Snow cover variability across central Canada (1978–2002) derived from satellite passive microwave data     

Michael A. Wulder  Trisalyn A. Nelson  Chris Derksen  David Seemann 《Climatic change》2007,82(1-2):113-130

Twenty-four winter seasons (1978–2002) of mean February snow water equivalent (SWE) values were analyzed in an exploration of the spatial pattern of temporal variability in snow cover across the non-mountainous interior of Canada. The SWE data were derived from space-borne passive microwave brightness temperatures processed with a land cover-sensitive suite of algorithms. Spatial patterns in the frequency and amount of variability were investigated on an annual basis through comparisons with average trends over all 24 years. Changes in temporal variability through time were also investigated by comparing three eight year time periods to general trends. Analyses were synthesized at the ecozone scale in order to link results both to potential land cover influences on algorithm performance and climatological variability in SWE. Prairie and northern ecozones were typically found to be the most variable in terms of SWE magnitude. Analyses indicate that non-treed land cover classes are generally more variable than treed classes. The results also indicate that extreme weather events appear to be occurring with increasing consistency in the Prairie and Arctic regions. Discerning climatologically significant variability in the time series, compared to algorithm-related issues can be a challenge, but in an era of eroding surface observing networks the passive microwave time series represents an important resource for monitoring and detecting trends and variability in terrestrial snow cover.  相似文献   

Two Supervised Neural Networks for Classification of Sedimentary Organic Matter Images from Palynological Preparations     

Andrew F. Weller  Anthony J. Harris  J. Andrew Ware 《Mathematical Geosciences》2007,39(7):657-671

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Synergy of multiple geophysical approaches to unravel explosive eruption conduit and source dynamics - A case study from Stromboli   总被引：1，自引：0，他引：1  

Andrew Harris  Maurizio Ripepe 《Chemie der Erde / Geochemistry》2007,67(1):1-35

An effective approach to understanding the dynamics of explosive volcanic eruptions and the conduit systems that drive them is through synergy of multiple data sets. Three data sets that lend themselves to ease of integration are seismic, infrasonic and thermal. Although approaches involving these data have been used to record volcanological phenomena since 1862, 1955 and 1965, respectively, their integrated use has only developed since 1999. When combined, these three data sets allow constraint of shallow system geometry and the dynamics of the explosive events that occur within that system. Using Stromboli volcano (Italy) as a case study, we review the complete range of geochemical and geophysical studies that can be applied. In doing so, we aim to show how integration of these diverse studies allows insights into a plumbing system and the dynamics of the eruptive activity that the system feeds. When combined at Stromboli, these data provide constraint of multiple system parameters including chamber depths, gas and magma fluxes, shallow system magma residence times, explosion source depths, and the rise/ejection velocities of ascending gas slugs and ejecta. In turn, these results allow various conduit and eruption dynamic models to be applied and tested.The persistent and repeated mildly explosive events that characterize Stromboli have been modeled in terms of the coalescence of gas within the magma to form large gas slugs that ascend the remaining portion of the conduit to burst at the free surface. Our integrated seismic, infrasonic and thermal data sets indicate that gas coalescence occurs at a depth of ∼260 m, with a typical event frequency of ∼9/h. Infrasonic and thermal data show the explosion source to be located 20-220 m below the vent. Thermal data give emission velocities for the ejected fragments of 8-20 m/s, which converts to gas jet velocities of 23-39 m/s. Tracking these parameters in space and time shows that, although eruptions at Stromboli can be grouped into two characteristic types (simple and complex-each of which characterizes a particular crater, NE and SW, respectively), events within each type show significant short-term variability. The system does, however, appear robust, maintaining its characteristic strombolian eruption style after significant effusive phases and more energetic explosive events.  相似文献   

Equilibrium interface segregation in the diopside-forsterite system I: Analytical techniques, thermodynamics, and segregation characteristics     

Takehiko Hiraga  David L. Kohlstedt 《Geochimica et cosmochimica acta》2007,71(5):1266-1280

After syntheses of partially molten diopside-forsterite polycrystalline aggregates doped with various solutes, we analyzed the equilibrium segregation of Ni, Mn, Sr, Al, Yb, Y, Nd, La, and Ti at interfaces between diopside/diopside, diopside/forsterite and, forsterite/forsterite grains based on STEM/EDX (scanning transmission electron microscopy/energy dispersive X-ray spectrometry) to examine the effects of ionic size, valence state, co-segregation, and interface type on interface chemistry. We derive relationships between two quantities describing interface segregation and X-ray intensities acquired both from areas that include an interface and from areas that do not. These segregation quantities are (i) interface excess density and (ii) interface enrichment factor, which rely on Gibbsian thermodynamics and the Langmuir-McLean segregation model, respectively. Interface excess densities, which vary from −0.5 to 10 atoms/nm², indicate that the level of interface excess density depends on solutes and sample assemblage. Interface enrichment factors, which range from almost 1 to 130, reveal that the ionic size of the solutes affects their segregation via production of misfit lattice strain due to the difference between the size of a solute ion and that of the ideal strain-free lattice site. The ionic sizes of Yb and Y are almost identical to the size of the strain-free site; however, their segregation is significant indicating that a difference in valence state between the host elements (i.e., Ca and Mg) and the solutes also drives segregation. In contrast to other solutes, segregation characteristics of Al differ from these simple segregation rules. Segregation quantities do not change with interface type, indicating that the number of sites available for segregants and the driving force for segregation are similar among type of interfaces. We compare the element partitioning between diopside-melt and diopside-interfaces within the same sample assemblages. These two partition coefficients coincide if we approximate the number of segregation sites at interfaces as equivalent to 2 mono-atomic layers. Examination of the energetics in crystal-melt partitioning reveals that the interface segregation energy is essentially equal to the solute solution energy in a crystal.  相似文献   

The effects of soil type and chemical treatment on nickel speciation in refinery enriched soils: A multi-technique investigation   总被引：1，自引：0，他引：1  

David H. McNear Jr.  Rufus L. Chaney 《Geochimica et cosmochimica acta》2007,71(9):2190-2208

Aerial deposition of Ni from a refinery in Port Colborne, Ontario, Canada has resulted in the enrichment of 29 km² of land with Ni concentrations exceeding the Canadian Ministry of the Environment’s remedial action level of 200 mg kg⁻¹. Several studies on these soils have shown that making the soils calcareous was effective at reducing chemically extractable Ni, as well as alleviating Ni phytotoxicity symptoms in vegetable crops grown in the vicinity of the refinery. Conversely, dolomitic limestone additions resulted in increased uptake of Ni in the Ni hyperaccumulator Alyssum murale ‘Kotodesh’, a plant whose use was proposed as a remediation strategy for this area. In this paper we use multiple techniques to directly assess the role soil type and lime treatments play in altering the speciation of Ni in the Welland loam and Quarry muck soils around the refinery and relate these findings to Ni mobility and bioavailability.Stirred-flow dissolution experiments using pH 4 HNO₃ showed that Ni release from the limed Quarry muck and Welland loam soils was reduced (∼0.10%) relative to the unlimed soils (∼2.0%). Electron microprobe analysis (EMPA) identified approximately spherical NiO and Ni metal particles, which are associated with no other metals, and range from 5 to 50 μm in diameter. Synchrotron micro-X-ray absorption fine structure and X-ray fluorescence spectroscopies showed that Ni and Al layered double hydroxide (Ni-Al LDH) phases were present in both the limed and unlimed mineral soils, with a tendency towards more stable (e.g., aged-LDH and phyllosilicate) Ni species in the limed soil, possibly aided by the solubilization of Si with increasing pH. In the muck soils, Ni-organic complexes (namely fulvic acid) dominated the speciation in both limed and unlimed soils.The results reported herein show that both soil type and treatment have a pronounced effect on the speciation of Ni in the soils surrounding the Port Colborne refinery. We provide the first evidence that Ni-Al LDH phases can form in anthropogenically enriched mineral field soils at circumneutral pH, and can lead to a reduction in Ni mobility. In the organic soils Ni is strongly complexed by soil organic matter; a property enhanced with liming. Interestingly, increased accumulation of Ni by A. murale grown in the limed muck and loam soils indicates that the plant may be capable of removing Ni from those fractions typically considered unavailable to most plants.  相似文献   

Superoxide-mediated reduction of organically complexed iron(III): Impact of pH and competing cations (Ca)     

Shikha Garg  T. David Waite 《Geochimica et cosmochimica acta》2007,71(23):5620-5634

The mechanism and kinetics of superoxide-mediated reduction of a variety of organic iron(III) complexes has been investigated over the pH range 7-9. Our experimental results show that the rate of iron(II) formation is a function of pH, ligand type and ligand concentration with the measured rate varying between 0.44 ± 0.07 and 39.25 ± 1.77 pM s⁻¹ in the systems investigated. Additionally, our results show that the presence of competing cations such as Ca²⁺ have a significant impact on iron(II) formation if the organic ligand is strongly complexed by Ca²⁺. Formation of iron(II) occurs by either (or, in some instances, both) reaction of superoxide with inorganic iron(III) after its dissociation from the complex (dissociative reduction) or by direct reaction of superoxide with the complex (non-dissociative reduction). In the presence of weak ligands, dissociative reduction (DR) dominates; however non-dissociative reduction (NDR) becomes important in the presence of either strongly binding ligands or high concentrations of weakly binding ligands. The major factors contributing to the pH dependence of the iron(II) formation rate are the complexation kinetics of inorganic iron(III) (which controls the DR contribution) and the reduction kinetics of the iron(III) complex (which controls the NDR contribution). The relative NDR contribution increases with increasing superoxide and ligand concentration and decreasing pH for all ligands examined. Since iron(II) formation occurring via NDR results in a significantly larger increase in the proportion of iron in free aquated form than does DR, this non-dissociative pathway of superoxide-mediated iron(III) reduction is particularly effective in increasing the lability of iron in aquatic systems.  相似文献   

Formation of iron sulfide nodules during anaerobic oxidation of methane   总被引：1，自引：0，他引：1  

Bart E. van Dongen  Andrew P. Roberts  Wei-Teh Jiang  Richard D. Pancost 《Geochimica et cosmochimica acta》2007,71(21):5155-5167

The biomarker compositions of iron sulfide nodules (ISNs; upper Pliocene Valle Ricca section near Rome, Italy) that contain the ferrimagnetic mineral greigite (Fe₃S₄) were examined. In addition to the presence of specific terrestrial and marine biomarkers, consistent with formation in coastal marine sediments, these ISNs contain compounds thought to originate from sulfate reducing bacteria (SRB). These compounds include a variety of low-molecular-weight and branched alkanols and several non-isoprenoidal dialkyl glycerol diethers (DGDs). In addition, archaeal biomarkers, including archaeol, macrocyclic isoprenoidal DGDs and isoprenoidal glycerol dialkyl glycerol tetraethers are also present. Both SRB and archaeal lipid δ¹³C values are depleted in ¹³C (δ¹³C values are typically less than −50‰), which suggests that the SRB and archaea consumed ¹³C depleted methane. These biomarker and isotopic signatures are similar to those found in cold seeps and marine sediments where anaerobic oxidation of methane (AOM) occurs with sulfate serving as the terminal electron acceptor. Association of AOM with formation of greigite-containing ISNs could provide an explanation for documented remagnetization of the Valle Ricca sediments. Upward migration of methane, subsequent AOM and associated authigenic greigite formation are widespread processes in the geological record that have considerable potential to compromise paleomagnetic records.  相似文献   

Preliminary investigations of outwash environments in the Tyne Valley: implications for Late Devensian (Dimlington Stadial) deglaciation     

Lynda Yorke  David G. Passmore 《Proceedings of the Geologists' Association. Geologists' Association》2007,118(2):201-211

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Quaternary depositional patterns and sea-level fluctuations, northeastern North Carolina     

Peter R. Parham  Stanley R. Riggs  David J. Mallinson 《Quaternary Research》2007,67(1):83-99

A detailed record of late Quaternary sea-level oscillations is preserved within the upper 45 m of deposits along an eight km transect across Croatan Sound, a drowned tributary of the Roanoke/Albemarle drainage system, northeastern North Carolina. Drill-hole and seismic data reveal nine relatively complete sequences filling an antecedent valley comprised of discontinuous middle and early Pleistocene deposits. On interfluves, lithologically similar marine deposits of different sequences occur stacked in vertical succession and separated by ravinement surfaces. Within the paleo-drainage, marine deposits are separated by fluvial and/or estuarine sediments deposited during periods of lowered sea level. Foraminiferal and molluscan fossil assemblages indicate that marine facies were deposited in a shallow-marine embayment with open connection to shelf waters. Each sequence modifies or truncates portions of the preceding sequence or sequences. Sequence boundaries are the product of a combination of fluvial, estuarine, and marine erosional processes. Stratigraphic and age analyses constrain the ages of sequences to late Marine Isotope Stage (MIS) 6 and younger (∼ 140 ka to present), indicating multiple sea-level oscillations during this interval. Elevations of highstand deposits associated with late MIS 5 and MIS 3 imply that sea level was either similar to present during those times, or that the region may have been influenced by glacio-isostatic uplift and subsidence.  相似文献   

Grounding the virtual: The material effects of electronic grocery shopping     

Andrew J. Murphy 《Geoforum》2007,38(5):941-953

This paper addresses the materiality of computer-mediated retailing. The paper uncovers the “hidden geography” of e-commerce, considering how the seemingly simple act of doorstep food delivery is explicated in urban form, and in transportation and communication infrastructures. The paper categorises electronic grocery shopping (EGS) enterprises into three types: “bricks and clicks”, “pure-play” and the “infomediary”, and examines how each type of operation has been materialised in the urban landscape, and the infrastructure upon which each draws. The paper then considers the strategies EGS operations have used to offset the “killer costs” of logistics for electronic commerce. The paper concludes by considering how electronic grocery shopping is embedded within broader trends in consumer behaviour, and how these trends are manifested in the materiality of urban life. The paper argues that online grocers are in the vanguard of ventures habituating customers to the remote ordering and delayed delivery of products to the home. Through controlling this “last mile”, online retailers hope to extend the product offer to higher-margin and more problematic products, which are in themselves unprofitable to distribute direct to the customer, but which can be profitably combined with a grocery shop.  相似文献