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121.
Large silicic explosive eruptions are the most catastrophic volcanic events. Yet, the intratelluric mechanisms underlying are not fully understood. Here we report a field and laboratory study of the Kos Plateau Tuff (KPT, 161 ka, Aegean Volcanic Arc), which provides an excellent geological example of conduit processes that control magma vesiculation and fragmentation during intermediate- to large-scale caldera-forming eruptions. A prominent feature of the KPT is the occurrence of quite unusual platy-shaped tube pumice clasts in pyroclastic fall and current deposits from the early eruption phases preceding caldera collapse. On macroscopic and SEM observations, flat clast faces are elongated parallel to tube vesicles, while transverse surfaces often occur at ~ 45° to vesicle elongation. This peculiar pumice texture provides evidence of high shear stresses related to strong velocity gradients normal to conduit walls, which induced vesiculation and fragmentation of the ascending magma. Either an increasing mass discharge rate without adequate enlargement of a narrow central feeder conduit or a developing fissure-like feeder system related to incipient caldera collapse provided suitable conditions for the generation of plate tube pumice within magma volumes under high shear during the pre-climactic KPT eruption phases. This mechanism implies that the closer to the conduit walls (where the stronger are the velocity gradients) the larger was the proportion of plate vs. conventional (lensoid) juvenile fragments in the ascending gas–pyroclast mixture. Consequently, plate pumice clasts were mainly entrained in the outer portions of the jet and convecting regions of a sustained, Plinian-type, eruption column, as well as in occasional lateral blast currents generated at the vent. As a whole, plate pumice clasts in the peripheral portions of the column were transported at lower altitudes and deposited by fallout or partial collapse closer to the vent relative to lensoid ones that dominated in the inner column portions. The plate tube pumice proportion decreased abruptly up to disappearance during the emplacement of the main pyroclastic currents and lithic-rich breccias related to extensive caldera collapse at the eruption climax, as a consequence of an overall widening of the magma feeder system through the opening of multiple conduits and eruptive vents, along with fissure erosion, concomitant to the disruption of the collapsing block.  相似文献   
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In this work, 8‐hydroxyquinoline is used as the active sites in cross‐linked chitosan beads with epichlorohydrin (CT‐8HQ). The CT‐8HQ material was shaped in bead form and used for heavy metal removal from aqueous solution. The study was carried out at pH 5.0 with both batch and column methods and the maximum adsorption capacity of metal ions by the CT‐8HQ was attained in 4 h in the batch experiment. The adsorption capacity order was: Cu2+ > Ni2+ > Zn2+ for both mono‐ and multi‐component systems with batch conditions. From breakthrough curves with column conditions, the adsorption capacity followed the order Cu2+ > Zn2+ > Ni2+ for both mono‐ and multi‐component systems. The CT‐8HQ beads maintained good metal adsorption capacity for all five cycles with absorbent restoration achieved with the use of 1.0 mol L–1 HCl solution, with 90% regeneration.  相似文献   
124.
The conservation of large water resources is essential for the preservation of human life. The quantification and, more importantly, the speciation of chemical substances that indicate the presence of anthropogenic contamination in water resources are of great importance. This paper presents the results of analysis for the determination of organic, inorganic and total phosphorus, pseudo‐sulfur, and iron and manganese, in five fractions, in water sediments collected from the Capivara Hydroelectric Power Plant, Brazil. A study on the seasonal variation of these parameters was conducted, with data having been collected in the winter and in the summer, at two sites along the dam, 5 km apart, close to the city of Primeiro de Maio. Phosphorous was found in sediments and adjacent soil in the organic form (OP), and was used as an indicator of anthropogenic influence on the reservoir banks. Speciation of potentially toxic Mn showed that it is present in the exchangeable fraction of the 0–5 cm depth layer (sediment/water interface), making its transfer to the water column possible. Results from this study showed that domestic and industrial effluent treatment measures are needed for the preservation of the quality of aquatic environments.  相似文献   
125.
Crystalline continental rocks and associated crust‐contaminated basaltic rocks were unexpectedly dredged on the crest and at seamounts of the Rio Grande Rise, South Atlantic. Zircon U–Pb ages of one gabbro (ca. 2,200 Ma) and four granitoids (between ca. 1,430–480 Ma) indicate that the breakup of SW Gondwana left behind continental fragments of dominantly African age. These rocks may have been incorporated into the oceanic lithosphere by complex processes including rifting and interaction of the Tristan‐Gough mantle plume with hyperextended continental margins. Until ca. 80–70 Ma, the Rio Grande Rise and an old portion of the Walvis Ridge formed a conjugate pair of aseismic ridges, and the Tristan‐Gough plume was positioned at the Mid‐Atlantic Ridge. The finding of continental rock fragments in one of these conjugate pairs opens new perspectives on the mechanisms of continental break‐up, the nature of this conjugate pair, and the geodynamic evolution of rifted Gondwana margins in the South Atlantic.  相似文献   
126.
It is well established that the Argentine passive margin is of the rifted volcanic margin type. This classification is based primarily on the presence of a buried volcanic wedge beneath the continental slope, manifested by seismic data as a seaward dipping reflector sequence (SDRS). Here, we investigate the deep structure of the Argentine volcanic margin at 44°S over 200 km from the shelf to the deep oceanic Argentine Basin. We use wide-angle reflection/refraction seismic data to perform a joint travel time inversion for refracted and reflected travel times. The resulting P-wave velocity-depth model confirms the typical volcanic margin structure. An underplated body is resolved as distinctive high seismic velocity (vp up to 7.5 km/s) feature in the lower crust in the prolongation of a seaward dipping reflector sequence. A remarkable result is that a second, isolated body of high seismic velocity (vp up to 7.3 km/s) exists landward of the first high-velocity feature. The centres of both bodies are 60 km apart. The high-velocity lower-crustal bodies likely were emplaced during transient magmatic–volcanic events accompanying the late rifting and initial drifting stages. The lateral variability of the lower crust may be an expression of a multiple rifting process in the sense that the South Atlantic rift evolved by instantaneous breakup of longer continental margin segments. These segments are confined by transfer zones that acted as rift propagation barriers. A lower-crustal reflector was detected at 3 to 5 km above the modern Moho and probably represents the lower boundary of stretched continental crust. With this finding we suggest that the continent–ocean boundary is situated 70 km more seaward than in previous interpretations.  相似文献   
127.
Groundwater may be highly enriched in dissolved carbon species, but its role as a source of carbon to coastal waters is still poorly constrained. Exports of deep and shallow groundwater-derived dissolved carbon species from a small subtropical estuary (Korogoro Creek, Australia, latitude ?31.0478°, longitude 153.0649°) were quantified using a radium isotope mass balance model (233Ra and 224Ra, natural groundwater tracers) under two hydrological conditions. In addition, air-water exchange of carbon dioxide and methane in the estuary was estimated. The highest carbon inputs to the estuary were from deep fresh groundwater in the wet season. Most of the dissolved carbon delivered by groundwater and exported from the estuary to the coastal ocean was in the form of dissolved inorganic carbon (DIC; 687 mmol m?2 estuary day?1; 20 mmol m?2 catchment day?1, respectively), with a large export of alkalinity (23 mmol m?2 catchment day?1). Average water to air flux of CO2 (869 mmol m?2 day?1) and CH4 (26 mmol m?2 day?1) were 5- and 43-fold higher, respectively, than the average global evasion in estuaries due to the large input of CO2- and CH4-enriched groundwater. The groundwater discharge contribution to carbon exports from the estuary for DIC, dissolved organic carbon (DOC), alkalinity, CO2, and CH4 was 22, 41, 3, 75, and 100 %, respectively. The results show that CO2 and CH4 evasion rates from small subtropical estuaries surrounded by wetlands can be extremely high and that groundwater discharge had a major role in carbon export and evasion from the estuary and therefore should be accounted for in coastal carbon budgets.  相似文献   
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129.
Experimental analysis was performed using multiplicative algebraic reconstruction technique (MART) to map the ionosphere over Brazil. Code and phase observations from the global navigation satellite system (GNSS) together with the international reference ionosphere (IRI) enabled the estimation of ionospheric profiles and total electron content (TEC) over the entire region. Twenty-four days of data collected from existing ground-based GNSS receivers during the recent solar maximum period were used to analyze the performance of the MART algorithm. The results were compared with four ionosondes. It was demonstrated that MART estimated the electron density peak with the same degree of accuracy as the IRI model in regions with appropriate geometrical coverage by GNSS receivers for tomographic reconstruction. In addition, the slant TEC, as estimated with MART, presented lower root-mean-square error than the TEC calculated by ionospheric maps available from the International GNSS Service (IGS). Furthermore, the daily variations of the ionosphere were better represented with the algebraic techniques, compared to the IRI model and IGS maps, enabling a correlation of the elevation of the ionosphere at higher altitudes with the equatorial ionization anomaly intensification. The tomographic representations also enabled the detection of high vertical gradients at the same instants in which ionospheric irregularities were evident.  相似文献   
130.
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