A Smart Sensor System for Detecting Hydrocarbon Volatile Organic Compounds in Sea Water          下载免费PDF全文

Alessandro Tonacci  Daniele Corda  Gennaro Tartarisco  Giovanni Pioggia  Claudio Domenici 《洁净——土壤、空气、水》2015,43(1):147-152

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Effects of pore-scale dispersion,degree of heterogeneity,sampling size,and source volume on the concentration moments of conservative solutes in heterogeneous formations     

Daniele Tonina  Alberto Bellin 《Advances in water resources》2008

Pore-scale dispersion (PSD), aquifer heterogeneity, sampling volume, and source size influence solute concentrations of conservative tracers transported in heterogeneous porous formations. In this work, we developed a new set of analytical solutions for the concentration ensemble mean, variance, and coefficient of variation (CV), which consider the effects of all these factors. We developed these models as generalizations of the first-order solutions in the log-conductivity variance of point concentration proposed by [Fiori A, Dagan G. Concentration fluctuations in aquifer transport: a rigorous first-order solution and applications. J Contam Hydrol 2000;45(1–2):139–163]. Our first-order solutions compare well with numerical simulations for small and moderate formation heterogeneity and from small to large sampling and source volumes. However, their performance deteriorates for highly heterogeneous formations. Successively, we used our models to study the interplay among sampler size, source volume, and PSD. Our analysis shows a complex and important interaction among these factors. Additionally, we show that the relative importance of these factors is also a function of plume age, of aquifer heterogeneity, and of the measurement location with respect to the mean plume center of gravity. We found that the concentration moments are chiefly controlled by the sampling volume with pore-scale dispersion playing a minor role at short times and for small source volumes. However, the effect of the source volume cannot be neglected when it is larger than the sampling volume. A different behavior occurs for long periods, which may be relevant for old contaminations, or for small injection volumes. In these cases, PSD causes a significant dilution, which is reflected in the concentration statistics. Additionally, at the center of the mean plume, where high concentrations are most likely to occur, we found that sampling volume and PSD are attenuating mechanisms for both concentration ensemble mean and coefficient of variation, except at very large source and sampler sizes, where the coefficient of variation increases with sampler size and PSD. Formation heterogeneity causes a faster reduction of the ensemble mean concentrations and a larger uncertainty at the center of the mean plume. Therefore, our results highlight the importance of considering the combined effect of formation heterogeneity, exposure volume, PSD, source size, and measurement location in performing risk assessment.  相似文献   

Subsurface mass redistributions at Mount Etna (Italy) during the 1995–1996 explosive activity detected by microgravity studies     

Gennaro Budetta  Daniele Carbone  & Filippo Greco 《Geophysical Journal International》1999,138(1):77-88

Gravity changes are presented from a series of field microgravity surveys conducted at Mt Etna between August 1994 and November 1996, a period including the 1995–1996 explosive summit activity. Data were collected along a microgravity network of 69 stations at a monthly to annual sampling rate, depending on each subarray of the network.
  Results show that seasonal changes in water level within the volcano may induce gravity changes of up to 20  μgal on Etna's southern slope, and indicate that significant magma movement occurred within and below Etna's edifice between 1994 and 1996. In particular, between September 1994 and October 1995, a mass increase of 2 × 10¹⁰  kg occurred 2000  m beneath the summit craters. Between October 1995 and July 1996 this mass was lost, while another 2 × 10¹⁰  kg was injected at about 1000  m  a.s.l. into the 1989 fracture system. From the gravity data alone, it is not possible to distinguish whether the first shallow intrusion (1994–1995) was then injected laterally into the 1989 fracture, or summit activity was fed by the first shallow intrusion, while new magma entered the 1989 fracture system.
  While magma was being redistributed within the volcanic edifice, measurements along an E–W-trending profile on the southern slope of the volcano detected some 1.5 × 10¹¹  kg of magma accumulating 2–3  km below sea level between October 1995 and November 1996.  相似文献   

S-wave splitting intensity analysis and inversion     

Daniele Boiero  Claudio Bagaini 《Geophysical Prospecting》2019,67(2):362-378

Analysing S-wave splitting has become a routine step in processing multicomponent data. Typically, this analysis leads to determining the principal directions of a transversely isotropic medium with a horizontal symmetry axis, which is assumed to be responsible for azimuthal anisotropy, and to the time delays between the fast and slow S-waves. These parameters are commonly estimated layer-by-layer from the top. Errors in layer stripping occurring in shallow layers might propagate to deeper layers. We propose a method for S-wave splitting analysis and compensation that consists of inverting interval values of splitting intensity to obtain a model of anisotropic parameters that vary with time and/or depth. Splitting intensity is a robust attribute with respect to structural variations and is commutative, which means that it can be summed along a ray (or throughout a sensitivity kernel volume) and can be linearly related to anisotropic perturbations at depth. Therefore, it is possible to estimate anisotropic properties within a geological formation (e.g. the reservoir) by analysing the differences of splitting intensity measured at the top and at the bottom of the layer. This allows us to avoid layer stripping, in particular, for shallow layers where anisotropic parameters are difficult to estimate due to poor coverage, and it makes S-wave splitting analysis simpler to apply. We demonstrate this method on synthetic and real data. Because the splitting intensity attribute shows usefulness in S-wave splitting analysis in transversely isotropic media, we extend the splitting intensity theory to lower symmetry classes. It enables the characterization of tilted transversely isotropic and tilted orthorhombic media, opening new opportunities for anisotropic model building.  相似文献   

Mapping river bathymetries: Evaluating topobathymetric LiDAR survey     

Daniele Tonina  James A. McKean  Rohan M. Benjankar  C. Wayne Wright  Jaime R. Goode  Qiuwen Chen  William J. Reeder  Richard A. Carmichael  Michael R. Edmondson 《地球表面变化过程与地形》2019,44(2):507-520

Advances in topobathymetric LiDARs could enable rapid surveys at sub-meter resolution over entire stream networks. This is the first step to improving our knowledge of riverine systems, both their morphology and role in ecosystems. The Experimental Advanced Airborne Research LiDAR B (EAARL-B) system is one such topobathymetric sensor, capable of mapping both terrestrial and aquatic systems. Whereas the original EAARL was developed to survey littoral areas, the new version, EAARL-B, was also designed for riverine systems but has yet to be tested. Thus, we evaluated the ability of EAARL-B to map bathymetry and floodplain topography at sub-meter resolution in a mid-size gravel-bed river. We coupled the EAARL-B survey with highly accurate field surveys (0.03 m vertical accuracy and approximately 0.6 by 0.6 m resolution) of three morphologically distinct reaches, approximately 200 m long 15 m wide, of the Lemhi River (Idaho, USA). Both point-to-point and raster-to-raster comparisons between ground and EAARL-B surveyed elevations show that differences (ground minus EAARL-B surveyed elevations) over the entire submerged topography are small (root mean square error, RMSE, and median absolute error, M, of 0.11 m), and large differences (RMSE, between 0.15 and 0.38 m and similar M) are mainly present in areas with abrupt elevation changes and covered by dense overhanging vegetation. RMSEs are as low as 0.03 m over paved smooth surfaces, 0.07 m in submerged, gradually varying topography, and as large as 0.24 m along banks with and without dense, tall vegetation. EAARL-B performance is chiefly limited by point density in areas with strong elevation gradients and by LiDAR footprint size (0.2 m) in areas with topographic features of similar size as the LiDAR footprint. © 2018 John Wiley & Sons, Ltd.  相似文献   

A new algorithm for estimating ground elevation and vegetation characteristics in coastal salt marshes from high-resolution UAV-based LiDAR point clouds     

Daniele Pinton  Alberto Canestrelli  Benjamin Wilkinson  Peter Ifju  Andrew Ortega 《地球表面变化过程与地形》2020,45(14):3687-3701

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Rotating magnetopolytropes: spherical figures of equilibrium due to balance of magnetic field and rotation     

Daniele Galli 《Astrophysics and Space Science》1993,204(1):111-127

In this paper we compute spherical figures of equilibrium resulting from the balance of toroidal magnetic field and rotation. These two distortion effects are assumed to act on rotating magneto-polytropic constant-mass sequences, that is, sequences with each of their members having mass constant and equal to that of the corresponding nondistorted model.  相似文献   

Hydrological and biogeochemical features of the Northern Adriatic Sea in the period 2003–2006     

Giorgio Socal  Francesco Acri  Mauro Bastianini  Fabrizio Bernardi Aubry  Franco Bianchi  Daniele Cassin  Joan Coppola  Amelia De Lazzari  Vinko Bandelj  Gianpiero Cossarini  Cosimo Solidoro 《Marine Ecology》2008,29(4):449-468

This paper reports on the main biogeochemical properties of the Northern Adriatic Sea in the period May 2003–November 2006 within the framework of the European program INTERREG III Italy‐Slovenia. Spatial and temporal distributions of water density, dissolved oxygen, nutrients (nitrogen, phosphorous and silicon) and chlorophyll a are presented. Multivariate methods such as fuzzy k‐means, self‐organising maps and cluster analysis were used to identify the different water masses and to characterise the temporal and spatial variability of the main biogeochemical features present in the area. The results confirm that the Po River outflows and the meteorological forcing factors are the main components triggering the alternation of stratification and mixing of the water column and that strongly affect the trophic state of the basin. In general, oligotrophic conditions dominate, and were more pronounced offshore, but mesotrophy occurred episodically in May 2004 and July 2005, when phytoplankton blooms were observed concomitant with vertical stability of the water column. A marked interannual variability was also observed, supporting the importance of maintaining long‐term observations of the basin.  相似文献   

The effects of discharge and slope on hyporheic flow in step‐pool morphologies          下载免费PDF全文

Marwan A. Hassan  Daniele Tonina  Roger D. Beckie  Matthew Kinnear 《水文研究》2015,29(3):419-433

This paper focuses on surface–subsurface water exchange in a steep coarse‐bedded stream with a step‐pool morphology. We use both flume experiments and numerical modelling to investigate the influence of stream discharge, channel slope and sediment hydraulic conductivity on hyporheic exchange. The model step‐pool reach, whose topography is scaled from a natural river, consists of three step‐pool units with 0.1‐m step heights, discharges ranging between base and over‐bankfull flows (scaled values of 0.3–4.5 l/s) and slopes of 4% and 8%. Results indicate that the deepest hyporheic flow occurs with the steeper slope and at moderate discharges and that downwelling fluxes at the base of steps are highest at the largest stream discharges. In contrast to findings in a pool‐riffle morphology, those in this study show that steep slopes cause deeper surface–subsurface exchanges than gentle slopes. Numerical simulation results show that the portion of the hyporheic zone influenced by surface water temperature increases with sediment hydraulic conductivity. These experiments and numerical simulations emphasize the importance of topography, sediment permeability and roughness elements along the channel surface in governing the locations and magnitude of downwelling fluxes and hyporheic exchange. Our results show that hyporheic zones in these steep streams are thicker than previously expected by extending the results from streams with pool‐riffle bed forms. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Early to mid‐Holocene climate change at Lago dell'Accesa (central Italy): climate signal or anthropogenic bias?     

Walter Finsinger  Daniele Colombaroli  Jacques‐Louis De Beaulieu  Verushka Valsecchi  Boris Vannière  Elisa Vescovi  Emmanuel Chapron  André F. Lotter  Michel Magny  Willy Tinner 《第四纪科学杂志》2010,25(8):1239-1247

Despite the high potential of pollen records for climate reconstruction, pollen–climate relationships may be biased due to past and present human activities on the landscape. We use (i) transfer functions based on modern pollen–climate relationships to infer seasonal temperature and summer precipitation for the period 11 500–4500 cal. a BP and (ii) lake‐level change records based on different sedimentary proxies in multiple cores that are mainly indicative for summer hydrology at Lago dell'Accesa (central Italy). Quantitative reconstructions indicate lowest summer precipitation during two phases (8500–7700 cal. a BP and after 6000 cal. a BP) and a gradual winter temperature increase from 11 500 to ca. 8000 cal. a BP. Lowest summer precipitation was reconstructed during these phases characterised by vegetation shifts from open forests dominated by summergreen oaks (Quercus) to forests dominated by evergreen oaks (Quercus ilex), which are at present most abundant where summer drought is stronger. Similarly, the lake‐level record indicates two long‐lasting low summer precipitation phases (8800–7700 and 6400–4400 cal. a BP) that were interrupted by short‐term high summer precipitation events. Based on the broad agreement between the pollen‐inferred summer precipitation and the low‐frequency lake‐level changes, we suggest that the duration of the high summer precipitation events may have been too short to maintain drought‐sensitive trees, which may have been affected by high mortality rates when summer dry conditions returned. Although past and modern pollen–climate relationships may very likely have been affected by human activities since the Neolithic (i.e. when exploitation of the landscape started), we reject the hypothesis of a significant anthropogenic bias in the pollen‐based climate reconstruction. In addition, we suggest that pollen‐based and lake‐level reconstructions may have different inherent abilities of capturing high‐ and low‐frequency precipitation signals. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献