Distribution,abundance and carbon isotopic composition of gaseous hydrocarbons in Big Soda Lake,Nevada: An alkaline,meromictic lake     

Ronald S. Oremland  David J. Des Marais 《Geochimica et cosmochimica acta》1983,47(12):2107-2114

Distribution and isotopic composition (δ¹³C) of low molecular weight hydrocarbon gases were studied in Big Soda Lake (depth = 64 m), an alkaline, meromictic lake with permanently anoxic bottom waters. Methane increased with depth in the anoxic mixolimnion (depth = 20–35 m), reached uniform concentrations (55 μM/l) in the monimolimnion (35–64 m) and again increased with depth in monimolimnion bottom sediments (>400 μM/kg below 1 m sub-bottom depth). The μ¹³C[CH₄] values in bottom sediment below 1 m sub-bottom depth (<?70 per mil) increased with vertical distance up the core (δ¹³C[CH₄] = ?55 per mil at sediment surface). Monimolimnion δ¹³C[CH₄] values (?55 to ?61 per mil) were greater than most δ¹³C[CH₄] values found in the anoxic mixolimnion (92% of samples had δ¹³C[CH₄] values between ?20 and ?48 per mil). No significant concentrations of ethylene or propylene were found in the lake. However ethane, propane, isobutane and n-butane concentrations all increased with water column depth, with respective maximum concentrations of 260, 80, 23 and 22 nM/l encountered between 50–60 m depth. Concentrations of ethane, propane and butanes decreased with depth in the bottom sediments. Ratios of $\text{CH}{}_4\text{[C}{}_2\text{H}{}_6\text{+ C}{}_3\text{H}{}_8\text{]}$ were high (250–620) in the anoxic mixolimnion, decreased to ~161 in the monimolimnion and increased with depth in the sediment to values as high as 1736. We concluded that methane has a biogenic origin in both the sediments and the anoxic water column and that C₂-C₄ alkanes have biogenic origins in the monimolimnion water and shallow sediments. The changes observed in δ¹³C[CH₄] and $\text{CH}{}_4\text{(C}{}_2\text{H}{}_6\text{+ C}{}_3\text{H}{}_8\text{)}$ with depth in the water column and sediments are probably caused by bacteria] processes. These might include anaerobic methane oxidation and different rates of methanogenesis and C₂ to C₄ alkane production by microorganisms.  相似文献   

Cosmic ray tracks in the Shalka meteorite     

R.K. Bull  S.A. Durrani 《Earth and Planetary Science Letters》1976,32(1):35-39

Track densities of heavy cosmic rays have been studied in hypersthene crystals taken from seven known depths below a fusion crust in the Shalka meteorite. By comparing these with a theoretical model, a preatmospheric radius of 20 ± 2cm has been estimated for the meteorite, assuming it to have been originally spherical. The fossil track-length distributions show a prominent peak in the region of 12–15 μm; and this has been attributed, on the basis of accelerated-ion calibration experiments, to cosmic ray Fe ions. The value (≥0.38 ± 0.04) of relative abundance of Fe ions to the total Fe-group ions (20 ≤ Z. ≤ 28) found in the cosmic ray flux averaged over the last ～19 m.y. is shown to be broadly similar to those given by present-day measurements.  相似文献   

Subaqueous,rhyolitic dome-top tuff cones: a model based on the Devonian Bunga Beds,southeastern Australia and a modern analogue     

Cas  R A F  Allen  R L  Bull  S W  Clifford  B A  Wright  J V 《Bulletin of Volcanology》1990,52(3):159-174

The relics of two Late Devonian subaqueous rhyolitic dome-top tuff and pumice cone successions are preserved in the Bunga Beds outlier of the Boyd Volcanic Complex, southeastern Australia. These cone successions and other rhyolitic volcanics of the Bunga Beds are associated with turbidite and other deep-water massflow sedimentary rocks. The two cone successions have a generally similar stratigraphy. At the base, flow-banded, variably autobrecciated and quench-fragmented rhyolite, representing an intrusive to extrusive dome, is overlain by rhyolitesediment breccia, representing extrusion of the dome through the deep-water sediment pile and resedimentation down its flanks. In the northern cone succession an overlying, succession of bedded pumiceous crystal-rich to crystal-poor tuffs represents the onset of pyroclastic activity and growth of a tuff cone. An overyling debris flow deposit represents degradation of part of the cone. The topmost unit, a stratified pumice succession, is thought to represent another cone-building eruptive phase, and is separated from the underlying strata by a major slide surface. The southern cone succession contains less tuff and abundant pumice, and is also terminated by a debris-flow deposit, indicating cone degradation. A modern analogue for the inferred eruptive style and sequence is the 1953–1957 rhyolite eruption that formed the Tuluman Island lava-tuff cone complex in the Bismarck Sea. The eruptions were often cyclical consisting of an initial inferred submarine-lava-forming stage, passing into a pumicecone-forming stage, in some cases a subaeriallava-forming stage, and a final stage, following the cessation of volcanism, during which the cones collapsed gravitationally or were destroyed by wave erosion. Using observations from both the Tuluman Island eruptions and the preserved stratigraphies of the Devonian tuff cones, a dynamic model is proposed for the formation of subaqueous rhyolitic dome-top tuff and pumice cones.  相似文献   

Stable isotopic compositions of carbonates from the Mesoproterozoic Bangemall Group, northwestern Australia     

Buick R  Des Marais DJ  Knoll AH 《Chemical Geology》1995,123(1-4):153-171

Marine carbonate rocks from the Mesoproterozoic Bangemall Group of northwestern Australia show little deviation (+/-1.3%) in whole-rock delta 13C(carb)-values about a mean of -0.5%. This narrow range persists despite close sampling (every 10-20 m) through long sections (up to 2500 m) that are geographically widespread (up to 250 km apart), over many depositional environments (supralittoral to outer shelf), sediment sources (stromatolitic bioherms to detrital calcilutites) and rock types (pure limestones to dolomitic shales). The only major excursions from the norm seem related to unusual environmental or post-depositional processes, as they are correlated with large enrichments (to -3%) or depletions (to -16%) in 18O. Relatively heavy delta 13C-values, up to +2.5%, occur in a single bed of brecciated ferruginous dolostone at a single locality; these abnormal values may result from local evaporitic conditions. Limey and shaley nodular dolostones have delta 13C-values as low as -4.3%, probably caused by remineralization of organic matter during late and patchy dolomitization. Most notably, sharp negative excursions in delta 13C, up to -8.4%, occur in bleached kerogen-free rocks with mineral assemblages of dolomite + quartz + calcite +/- tremolite + talc, reflecting isotopic re-equilibration in thick metamorphic aureoles around dolerite intrusions. General environmental variations are minor, with delta 13C-values of peritidal facies tending to be slightly positive whereas those of subtidal facies are slightly negative. There are no strong secular trends, but subtle fluctuations within the range -2 to +l% can be correlated along the northwestern margin of the basin. This resembles the pattern seen in other Mesoproterozoic successions, but is markedly unlike the heavy background (> +5%) and extreme variations (up to l0%) in delta 13C evident in Neoproterozoic successions of similar thickness and environmental setting. Hence, in contrast to the Neoproterozoic, the global rate of organic carbon burial was probably fairly constant during deposition of the Bangemall Group, and perhaps generally during the Mesoproterozoic, as was the redox state of the atmosphere and hydrosphere.  相似文献   

The fission track records of the Estherville,Nakhla and Odessa meteorites     

P.F. Green  R.K. Bull  S.A. Durrani 《Geochimica et cosmochimica acta》1978,42(9):1359-1366

Investigation of fossil charged-particle track densities in various mineral phases of three meteorites—Estherville, Nakhla and Odessa—coupled with U content determination, has led to the evaluation of various contributions to the total fossil track density, including those due to the spontaneous fission of ²³⁸U and ²⁴⁴Pu. A fission-track age for Estherville of around 4 × 10⁹ yr is found, which is thought to reflect slow cooling of the parent body. A Pu track excess of (106 ± 9): 1 over the spontaneous fission of ²³⁸U is found in Odessa diopside, which is larger than may be allówed on a simple ‘continuous synthesis’ model for the production of heavy elements prior to solar system formation. Possible explanations for this value are discussed, including fractionation of Pu relative to U. No detectable U was found in Nakhla diopside, and a measurable contribution of track densities from the fission of superheavy elements is ruled out on the basis of track-length measurements and laboratory calibration with Fe ions.  相似文献   

Fiamme textures in volcanic successions: Flaming issues of definition and interpretation     

Katharine F. Bull  Jocelyn McPhie 《Journal of Volcanology and Geothermal Research》2007

  相似文献   

Heterogeneity in hedonic modelling of house prices: looking at buyers’ household profiles   总被引：2，自引：0，他引：2  

Yan Kestens  Marius Thériault  François Des Rosiers 《Journal of Geographical Systems》2006,8(1):61-96

This paper introduces household-level data into hedonic models in order to measure the heterogeneity of implicit prices regarding household type, age, educational attainment, income, and the previous tenure status of the buyers. Two methods are used for this purpose: a first series of models uses expansion terms, whereas a second series applies Geographically Weighted Regressions. Both methods yield conclusive results, showing that the marginal value given to certain property specifics and location attributes do vary regarding the characteristics of the buyer’s household. Particularly, major findings concern the significant effect of income on the location rent as well as the premium paid by highly-educated households in order to fulfil social homogeneity.  相似文献   

Numerical investigation of salinity in controlling ore-forming fluid transport in sedimentary basins: example of the HYC deposit, Northern Australia     

Jianwen Yang  Stuart Bull  Ross Large 《Mineralium Deposita》2004,39(5-6):622-631

This paper presents the first hydrogeological model that fully couples transient fluid flow, heat and solute transport associated with the formation of the HYC SEDEX deposit in the McArthur Basin, northern Australia. Numerical results reveal that salinity plays an important role in controlling hydrothermal fluid migration. In particular, it appears that it is the distribution of evaporitic units within a given basin, rather than their absolute abundance, that controls the development of free convection. Relatively saline conditions at the seafloor strengthen the thermally-induced buoyancy force and hence promote free convection of basinal solutions; whereas high salinities at the bottom counteract the thermal function of natural geothermal gradient and suppress the development of convective hydrothermal fluid circulation. In the latter case, higher thermal gradients are required to initiate substantial free convective fluid flow.Numerical experiments also suggest the position of an ore body with respect to its vent system may be controlled by the spatial and temporal salinity distributions in the basin. Vent-distal ore formation, a result of exhalation of brines that are denser than seawater and hence can flow away from the vent region, is promoted by moderate salinity at the seafloor and higher salinity in the aquifer. Vent-proximal ore accumulation, a result of pluming upon exhalation of brines less dense than seawater, is favored by the highest salinity conditions occurring near the level of the seafloor.Editorial Handling: G. Beaudoin  相似文献   

Taking varves to bits: Scanning electron microscopy in the study of laminated sediments and varves   总被引：2，自引：0，他引：2  

Jean M. Dean  Alan E.S. Kemp  David Bull  Jennifer Pike  Gunilla Patterson  Bernd Zolitschka 《Journal of Paleolimnology》1999,22(2):121-136

Conventional high resolution studies of varved sediments are able to identify clastic and biogenic laminae, but are often unable to resolve the nature of fine-scale lamination contained therein. This intra-annual signal provides us with the highest potential resolution from the sedimentary record and can be resolved using scanning electron microscopy (SEM). Six case studies from lacustrine and marine settings are presented to illustrate the combination of clastic and biogenic fabric types typically found in laminated sediments. Clastic laminae fabrics include those which originate through grain settling and those which are event deposits. The correct identification of event deposits is essential if varves are to be used chronologically. SEM-based biogenic laminae fabric studies have identified seasonal faunal successions where individual laminae may be less than 100 thick and most recently, deep chlorophyll maxima (DCM) summer diatom floras, providing an insight into seasonal scale processes. High resolution lamina fabric studies can provide a basis for generating records of seasonal and inter-annual variability, thus contributing to our understanding of lacustrine and marine processes and palaeoenvironmental interpretation.  相似文献   

The sedimentology of river confluences     

Gregory H. Sambrook Smith  Andrew P. Nicholas  James L. Best  Jonathan M. Bull  Simon J. Dixon  Steven Goodbred  Maminul H. Sarker  Mark E. Vardy 《Sedimentology》2019,66(2):391-407

Channel confluences are key nodes within large river networks, and yet surprisingly little is known about their spatial and temporal evolution. Moreover, because confluences are associated with vertical scour that typically extends to several times the mean channel depth, the deposits associated with such scours should have a high preservation potential within the rock record. Paradoxically, such scours are rarely observed, and their preservation and sedimentological interpretation are poorly understood. The present study details results from a physically‐based morphodynamic model that is applied to simulate the evolution and alluvial architecture of large river junctions. Boundary conditions within the model were defined to approximate the junction of the Ganges and Jamuna rivers, Bangladesh, with the model output being supplemented by geophysical datasets collected at this junction. The numerical simulations reveal several distinct styles of sedimentary fill that are related to the morphodynamic behaviour of bars, confluence scour downstream of braid bars, bend scour and major junction scour. Comparison with existing, largely qualitative, conceptual models reveals that none of these can be applied simply, although elements of each are evident in the deposits generated by the numerical simulation and observed in the geophysical data. The characteristics of the simulated scour deposits are found to vary according to the degree of reworking caused by channel migration, a factor not considered adequately in current conceptual models of confluence sedimentology. The alluvial architecture of major junction scours is thus characterized by the prevalence of erosion surfaces in conjunction with the thickest depositional sets. Confluence scour downstream of braid bar and bend scour sites may preserve some large individual sets, but these locations are typically characterized by lower average set thickness compared to major junction scour and by a lack of large‐scale erosional surfaces. Areas of deposition not related to any of the specific scour types highlighted above record the thinnest depositional sets. This variety in the alluvial architecture of scours may go some way towards explaining the paradox of ancient junction scours, that while abundant large scours are likely in the rock record, they have been reported rarely. The present results outline the likely range of confluence sedimentology and will serve as a new tool for recognizing and interpreting these deposits in the ancient fluvial record.  相似文献