Amino acid analyses of Antarctic CM2 meteorites using liquid chromatography‐time of flight‐mass spectrometry     

Daniel P. Glavin  Jason P. Dworkin  Andrew Aubrey  Oliver Botta  James H. Doty  Zita Martins  Jeffrey L. Bada 《Meteoritics & planetary science》2006,41(6):889-902

Abstract— Amino acid analyses of the Antarctic CM2 chondrites Allan Hills (ALH) 83100 and Lewis Cliff (LEW) 90500 using liquid chromatography‐time of flight‐mass spectrometry (LC‐ToF‐MS) coupled with UV fluorescence detection revealed that these carbonaceous meteorites contain a suite of indigenous amino acids not present in Antarctic ice. Several amino acids were detected in ALH 83100, including glycine, alanine, β‐alanine, γ‐amino‐n‐butyric acid (γ‐ABA), and α‐aminoisobutyric acid (AIB) with concentrations ranging from 250 to 340 parts per billion (ppb). In contrast to ALH 83100, the CM2 meteorites LEW 90500 and Murchison had a much higher total abundance of these amino acids (440–3200 ppb). In addition, ALH 83100 was found to have lower abundances of the α‐dialkyl amino acids AIB and isovaline than LEW 90500 and Murchison. There are three possible explanations for the depleted amino acid content in ALH 83100: 1) amino acid leaching from ALH 83100 during exposure to Antarctic ice meltwater, 2) a higher degree of aqueous alteration on the ALH 83100 parent body, or 3) ALH 83100 originated on a chemically distinct parent body from the other two CM2 meteorites. The high relative abundance of ?‐amino‐n‐caproic acid (EACA) in the ALH 83100 meteorite as well as the Antarctic ice indicates that Nylon‐6 contamination from the Antarctic sample storage bags may have occurred during collection.  相似文献   

The impact of broad mid-infrared emission bands on extragalactic surveys – a case study: the unidentified 22-μm feature     

Chris P. Pearson  K.-W. Chan  T. Onaka 《Monthly notices of the Royal Astronomical Society》2004,350(2):473-484

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Chemical alteration of tephra in the depositional environment: theoretical stability modelling     

A. M. Pollard  S. P. E. Blockley  K. R. Ward 《第四纪科学杂志》2003,18(5):385-394

The study of the chemical stability of vitreous material in aqueous media is well‐established. There has to date been little consideration of the implications of variations in the chemical durability of tephra in Quaternary tephrochronology. Chemical alteration can take the form of cationic leaching from the matrix, or complete destruction of the silica network, either of which could constrain the ability to chemically identify distal tephra. Here we apply established models of vitreous durability to the published chemical analyses of a large number of Icelandic tephras in order to predict their relative durabilities under equivalent conditions. This suggests that some important tephras have relatively poor chemical stability, and that rhyolitic tephras are, in general, more stable than basaltic. We conclude that tephras should be expected to show predictable differential chemical stability in the post‐depositional environment. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Parameters of the intense X-ray and gamma-ray radiation from the solar flare of May 20, 2002, as observed from the Coronas-F spacecraft     

A. V. Bogomolov  A. P. Ignat’ev  K. Kudela  S. N. Kuznetsov  Yu. I. Logachev  O. V. Morozov  I. N. Myagkova  S. N. Oparin  A. A. Pertsov  S. I. Svertilov  B. Yu. Yushkov 《Astronomy Letters》2003,29(3):199-204

We consider temporal, spectral, and polarization parameters of the hard X-ray and gamma-ray radiation observed during the solar flare of May 20, 2002, in the course of experiments with the SONG and SPR-N instruments onboard the Coronas-F spacecraft. This flare is one of the most intense gamma-ray events among all of the bursts of solar hard electromagnetic radiation detected since the beginning of the Coronas-F operation (since July 31, 2001) and one of the few gamma-ray events observed during solar cycle 23. A simultaneous analysis of the Coronas-F and GOES data on solar thermal X-ray radiation suggests that, apart from heating due to currents of matter in the the flare region, impulsive heating due to the injection of energetic electrons took place during the near-limb flare S21E65 of May 20, 2002. These electrons produced intense hard X-ray and gamma-ray radiation. The spectrum of this radiation extends up to energies ≥7 MeV. Intense gamma-ray lines are virtually unobservable against the background of the nonthermal continuum. The polarization of the hard X-ray (20–100 keV) radiation was estimated to be ≤15–20%. No significant increase in the flux of energetic protons from the flare under consideration was found. At the same time, according to ACE data, the fluxes of energetic electrons in interplanetary space increased shortly (～25 min) after the flare.  相似文献   

The D-CIXS X-ray mapping spectrometer on SMART-1     

M Grande  R BrowningN Waltham  D ParkerS.K Dunkin  B KentB Kellett  C.H PerryB Swinyard  A PerryJ Feraday  C HoweG McBride  K PhillipsJ Huovelin  P MuhliP.J Hakala  O VilhuJ Laukkanen  N ThomasD Hughes  H AlleyneM Grady  R LundinS Barabash  D BakerP.E Clark  C.D MurrayJ Guest  I CasanovaL.C d'Uston  S MauriceB Foing  D.J Heather  V FernandesK Muinonen  S.S RussellA Christou  C OwenP Charles  H KoskinenM Kato  K SipilaS Nenonen  M HolmstromN Bhandari  R ElphicD Lawrence 《Planetary and Space Science》2003,51(6):427-433

The D-CIXS Compact X-ray Spectrometer will provide high quality spectroscopic mapping of the Moon, the primary science target of the ESA SMART-1 mission. D-CIXS consists of a high throughput spectrometer, which will perform spatially localised X-ray fluorescence spectroscopy. It will also carry a solar monitor, to provide the direct calibration needed to produce a global map of absolute lunar elemental abundances, the first time this has been done. Thus it will achieve ground breaking science within a resource envelope far smaller than previously thought possible for this type of instrument, by exploiting two new technologies, swept charge devices and micro-structure collimators. The new technology does not require cold running, with its associated overheads to the spacecraft. At the same time it will demonstrate a radically novel approach to building a type of instrument essential for the BepiColombo mission and potential future planetary science targets.  相似文献   

Mezen Bay—a key area for understanding Weichselian glaciations in northern Russia     

Kurt H. Kjr  Igor N. Demidov  Eiliv Larsen  Andrew Murray  Jan K. Nielsen 《第四纪科学杂志》2003,18(1):73-93

Sediment successions in coastal cliffs around Mezen Bay, southeastern White Sea, record an unusually detailed history of former glaciations, interstadial marine and fluvial events from the Weichselian. A regional glaciation model for the Weichselian is based on new data from the Mezen Bay area and previously published data from adjacent areas. Following the Mikulinian (Eemian) interglacial a shelf‐centred glaciation in the Kara Sea is reflected in proglacial conditions at 100–90 ka. A local ice‐cap over the Timan ridge existed between 75 and 65 ka. Renewed glaciation in the Kara Sea spread southwestwards around 60 ka only, interrupted by a marine inundation, before it advanced to its maximum position at about 55–50 ka. After a prolonged ice‐free period, the Scandinavian ice‐sheet invaded the area from the west and terminated east of Mezen Bay about 17 ka. The previously published evidence of a large ice‐dammed lake in the central Arkhangelsk region, Lake Komi, finds no support in this study. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

X-ray spectral evolution of low-mass X-ray binary GX 349+2     

V. K. Agrawal  P. Sreekumar 《Monthly notices of the Royal Astronomical Society》2003,346(3):933-939

We present the results of a systematic investigation of spectral evolution in the Z source GX 349+2, using data obtained during 1998 with the Proportional Counter Array (PCA) on-board the RXTE satellite. The source traced a extended normal branch (NB) and flaring branch (FB) in the colour–colour diagram (CD) and the hardness-intensity diagram (HID) during these observations. The spectra at different positions of the Z-track were best fitted by a model consisting of a disc blackbody and a Comptonized spectrum. A broad (Gaussian) iron line at ∼6.7 keV is also required to improve the fit. The spectral parameters showed a systematic and significant variation with the position along the Z-track. The evolution in spectral parameters is discussed in view of the increasing mass accretion rate scenario, proposed to explain the motion of Z sources in the CD and the HID.  相似文献   

On the most general accurate solutions for Buchdahl's fluid spheres     

Y.K. Gupta  M.K. Jasim 《Astrophysics and Space Science》2003,283(3):337-346

The most general accurate solutions for the Buchdhal fluid sphere were obtained and matched with the Schwarzchild's exterior solution at the pressure free interface. Various parameters of the solutions were so adjusted that the energy density, pressure and temperature were positive and decreasing away from the centre, and the velocity of sound was less than unity throughout the spheroid model. Using this procedure, the maximum mass of the fluid sphere with a surface density of2 × 10¹⁴gm cm^-3 was determined to be 3.82MΘ and 4.57 MΘ for strong and weak energy conditions respectively. PACS number: 0402, 0402J, 0440D, 95301 This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Detailed comparison of the structures and kinematics of simulated and observed barred galaxies     

J. K. O'Neill  John Dubinski 《Monthly notices of the Royal Astronomical Society》2003,346(1):251-264

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Photometry of pluto in the last decade and before: evidence for volatile transport?     

B.J. Buratti  J.K. Hillier  A. Heinze  K.A. Tryka  J. Ward  J. Young 《Icarus》2003,162(1):171-182

Photometric observations of Pluto in the BVR filter system were obtained in 1999 and in 1990-1993, and observations in the 0.89-μm methane absorption band were obtained in 2000. Our 1999 observations yield lightcurve amplitudes of 0.30 ± 0.01, 0.26 ± 0.01, and 0.21 ± 0.02 and geometric albedos of 0.44 ± 0.04, 0.52 ± 0.03, and 0.58 ± 0.02 in the B, V, and R filters, respectively. The low-albedo hemisphere of Pluto is slightly redder than the higher albedo hemisphere. A comparison of our results and those from previous epochs shows that the lightcurve of Pluto changes substantially through time. We developed a model that fully accounts for changes in the lightcurve caused by changes in the viewing geometry between the Earth, Pluto, and the Sun. We find that the observed changes in the amplitude of Pluto’s lightcurve can be explained by viewing geometry rather than by volatile transport. We also discovered a measurable decrease since 1992 of ∼0.03 magnitudes in the amplitude of Pluto’s lightcurve, as the model predicts. Pluto’s geometric albedo does not appear to be currently increasing, as our model predicts, although given the uncertainties in both the model and the measurements of geometric albedo, this result is not firm evidence for volatile transport. The maximum of methane-absorption lightcurve occurs near the minimum of the BVR lightcurves. This result suggests that methane is more abundant in the brightest regions of Pluto. Pluto’s phase coefficient exhibits a color dependence, ranging from 0.037 ± 0.01 in the B filter to 0.032 ± 0.01 in the R filter. Pluto’s phase curve is most like those of the bright, recently resurfaced satellites Triton and Europa. Although Pluto shows no strong evidence for volatile transport now (unlike Triton), it is important to continue to observe Pluto as it moves away from perihelion.  相似文献