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101.
Chloride contamination of groundwater in urban areas due to deicing is a well‐documented phenomenon in northern climates. The objective of this study was to evaluate the effects of permeable pavement on degraded urban groundwater. Although low impact development practices have been shown to improve stormwater quality, no infiltration practice has been found to prevent road salt chlorides from entering groundwater. The few studies that have investigated chlorides in permeable asphalt have involved sampling directly beneath the asphalt; no research has looked more broadly at surrounding groundwater conditions. Monitoring wells were installed upgradient and downgradient of an 860 m2 permeable asphalt parking lot at the University of Connecticut (Storrs, Connecticut). Water level and specific conductance were measured continuously, and biweekly samples were analyzed for chloride. Samples were also analyzed for sodium (Na), calcium (Ca), and magnesium (Mg). Analysis of variance analysis indicated a significantly (p < 0.001) lower geometric mean Cl concentration downgradient (303.7 mg/L) as compared to upgradient (1280 mg/L). Concentrations of all alkali metals increased upgradient and downgradient during the winter months as compared to nonwinter months, indicating that cation exchange likely occurred. Despite the frequent high peaks of chloride in the winter months as well as the increases in alkali metals observed, monitoring revealed lower Cl concentrations downgradient than upgradient for the majority of the year. These results suggest that the use of permeable asphalt in impacted urban environments with high ambient chloride concentrations can be beneficial to shallow groundwater quality, although these results may not be generalizable to areas with low ambient chloride concentrations.  相似文献   
102.
Three dated structures up to 450 years in age display the effects of coastal weathering of the greenschist of which they are constructed. A variety of weathering forms is present. The various topographic surfaces of the structures create variation in weathering environments and consequent weathering processes and rates. Weathering is enhanced by direct exposure to salt-bearing spray and by humid conditions, and apparently limited by direct exposure to solar radiation. The maximum rates of weathering on the three surfaces approximate to 0·6 mm a−1 over this period, consistent with measured contemporary weathering rates for a natural surface formed by this rock type in a nearby coastal location. © 1997 by John Wiley & Sons, Ltd.  相似文献   
103.
Six major groups of trilobites from the Silurian and Devonian of Japan are evaluated for their paleobiogeographical signature. Silurian illaenids and scutelluids show four generic‐level and at least two species‐level links with the Australian segment of the Gondwana paleocontinent; encrinurids also indicate two generic‐level links with Australia and also the South China paleocontinent; whilst Devonian phacopids, and possibly proetids, suggest at least two generic‐level links with the North China paleocontinent. These different patterns may reflect the fragmentary biostratigraphical record of Japanese trilobites, but they also appear to reflect paleoenvironmental parameters associated with lithofacies, and paleoecology. Thus, Japanese assemblages of proetids and phacopids occurring in deep‐water clastic lithofacies have counterparts in similar settings in North China, and Japanese scutelluids and illaenids are strongly associated with shallow marine carbonate lithofacies that are similar to those of their occurrences in Australia. Japanese encrinurids occur in carbonate rocks indicative of shallow marine settings in the Kurosegawa Terrane, and they demonstrate a consistent paleobiogeographical affinity with Australia and South China. Larval ecology cannot be directly assessed for Japanese trilobite groups. However, proetids have consistently been shown to have planktonic protaspides, whereas illaenids, scutelluids, and encrinurids have benthic protaspides. Planktonic protaspides would have a greater propensity for distribution in ocean currents than benthic ones, and therefore may be of more limited paleobiogeographical utility. The combined data from the six different groups indicates that the complex paleobiogeographical patterns of the Japanese trilobite assemblages need to be interpreted with caution, and similarity of taxa does not necessarily denote paleogeographical proximity to other regions.  相似文献   
104.
A large number of pitchstone fragments and artefacts have recently been discovered at a Neolithic settlement site in Ballygalley, Co. Antrim, Northern Ireland. They consist predominantly of flakes and un‐reworked lumps and cores, with only one complete tool being found. Since no sources of workable pitchstone exist in Ireland, the source must have been the abundant pitchstone volcanic rocks found on the Hebridean Islands of northwest Scotland. The composition of the glass from a number of artefacts is highly siliceous, indicating that they were derived from pitchstones on the Island of Arran; pitchstones from all other Scottish locations are less silica‐rich. In addition, analysis of pyroxene and amphibole microcrystallites within the pitchstone suggests that the Corriegills area of Arran is the most likely source of the Ballygalley artefacts, although the precise outcrop has proved elusive. These finds, and others across Ireland, show that raw materials were being transported and probably traded over considerable distances despite there being suitable alternative sources of material for making tools (flint, etc.) available in the local area. This suggests that the pitchstone had a very specialist use. © 2002 Wiley Periodicals, Inc.  相似文献   
105.
Rock falls represent a large percentage of landslide-related hazards reported by Canadian railways in mountainous terrain. A 54.7?km-long section of railway through the Canadian Cordillera is examined that experiences, on average, 18 rock falls each year. An approach for rock fall hazard management is developed based on quantified risk. The approach focuses on defining railway operation procedures (freight train operations and track maintenance) that comply with quantified risks. Weather-based criteria that define periods when rock falls are more likely to occur along the study area are examined. These criteria are used herein to reduce exposure to rock falls and reduce their consequences. Several freight train operation strategies are proposed that comply with a tolerable level of risk adopted in this study for illustrative purposes. The approach provides a simple, flexible and practical strategy for railway operations that can be regularly adopted by the operators, and that is based on a more comprehensive assessment of quantified risk.  相似文献   
106.
东塔尔别克金矿区位于西天山吐拉苏盆地内阿希金矿区南侧,构造上属于伊犁-中天山微板块与准噶尔板块之间的博罗科努早古生代岛弧带西段。东塔尔别克矿区出露有一些安山岩,这些岩石具有典型高镁安山岩特征,如高硅(SiO2=58.94%~63.85%),具有较高的MgO含量(3.75%~6.59%)和Mg#(58~69)、高的Cr(94.2×10-6~241×10-6)、和Ni(54.5×10-6~126 ×10-6)含量,以及低的FeOT/MgO比值。除了Sr含量略微偏低(235×10-6~696×10-6)之外,这些岩石基本显示了埃达克岩的地球化学特征:高的Al2O3(15.39%~16.65%),低Y(9.86×10-6~14.9×10-6)含量,以及高的Sr/Y比值(23.8~48.1),无Eu异常,Nb、Ta、Ti亏损等。LA-ICP-MS锆石U-Pb测年结果显示安山岩的年龄为347.2±1.6Ma,为早石炭世。安山岩富集Rb、Th、U 等大离子亲石元素,相对亏损Nb、Ta、Ti等高场强元素,轻重稀土元素分馏明显,具有俯冲带岛弧岩浆的特征。东塔尔别克安山岩可能形成于岛弧环境中,并可能由俯冲的晚古生代北天山洋洋壳以及少量上覆沉积物熔融形成,产生的熔体在上升过程中与地幔橄榄岩发生了相互作用. 熔体-地幔相互作用对区内金矿的形成具有重要意义。  相似文献   
107.
Increases in the frequency and magnitude of extreme water levels and storm surges are correlated with known indices of climatic variability (CV), including the El Niño Southern Oscillation (ENSO) and the Pacific Decadal Oscillation (PDO), along some areas of the British Columbia coast. Since a shift to a positive PDO regime in 1977, the effects of ENSO events have been more frequent, persistent, and intense. Teleconnected impacts include more frequent storms, higher surges, and enhanced coastal erosion. The response of oceanographic forcing mechanisms (i.e. tide, surge, wave height, wave period) to CV events and their role in coastal erosion remain unclear, particularly in western Canada. As a first step in exploring the interactions between ocean–atmosphere forcing and beach–dune responses, this paper assembles the historic erosive total water level (TWL) regime and explores relations with observed high magnitude storms that have occurred in the Tofino‐Ucluelet region (Wickaninnish Bay) on the west coast of Vancouver Island, British Columbia, Canada. Extreme events where TWL exceeded an erosional threshold (i.e. elevation of the beach–foredune junction) of 5·5 m aCD are examined to identify dominant forcing mechanisms and to classify a regime that describes erosive events driven principally by wave conditions (61·5%), followed by surge (21·8%), and tidal (16·7%) effects. Furthermore, teleconnections between regional CV phenomena, extreme storm events and, by association, coastal erosion, are explored. Despite regional sea level rise (eustatic and steric), rapid crustal uplift rates have resulted in a falling relative sea level and, in some sedimentary systems, shoreline progradation at rates approaching +1·5 m a–1 over recent decades. Foredune erosion occurs locally with a recurrence interval of approximately 1·53 years followed by rapid rebuilding due to high onshore sand supply and often in the presence of large woody debris and rapidly colonizing vegetation in the backshore. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
108.
Co-management institutional arrangements have an important role in creating conditions for social learning and adaptation in a rapidly changing Arctic environment, although how that works in practice has not been clearly articulated. This paper draws on three co-management cases from the Canadian Arctic to examine the role of knowledge co-production as an institutional trigger or mechanism to enable learning and adapting. Experience with knowledge co-production across the three cases is variable but outcomes illustrate how co-management actors are learning to learn through uncertainty and environmental change, or learning to be adaptive. Policy implications of this analysis are highlighted and include the importance of a long-term commitment to institution building, an enabling policy environment to sustain difficult social processes associated with knowledge co-production, and the value of diverse modes of communication, deliberation and social interaction.  相似文献   
109.
A borehole permeameter is well suited for testing saturated hydraulic conductivity (K(sat)) at specific depths in the vadose zone. Most applications of the method involve fine-grained soils that allow hand auguring of test holes and require a small water reservoir to maintain a constant head. In non-cohesive gravels, hand-dug test holes are difficult to excavate, holes are prone to collapse, and large volumes of water are necessary to maintain a constant head for the duration of the test. For coarse alluvial gravels, a direct-push steel permeameter was designed to place a slotted pipe at a specific sampling depth. Measurements can be made at successive depths at the same location. A 3790 L (1000 gallons) trailer-mounted water tank maintained a constant head in the permeameter. Head in the portable tank was measured with a pressure transducer and flow was calculated based on a volumetric rating curve. A U.S. Bureau of Reclamation analytical method was utilized to calculate K(sat). Measurements with the permeameter at a field site were similar to those reported from falling-head tests.  相似文献   
110.
We have developed cleaning methods for extracting diatomopal from bulk marine sediment samples, for measurement of both zinc (Zn) abundance and isotope composition. This cleaning technique was then applied to a set of Holocene core-top samples from the Southern Ocean. The measured δ66Zn (reported relative to the JMCLyon standard) and Zn/Si ratios from the Southern Ocean diatomopal samples range from 0.7 to 1.5‰, and from 14 to 0.9 μmol/mol, respectively. The Zn abundance and isotope composition data show a clear correlation with opal burial rates and other oceanographic parameters. In common with previous work, we interpret the systematic changes in the Zn/Si ratio to be linked to the variability in the concentrations of bioavailable Zn in the ambient surface seawater where the diatom opal is formed. This variability is likely to be primarily controlled by the degree to which Zn is taken up into phytoplankton biomass. The observed systematic pattern in the δ66Zn compositions of the diatomopal core-top samples is, similarly, likely to reflect changes in the δ66Zn composition of the ambient Zn in the surface waters above the core-top sites, which is progressively driven towards isotopically heavier values by preferential incorporation of the lighter isotopes into phytoplankton organic material. Thus, the systematic relationship between Zn isotopes and abundance observed in the core-top diatomopal samples suggests a potential tool for investigating the biogeochemical cycling of Zn in the past surface ocean for down-core diatomopal material. In this respect, it may be possible to test hypotheses that attribute variations in atmospheric CO2 on glacial–interglacial timescales to the degree to which trace metals limited primary productivity in HNLC zones.  相似文献   
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