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21.
The circulation of the Southern Ocean is studied in the eddy-resolving model POP (Parallel Ocean Program) by an analysis
of zonally integrated balances. The TEM formalism (Transformed Eulerian Mean) is extended to include topography and continental
boundaries, thus deviations from a zonally integrated state involve transient and standing eddies. The meridional circulation
is presented in terms of the Eulerian, eddy-induced, and residual streamfunctions. It is shown that the splitting of the meridional
circulation into Ekman and geostrophic transports and the component induced by subgrid and Reynolds stresses is identical
to a particular form of the zonally integrated balance of zonal momentum. In this balance, the eddy-induced streamfunctions
represent the interfacial form stresses by transient and standing eddies and the residual streamfunction represents the acceleration
of the zonal current by density fluxes in a zonally integrated frame. The latter acceleration term is directly related to
the surface flux of density and interior fluxes due to the resolved and unresolved eddies. The eddy-induced circulation is
extremely vigorous in POP. In the upper ocean a shallow circulation, reversed in comparison to the Deacon cell and mainly
due to standing eddies, appears to the north of Drake Passage latitudes, and in the Drake Passage belt of latitudes a deep-reaching
cell is induced by transient eddies. In the resulting residual circulation the Deacon cell is largely cancelled and the residual
advection of the zonal mean potential density is balanced by diapycnal eddy and subgrid fluxes which are strong in the upper
few hundred meters but small in the ocean interior. The balance of zonal momentum is consistent with other eddy-resolving
models; a new aspect is the clear identification of density effects in the zonally integrated balance. We show that the wind
stress and the stress induced by the residual circulation drive the eastward current, whereas both eddy species result in
a braking. Finally, we extend the Johnson–Bryden model of zonal transport to incorporate all relevant terms from the zonal
momentum balance. It is shown that wind stress and induction by the residual circulation carry an eastward transport while
bottom form stress and the stress induced by standing eddies yield westward components of transport.
Received: 26 June 2001 / Accepted: 2 November 2001 相似文献
22.
Dirk Goossens 《地球表面变化过程与地形》2001,26(11):1213-1219
This article presents a simple physical concept of aeolian dust accumulation, based on the behaviour of the subprocesses of dust deposition and dust erosion. The concept is tested in an aeolian dust wind tunnel. The agreement between the accumulation curve predicted by the model and the accumulation curve obtained in the experiments is close to perfect and shows that it is necessary to discriminate between the processes of aeolian dust deposition and aeolian dust accumulation. Two important thresholds determine the accumulation process. For wind speeds below the deflation threshold, the aeolian accumulation of dust increases linearly with the wind speed. For wind velocities between the deflation threshold and the accumulation limit, the sedimentation balance is above unity and there is still accumulation, though it rapidly drops once the deflation threshold has been exceeded. At wind speeds beyond the accumulation limit, the sedimentation balance is below unity and there will no longer be an accumulation of dust. The thresholds have been determined in a wind tunnel test at friction velocity u* = 0·34 m s?1 (deflation threshold) and u* = 0·43 m s?1 (accumulation limit), but these values are only indicative since they depend heavily on the characteristics of the accumulation surface and of the airborne grains. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献
23.
Martin Sudmanns Dirk Tiede Stefan Lang Helena Bergstedt Georg Trost Hannah Augustin 《International Journal of Digital Earth》2020,13(7):832-850
ABSTRACT Turning Earth observation (EO) data consistently and systematically into valuable global information layers is an ongoing challenge for the EO community. Recently, the term ‘big Earth data’ emerged to describe massive EO datasets that confronts analysts and their traditional workflows with a range of challenges. We argue that the altered circumstances must be actively intercepted by an evolution of EO to revolutionise their application in various domains. The disruptive element is that analysts and end-users increasingly rely on Web-based workflows. In this contribution we study selected systems and portals, put them in the context of challenges and opportunities and highlight selected shortcomings and possible future developments that we consider relevant for the imminent uptake of big Earth data. 相似文献
24.
Żelaźniewicz Andrzej Marheine Dirk Oberc-Dziedzic Teresa 《International Journal of Earth Sciences》2003,92(2):185-194
A Variscan foreland in western Poland comprises two NW-trending basement highs, which are concealed under Carboniferous through Triassic strata of the Fore-Sudetic Monocline (FSM). Both highs consist of multiply deformed quartz-sericite - albite - chlorite phyllites of unknown protolith age. 40Ar/39Ar laser probe dating of white micas in up to 0.5-mm-thick mica layers, which form the S2 axial-plane foliation in phyllites of the Wolsztyn-Leszno High, yielded an age of 340.1DŽ.6 Ma for the lower greenschists facies metamorphism and probably also for the F2 folding. This deformation was associated and followed by thrusting, which brought about the basement highs. The latter delivered clasts to overlying late Viséan-early Namurian flysch basin that was mainly sourced from the Saxothuringian Sudetes in which most of the deformation occurred between 345-335 Ma. The FSM basement may represent an independent terrane, referred to as the Wielkopolska terrane, belonging to the Armorican Terrane Assemblage. 相似文献
25.
Harald Geiger Ian Barnes Karl H. Becker Birger Bohn Theo Brauers Birgit Donner Hans-Peter Dorn Manfred Elend Carlos M. Freitas Dinis Dirk Grossmann Heinz Hass Holger Hein Axel Hoffmann Lars Hoppe Frank Hülsemann Dieter Kley Björn Klotz Hans G. Libuda Tobias Maurer Djuro Mihelcic Geert K. Moortgat Romeo Olariu Peter Neeb Dirk Poppe Lars Ruppert Claudia G. Sauer Oleg Shestakov Holger Somnitz William R. Stockwell Lars P. Thüner Andreas Wahner Peter Wiesen Friedhelm Zabel Reinhard Zellner Cornelius Zetzsch 《Journal of Atmospheric Chemistry》2002,42(1):323-357
Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere. 相似文献
26.
Richard Winterhalter Peter Neeb Dirk Grossmann Antje Kolloff Osamu Horie Geert Moortgat 《Journal of Atmospheric Chemistry》2000,35(2):165-197
Gas phase ozonolysis of -pinene was performedin a 570 l static reactor at 730 Torr and 296 K insynthetic air and the products were analysed by acombination of gas phase FTIR spectroscopy, HPLC andIC analyses of gas phase and aerosol samples,respectively. The reaction mechanism was investigatedby adding HCHO, HCOOH and H2O as Criegeeintermediate scavenger and cyclohexane as OH radicalscavenger. Main identified products (yields inparentheses) in the presence of cyclohexane as OHradical scavenger were HCHO (0.65 ± 0.04),nopinone (0.16 ± 0.04), 3-hydroxy-nopinone (0.15± 0.05), CO2 (0.20 ± 0.04), CO (0.030± 0.002), HCOOH (0.020 ± 0.002), the secondaryozonide of -pinene (0.16 ± 0.05), andcis-pinic acid (0.02 ± 0.01). The decompositionof the primary ozonide was found to yieldpredominantly the excited C9-Criegee intermediateand HCHO (0.84 ± 0.04) and to a minor extent theexcited CH2OO intermediate and nopinone (0.16± 0.04). Roughly 40% of the excitedC9-Criegee intermediate becomes stabilised andcould be shown to react with HCHO, HCOOH and H2O. The atmospherically important reaction of thestabilised C9-Criegee intermediate with H2Owas found to result in a nopinone increase of (0.35± 0.05) and in the formation of H2O2(0.24 ± 0.03). Based on the observed products,the unimolecular decomposition/isomerisationchannels of the C9-Criegee intermediate arediscussed in terms of the hydroperoxide and esterchannels. Subsequent reactions of the nopinonylradical, formed in the hydroperoxide channel, lead tomajor products like 3-hydroxy-nopinone but also tominor products like cis-pinic acid. A mechanismfor the formation of this dicarboxylic acid isproposed and its possible role in aerosol formationprocesses discussed. 相似文献
27.
Alexander Müller Dirk Flottmann Wolfgang Schulz Wolfram Seitz Walter H. Weber 《洁净——土壤、空气、水》2007,35(4):329-338
The development of instrumental analytics such as the LC-MS/MS has made it possible to quickly determine many component concentrations in a single chromatogram. However, the validation of such multi-methods needs new strategies for robustness and optimization. Statistical execution of analytical tests is one tool that can be utilized to meet this requirement. A Central Composite Design (CCD) was utilized for the validation of an LC-MS/MS multi-method for 84 analytes. The experimental design includes six design variables and two non-design variables (response variables). Concentration, ionization temperature, dwell time, gradient, flow (of eluent), and spraying/curtain gas (continuous design variables) were varied on five different levels; the whole design encompassed 91 runs. To investigate the robustness of a LC-MS/MS method both peak sensitivity and chromatographic separation had to be verified. Therefore, two non-design variables were necessary. The distribution of the peaks over analysis time was applied to describe the quality of the chromatographic separation. The sensitivity was described with the signal to noise ratio (S/N). The evaluation of the measured data was accomplished with the Analysis of Variance (ANOVA) and the Response Surface Methodology (RSM). Three main effects (concentration, ionization temperature, dwell time) and no significant interaction effect were found for the response variable “S/N”. The variables of concentration, ionization temperature, and dwell time had no significant effects for the response variable “S/N”. The ANOVA of the response variable chromatographic separation abandoned no significant effects as well. Therefore, robustness of the method can be guaranteed for all non significant design variables. 相似文献
28.
The solubility of KFe(CrO4)2·2H2O, a precipitate recently identified in a Cr(VI)-contaminated soil, was studied in dissolution and precipitation experiments. Ten dissolution experiments were conducted at 4–75°C and initial pH values between 0.8 and 1.2 using synthetic KFe(CrO4)2·2H2O. Four precipitation experiments were conducted at 25°C with final pH values between 0.16 and 1.39. The log KSP for the reaction
相似文献
29.
Matthias Zillmer Boris Kashtan & Dirk Gajewski 《Geophysical Journal International》1998,132(3):643-653
Wave propagation in weakly anisotropic inhomogeneous media is studied by the quasi-isotropic approximation of ray theory. The approach is based on the ray-tracing and dynamic ray-tracing differential equations for an isotropic background medium. In addition, it requires the integration of a system of two complex coupled differential equations along the isotropic ray.
The interference of the qS waves is described by traveltime and polarization corrections of interacting isotropic S waves. For qP waves the approach leads to a correction of the traveltime of the P wave in the isotropic background medium.
Seismograms and particle-motion diagrams obtained from numerical computations are presented for models with different strengths of anisotropy.
The equivalence of the quasi-isotropic approximation and the quasi-shear-wave coupling theory is demonstrated. The quasi-isotropic approximation allows for a consideration of the limit from weak anisotropy to isotropy, especially in the case of qS waves, where the usual ray theory for anisotropic media fails. 相似文献
The interference of the qS waves is described by traveltime and polarization corrections of interacting isotropic S waves. For qP waves the approach leads to a correction of the traveltime of the P wave in the isotropic background medium.
Seismograms and particle-motion diagrams obtained from numerical computations are presented for models with different strengths of anisotropy.
The equivalence of the quasi-isotropic approximation and the quasi-shear-wave coupling theory is demonstrated. The quasi-isotropic approximation allows for a consideration of the limit from weak anisotropy to isotropy, especially in the case of qS waves, where the usual ray theory for anisotropic media fails. 相似文献
30.
Dr. Heinz Ziehr Klaus Matzke Dr Gert Ott Dr. Vassilios Vouttsidis 《International Journal of Earth Sciences》1980,69(2):325-348
Zusammenfassung Im Hauptdolomit (Ca2) und im Plattendolomit (Ca3) des mittleren Zechsteins bei Eschwege und Sontra in Hessen wurde 1974 erstmals Fluorit entdeckt. Durch Bohrungen, chemische und geochemische Untersuchungen konnte nachgewiesen werden, daß im Hauptdolomit der Fluorit schichtgebunden, gelegentlich in dunklen Lagen und Linsen bis 0,5 m mächtig, makroskopisch sichtbar auftritt. Häufiger kommt er in 18–20 m mächtigen Zonen vor, die aber wegen des geringen Fluoritgehaltes von unter 10 % CaF2 sich von dem grauweißen Dolomit ohne Fluorit nicht unterscheiden.In den dunklen bis schwarz gefärbten Lagen schwanken die Fluoritgehalte zwischen 10 und 50 % CaF2. Einzelproben enthalten bis 80 % CaF2. Die Dunkelfärbung ist teils durch den Gehalt von violettem Fluorit, mehr noch durch Bitumen bedingt.Fluorit wurde ferner im stratigraphisch höher gelegenen Plattendolomit (Ca3) der Leine-Serie Z3 gefunden. In Aufschlüssen und Steinbrüchen in der Nähe von Sontra enthält der Plattendolomit lokal 1–4 % CaF2.Die makro- und mikroskopisch sichtbare Wechsellagerung von Fluorit und Dolomit mit einem deutlichen Lagengefüge und das Fehlen von hydrothermalem Fluorit und anderen Mineralien auf Gängen und Klüften sind Beweise für eine synsedimentäre Bildung des Fluorites im Hauptdolomit (Ca2) und Plattendolomit (Ca3) in Hessen. Für den Hauptdolomit wird angenommen, daß er spätdiagenetisch entstanden ist. Dies dürfte auch für den Fluorit zutreffen. Als Bildungsbereich werden flache Lagunen mit salinärer Fazies angenommen. Das Fluor stammt aus dem normalen Gehalt des Meerwassers. Es muß aber angenommen werden, daß der Fluorgehalt des Meerwassers durch Zufuhr von Fluor aus dem Festlande, z. B. aus den fluorreichen Graniten des Harzes merklich erhöht wurde. Nur so sind die großen Fluoritmengen im Zechsteindolomit in Hessen zu erklären. Sie werden auf 5–7·106 + CaF2 geschätzt.
Unserem Lehrer, Herrn Professor Dr. Georg Fischer, München, zum 80. Geburtstag gewidmet. 相似文献
In 1974, fluorite was detected for the first time in the Hauptdolomit (Ca2) and in the Plattendolomit (Ca3) of the Middle Zechsteinformation near Eschwege and Sontra, Hessia. It was confirmed by means of drilling, chemical and geochemical investigations that the fluorite in the Hauptdolomit is stratabound. It occurs both locally in the form of macroscopic dark layers and lenses of up to 0,5 m thickness and moreoften, as zones up to 18–20 m thick which cannot macroscopically be distinguished from the greyish white dolomite without fluorite because of the low CaF2 content (less than 10 %).The fluorite contents vary between 10 an 50 % CaF2 in the dark black layers. Special samples may contain up to 80 % CaF2. The dark colour derives partly from the lilac fluorite but to a greater degree from bitumous material.Fluorite has also been detected in the stratigraphically higher Plattendolomit (Ca3) of the Leine-Series Z 3. Outcrops and quarries near Sontra have local contents of 1–4 % CaF2.The macroscopic and microscopic interstratification of fluorite and dolomite with clear layer textures and the absence of hydrothermal fluorite and other minerals in veins of fissures are evidence for a synsedimentary formation of the fluorite in the Hauptdolomit (Ca2) and the Plattendolomit (Ca3). The Hauptdolomit is thought to have developed during late diagenesis. This should be valid for the fluorite, too. Shallow lagoons of a salinar facies are thought to have been the depositional environment. The fluorite precipitated from the sea waters, which were apparently enriched in fluorine by erosion at the fluorine rich granites of the Harz mountains. This is the only obvious explanation of the large amounts of fluorine in the Zechstein dolomite, estimated at 5–7×106 tonnes CaF2.
Résumé En 1974, de la fluorine fut découverte dans la dolomie dite »Hauptdolomit« (Ca2) et dans la dolomie dite »Plattendolomit» (Ca3) du Zechstein moyen, près d'Eschwege et de Sontra, en Hesse. Les sondages effectués ainsi que les analyses chimiques et géochimiques ont montré que la fluorine se rencontre de façon stratiforme dans la »Hauptdolomit«, quelquefois en couches et lentilles foncées d'une épaisseur maximale de 0,5 m, ou elle est visible macroscopiquement. La fluorine est souvent présente en faibles teneurs (moins de 10% de CaF2) dans des couches de 18 à 20 m d'épaisseur; de ce fait, ces dernières ne se distinguent pas de la dolomie gris-blanche exempte de fluorine.La teneur en fluorine varie de 10 % à 50% de CaF2 dans les couches foncées à noires. Certains échantillons renferment jusqu'à 80% de CaF2. La coloration foncée est due en partie à la fluorine violette, mais plus encore à la présence de bitume.De la fluorine fut également localisée dans la »Plattendolomit« (Ca3) de la »LeineSerie Z 3«, qui est située à un niveau stratigraphique supérieur. Cette »Plattendolomit« telle qu'on la rencontre dans les affleurements et carrières des environs de Sontra, contient de 1–4% de CaF2.L'alternance de fluorine et de dolomie qui, avec sa structure en couches nettement développées, est visible tant macroscopiquement que microscopiquement, ainsi que l'absence de fluorine hydrothermale et d'autres minéraux dans les filons et cassures, sont considérées comme preuves de la formation syn-sédimentaire de la fluorine dans la »Hauptdolomit« (Ca2) et dans la »Plattendolomit« (Ca3) de la Hesse. On suppose que la formation de la »Hauptdolomit« est diagénétique tardive. Cette hypothèse devrait également s'appliquer à la fluorine. Il est probable que ce processus a eu lieu dans les lagunes peu profondes à faciès salin. Le fluor provient de l'eau de mer à teneur normale. On peut cependant supposer que la teneur en fluor de l'eau de mer s'est accrue suite à l'apport de fluor provenant du continent, p.ex. à partir de granites riches en fluor du Harz. C'est seulement ainsi que peuvent s'expliquer les grandes quantités de fluorine de la dolomie du Zechstein, en Hesse. Elles sont évaluées entre 5 et 7 · 106 de CaF2.
(Ca2) (Ca3) . , , , 0,5 . 18–20 , - — CaF2 10% — , . 10 50% CaF2. 80% CaF2. , . (Ca3). 1–4% CaF2. , , ; , . , Ca2 . . , . . , ., , . . 5–7 × 106 CaF2.
Unserem Lehrer, Herrn Professor Dr. Georg Fischer, München, zum 80. Geburtstag gewidmet. 相似文献