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21.
The effects of oxygen supply rate and the presence or absence of nutrients on the kinetics of phenol degradation and oxygen consumption by a mixed microbial population were tested in a model system. The values for the maximum specific rate of phenol degradation (qSmax), the saturation constant (KS), and the inhibition concentration (SCR) were determined for unlimited growth (KLa = 340 h?1, growth medium) with 1.7 mmol g?1 h?1, 65 mg L?1, and 190 mg L?1. Under limitation conditions, alterations occur depending on the type of limitation. Nutrient limitations lead to values of 0.8 mmol g?1 h?1, 45 mg L?1, and 160 mg L?1, and oxygen limitations lead to 1.2 mmol g?1 h?1. 30 mg L?1, and 120 mg L?1, respectively. The results suggest that with excess oxygen, the rate of phenol degradation was higher and the inhibition effect of phenol was suppressed to some extent. Under the same high oxygen supply rate, the presence of nutrients in the model water significantly supported the phenol degradation rate.  相似文献   
22.
In Turkey, neotectonic activity originated from the collision of the Arabian and Anatolian land masses during the Middle Miocene. As a result of the collision, westward escape of the Anatolian block introduced E-W compression in Western Turkey which began to be relieved by N-S extension. The North Anatolian Fault (NAF) is the major active strike-slip fault that was formed under the neotectonic regime. The rates of the motion along this fault estimated by several authors are in the range of 0.4–2.9 cm/a according to kinematic data. In Turkey, the first studies of crustal movements by geodetic methods were started in the west section of the NAF in 1972. So far, individual activities and studies coordinated by multidisciplinary projects have been realized in this region. The results obtained from available geodetic data indicate the motion of the Anatolian block relative to Eurasia.  相似文献   
23.
The historical tsunamis in the Marmara Seawere mainly caused by earthquakes andneeded to be documented. Following 1999Izmit earthquake occurred at the EasternMarmara region, a complete inventory ofactive faults in the Marmara Sea regionbecame much more stressed. To the west, thelatest event is 09.08.1912arköy-Mürefte Earthquake. Itoccurred on the active Ganos Fault zone andwas one of the largest earthquakes in theBalkans. The eastern termination of theassociated faulting is in the deep WestMarmara Trough, westernmost of thesuccessive basins forming the Marmara Sea.On the basis of recent multibeam bathymetryand seismic reflection data, estimatedtotal length of the surface rupture isabout 56 km. The historical data reviewedfrom library and archive documents,geological field surveys and offshoregeophysical investigations have shown thatthe 1912 earthquake produced a tsunami. Inaddition a seabed dislocation, the sourceof 1912 tsunami can also be assigned to thesediment slumps appearing in the form ofechelon landslide prisms along the southernslopes of the West Marmara Trough.  相似文献   
24.
Large subvolcanic intrusions are recognized within most Precambrian VMS camps. Of these, 80% are quartz diorite–tonalite–trondhjemite composite intrusions. The VMS camps spatially associated with composite intrusions account for >90% of the aggregate sulfide tonnage of all the Precambrian, intrusion-related VMS camps. These low-alumina, low-K, and high-Na composite intrusions contain early phases of quartz diorite and tonalite, followed by more voluminous trondhjemite. They have a high proportion of high silica (>74% SiO 2) trondhjemite which is compositionally similar to the VMS-hosting rhyolites within the volcanic host-rock successions. The quartz-diorite and possibly tonalite phases follow tholeiitic fractionation trends whereas the trondhjemites fall within the composition field for primitive crustal melts. These transitional M-I-type primitive intrusive suites are associated with extensional regimes within oceanic-arc environments. Subvolcanic composite intrusions related to the Archean Sturgeon Lake and Noranda, and Paleoproterozoic Snow Lake VMS camps range in volume from 300 to 1,000 km 3. Three have a sill morphology with strike lengths between 15 and 22 km and an average thickness between 1,500 and 2,000 m. The fourth has a gross stock-like shape. The VMS deposits are principally restricted to the volcanic strata above the strike length of the intrusions, as are areally extensive, thin exhalite units. The composite intrusions contain numerous internal phases which are commonly clustered within certain parts of the composite intrusion. These clusters underlie eruptive centers surrounded by areas of hydrothermal alteration and which contain most of the VMS deposits. Early quartz-diorite and tonalite phases appear to have intruded in rapid succession. Evidence includes gradational contacts, magma mixing and disequilibrium textures. They appear to have been emplaced as sill-dike swarms. These early phases are present as pendants and xenoliths within later trondhjemite phases. The trondhjemite phases contain numerous internal contacts indicating emplacement as composite sills. Common structural features of the composite intrusions include early xenolith phases, abundant small comagmatic dikes, fractures and veins and, in places, columnar jointing. Internal phases may differ greatly in texture from fine- to coarse-grained, aphyric and granophyric through seriate to porphyritic. Mineralogical and isotopic evidence indicates that early phases of each composite intrusion are affected by pervasive to fracture-controlled high-temperature (350–450 °C) alteration reflecting seawater-rock interaction. Trondhjemite phases contain hydrothermal-magmatic alteration assemblages within miarolitic cavities, hydrothermal breccias and veins. This hydrothermal-magmatic alteration may, in part, be inherited from previously altered wall rocks. Two of the four intrusions are host to Cu-Mo-rich intrusive breccias and porphyry-type mineralization which formed as much as 14 Ma after the main subvolcanic magmatic activity. The recognition of these Precambrian, subvolcanic composite intrusions is important for greenfields VMS exploration, as they define the location of thermal corridors within extensional oceanic-arc regimes which have the greatest potential for significant VMS mineralization. The VMS mineralization may occur for 2,000 m above the intrusions. In some cases, VMS mineralization has been truncated or enveloped by late trondhjemite phases of the composite intrusions. Evidence that much of the trondhjemitic magmatism postdates the principal VMS activity is a critical factor when developing heat and fluid flow models for these subseafloor magmatic-hydrothermal systems.  相似文献   
25.
The Late Archean Blake River Group is a thick succession of predominantly mafic volcanic rocks within the southern zone of the Abitibi greenstone belt. It contains a number of silicic volcanic centers of different size, including the large Noranda volcanic complex, which is host to 17 past-producing volcanogenic massive sulfide deposits. The Noranda complex consists of a 7- to 9-km-thick succession of bimodal mafic and felsic volcanic rocks erupted during five major cycles of volcanism. Massive sulfide formation coincided with a period of intense magmatic activity (cycle III) and the formation of the Noranda cauldron. Hydrothermal alteration in these rocks is interpreted to reflect large-scale hydrothermal fluid flow associated with rapid crustal extension and rifting of the volcanic complex. The alteration includes abundant albite, chlorite, epidote and quartz (silicification), which exhibit broad stratigraphic and structural control and correlate with previously mapped whole-rock oxygen isotope zonation. The Mine Sequence volcanic rocks are characterized by abundant iron-rich chlorite (Fe/Fe+Mg >0.5), hydrothermal amphibole (ferroactinolite) and coarse-grained epidote of clinozoisite composition (<10 wt% Fe 2O 3). Volcanic rocks of the pre-cauldron sequences, which contain only subeconomic stringer mineralization, are characterized by less abundant chlorite and mainly fine-grained epidote (>10 wt% Fe 2O 3) lacking the clinozoisite solid solution. Alteration in the Mine Sequence volcanic rocks persists along strike well beyond the limits of the main ore deposits (as far as several tens of kilometers) and can be readily distinguished from greenschist facies metamorphic assemblages at a regional scale. The lack of similar alteration in the pre-cauldron sequences is consistent with limited 18O-depletion and suggests that the early history of the volcanic complex did not support large-scale, high-temperature fluid flow in these rocks. Comparisons with a much smaller, barren volcanic complex in nearby Ben Nevis township reveal important differences in the alteration mineralogy between volcanoes of different size, with implications for area selection during regional-scale mineral exploration. The Ben Nevis Complex consists of a 3- to 4-km-thick succession of mafic, intermediate and felsic volcanic rocks centered on a small subvolcanic intrusion. Alteration of the volcanic rocks comprises mainly low-temperature assemblages of prehnite, pumpellyite, magnesium-rich chlorite (Fe/Fe+Mg <0.5), iron-rich epidote (>10 wt% Fe 2O 3) and calcite. Actinolite ± magnetite alteration occurs proximal to the intrusive core of the complex, but the limited extent of this alteration indicates only local high-temperature fluid circulation adjacent to the intrusion. A distal zone of carbonate alteration is located 4–6 km from the center of the volcano. Although iron-bearing carbonates are present locally within this zone, the absence of siderite argues against a high-temperature origin for this alteration. These observations do not offer positive encouragement for the existence of a fossil geothermal system of sufficient size or intensity to have produced a large massive sulfide deposit.  相似文献   
26.
Infrared and Raman spectra of cristobalite are presented as a function of temperature through the phase transition. The modes are assigned and the assignments compared to those of earlier workers. The compatibility of modes at the G-point of the a-phase with the X and G-points of the ß-phase is given. In the transition region of ca. 500–550 K, smooth changes in intensity, frequency and linewidths are seen in many modes, indicative of coexistence of a- and ß-forms.  相似文献   
27.
The 1,500- to 2,000-m-thick Permian volcano-sedimentary Malu?iná Formation of the uppermost nappe of the Central Western Carpathians (a segment of the Alpine-Carpathian orogenic belt) occurs in several fault blocks distributed across Slovakia. This unit is a part of a post-Variscan overstep suite that followed accretion of the Gothic terranes to Laurussia. It consists of three upward-fining megacycles of semi-arid/arid, fluvial-lacustrine clastic redbeds and local dolomites and evaporites. Abundant intercalated volcanic rocks are predominantly mafic lava flows; volcaniclastic rocks and dykes are subordinate. Felsic rocks are represented by rare volcaniclastics and dykes. Compositionally, the mafic rocks are rift-related continental tholeiites with enriched light REE patterns having (La/Yb)n ratios between 2 and 5.5 and with mantle-normalized patterns characterized by negative Nb-Ta anomalies. The rocks were derived from subcontinental lithospheric mantle and were affected by crustal contamination. It is inferred that the volcanism of the Malu?iná Formation formed in a Basin and Range tectonic setting in which rifting followed collision of the Palaeo-Tethys ridge with the trench bordering southern Laurussia. This model can be applied to other Permian volcanic suites of rift basins in the Eastern Alps and Carpathians over a strike-length of about 1,000 km, which indicates the width of the slab window.  相似文献   
28.
Outlier trimming and homogeneity checking/correction were performed on the monthly precipitation time series of various lengths from 267 stations in Turkey. Outlier values are usually found during dry summer months, and are concentrated mostly over the southern parts of the country, where the dry period is most pronounced, implying natural extremes rather than wrong measurements. Homogeneity analysis was done using the Standard Normal Homogeneity Test, on an individual monthly basis, which led to many non‐testable series due to lack of reference stations, especially during summer months. Yet, remaining testable months were usually helpful for the assessment of homogenity, revealing a well distributed set of stations that proved to be homogeneous. There were still a number of stations which either could not be tested efficiently, or were classified as inhomogeneous. Lack of metadata is argued to be largely responsible for inefficient homogeneity testing. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
29.
The interaction between waves and artificial reefs (ARs; a hollow cube weighing 8.24 kN (0.84 t) and a water pipe weighing 1.27 kN (0.13 t)) in shallow waters was investigated with respect to variations in design weight, orientation (for cube; 45° and 90° angles, for pipe; 0°, 90°, and 180° angles to flow), depth (1–20 m), and bottom slope (10?1, 30?1, and 50?1). Physics equations and FLUENT software were used to estimate resisting and mobilising forces, and drag coefficients. Drag coefficients for the hollow cube were 0.76 and 0.85 at 45° and 90° angles to the current, respectively, and 0.97, 0.38, and 1.42 for the water pipe at 0°, 90°, and 180° angles to the current, respectively. Deepwater offshore wave conditions at six stations were transformed into shallow nearshore waters representative of the artificial reef site. Waters deeper than 12 and 16 m are safe to deploy blocks with angles of 45° and 90°, respectively. However, water pipes constructed at angles of 90° and 180° to the current were estimated as being unstable for 365 out of 720 cases at all stations (only one station was stable for all cases). Water pipes angled at 0° were found to be stable in all 360 cases. Slope had a significant effect on weight and depth. Results from this study provide an important reference for engineers performing projects aiming to increase the performance and service life of ARs.  相似文献   
30.
Sensitive spectral observations made in two frequency bands near 6.0 and 17.6 GHz are described for Orion and W51. Using frequency switching we were able to achieve a dynamic range in excess of 10,000 without fitting sinusoidal or polynomial baselines. This enabled us to detect lines as weak as T A ∼1 mK in these strong continuum sources. Hydrogen recombination lines with Δn as high as 25 have been detected in Orion. In the Orion data, where the lines are stronger, we have also detected a systematic shift in the line center frequencies proportional to linewidth that cannot be explained by normal optical depth effects.  相似文献   
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