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71.
Despite the scant quantitative data available in the literature, it has been hypothesized that some chemical compounds can have deleterious effects on soil stabilization with lime and cements (e.g., nitrates, phosphates and chlorides). This study intends to assess their influence on soil stabilization quantitatively. An original experimental procedure was followed. Selected soils were mixed with a potential deleterious compound at a concentration representative of what can be found in the field. The performance of the different mixtures in terms of soil stabilization was then assessed by performing mechanical tests on samples submitted to several curing conditions (temperature and humidity). The results showed that the tested compounds are likely to alter the soil stabilization processes and thus lower the mechanical performance of the stabilized soil. The results also showed that it is not possible to determine a single threshold value for the compounds considered because their influence on soil stabilization is also a function of the nature of the soil (silt or fine sand), the type of cement (CEM I or CEM II) and the curing conditions.  相似文献   
72.
Data‐driven techniques based on machine learning algorithms are becoming popular in hydrological modelling, in particular for forecasting. Artificial neural networks (ANNs) are often the first choice. The so‐called instance‐based learning (IBL) has received relatively little attention, and the present paper explores the applicability of these methods in the field of hydrological forecasting. Their performance is compared with that of ANNs, M5 model trees and conceptual hydrological models. Four short‐term flow forecasting problems were solved for two catchments. Results showed that the IBL methods often produce better results than ANNs and M5 model trees, especially if used with the Gaussian kernel function. The study showed that IBL is an effective data‐driven method that can be successfully used in hydrological forecasting. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   
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74.
Strong ground motions caused by earthquakes with magnitudes ranging from 3.5 to 6.9 and hypocentral distances of up to 300 km were recorded by local broadband stations and three-component accelerograms within Georgia’s enhanced digital seismic network. Such data mixing is particularly effective in areas where strong ground motion data are lacking. The data were used to produce models based on ground-motion prediction equations (GMPEs), one benefit of which is that they take into consideration information from waveforms across a wide range of frequencies. In this study, models were developed to predict ground motions for peak ground acceleration and 5%-damped pseudo-absolute-acceleration spectra for periods between 0.01 and 10 s. Short-period ground motions decayed faster than long-period motions, though decay was still in the order of approximately 1/r. Faulting mechanisms and local soil conditions greatly influence GMPEs. The spectral acceleration (SA) of thrust faults was higher than that for either strike-slip or normal faults but the influence of strike-slip faulting on SA was slightly greater than that for normal faults. Soft soils also caused significantly more amplification than rocky sites.  相似文献   
75.
76.
A 1-D biogeochemical reactive transport model with a full set of equilibrium and kinetic biogeochemical reactions was developed to simulate the fate and transport of arsenic and mercury in subaqueous sediment caps. Model simulations (50?years) were performed for freshwater and estuarine scenarios with an anaerobic porewater and either a diffusion-only or a diffusion plus 0.1-m/year upward advective flux through the cap. A biological habitat layer in the top 0.15?m of the cap was simulated with the addition of organic carbon. For arsenic, the generation of sulfate-reducing conditions limits the formation of iron oxide phases available for adsorption. As a result, subaqueous sediment caps may be relatively ineffective for mitigating contaminant arsenic migration when influent concentrations are high and sorption capacity is insufficient. For mercury, sulfate reduction promotes the precipitation of metacinnabar (HgS) below the habitat layer, and associated fluxes across the sediment–water interface are low. As such, cap thickness is a key design parameter that can be adjusted to control the depth below the sediment–water interface at which mercury sulfide precipitates. The highest dissolved methylmercury concentrations occur in the habitat layer in estuarine environments under conditions of advecting porewater, but the highest sediment concentrations are predicted to occur in freshwater environments due to sorption on sediment organic matter. Site-specific reactive transport simulations are a powerful tool for identifying the major controls on sediment- and porewater-contaminant arsenic and mercury concentrations that result from coupling between physical conditions and biologically mediated chemical reactions.  相似文献   
77.
This paper summarizes the results of an extensive study on the inelastic seismic response of X‐braced steel buildings. More than 100 regular multi‐storey tension‐compression X‐braced steel frames are subjected to an ensemble of 30 ordinary (i.e. without near fault effects) ground motions. The records are scaled to different intensities in order to drive the structures to different levels of inelastic deformation. The statistical analysis of the created response databank indicates that the number of stories, period of vibration, brace slenderness ratio and column stiffness strongly influence the amplitude and heightwise distribution of inelastic deformation. Nonlinear regression analysis is employed in order to derive simple formulae which reflect the aforementioned influences and offer a direct estimation of drift and ductility demands. The uncertainty of this estimation due to the record‐to‐record variability is discussed in detail. More specifically, given the strength (or behaviour) reduction factor, the proposed formulae provide reliable estimates of the maximum roof displacement, the maximum interstorey drift ratio and the maximum cyclic ductility of the diagonals along the height of the structure. The strength reduction factor refers to the point of the first buckling of the diagonals in the building and thus, pushover analysis and estimation of the overstrength factor are not required. This design‐oriented feature enables both the rapid seismic assessment of existing structures and the direct deformation‐controlled seismic design of new ones. A comparison of the proposed method with the procedures adopted in current seismic design codes reveals the accuracy and efficiency of the former. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   
78.
The nature of adsorbed arsenate species for a wide range of minerals and environmental conditions is fundamental to prediction of the migration and long-term fate of arsenate in natural environments. Spectroscopic experiments and theoretical calculations have demonstrated the potential importance of a variety of arsenate surface species on several iron and aluminum oxides. However, integration of the results of these studies with surface complexation models and extrapolation over wide ranges of conditions and for many oxides remains a challenge. In the present study, in situ X-ray and infrared spectroscopic and theoretical molecular evidence of arsenate (and the analogous phosphate) surface speciation are integrated with an extended triple layer model (ETLM) of surface complexation, which takes into account the electrostatic work associated with the ions and the water dipoles involved in inner-sphere surface complexation by the ligand exchange mechanism.Three reactions forming inner-sphere arsenate surface species
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79.
Considerable efforts have been dedicated to desertification research in the arid and semi-arid drylands of central Asia. However, there are few quantitative studies in conjunction with proper qualitative evaluation concerning land degradation and aeolian activity in the alpine realm. In this study, spectral information from two Landsat-5 TM scenes (04.08.1994 and 28.07.2009, respectively) was combined with reference information obtained in the field to run supervised classifications of eight landscape types for both time steps. Subsequently, the temporal and spatial patterns of the alpine wetlands/grasslands evolutions in the Zoige Basin were quantified and assessed based on these two classification maps. The most conspicuous change is the sharp increase of ~627 km2 degraded meadow. Concerning other land-covers, shallow wetland increases ~107 km2 and aeolian sediments (mobile dunes and sand sheets) have an increase of ~30 km2. Considering the deterioration, an obvious decrease of ~440 km2 degraded wetland can be observed. Likewise, decrease of deep wetland (~78 km2), humid meadow (~80 km2) and undisturbed meadow (~88 km2) were determined. These entire evolution matrixes undoubtedly hint a deteriorating tendency of the Zoige Basin ecosystem, which is characterized by significantly declined proportion of intact wetlands, meadow, rangeland and a considerable increase of degraded meadow and larger areas of mobile dunes. In particular, not only temporal alteration of the land-cover categories, the spatial and topographical characteristics of the land degradation also deserves more attention. In the alpine rangelands, the higher terraces of the river channels along with their slopes are more liable to the degradation and desertification. This tendency has significantly impeded the nomadic and agriculture activities. The set of anthropozoogenic factors encompassing enclosures, overgrazing and trampling, rodent damaging and exceedingly ditching in the wetlands are assumed to be the main controlling mechanisms for the landscape degradation. A suite of strict protection policies is urgent and indispensable for self-regulation and restoration of the alpine meadow ecosystem. Controlling the size of livestock, less ditching in the rangeland, and the launching of a more strict nature reserve management by adjacent Ruoergai, Maqu and Hongyuan Counties would be practical and efficacious in achieving these objectives.  相似文献   
80.
Close to the village of Pulle (N Belgium), six trenches were opened for archaeological research. This resulted in the discovery of a dense spread of traces of human settlement. Only a relatively small number of artefacts was found, but these allowed attributing the traces to habitation during the Iron Age and Early Middle Ages. In one of the trenches, the level with the archaeological finds was covered by a drift-sand dune. The accumulation of these aeolian sediments presumably put an end to the human occupation. Hence, dating these sediments might provide essential information as to the chronology of the occupational history of the site.Quartz-based optical dating was applied to constrain the timing of sand-drifting at Pulle. All samples showed satisfactory luminescence characteristics and yielded an internally consistent set of optical ages. Within analytical uncertainty, the age results show no increase with depth and do not allow differentiating between distinct phases of sand-drifting. An average age of 1.2 ± 0.1 ka was obtained, which is interpreted as an upper age limit for human occupation at the site. The results also illustrate (the limit on) the time resolution that can be achieved through conventional quartz single-aliquot optical dating techniques; considering these limitations, we conclude that the sand-drifting at Pulle occurred during a single, fairly short event in the Early Middle Ages.  相似文献   
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