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31.
Arsenic(III) adsorption reactions are thought to play a critical role in the mobility of arsenic in the environment. It is the nature of the As(III) surface species that must be known on a wide variety of minerals and over a range of pH, ionic strength and surface coverage in order to be able to predict adsorption behavior. EXAFS and XANES spectroscopic studies have identified bidentate, binuclear inner-sphere surface species and/or an outer-sphere species, but only a few oxides have been examined. These results need to be integrated with a predictive surface complexation model in order to ascertain the environmental conditions under which the different surface species may be important on a wide range of solids. In the present study, the surface species information from XAFS and XANES studies has been built into a recent extension of the triple-layer model (ETLM) for the formation of inner-sphere complexes of anions that takes into account the electrostatics of water dipole desorption during ligand exchange reactions. The ETLM has been applied to regress surface titration, proton coadsorption, and As(III) adsorption data over extensive ranges of pH, ionic strength, electrolyte type and surface coverage for magnetite, goethite, gibbsite, amorphous hydrous alumina, hydrous ferric oxide (HFO), ferrihydrite, and amorphous iron oxide. Two principal reactions forming inner- and outer-sphere As(III) surface species,
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Floodplain deposition is an essential part of the Holocene sediment dynamics of many catchments and a thorough dating control of these floodplain deposits is therefore essential to understand the driving forces of these sediment dynamics. In this paper we date floodplain and colluvial deposition in the Belgian Dijle catchment using accelerator mass spectrometric radiocarbon and optical stimulated luminescence dating. Relative mass accumulation curves for the Holocene were constructed for three colluvial sites and 12 alluvial sites. A database was constructed of all available radiocarbon ages of the catchment and this database was analysed using relative sediment mass accumulation rates and cumulative probability functions of ages and site‐specific sedimentation curves. Cumulative probability functions of ages were split into different depositional environments representing stable phases and phases of accelerated clastic deposition. The results indicate that there is an important variation between the different dated sites. After an initial stable early and middle Holocene phase with mainly peat growth in the floodplains, clastic sedimentation rates increased from 4000 BC on. This first phase was more pronounced and started somewhat earlier for colluvial deposits then for alluvial deposits. The main part of the Holocene deposits, both in colluvial and alluvial valleys, was deposited during the last 1 ka. The sedimentation pattern of the individual dated sites and the catchment‐wide pattern indicate that land use changes are responsible for the main variations in the Holocene sediment dynamics of this catchment, while the field data do not provide indications for a climatological influence on the sediment dynamics. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
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We introduce a surface approximation technique to address the problem of fitting a surface to a given set of curves. The originality of the method lies in its ability to take into account the continuous aspect of the data, and also in the possibility to arbitrarily select the regularity (C0, C1, or higher) of the approximant obtained. We demonstrate the efficiency of the approach by constructing a bathymetry map of the Marianas trench based upon a set of SONAR (SOnic Navigation And Ranging) bathymetry ship track data.  相似文献   
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We introduce a surface approximation technique to address the problem of fitting a surface to a given set of curves. The originality of the method lies in its ability to take into account the continuous aspect of the data, and also in the possibility to arbitrarily select the regularity (C0, C1, or higher) of the approximant obtained. We demonstrate the efficiency of the approach by constructing a bathymetry map of the Marianas trench based upon a set of SONAR (SOnic Navigation And Ranging) bathymetry ship track data.  相似文献   
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Elastic wave propagation in an irregularly layered medium   总被引:1,自引:0,他引:1  
The indirect boundary element method (IBEM) is used to simulate wave propagation in two-dimensional irregularly layered elastic media for internal line sources. The method is based on the integral representation for scattered elastic waves using single layer boundary sources. Fulfillment of the boundary conditions leads to a system of integral equations. Results are obtained in the frequency domain and seismograins are computed through Fourier synthesis. In order to test and validate the method we present various comparisons between our results and the time series obtained analytically for a buried line source in a half-space and by using the recently developed spectral element method (SEM).  相似文献   
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This methods paper details the first attempt at monitoring bank erosion, flow and suspended sediment at a site during flooding on the Mekong River induced by the passage of tropical cyclones. We deployed integrated mobile laser scanning (MLS) and multibeam echo sounding (MBES), alongside acoustic Doppler current profiling (aDcp), to directly measure changes in river bank and bed at high (~0.05 m) spatial resolution, in conjunction with measurements of flow and suspended sediment dynamics. We outline the methodological steps used to collect and process this complex point cloud data, and detail the procedures used to process and calibrate the aDcp flow and sediment flux data. A comparison with conventional remote sensing methods of estimating bank erosion, using aerial images and Landsat imagery, reveals that traditional techniques are error prone at the high temporal resolutions required to quantify the patterns and volumes of bank erosion induced by the passage of individual flood events. Our analysis reveals the importance of cyclone‐driven flood events in causing high rates of erosion and suspended sediment transport, with a c. twofold increase in bank erosion volumes and a fourfold increase in suspended sediment volumes in the cyclone‐affected wet season. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
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It is shown that the ultraviolet flux-deficiency, recently discovered by Carruthers, in early-type supergiants compared to dwarfs of the same spectral type can be explained in terms of the effects of differences in surface-gravity and effective temperature between stars of these two luminosity classes. It thus appears that this deficiency does not represent a serious discrepancy between theory and observation.  相似文献   
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