Crystal chemistry, surface morphology and X-ray photoelectron spectroscopy of Fe-rich osumilite from Mt. Arci, Sardinia (Italy)     

Chiara Elmi  Maria Franca Brigatti  Luca Pasquali  Monica Montecchi  Angela Laurora  Daniele Malferrari  Stefano Nannarone 《Physics and Chemistry of Minerals》2010,37(8):561-569

Microprobe analysis, single crystal X-ray diffraction, X-ray photoelectron spectroscopy, atomic force microscopy, and X-ray absorption spectroscopy were applied on Fe-rich osumilite from the volcanic massif of Mt. Arci, Sardinia, Italy. Osumilite belongs to the space group P6/mcc with unit cell parameters a = 10.1550(6), c = 14.306(1) Å and chemical formula (K_0.729)_C (Na_0.029)_B (Si_10.498 Al_1.502)_T1 (Al_2.706 Fe _0.294 ²⁺ )_T2 (Mg_0.735 Mn_0.091 Fe _1.184 ²⁺ )_AO₃₀. Structure refinement converged at R = 0.0201. Unit cell parameter a is related to octahedral edge length as well as to Fe²⁺ content, unlike the c parameter which does not seem to be affected by chemical composition. The determination of the amount of each element on the mineral surface, obtained through X-ray photoelectron spectroscopy high-resolution spectra in the region of the Si_2p, Al_2p, Mg_1s and Fe_2p core levels, suggests that Fe presents Fe²⁺ oxidation state and octahedral coordination. Two peaks at 103.1 and 100.6 eV can be related to Si⁴⁺ and Si¹⁺ components, respectively, both in tetrahedral coordination. The binding energy of Al_2p, at 74.5 eV, indicates that Al is mostly present in the distorted T2 site, whereas the Mg peak at 1,305.2 eV suggests that this cation is located at the octahedral site. X-ray absorption at the Fe L_2,3-edges confirms that iron is present in the mineral structure, prevalently in the divalent state and at the A octahedral site.  相似文献   

Sequential solution to Kepler’s equation     

Jeremy J. Davis  Daniele Mortari  Christian Bruccoleri 《Celestial Mechanics and Dynamical Astronomy》2010,108(1):59-72

Seven sequential starter values for solving Kepler’s equation are proposed for fast orbit propagation. The proposed methods have constant complexity (not iterative), do not require pre-computed data, and can be implemented in just a few lines of code. The resulting sequential orbit propagation techniques can be done at different levels of accuracy and speed, depending essentially on the value of orbit eccentricity. Accuracy and algorithmic complexity are evaluated for all the proposed approaches and compared with several existing single-point techniques to solve Kepler’s equation. The new methods obtain improved accuracy at lower computational cost as compared to the best existing methods.  相似文献   

U-Pb Zircon Geochronology with an Integrated LA-ICP-MS Microanalytical Workstation: Achievements in Precision and Accuracy   总被引：1，自引：0，他引：1  

Luigi A. Solari  Arturo Gómez-Tuena  Juan Pablo Bernal  Ofelia Pérez-Arvizu  Martin Tanner 《Geostandards and Geoanalytical Research》2010,34(1):5-18

Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) is a microanalytical tool especially suitable for providing fast and precise U-Pb geochronological results on zircon grains. A new 193 nm excimer laser adapted to a micromachining workstation, equipped with a newly designed two-volume ablation cell and coupled with a quadrupole ICP-MS, is presented here. The system was tuned routinely to achieve sensitivities in the range of 3000 cps/μg g⁻¹ for ²³⁸U (< 2% RSD), with a 34 μm spot size, at 5 Hz and ∼ 8 J cm⁻², while ablating the NIST SRM 612 glass reference material. The system was capable of providing fast (< 1.5 minutes each analysis) and precise (generally < 1.5% 1s errors) ²⁰⁶Pb/²³⁸U zircon ages. The ages of widely used reference material zircons (Plesovice, 337 Ma; Temora, 416 Ma; R33, 418 Ma; Sri Lanka, 564 Ma; 91500, 1065 Ma) could be precisely matched, with an accuracy on isotopic ratios that ranged from ∼ 2 to ∼ 6%, depending on the homogeneity of the natural reference materials.  相似文献   

Holocene environmental and climatic changes at Gorgo Basso,a coastal lake in southern Sicily,Italy     

Willy Tinner  Jacqueline F.N. van Leeuwen  Daniele Colombaroli  Elisa Vescovi  W.O. van der Knaap  Paul D. Henne  Salvatore Pasta  Stefania D'Angelo  Tommaso La Mantia 《Quaternary Science Reviews》2009,28(15-16):1498-1510

We used a new sedimentary record to reconstruct the Holocene vegetation and fire history of Gorgo Basso, a coastal lake in south-western Sicily (Italy). Pollen and charcoal data suggest a fire-prone open grassland near the site until ca 10,000 cal yr BP (8050 cal BC), when Pistacia shrubland expanded and fire activity declined, probably in response to increased moisture availability. Evergreen Olea europaea woods expanded ca 8400 to decline abruptly at 8200 cal yr BP, when climatic conditions became drier at other sites in the Mediterranean region. Around 7000 cal yr BP evergreen broadleaved forests (Quercus ilex, Quercus suber and O. europaea) expanded at the cost of open communities. The expansion of evergreen broadleaved forests was associated with a decline of fire and of local Neolithic (Ficus carica–Cerealia based) agriculture that had initiated ca 500 years earlier. Vegetational, fire and land-use changes ca 7000 cal yr BP were probably caused by increased precipitation that resulted from (insolation-forced) weakening of the monsoon and Hadley circulation ca 8000–6000 cal yr BP. Low fire activity and dense coastal evergreen forests persisted until renewed human activity (probably Greek, respectively Roman colonists) disrupted the forest ca 2700 cal yr BP (750 BC) and 2100 cal yr BP (150 BC) to gain open land for agriculture. The intense use of fire for this purpose induced the expansion of open maquis, garrigue, and grassland-prairie environments (with an increasing abundance of the native palm Chamaerops humilis). Prehistoric land-use phases after the Bronze Age seem synchronous with those at other sites in southern and central Europe, possibly as a result of climatic forcing. Considering the response of vegetation to Holocene climatic variability as well as human impact we conclude that under (semi-)natural conditions evergreen broadleaved Q. ilex–O. europaea (s.l.) forests would still dominate near Gorgo Basso. However, forecasted climate change and aridification may lead to a situation similar to that before 7000 cal yr BP and thus trigger a rapid collapse of the few relict evergreen broadleaved woodlands in coastal Sicily and elsewhere in the southern Mediterranean region.  相似文献   

Hydrothermal dolomitization in platform and basin carbonate successions during thrusting: A hydrocarbon reservoir analogue (Mesozoic of Venetian Southern Alps,Italy)     

Paola Ronchi  Daniele Masetti  Stefano Tassan  Davide Camocino 《Marine and Petroleum Geology》2012,29(1):68-89

The Early Jurassic dolomitized carbonates in the Venetian Alp, represent a surface analogue of the hydrocarbon exploration targets in Adriatic offshore and Po Plain, Italy. Dolomitization affected the carbonate platform of Monte Zugna Formation (Lower Jurassic) and the Neptunian dikes breccia in the pelagic Maiolica Formation (Uppermost Jurassic–Lower Cretaceous) improving the poro-perm characteristics. Petrography, stable isotope, strontium isotope ratio, trace element and fluid inclusion analyses were carried out on samples from the Monte Grappa Anticline, which is the direct analogue for subsurface. The petrographic analyses showed a first pervasive, replacement dolomitization phase (D1) followed by volumetrically less important dolomite cement precipitation phases (D2, D3, DS). The same, quite wide range of oxygen isotope (?9 to ?2‰ V-PDB) is observed in all dolomite types. The δ¹³C range is in the positive field of marine derived carbonate (from +0.5 to +3.2‰ PDB). The trace element analysis showed a slight enrichment in Fe and Mn contents in the Monte Zugna dolostones with respect the original limestone. The same dolomite precipitation temperature (up to 105 °C Th) was observed in the replacement and cement dolomites, suggesting a unique dolomitization event. This temperature, largely higher than the maximum burial temperature (about 50 °C), supports a hydrothermal origin of the dolomitizing fluids, which had a seawater to brackish composition. The data collected suggest a hydrothermal dolomitization occurring during to the South Alpine thrusting according to the “squeegee model”. The interpretation is consistent with the dolomitization model proposed for similar Jurassic successions in the Central Southern Alps. This study indicates that the deformed foreland and thrust fold belts carbonates in Po Plain and Adriatic offshore are suitable to be dolomitized, and therefore reflect an efficient hydrocarbon exploration play.  相似文献   

An individual-based population dynamic model for estimating biomass yield and nutrient fluxes through an off-shore mussel (Mytilus galloprovincialis) farm     

Daniele Brigolin  Gabriele Dal Maschio  Federico Rampazzo  Michele Giani  Roberto Pastres 《Estuarine, Coastal and Shelf Science》2009

The fluxes of carbon, nitrogen and phosphorus through an off-shore long-line Mytilus galloprovincialis farm during a typical rearing cycle were estimated by combining a simple population dynamic model, based on a new individual model, and a set of field data, concerning the composition of the seston, as well as that of mussel meat and faeces. The individual model, based on an energy budget, was validated against a set of original field data, which were purposely collected from July 2006 to May 2007 in the North-Western Adriatic Sea (Italy) and was further tested using historical data. The model was upscaled to the population level by means of a set of Monte Carlo simulations, which were used for estimating the size structure of the population. The daily fluxes of C, N and P associated with mussel filtration, excretion and faeces and pseudo-faeces production were integrated over the 10-month-long rearing cycle and compared with the total amount of C, N and P removed by harvesting. The results indicate that the individual model compares well with an existing literature model and provides reliable estimations of the growth of mussel specimen over a range of trophic conditions which are typical of the Northern Adriatic Sea coastal area. The results of the budget calculation indicate that, even though the harvest represents a net removal of phosphorus and nitrogen from the ecosystem, the mussel farm increases the retention time of both nutrients in the coastal area, via the deposition of faeces and pseudo-faeces on the sea-bed. In fact, the amount of nitrogen associated with deposition is approximately twice the harvested one and the amount of phosphorus is approximately five times higher. These findings are in qualitative agreement with the results of literature budget and model calculations carried out in a temperate coastal embayment. This agreement suggests that the proper assessment of the overall effect of long-line mussel farming on both the benthic and pelagic ecosystem asks for an integrated modelling approach, which should include the dynamic of early diagenesis processes, as well as of that of nutrients released from the surface sediment.  相似文献   

Hybrid character and pre-eruptive events of Mt Amiata volcano (Italy) inferred from geochronological,petro-geochemical and isotopic data     

Anita Cadoux  Daniele L. Pinti 《Journal of Volcanology and Geothermal Research》2009,179(3-4):169-190

A new geochronological and geochemical study was carried out to better constrain the petrogenesis and eruptive history of Monte Amiata, a large Pleistocene trachydacitic volcano of Southern Tuscany. Previous studies suggested a magma mixing origin between calc-alkaline silicic melts from the Tuscan Magmatic Province (TMP) and potassic mafic melts like those found in the Roman Magmatic Province (RMP). Two eruptive episodes–the first at ca. 300 kyr, the second at ca. 200 kyr–were distinguished from the few available ages. However, both the involvement of a RMP-like melt as mafic end-member and the timing of volcanic activity remained to be ascertained. The K–Ar ages obtained on plagioclase, sanidine and glass separated from Mt Amiata volcanic rocks demonstrate the sanidine is the most suitable phase for K–Ar dating. Sanidine yields ages of 304–293 kyr for the basal trachydacitic unit (BTC), 298–280 kyr in the domes unit (DLC) and unexpected older ages of 312–308 kyr for the more mafic summit lava unit (OLL). A careful re-examination of the literature ages together with those obtained in this study shows that they tend to a common age of ca. 300 kyr whatever the volcanic unit. We interpret this as a reset of the K–Ar chronometer in response to a consequent recharge of the silicic magma reservoir by hot mafic melts. This recharge most probably triggered the first volcanic eruption of Mt Amiata magmas. In our model, we suppose an initially chemically-stratified magma chamber; the input of deep hot mafic melts reset the crystals clock and probably allowed the eruption of the huge amount of trachydacitic crystal mush. We propose that the controversial BTC unit could have emplaced during a non-explosive eruption if we consider either pre-eruption passive degassing or extrusion of the trachydacites as magmatic foam.First Pb isotopic data of mafic enclaves from the trachydacitic units, together with major and trace elements and new Sr and Nd data support the magma mixing as the dominant process at the origin of the Mt Amiata volcanic rocks. The similar LILE/HFSE ratios evidenced in this contribution between the magmatic enclaves of Mt Amiata and RMP volcanic rocks, together with their comparable Sr, Nd and Pb isotopic compositions, definitively argue for the involvement of a RMP-like melt in the mixing. The Mt Amiata is thus indisputably a hybrid volcano between TMP and RMP in terms of petrogenesis and ages.  相似文献   

Anomalously deep earthquakes in northwestern Italy     

Marco Cattaneo  Paolo Augliera  Stefano Parolai  Daniele Spallarossa 《Journal of Seismology》1999,3(4):421-435

It is usually assumed that earthquakes in intraplate regions occur in the upper crust, and northwestern Italy is generally assigned to this kind of normal seismicity. In this work, the depth distribution of the events localized in this area by the Istituto Geofisico Geodetico (IGG) seismic network in the period 1991–1997 is analyzed in detail. In particular, the location capability of the network is discussed, adopting as reference quarry blasts (for the epicentral position) and the locations obtained from a dense temporary network (for the depth estimate). Within the so-obtained error limits, the depth distribution of events show a characteristic pattern: while for most of the area covered by the network the well-located seismicity lies within the first 20 km of depth, in a band following the inner arc of the Western Alps, numerous events have anomalously large focal depths, reaching a maximum of 114 km. These depth determinations cannot be attributed to instabilities of the location procedure: different choices of the propagation models used for the hypocentral determination led to very similar depth values, always significantly larger than the standard values for the surrounding areas. A strong correlation has been found between the 3-dimensional distribution of these foci and the P-wave propagation anomalies obtained from tomographic studies, suggesting a direct link between elastic and rheological properties of lower crust and upper mantle in this area.  相似文献   

Water table variations in Atacama Desert alluvial fans: discussion of “Evidence of short-term groundwater recharge signal propagation from the Andes to the central Atacama Desert: a singular spectrum analysis approach”*     

Benoît Viguier  Hervé Jourde  Véronique Leonardi  Elisabeth Lictevout  Linda Daniele 《水文科学杂志》2020,65(9):1606-1613

ABSTRACT

Using a statistical approach, Scheihing attempts to demonstrate the direct influence of recharge events in the Precordillera and the Andean Piedmont on water table variations in downstream alluvial fans. The author “unquestionably” discards the existence of ephemeral recharge processes in alluvial fans although they are frequently impacted by major floods. However, the author does not consider previous publications about recharge processes in arid alluvial fans, the hydraulic setting of the Pampa del Tamarugal Aquifer (PTA) and anthropogenic pressure changes in the PTA. Because the sustainable management of groundwater resources in drylands depends on a good understanding of hydrogeological processes, we propose a thorough reinterpretation of the short- and long-term PTA water table variations addressed by the author. In this comment, we illustrate the limits of the sole use of a statistical approach for characterizing both recharge processes and factors controlling the water table variations in the Atacama Desert.  相似文献   

Seismic safety of reinforced concrete members and structures     

Hooshang Banon  Daniele Veneziano 《地震工程与结构动力学》1982,10(2):179-193

Based on cyclic load tests of large-scale reinforced concrete elements and assemblages, a probabilistic model of member failure is developed. The model gives the probability of survival at time t as a functional of damage ratio and dissipated energy up to t. After extension to multivariate survival of several members with correlated resistance, the model is used to calculate the safety of reinforced concrete frames subjected to given input motions. Results are in terms of the probability of local failure and of no failure anywhere in the system.  相似文献