where k (M− 2 s− 1) can be determined from the
in the pH range 2 to 5, from 5 to 40 °C and 0.01 to 1 M.The effect of pH and ionic strength on the reaction suggest that the rates are due to
where H2A = H2CrO4, HA = HCrO4, H2B = H2SO3 and HB = HSO3. The overall rate expression over the investigated pH range can be determined from
k=kH2A–H2B(αH2A)(αH2B)2+kHA–H2B(αHA)(αH2B)2+kH2A–HB(αH2A)(αHB)2
with kH2A−H2B = 5.0 × 107, kHA–H2B = 1.5 × 106 and kH2A–HB = 6.7 × 107.Fe(III) in the range 1.5 to 20 μM exerts a small catalytic effect on the reaction and significantly lowers the initial concentration of Cr(VI) compared to the nominal value. Contrary to Fe(III), formaldehyde (20 to 200 μM) reacts with S(IV) to form the hydroxymethanesulfonate adduct (CH2OHSO3), which does not react with Cr(VI). Major cations Mg2+ and some minor elements such as Ba2+ and Cu2+ did not affect the rates. The application of this rate law to environmental conditions suggest that this reaction may have a role in acidic solutions (aerosols and fog droplets). This reaction becomes more important in the presence of high Fe(III) and low HMS concentrations, contributing to affect the atmospheric transport of chromium species and the distribution of redox species of chromium, which reach surface water from atmospheric depositions.  相似文献   
17.
Sequential sampling to contour an uncertain function     
Daniele Veneziano  Peter K. Kitanidis 《Mathematical Geology》1982,14(5):387-404
Sampling exploration of uncertain functions to locate critical contour levels is most effective if sampling decisions are made sequentially. A simple sequential exploration strategy, based on pseudo-Bayesian second-moment analysis, is proposed and compared with non-sequential systematic sampling. Repeated application to functions simulated pseudorandomly from stationary random processes on the line and on the plane indicates uniform superiority of the sequential strategy. The method is particularly advantageous when the function of interest,h(X), has an uncertain trend, and in general when the random process that quantifies prior uncertainty onh(X) is highly correlated.  相似文献   
18.
Evidence of climate change within the Adamello Glacier of Italy   总被引:2,自引:2,他引:0  
Daniele Bocchiola  Guglielmina Diolaiuti 《Theoretical and Applied Climatology》2010,100(3-4):351-369
We analyze a daily series of rainfall, snowfall, air temperature, and snow water equivalent at fixed dates from 40 high-altitude stations on the Adamello Glacier area (Italian Alps), for the period 1965–2007. Purposes of the study are (1) to investigate significant variation in time, (2) to evaluate effect of temperature changes on cryospheric water cycle, and (3) to evaluate underlying climate patterns and the most significant variables for climate change studies. We detect the presence of a trend using linear regression, moving window average and Mann Kendall test. Linear dependence of water related variables on temperatures is assessed. We find substantially unchanged atmospheric water input along with increasing temperature and rainfall, decreasing snowfall and snow water equivalent at thaw, and shortening of snow cover extent and duration. We carry out a principal components analysis which highlights patterns of precipitation distribution resulting from local temperature and external forcing. A set of the most representative variables for climate and glacier studies is then assessed. A comparison with three nearby Southern Alpine glacierized areas in Italy and Switzerland shows substantial agreement. In spite of the relative shortness of the series, the results here are of interest and can be used as a benchmark for climate change impact assessment for the Adamello Glacier area and southern Alps.  相似文献   
19.
Dynamics of sea-surface temperature anomalies in the Southern Ocean diagnosed from a 2D mixed-layer model     
Frédéric Vivier  Daniele Iudicone  Fabiano Busdraghi  Young-Hyang Park 《Climate Dynamics》2010,34(2-3):153-184
We analyze the processes responsible for the generation and evolution of sea-surface temperature anomalies observed in the Southern Ocean during a decade based on a 2D diagnostic mixed-layer model in which geostrophic advection is prescribed from altimetry. Anomalous air–sea heat flux is the dominant term of the heat budget over most of the domain, while anomalous Ekman heat fluxes account for 20–40% of the variance in the latitude band 40°?60°S. In the ACC pathway, lateral fluxes of heat associated with anomalous geostrophic currents are a major contributor, dominating downstream of several topographic features, reflecting the influence of eddies and frontal migrations. A significant fraction of the variability of large-scale SST anomalies is correlated with either ENSO or the SAM, each mode contributing roughly equally. The relation between the heat budget terms and these climate modes is investigated, showing in particular that anomalous Ekman and air–sea heat fluxes have a co-operating effect (with regional exceptions), hence the large SST response associated with each mode. It is further shown that ENSO- or SAM-locked anomalous geostrophic currents generate substantial heat fluxes in all three basins with magnitude comparable with that of atmospheric forcings for ENSO, and smaller for the SAM except for limited areas. ENSO-locked forcings generate SST anomalies along the ACC pathway, and advection by mean flows is found to be a non-negligible contribution to the heat budget, exhibiting a wavenumber two zonal structure, characteristic of the Antarctic Circumpolar Wave. By contrast SAM-related forcings are predominantly zonally uniform along the ACC, hence smaller zonal SST gradients and a lesser role of mean advection, except in the SouthWest Atlantic. While modeled SST anomalies are significantly correlated with observations over most of the Southern Ocean, the analysis of the data-model discrepancies suggests that vertical ocean physics may play a significant role in the nonseasonal heat budget, especially in some key regions for mode water formation.  相似文献   
20.
Earth–Moon Weak Stability Boundaries in the restricted three and four body problem     
Daniele Romagnoli  Christian Circi 《Celestial Mechanics and Dynamical Astronomy》2009,103(1):79-103
This work deals with the structure of the lunar Weak Stability Boundaries (WSB) in the framework of the restricted three and four body problem. Geometry and properties of the escape trajectories have been studied by changing the spacecraft orbital parameters around the Moon. Results obtained using the algorithm definition of the WSB have been compared with an analytical approximation based on the value of the Jacobi constant. Planar and three-dimensional cases have been studied in both three and four body models and the effects on the WSB structure, due to the presence of the gravitational force of the Sun and the Moon orbital eccentricity, have been investigated. The study of the dynamical evolution of the spacecraft after lunar capture allowed us to find regions of the WSB corresponding to stable and safe orbits, that is orbits that will not impact onto lunar surface after capture. By using a bicircular four body model, then, it has been possible to study low-energy transfer trajectories and results are given in terms of eccentricity, pericenter altitude and inclination of the capture orbit. Equatorial and polar capture orbits have been compared and differences in terms of energy between these two kinds of orbits are shown. Finally, the knowledge of the WSB geometry permitted us to modify the design of the low-energy capture trajectories in order to reach stable capture, which allows orbit circularization using low-thrust propulsion systems.  相似文献   
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11.
12.
A solution to the fixed-time minimum-fuel two-impulse rendezvous problem for the general non-coplanar elliptical orbits is provided. The optimal transfer orbit is obtained using the constrained multiple-revolution Lambert solution. Constraints consist of lower bound for perigee altitude and upper bound for apogee altitude. The optimal time-free two-impulse transfer problem between two fixed endpoints implies finding the roots of an eighth order polynomial, which is done using a numerical iterative technique. The set of feasible solutions is determined by using the constraints conditions to solve for the short-path and long-path orbits semimajor axis ranges. Then, by comparing the optimal time-free solution with the feasible solutions, the optimal semimajor axis for the two fixed-endpoints transfer is identified. Based on the proposed solution procedure for the optimal two fixed-endpoints transfer, a contour of the minimum cost for different initial and final coasting parameters is obtained. Finally, a numerical optimization algorithm (e.g., evolutionary algorithm) can be used to solve this global minimization problem. A numerical example is provided to show how to apply the proposed technique.  相似文献   
13.
Since the birth of X-ray astronomy, spectral, spatial and timing observation improved dramatically, procuring a wealth of information on the majority of the classes of the celestial sources. Polarimetry, instead, remained basically unprobed. X-ray polarimetry promises to provide additional information procuring two new observable quantities, the degree and the angle of polarization. Polarization from celestial X-ray sources may derive from emission mechanisms themselves such as cyclotron, synchrotron and non-thermal bremsstrahlung, from scattering in aspheric accreting plasmas, such as disks, blobs and columns and from the presence of extreme magnetic field by means of vacuum polarization and birefringence. Matter in strong gravity fields and Quantum Gravity effects can be studied by X-ray polarimetry, too. POLARIX is a mission dedicated to X-ray polarimetry. It exploits the polarimetric response of a Gas Pixel Detector, combined with position sensitivity, that, at the focus of a telescope, results in a huge increase of sensitivity. The heart of the detector is an Application-Specific Integrated Circuit (ASIC) chip with 105,600 pixels each one containing a full complete electronic chain to image the track produced by the photoelectron. Three Gas Pixel Detectors are coupled with three X-ray optics which are the heritage of JET-X mission. A filter wheel hosting calibration sources unpolarized and polarized is dedicated to each detector for periodic on-ground and in-flight calibration. POLARIX will measure time resolved X-ray polarization with an angular resolution of about 20 arcsec in a field of view of 15 × 15 arcmin and with an energy resolution of 20% at 6 keV. The Minimum Detectable Polarization is 12% for a source having a flux of 1 mCrab and 105 s of observing time. The satellite will be placed in an equatorial orbit of 505 km of altitude by a Vega launcher. The telemetry down-link station will be Malindi. The pointing of POLARIX satellite will be gyroless and it will perform a double pointing during the earth occultation of one source, so maximizing the scientific return. POLARIX data are for 75% open to the community while 25% + SVP (Science Verification Phase, 1 month of operation) is dedicated to a core program activity open to the contribution of associated scientists. The planned duration of the mission is one year plus three months of commissioning and SVP, suitable to perform most of the basic science within the reach of this instrument. A nice to have idea is to use the same existing mandrels to build two additional telescopes of iridium with carbon coating plus two more detectors. The effective area in this case would be almost doubled.  相似文献   
14.
Quality assessment of the Italian Landslide Inventory using GIS processing   总被引:4,自引:1,他引:3  
Landslides constitute one of the most important natural hazards in Italy as they are widespread and result in considerable damage and fatalities every year. The Italian Landslide Inventory (IFFI) Project was launched in 1999 with the aim of identifying and mapping landslides over the entire Italian territory. The inventory currently holds over 480,000 landslides and has been available by means of Web services since 2005. The aim of this study is to define quality indices for evaluation of the homogeneity and completeness of the IFFI database. In order to estimate the completeness of the landslide attribute information, a heuristic approach has been used to assign weighting values to significant parameters selected from the landslide data sheet. The completeness and homogeneity of the landslide mapping has been evaluated by means of three different methods: an area-frequency distribution analysis; the proximity of the landslides surveyed to urban areas; variation of the landslide index within the same lithology. The quality indices have allowed identification of areas with a high level of completeness and critical areas in which the data collected have been underestimated or are not very accurate. The quality assessment of collected and stored data is essential in order to use the IFFI database for definition and implementation of landslide susceptibility models and for land use planning and management.  相似文献   
15.
We present experimental results showing the impact of the proposed LightSquared (LS) Long-term Evolution (LTE) signals on both GPS and Galileo civil modulations in the L1/E1 band. The experiments were conducted in radiated mode in a large anechoic chamber. Three Galileo enabled receivers were chosen for the tests, and a state of the art GNSS signal generator was used to simulate both GPS and Galileo signals. The LTE signals were generated by an Agilent Programmable Signal Generator with a license to generate the signals according to the 3GPP LTE FDD standard. The interference impact was measured in terms of a Carrier-to-Noise power spectral density ratio (C/N 0) degradation, in accordance with the methodology which the LS/GPS Technical Working Group (TWG) established by mandate of the FCC. A model for determining the impact of the LS signal on the considered GNSS signals is provided and is validated against experimental data. It is shown that the Galileo E1 Open Service (OS) signal is marginally more susceptible to this form of interference than the GPS L1 C/A signal due to its greater proximity to the lower edge of the L1 band. The impact of LS interference was further analyzed in terms of pseudorange and position errors. Despite its relevance for most GNSS users, this aspect was not considered by the TWG. Measurement and position domain analysis along with the study of the LS impact on the Galileo OS signals are the major contributions. The analysis confirms the results obtained by the TWG and shows that the receiver front-end plays a major role in protecting GNSS signals against RF interference. While it appears that, for now, the LS network will not be deployed, the approach taken and the results obtained herein can be readily adapted for any future terrestrial mobile network that may take the place of LS.  相似文献   
16.
The rates of the reduction of Cr(VI) with S(IV) were measured in deaerated NaCl solution as a function of pH, temperature and ionic strength. The rates of the reaction were found to be first order with respect to Cr(VI) and second order with respect to S(IV), in agreement with previous results obtained at concentrations two order higher than the present study. The reaction also showed a first-order dependence of the rates on the concentration of the proton and a small influence of temperature with an apparent energy of activation ΔHapp of 22.8 ± 3.4 kJ/mol. The rates were independent of ionic strength from 0.01 to 1 M. The rate of Cr(VI) reduction is described by the general expression
−d[Cr(VI)]/dt=k[Cr(VI)][S(IV)]2
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