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Shallow marine sediments were collected from seven stations (three of which located at Gerlache Inlet, two at Tethys Bay, one at Adelie Cove and one just beneath the Italian Research Base) along the Terra Nova Bay coast (Ross Sea, Antarctica). Their chemical, biochemical and microbiological properties were studied in order to provide further insights in the knowledge of this Antarctic benthic ecosystem. Overall, the organic carbon (OC) represented the major fraction of total carbon (TC) and displayed concentrations similar to or slightly lower than those previously measured in Antarctic bottom sediments. The biopolymeric carbon within OC ranged from 4.1% to 19.9% and showed a wide trophic range (65–834 μg g−1 d.w.). Proteins (PRT) represented on average the main biochemical class contributing to labile organic carbon, followed by lipids (LIP) and carbohydrates (CHO). The activity of aminopeptidase, β-d-glucosidase, alkaline phosphatase and esterase was checked, giving the highest values at Tethys Bay and at the deepest water sediments. The principal component analysis, which was computed considering physical, chemical (elemental and biochemical sedimentary composition) and microbiological parameters (including bacterial abundance, ectoenzymatic activities, T-RFs richness and diversity indices), allowed to obtain two main clusters (“Tethys Bay” and “other stations”). Based on data obtained, two representative 16S rRNA clone libraries using samples from Tethys Bay and Gerlache Inlet were constructed. The sequences of 171 clones were compared to those available in public databases to determine their approximate phylogenetic affiliations. Both aerobic and anaerobic bacteria were disclosed, with the majority of them affiliated with the Gamma- and Deltaproteobacteria, Bacteroidetes and Acidobacteria. The occurrence of strictly anaerobic bacteria suggests that sediments might also undergo anoxic conditions that, in turn, could favor the accumulation of PRT in respect to CHO, assuming that fermentation of amino acids is slower than that of sugars from decomposing polysaccharides.  相似文献   
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The volcano–clastic sequence of Trompia Valley, which caps the Tre Valli Bresciane Variscan basement (TVB), comprises the Dosso dei Galli Conglomerate (DGC), the oldest deposit containing up to metre-sized metamorphic pebbles. This Lower Permian formation of the Trompia Basin was fed by the erosion products of the Variscan chain. We used microstructural and mineral chemical data on metamorphic pebbles of the DGC to infer a quantitative tectono-thermal evolution of the eroded pre-Permian basement and to compare them with those of TVB and the surrounding Southalpine basement units (tectono-metamorphic units = TMUs). Metapelitic and metaintrusive pebbles record a polyphase metamorphism with two metamorphic re-equilibrations: the first under epidote amphibolite facies (M1, ) and the second under greenschist facies (M2) conditions. Rock types and metamorphic data largely match those of TVB basement unit. The structural and metamorphic records in the pebbles are pre-Permian, and the conglomerate matrix is non-metamorphic. The DGC deposition age (283 ± 1–280.5 ± 2 Ma) constrains the minimal exhumation age of its basement source. The lack of staurolite bearing assemblages in metamorphic pebbles suggests that the DGC basement source was already exhumed to shallow structural levels (greenschist facies conditions) before the thermal equilibration consequent upon continental crust thickening induced by the Variscan collision.  相似文献   
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The Šambron–Kamenica Zone is situated on the northern margin of the Levočské vrchy mountains and Šarišskà vrchovina Highland, where the Central Carpathian Paleogene joins the Pieniny Klippen Belt. Sandstone outcrops in this area. From Cretaceous to Late Oligocene in age, these sediments suggest transport directions from S and SE. The heavy mineral assemblages of this sandstone include Cr-spinel grains, mainly displaying types II and III alpine-peridotite affinities, and are representative of Ocean Island Basalt volcanism. A sample from Upper Eocene sediments at Vit’az shows a clear change in Cr-spinel composition, which turns out to have types I and II peridotite affinities, and to derive from arc and Middle Ocean Ridge Basalt volcanism, with sediment transport directions from SW and WSW. These data indicate major variations in the Upper Eocene tectonic setting, giving constraints to paleogeographic reconstruction of the Slovak Central Carpathians.  相似文献   
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The recently detected linear polarization in the optical light curve of GRB 990510 renewed interest in how polarization can be produced in gamma-ray burst fireballs. Here we present a model based on the assumption that we are seeing a collimated fireball, observed slightly off-axis. This introduces some degree of anisotropy, and makes it possible to observe a linearly polarized flux even if the magnetic field is completely tangled in the plane orthogonal to the line of sight. We construct the light curve of the polarization flux, showing that it is always characterized by two maxima, with the polarization position angle changing by 90° between the first and the second maximum. The very same geometry as assumed here implies that the total flux initially decays in time as a power law, but gradually steepens as the bulk Lorentz factor of the fireball decreases.  相似文献   
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This paper reports the results of a study on the transformation of benzene in the presence of solid nitrate salts (NaNO3, NH4NO3) under irradiation in a gas-solid photoreactor. Sodium and ammonium nitrate have been chosen as representative of the composition of atmospheric particulate, benzene as a model aromatic molecule. The purpose is to simulate the transformations that aromatic compounds undergo on the surface of dispersed particles in the atmosphere. Irradiation of sodium nitrate causes hydroxylation and nitration of benzene, yielding phenol and nitrobenzene. This is most likely due to the generation of OH and NO2 radicals upon nitrate photolysis, with OH + O2 leading to the formation of phenol and OH + NO2 yielding nitrobenzene. The percentage of oxygen in the reaction environment influences the transformation pathways, with phenol formation being favoured and nitrobenzene formation depressed by high O2 concentration. In the presence of hematite (α-Fe2O3, another component of atmospheric particulate) very relevant formation of nitrobenzene takes place even with 21% oxygen (simulated air), indicating that the interaction between hematite and nitrate can lead to the formation of aromatic nitroderivatives on the surface of atmospheric particulate. The effect of hematite is possibly due to protonation of peroxynitrite, formed upon nitrate photoisomerisation, to peroxynitrous acid, a powerful nitrating agent. A similar effect leads to relevant formation of nitrobenzene under atmospheric conditions upon irradiation of the acid salt ammonium nitrate.  相似文献   
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The thermal regime of rivers is threatened by anthropogenic stresses at a large variety of timescales. We focus on sub‐daily thermal alterations induced by the release of hypolimnetic water for hydropower production (thermopeaking). We analyse the thermal signal focusing on the following characteristics that are potentially affected by hypolimnetic releases: (i) sub‐daily thermal rate of change and (ii) oscillation frequencies contained in the thermal signal. Through a proper scaling, we derive two dimensionless at‐a‐station indicators to compare alterations among stations with different locations and physiographic characteristics of the basins. Then we analyse the data from two different thermal datasets (Italy/Switzerland) for a total of 48 stations with 10 min time resolution of temperature data. The stations are grouped according to the absence of upstream hydropeaking releases (29 stations, reference group) and the existence of upstream hydropeaking, hence potentially impacted by thermopeaking (19 stations, altered group). Using a simple statistical approach, based on a non‐parametric definition of outliers, we identify the range of variability of the two indicators for the reference, unaltered group. This range measures the ‘natural’ sub‐daily thermal variability of the proposed indicators. Finally, we investigate the seasonality effects on the two proposed indicators and it results, that sub‐daily alterations mostly occur during summer. The two indicators represent a novel tool for the assessment of river thermal regime alterations and can be easily included in existing methodologies to assess river quality. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
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