Characterization of high molecular weight biomarkers in crude oils     

Michael Hsieh  R. Paul Philp  J. C. del Rio 《Organic Geochemistry》2000,31(12):794

High-temperature gas chromatography (HTGC) has enhanced our ability to characterize hydrocarbons extending to C₁₂₀ in crude oils. As a result, hydrocarbons in waxes (> C₂₀) have been observed to vary significantly between crude oils, even those presumed to originate from the same source. Prior to this development, microcrystalline waxes containing hydrocarbons above C₄₀ were not characterized on a molecular level due to the analytical limitations of conventional gas chromatography. Routine screenings of high pour-point crude oils by high-temperature gas chromatography has revealed that high molecular weight hydrocarbons (> C₄₀) are very common in most oils and may represent 2% of the crude oil. Precise structures, origins, and significance of these high molecular weight compounds remain elusive. As a preliminary step to expand our knowledge of these compounds their general molecular structures and formulas have been investigated in this study. Initial results suggest that the major high molecular weight compounds include a homologous series of n-alkanes, methylbranched alkanes, alkylcyclopentanes, alkylcyclohexanes, alkylbenzenes and alkylcycloalkanes.  相似文献   

Effects of waterborne nitrite on phase I-II biotransformation in channel catfish (Ictalurus punctatus).     

J F González  P L Del Valle  S Thohan  A S Kane 《Marine environmental research》2000,50(1-5):29-32

The effects of waterborne nitrite (3 mg/l NO2) on channel catfish were studied to evaluate changes in hematological parameters and phase I-II biotransformation in liver slices. Nitrite-exposed fish had significantly higher methemoglobin, blood and liver nitrite, and significantly lower pO2 than control fish. Total phase I-mediated metabolism of 7-ethoxycoumarin (EC) was not altered in nitrite-exposed fish compared with control fish (291 +/- 43 and 312 +/- 20 pmol/mg/h, respectively). However, phase II glucuronosyltransferase-mediated metabolism of 7-hydroxycoumarin (HC), both as a phase I metabolite of EC and as a parent substrate, was elevated in nitrite-exposed fish (204 +/- 17 and 1007 +/- 103 pmol/mg/h, respectively) as compared to control fish (149 +/- 14 and 735 +/- 87 pmol/mg/h) (P < 0.05). Sulfotransferase-mediated metabolism of HC (as a metabolite of EC and as a parent substrate) was not notably altered in nitrite-exposed fish (95 +/- 16 and 617 +/- 33 pmol/mg protein/h, respectively) as compared with control fish (118 +/- 24 and 575 +/- 55 pmol/mg/h, respectively). These studies indicate that in vivo nitrite exposure and associated changes in hematological parameters do not appear to affect hepatic phase I EC biotransformation in channel catfish. However, subtle but significant changes in phase II glucuronidation, but not sulfation activity, were observed. The mechanism of these alterations is unclear. However, the data suggest that environmentally realistic concentrations of nitrite may affect the dynamics of conjugative metabolism in exposed fish.  相似文献   

Evidences of Holocene transgression on Domingos Petrolini Swamp, southern coastal plain, Rio Grande do Sul, Brazil     

Soraia G.Bauermann  Paulo C.P.Neves  Marleni Marques-Toigo  Abdul R.Ashraf 《东北亚地学研究》2005,(Z1)

The Domingos Petrolini Swamp, located on the Southern Coastal Plain of Rio Grande do Sul, near the town of Rio Grande, constitutes an ample holocene lagoonal deposit. Events related to the holocene transgression and their diverse phases of glacial-eustatic ocillations were found through palynological analysis. Bases on these palynological data, four distinct phases to the paleoenvironmental evolution of the ecosystem were identified. It has also shown a transgressive restricted marine sequence on the base , which suggests the existence of a coastal brackish lagoon or a marisme type of environment. Later, there was a gradation for continentality conditions along with a scarce pollinical record. The third phase is characterized by the presence of marine components and halophyte vegetation, showing another transgressive event in that place. Lastly, the end of direct marine influence over the swamp was recorded and also the vegetation development as it appears these days.  相似文献   

First Implementation Of Phase Diversity At Themis     

S. Criscuoli  D. Del Moro  J. A. Bonet  I. Márquez 《Solar physics》2005,228(1-2):177-189

Phase diversity techniques are robust post-processing tools for image enhancement and correction of telescopic and atmospheric induced aberrations. We present results obtained applying the Partitioned Phase-Diverse Speckle (PPDS) technique to images acquired at THEMIS. We also present an image quality estimator based on image power spectrum content we developed in order to automatically evaluate the results of large amount of data.  相似文献   

Stokes profiles inversion techniques     

J. C. Del Toro Iniesta  B. Ruiz Cobo 《Solar physics》1996,164(1-2):169-182

Inversion techniques of the radiative transfer equation for polarized light are presented as one of the best current procedures to infer the vector magnetic field, as well as other quantities governing the physical state of the atmospheric layers that photons are coming from. Several characteristics of the various available inversion procedures are pointed out. They are mostly based on the diagnostic contents of the spectral lines as well as on the main hypotheses assumed in these procedures. In particular, the role of gradients in the atmospheric quantities is emphasized as of paramount importance in any diagnostic analysis and, hence, in any interpretation of inversion results.  相似文献   

Strain rates in the Alpine Mediterranean region: insights from advanced techniques of data processing     

Gregorio Farolfi  Chiara Del Ventisette 《GPS Solutions》2017,21(3):1027-1036

Strain rates and Euler poles for various subregions of the Alpine Mediterranean region were calculated by using global navigation satellite system data from permanent stations. The main scope of the study is to compare and analyze strain rate maps that were calculated using different approaches. This area presents a complex tectonic setting due to the interaction of the Eurasian and Nubian plates. The horizontal velocity gradient tensor was computed starting from a new set of site velocities determined by using continuous long-series geodetic data, state-of-the-art antenna calibrations and recomputed precise orbits. Geodesy provides velocities for a sparsely distributed, discrete number of sites, while deformation has a spatially continuous distribution. For this reason, the interpolation method and the geometric approach to the problem play a fundamental role in the estimation of the strain rate field. In the present study, principal deformation axes and principal angle were estimated by applying two different approaches: the Delaunay triangulation and a grid solution. Both methods produce results with broad coherence, providing new information about the deformation throughout the entire study area. Moreover, an evaluation and analysis of Euler poles related to the different velocity patterns, give complementary information to reconstruct the active deformation in the Mediterranean area.  相似文献   

Timing of diagenesis and very low‐grade metamorphism in the eastern sector of the Sierra de Cameros (Iberian Range,Spain): a U–Pb SHRIMP study on monazite     

P. Del Río  L. Barbero  P. Mata  C. M. Fanning 《地学学报》2009,21(6):438-445

The Sierra de Cameros is an intracontinental orogen and represents the north‐western part of the Iberian Range in Northern Spain. It comprises a thick sequence of syn‐rift continental sediments (mainly sandstones and carbonates) deposited during lower Cretaceous times. A unique characteristic of the Sierra de Cameros in relation to the rest of the Iberian Range is the presence of low‐grade metamorphism in certain parts of the basin, an event that predates basin inversion. This paper describes the presence, textural relationships and geochemical aspects of authigenic and/or metamorphic monazite within different lithologies from the deepest parts of the basin. Sensitive high resolution ion microprobe (SHRIMP) U–Pb dating of monazite records the presence of two age populations: the first with ²⁰⁶Pb/²³⁸U ages ranging from 122 to 116 Ma which is considered as diagenetic in origin, whilst the second is dated at 99 ± 2 Ma and postdates the metamorphic climax.  相似文献   

Magnetized relativistic jets and long-duration GRBs from magnetar spin-down during core-collapse supernovae     

N. Bucciantini  E. Quataert  B. D. Metzger  T. A. Thompson  J. Arons  L. Del Zanna 《Monthly notices of the Royal Astronomical Society》2009,396(4):2038-2050

We use ideal axisymmetric relativistic magnetohydrodynamic simulations to calculate the spin-down of a newly formed millisecond,   B ∼ 10¹⁵ G  , magnetar and its interaction with the surrounding stellar envelope during a core-collapse supernova (SN) explosion. The mass, angular momentum and rotational energy lost by the neutron star are determined self-consistently given the thermal properties of the cooling neutron star's atmosphere and the wind's interaction with the surrounding star. The magnetar drives a relativistic magnetized wind into a cavity created by the outgoing SN shock. For high spin-down powers  (∼10⁵¹–10⁵² erg s⁻¹)  , the magnetar wind is superfast at almost all latitudes, while for lower spin-down powers  (∼10⁵⁰ erg s⁻¹)  , the wind is subfast but still super-Alfvénic. In all cases, the rates at which the neutron star loses mass, angular momentum and energy are very similar to the corresponding free wind values (≲30 per cent differences), in spite of the causal contact between the neutron star and the stellar envelope. In addition, in all cases that we consider, the magnetar drives a collimated  (∼5–10°)  relativistic jet out along the rotation axis of the star. Nearly all of the spin-down power of the neutron star escapes via this polar jet, rather than being transferred to the more spherical SN explosion. The properties of this relativistic jet and its expected late-time evolution in the magnetar model are broadly consistent with observations of long duration gamma-ray bursts (GRBs) and their associated broad-lined Type Ic SN.  相似文献   

Resolved Versus Parametrized Boundary-Layer Plumes. Part I: A Parametrization-Oriented Conditional Sampling in Large-Eddy Simulations     

F. Couvreux  F. Hourdin  C. Rio 《Boundary-Layer Meteorology》2010,134(3):441-458

A conditional sampling based on the combination of a passive tracer emitted at the surface and thermodynamic variables is proposed to characterise organized structures in large-eddy simulations of cloud-free and cloudy boundary layers. The sampling is evaluated against more traditional sampling of dry thermals or clouds. It enables the characterization of convective updrafts from the surface to the top of the boundary layer (or the top of cumulus clouds), describing in particular the transition from the sub-cloud to the cloud layer, and retrieves plume characteristics, entrainment and detrainment rates, variances and fluxes. This sampling is used to analyze the contribution of boundary-layer thermals to vertical fluxes and variances.  相似文献   

Monitoring, prediction, and early warning using ground-based radar interferometry   总被引：11，自引：8，他引：3  

Nicola Casagli  Filippo Catani  Chiara Del Ventisette  Guido Luzi 《Landslides》2010,7(3):291-301

In order to define adequate prevention measures and to manage landslide emergencies, real-time monitoring is required. This paper presents two different applications of the remote sensing technique: the ground-based synthetic aperture radar interferometry, here proposed as a monitoring and early warning support for slope instability. Data acquisitions carried out through a ground-based synthetic aperture radar interferometer, operating in K_u band, installed in front of the observed slopes, are discussed. Two case studies, based on the use of the same apparatus (formerly developed by the Joint Research Center of the European Commission and by Ellegi-LiSALab srl), are reported: the first one concerns the monitoring of a large landslide, named Ruinon (Valfurva, Italy). The second one deals with the monitoring of the NW unstable slope in the Stromboli island aimed to implementing an early warning system. Acquired interferometric data are processed to provide displacements and velocity maps of the monitored area. The monitoring services ongoing on the Ruinon landslide and on Stromboli demonstrate the capability of this technique to operate in different operative settings (i.e., different phenomena and geological framework) and for different aims (monitoring for prevention, early warning, and emergency assessment). This methodology has also been proved by national and regional authorities of civil protection in order to provide a real-time monitoring for emergency management.  相似文献