Suitability of Existing Numerical Model Codes and Thermodynamic Databases for the Prognosis of Calcite Dissolution Processes in Near-Surface Sediments Due to a CO2 Leakage Investigated by Column Experiments     

Christoph Haase  Andreas Dahmke  Markus Ebert  Dirk Schäfer  Frank Dethlefsen 《Aquatic Geochemistry》2014,20(6):639-661

Among the risks of CO₂ storage is the potential of CO₂ leakage into overlaying formations and near-surface potable aquifers. Through a leakage, the CO₂ can intrude into protected groundwater resources, which can lead to groundwater acidification followed by potential mobilisation of heavy metals and other trace metals through mineral dissolution or ion exchange processes. The prediction of pH buffer reactions in the formations overlaying a CO₂ storage site is essential for assessing the impact of CO₂ leakages in terms of trace metal mobilisation. For buffering the pH-value, calcite dissolution is one of the most important mechanisms. Although calcite dissolution has been studied for decades, experiments conducted under elevated CO₂ partial pressures are rare. Here, the first study for column experiments is presented applying CO₂ partial pressures from 6 to 43 bars and realising a near-natural flow regime. Geochemical calculations of calcite dissolution kinetics were conducted using PHREEQC together with different thermodynamic databases. Applying calcite surface areas, which were previously acquired by N₂-BET or calculated based on grain diameters, respectively, to the rate laws according to Plummer et al. (Am J Sci 278:179–216, doi:10.2475/ajs.278.2.179, 1978) or Palandri and Kharaka (US Geol Surv Open file Rep 2004–1068:71, 2004) in the numerical simulations led to an overestimation of the calcite dissolution rate by up to three orders of magnitude compared to the results of the column experiments. Only reduction of the calcite surface area in the simulations as a fitting procedure allowed reproducing the experimental results. A reason may be that the diffusion boundary layer (DBL), which depends on the groundwater flow velocity and develops at the calcite grain surface separating it from the bulk of the solution, has to be regarded: The DBL leads to a decrease in the calcite dissolution rate under natural laminar flow conditions compared to turbulent mixing in traditional batch experiments. However, varying the rate constants by three orders of magnitudes in a field scale PHREEQC model simulating a CO₂ leakage produced minor variations in the pH buffering through calcite dissolution. This justifies the use of equilibrium models when calculating the calcite dissolution in CO₂ leakage scenarios for porous aquifers and slow or moderate groundwater flow velocities. However, the selection of the thermodynamic database has an impact on the dissolved calcium concentration, leading to an uncertainty in the simulation results. The resulting uncertainty, which applies also to the calculated propagation of an aquifer zone depleted in calcite through dissolution, seems negligible for shallow aquifers of approximately 60 m depth, but amounts to 35 % of the calcium concentration for aquifers at a depth of approximately 400 m.  相似文献   

Application of a hydrometeorological model chain to investigate the effect of global boundaries and downscaling on simulated river discharge     

T. Marke  W. Mauser  A. Pfeiffer  G. Zängl  D. Jacob  U. Strasser 《Environmental Earth Sciences》2014,71(11):4849-4868

In the current study, two regional climate models (MM5 and REMO) driven by different global boundary conditions (the ERA40 reanalysis and the ECHAM5 model) are one-way coupled to the uncalibrated hydrological process model PROMET to analyze the impact of global boundary conditions, dynamical regionalization and subsequent statistical downscaling (bilinear interpolation, correction of subgrid-scale variability and combined correction of subgrid-scale variability and bias) on river discharge simulation. The results of 12 one-way coupled model runs, set up for the catchment of the Upper Danube (Central Europe) over the historical period 1971–2000, prove the expectation that the global boundaries applied to force the RCMs strongly influence the accuracy of simulated river discharge. It is, however, noteworthy that all efficiency criteria in case of bias corrected MM5 simulations indicate better performance under ERA40 boundaries, whereas REMO-driven hydrological simulations better correspond to measured discharge under ECHAM5 boundaries. Comparing the hydrological results achievable with MM5 and REMO, the application of bias-corrected MM5 simulations turned out to allow for a more accurate simulation of discharge, while the variance in simulated discharge in most cases was better reflected in case of REMO forcings. The correction of subgrid-scale variability within the downscaling of RCM simulations compared to a bilinear interpolation allows for a more accurate simulation of discharge for all model configurations and all discharge criteria considered (mean monthly discharge, mean monthly low-flow and peak-flow discharge). Further improvements in the hydrological simulations could be achieved by eliminating the biases (in terms of deviations from observed meteorological conditions) inherent in the driving RCM simulations, regardless of the global boundary conditions or the RCM applied. In spite of all downscaling and bias correction efforts described, the RCM-driven hydrological simulations remain less accurate than those achievable with spatially distributed meteorological observations.  相似文献   

A new geospatial overlay method for the analysis and visualization of spatial change patterns using object-oriented data modeling concepts     

Dirk Tiede 《制图学和地理信息科学》2014,41(3):227-234

Traditional geographic information system (GIS)-overlay routines usually build on relatively simple data models. Topology is – if at all – calculated on the fly for very specific tasks only. If, for example, a change comparison is conducted between two or more polygon layers, the result leads mostly to a complete and also very complex from–to class intersection. A lot of additional processing steps need to be performed to arrive at aggregated and meaningful results. To overcome this problem a new, automated geospatial overlay method in a topologically enabled (multi-scale) framework is presented. The implementation works with polygon and raster layers and uses a multi-scale vector/raster data model developed in the object-based image analysis software eCognition (Trimble Geospatial Imaging, Munich, Germany). Advantages are the use of the software inherent topological relationships in an object-by-object comparison, addressing some of the basic concepts of object-oriented data modeling such as classification, generalization, and aggregation. Results can easily be aggregated to a change-detection layer; change dependencies and the definition of different change classes are interactively possible through the use of a class hierarchy and its inheritance (parent–child class relationships). Implementation is exemplarily shown for a change comparison of CORINE Land Cover data sets. The result is a flexible and transferable solution which is – if parameterized once – fully automated.  相似文献   

Satellite-based peatland mapping: Potential of the MODIS sensor     

Dirk Pflugmacher  Olga N. Krankina  Warren B. Cohen 《Global and Planetary Change》2007,56(3-4):248

Peatlands play a major role in the global carbon cycle but are largely overlooked in current large-scale vegetation mapping efforts. In this study, we investigated the potential of the Moderate Resolution Imaging Spectroradiometer (MODIS) to capture the extent and distribution of peatlands in the St. Petersburg region of Russia by analyzing the relationships between peatland cover fractions derived from reference maps and  1-km resolution MODIS Nadir BRDF-Adjusted Reflectance (NBAR) data from year 2002.First, we characterized and mapped 50 peatlands from forest inventory and peat deposit inventory data. The peatlands represent three major nutritional types (oligotrophic, mesotrophic, eutrophic) and different sizes (0.6–7800 ha). In addition, parts of 6 peatlands were mined for peat and these were mapped separately. The reference maps provided information on peatland cover for 1105 MODIS pixels. We performed regression analysis on 50% of the pixels and reserved the remainder for model validation. Canonical correlation analysis on the MODIS reflectance bands and the peatland cover fractions produced a multi-spectral peatland cover index (PCI), which served as the predictor in a reduced major axis (RMA) regression model. The results suggest a high potential for mapping peatlands with MODIS. The RMA regression models explained much of the variance in the PCI (r² = 0.74 for mined and r² = 0.81 for unmined peatlands). Model validation showed high correlation between observed versus predicted peatland cover (mined: r = 0.87; unmined: r = 0.92). We used the models to derive peatland cover estimates for the St. Petersburg region and compared the results to current MODIS land cover maps.  相似文献   

The Australia telescope 20 GHz survey: hardware, observing strategy, and scanning survey catalog     

Paul Jacob Hancock  Paul Roberts  Michael J. Kesteven  Ronald D. Ekers  Elaine M. Sadler  Tara Murphy  Marcella Massardi  Roberto Ricci  Mark Calabretta  Gianfranco de Zotti  Philip G. Edwards  Jennifer A. Ekers  Carole A. Jackson  Mark Leach  Chris Phillips  Robert J. Sault  Lister Staveley-Smith  Ravi Subrahmanyan  Mark A. Walker  Warwick E. Wilson 《Experimental Astronomy》2011,32(2):147-177

The Australia Telescope 20 GHz (AT20G) survey is a large area (2?? sr), sensitive (40 mJy), high frequency (20 GHz) survey of the southern sky. The survey was conducted in two parts: an initial fast scanning survey, and a series of more accurate follow-up observations. The follow-up survey catalog has been presented by Murphy et al. (MNRAS 402:2403, 2010). In this paper we discuss the hardware setup and scanning survey strategy as well as the production of the scanning survey catalog.  相似文献   

New Reference Materials,Analytical Procedures and Data Reduction Strategies for Sr Isotope Measurements in Geological Materials by LA-MC-ICP-MS     

Jacob Mulder  Graham Hagen-Peter  Teresa Ubide  Rasmus Andreasen  Ellen Kooijman  Melanie Kielman-Schmitt  Yue-Xing Feng  Bence Paul  Andreas Karlsson  Christian Tegner  Charles Lesher  Fidel Costa 《Geostandards and Geoanalytical Research》2023,47(2):311-336

Laser ablation multi-collector mass spectrometry (LA-MC-ICP-MS) has emerged as the technique of choice for in situ measurements of Sr isotopes in geological minerals. However, the method poses analytical challenges and there is no widely adopted standardised approach to collecting these data or correcting the numerous potential isobaric inferences. Here, we outline practical analytical procedures and data reduction strategies to help establish a consistent framework for collecting and correcting Sr isotope measurements in geological materials by LA-MC-ICP-MS. We characterise a new set of plagioclase reference materials, which are available for distribution to the community, and present a new data reduction scheme for the Iolite software package to correct isobaric interferences for different materials and analytical conditions. Our tests show that a combination of Kr-baseline subtraction, Rb-peak-stripping using βRb derived from a bracketing glass reference material, and a CaCa or CaAr correction for plagioclase and CaCa or CaAr + REE²⁺ correction for rock glasses, yields the most accurate and precise ⁸⁷Sr/⁸⁶Sr measurements for these materials. Using the analytical and correction procedures outlined herein, spot analyses using a beam diameter of 100 μm or rastering with a 50–65 μm diameter beam can readily achieve < 100 ppm 2SE repeatability ("internal") precision for ⁸⁷Sr/⁸⁶Sr measurements for materials with < 1000 μg g^-1 Sr.  相似文献