-level effects, potentially causing ecosystem change via disruption of a species-process linkage influential in seagrass detrital food web dynamics.  相似文献   

Copper(II) interaction with carbonate species based on malachite solubility in perchlorate medium at the ionic strength of seawater     

James L Symes  Dana R Kester 《Marine Chemistry》1985,16(3):189-211

Equilibrium constants for copper(II)-carbonate and -bicarbonate species have been determined at 25°C from consideration of malachite, Cu₂(OH)₂CO_3(s), solubility in UV-photo-oxidized perchlorate solutions of 0.72 m ionic strength. The ratios of total dissolved copper, T(Cu), to free copper(II) ion, [Cu ²⁺], in 30 malachite saturated experimental solutions of 1–10 × 10^?3eq kg^?1 H₂O initial total alkalinity (TA_i in the pH range 5.0–9.3 were fitted to a copper(II)-ion speciation model. The experimental data indicate the existence of CuCO₃⁺, CuHCO₃⁺ and Cu(OH)CO₃^? in addition to the hydrolys and Cu(OH)CO₃^? in addition to the hydrolysis products in the range of conditions defined by this study. The stoichiometric equilibrium constants, applicable to seawater at 0.72 m ionic strength, 25°C and 1 atm are A speciation model employing the equilibrium constants determined in this study and copper(II) hydrolysis constants from previous work suggests that the inorganic speciation in seawater (pH = 8.2, TA = 2.3 meq kg ^?1, 25°C) is dominated by the CuCO₃⁰ complex (82%) and that only 2.9% of the total inorganic copper exists as the free copper(II) ion. Hydrolysis products, CuOH⁺ and Cu(OH)₂⁰, account for 6.5% while CuHCO₃⁺ and Cu(OH)CO₃^? species comprise 1.0 and 6.3% of the total inorganic copper, respectively.  相似文献   

Sodium fluoride ion-pairs in seawater     

Gerard R. Miller  Dana R. Kester 《Marine Chemistry》1976,4(1):67-82

Laboratory investigations were conducted on the formation of NaF° ion-pairs at the ionic strength of seawater using specific ion electrodes. Sodium and fluoride ion electrodes produced results which are consistent with the ion-pairing model for these ionic interactions. The stoichiometric association constant for NaF°, $\text{K}{}^1{}_{\mathrm{<mtext>NaF</mtext>}}$, was determined at 15, 25, and 35°C. It was assumed that $\text{K}{}^1{}_{\mathrm{<mtext>NaF</mtext>}}$ was a function of temperature, pressure, and ionic strength but not of solution composition. The value for $\text{K}{}^1{}_{\mathrm{<mtext>NaF</mtext>}}$ at 25°C and I = 0.7 m is 0.045 ± 0.006. $\text{K}{}^1{}_{\mathrm{<mtext>NaF</mtext>}}$ increased with decreasing temperature. This result was used to recompute values of $\text{K}{}^1{}_{\mathrm{<mtext>MgF</mtext>}}$ and $\text{K}{}^1{}_{\mathrm{<mtext>CaF</mtext>}}$ accounting for the presence of NaF° ion-pairs. The value for $\text{K}{}^1{}_{\mathrm{<mtext>NaF</mtext>}}$ indicates that 1.1% of the fluoride in seawater is ion-paired with sodium at 25°C and 35‰ salinity. This fraction increases to approximately 2% at the lower temperatures found in the deep ocean. The percentage of free fluoride in natural seawater was measured at 15, 25, and 35°C to verify the speciation calculated from equilibrium constants.  相似文献   

Characterizing and predicting essential habitat features for juvenile coastal sharks          下载免费PDF全文

Christine A. Ward‐Paige  Gregory L. Britten  Dana M. Bethea  John K. Carlson 《Marine Ecology》2015,36(3):419-431

The successful management of shark populations requires juvenile recruitment success. Thus, conservation initiatives now strive to include the protection of areas used by pre‐adult sharks in order to promote juvenile survivorship. Many shark species use inshore areas for early life stages; however, species often segregate within sites to reduce competition. Using a fisheries‐independent gillnet survey from the Northern Gulf of Mexico (2000–2010) we describe distribution patterns and preferred habitat features of the juveniles of six shark species. Our results suggest that multiple shark species concurrently use the area for early life stages and although they overlap, they exhibit distinct habitat preferences characterized by physical variables. Habitat suitability models suggest that temperature, depth, and salinity are the important factors driving juvenile shark occurrence. Within each site, across the sampled range of physical characteristics, blacktip shark (Carcharhinus limbatus) preferred higher temperature (>30 °C) and mid‐depth (~5.5 m); bonnethead shark (Sphyrna tiburo) preferred higher temperature (>30 °C) and mid‐salinity (30–35 PSU), finetooth shark (Carcharhinus isodon) preferred low salinity (<20 PSU) with mid‐depth (~4 m), scalloped hammerhead shark (Sphyrna lewini) preferred high temperature (>30 °C) and salinity (>35 PSU), Atlantic sharpnose shark (Rhizoprionodon terraenovae) preferred high temperature (>30 °C) and deep water (>6 m), and spinner shark (Carcharhinus brevipinna) preferred deep water (>8 m) and high temperature (>30 °C). The other investigated factors, including year, month, latitude, longitude, bottom type, inlet distance, coastline and human coast were not influential for any species. Combining habitat preferences with the sampled environmental characteristics, we predicted habitat suitability throughout the four sites for which physical characteristics were sampled. Habitat suitability surfaces highlight the differences in habitat use between and within sites. This work provides important insight into the habitat ecology of juvenile shark populations, which can be used to better manage these species and protect critical habitat.  相似文献   

Siderophile and chalcophile element abundances in shergottites: Implications for Martian core formation          下载免费PDF全文

Shuying Yang  Munir Humayun  Kevin Righter  Gwendolyn Jefferson  Dana Fields  Anthony J. Irving 《Meteoritics & planetary science》2015,50(4):691-714

Elemental abundances for volatile siderophile and chalcophile elements for Mars inform us about processes of accretion and core formation. Such data are few for Martian meteorites, and are often lacking in the growing number of desert finds. In this study, we employed laser ablation inductively coupled plasma–mass spectrometry (LA‐ICP‐MS) to analyze polished slabs of 15 Martian meteorites for the abundances of about 70 elements. This technique has high sensitivity, excellent precision, and is generally accurate as determined by comparisons of elements for which literature abundances are known. However, in some meteorites, the analyzed surface is not representative of the bulk composition due to the over‐ or underrepresentation of a key host mineral, e.g., phosphate for rare earth elements (REE). For other meteorites, the range of variation in bulk rastered analyses of REE is within the range of variation reported among bulk REE analyses in the literature. An unexpected benefit has been the determination of the abundances of Ir and Os with a precision and accuracy comparable to the isotope dilution technique. Overall, the speed and small sample consumption afforded by this technique makes it an important tool widely applicable to small or rare meteorites for which a polished sample was prepared. The new volatile siderophile and chalcophile element abundances have been employed to determine Ge and Sb abundances, and revise Zn, As, and Bi abundances for the Martian mantle. The new estimates of Martian mantle composition support core formation at intermediate pressures (14 ± 3 GPa) in a magma ocean on Mars.  相似文献   

Evidence of centennial-scale drought from southeastern Massachusetts during the Pleistocene/Holocene transition     

Paige E. Newby  Jeffrey P. Donnelly  Bryan N. Shuman  Dana MacDonald 《Quaternary Science Reviews》2009,28(17-18):1675-1692

A principal method for studying past hydroclimatic change is the reconstruction of paleo-lake levels. Here, we provide high-resolution lake-level records from New Long Pond and Rocky Pond in southeastern Massachusetts, which each contain evidence for multiple, sub-centennial-to-millennial scale low stands during the transition between the Late Pleistocene (15.0 ka) and Middle Holocene (ca 7.0 ka). Data from New Long Pond also demonstrate sedimentary evidence for a drop in water levels in the early to mid AD 20th century, when long-term trends in instrumental data show lower-than-average precipitation in the northeastern United States. Local data show the most precipitous declines in precipitation and groundwater levels are concurrent with the most severe drought in the AD 1960s, which occurred during a period of low sea-surface temperatures in the western North Atlantic. Ground penetrating radar and sediment core data indicate five intervals with numerous paleo-shoreline deposits between ca 15.0 and 7.0 ka, similar to the layer deposited in the AD 1960s. Many of the intervals of low lake levels coincide with proposed meltwater release events or abrupt climate oscillations in the circum North Atlantic. For example, we document at least three low stands during the Younger Dryas (12.9–11.6 ka) and in association with the “9.2” and “8.2” ka events. The combined evidence of (1) concurrent paleo-droughts in southeastern New England with documented North Atlantic abrupt cooling events and (2) recent drought with the modern association of low sea-surface temperatures indicates that freshening and cooling of the western North Atlantic is a viable mechanism for decreasing moisture within the region. Large-scale changes in seasonality and ice sheet extent also may have increased the susceptibility of the northeast to dry conditions triggered by changes in the North Atlantic.  相似文献