Do clay mineral dissolution rates reach steady state?     

Stephan J. Köhler  Dirk Bosbach 《Geochimica et cosmochimica acta》2005,69(8):1997-2006

The temporal evolution of natural illite du Puy dissolution rates was measured from Si release rates in single-pass flow-through experiments lasting at least 100 days at 25°C and pH ranging from 2 to 12. Si release rates decreased by a factor of five and three at pH 12 and 2, respectively, during the experiments. These observations are interpreted to stem from changes in illite du Puy reactive surface area during these experiments. As the edges of clay minerals dissolve faster than the basal planes, dissolution tends to change clay mineral morphology decreasing the percentage of reactive edge sites. This continuously changing morphology prevents illite dissolution rates from attaining steady state during laboratory experiments lasting 100 to 200 days. A similar temporal decrease in dissolution rates is evident for many different sets of clay mineral dissolution rate data available in the literature. It seems reasonable, therefore, to expect that clay mineral dissolution does not attain steady state in nature, but rather their dissolution rates decrease continuously during their dissolution.  相似文献   

Authors'' Reply     

Dirk Schulze-Makuch 《Ground water》2006,44(2):140-141

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Efficient finite-difference modelling of seismic waves using locally adjustable time steps     

Joachim Falk  Ekkehart Tessmer  Dirk Gajewski 《Geophysical Prospecting》1998,46(6):603-616

Conventional finite-difference modelling algorithms for seismic forward modelling are based on a time-stepping scheme with a constant (global) time step. Large contrasts in the velocity model or in the spatial sampling rate cause oversampling in time for some regions of the model. The use of locally adjustable time steps can save large amounts of computation time for certain modelling configurations. The computation of spatial derivatives across the transition zone between regions of the model with different temporal sampling requires the definition of the wavefield at corresponding time levels on both sides of the transition zone. This condition can be obtained by extrapolation in time, which is inaccurate, or by multiple time integration in the transition zone. The error in the latter solution is of the same order as the conventional time-stepping scheme because both methods are based on the same iteration formula. The technique of multiple time integration simply requires the use of different sizes of time step. It is applicable only for certain factors of variation of the time step.  相似文献   

Synsedimentäre Gleitschollen großen Ausmaßes im terrestrischen Jungtertiär der Karawanken     

Univ. Doz. Dr. Dirk van Husen 《International Journal of Earth Sciences》1984,73(1):433-445

Zusammenfassung Während der Sedimentation der Rosenbacher Kohleschichten (W.Klaus 1956, Untersarmat) spielten die Karawanken als Liefergebiet der Sedimente kaum eine Rolle. Wie aus der Verbreitung dieser Sedimente im Bereich des Karawankenkörpers zu erkennen ist, wurden zumindest seine nördlichen Teile damit bedeckt. Im Hangenden dieser, aus gut gerollten, tonig sandigen Kiesen (mit hohem Quarzanteil) gebildeten Rosenbacher Kohleschichten treten dann die ersten deutlichen Einschüttungen aus den Karawanken auf. Diese deuten auf eine beginnende Heraushebung hin. Ihre Geröllzusammensetzung zeigt an, daß am Beginn dieser Entwicklung noch ein deutlicher Gerölltransport aus dem Bereich der Periadriatischen Naht über den Nordstamm der Karawanken stattfand.Die fortschreitende Heraushebung unterbrach diese Transportwege und führte zum Lösen großer Schollen von Wettersteinkalk, die nach Norden abglitten. Begünstigt wurde dieser Vorgang durch die Unterlagerung des Wettersteinkalkes durch mächtige Raibler Schiefer, die als Gleitmittel dienten.Die abgeglittenen Schollen (Tafeln bis zu 100–150 m Mächtigkeit und Längserstreckungen bis 2000 m) wurden dann in die grobklastischen Sedimente des Vorlandes konkordant eingelagert. Beide Vorgänge, Lösen und Abgleiten ins Vorland dieser Tafeln deuten auf eine rasche Hebung des Karawankenkörpers hin.Die weitere Hebung brachte dann nur noch sehr grobe Karbonatkiese, die die hangenden Anteile des grobklastischen Jungtertiärs (Bärental Konglomerat) bilden.In der weiteren Folge wurden diese Sedimente noch vom Karawankenkörper über eine kurze Strecke überschoben und auch in die fortschreitende Hebung (Ostteile) miteinbezogen.

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During the sedimentation of the Rosenbacher Kohleschichten (W.Klaus 1956, Untersarmat) the Karawanken were not so important for yielding sediments. As to be seen by the distribution of these sediments in the Karawanken area, at least its northern parts were covered by them. The top layers of the Rosenbacher Kohleschichten, consisting of clayey, sandy, well shaped gravels (with a high percentage of quartz) show first strong embankments from the Karawanken indicating a beginning uplift. Their gravel composition assigns that at the beginning of this development there was yet a transport northward from the area of the Periadriatische Naht through the Nordstamm of the Karawanken on many places.The proceeding uplift interrupted some of these spillways and lead to a discharge of large plates of Wettersteinkalk which glided northward. This procedure was favored by the thick Raibler Schiefer underlying the Wettersteinkalk and working as a lubricant.The down-glided plates (to 100–200 m thickness and a width up to 2000 m) were then embedded concordantly in the coarse clastic sediments of the forelands. Both, discharge and gliding of the plates point to a quick uplift of the Karawanken during Obersarmat.The further uplift yielded only very coarse carbonate gravels forming the top layers of the coarse clastic Young Tertiary (Bärental Konglomerat).Henceforth these sediments were overthrust by the Karawankenbody over a short distance and included in the advancing uplift (Eastern parts).

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Résumé Pendant la sédimentation des Rosenbacher Kohleschichten (W. Klaus 1956, Sarmatien inférieur) les Karawanken ne jouaient pas un grand rôle dans l'apport de sédiments. Tout au moins les sédiments couvraient-ils les pentes nord des Karawanken. Le toit des Rosenbacher Kohleschichten (formées par les graviers sableux et argileux, bien roulés, avec quartz abondant) montrent les premiers remblaiements provenant des Karawanken. Ceuxci indiquent le commencement du soulèvement des Karawanken. La composition des galets indiquent que, au commencement de ce développement, il y avait encore un transport bien marqué de galets depuis la suture périadriatique par dessus le rameau septentrional des Karawanken. Le soulèvement progressif interrompit cette voie de transport et conduisit à la séparation des grands blocaux du Wettersteinkalk, qui glissèrent vers le Nord. Ce processus était favorisé par la présence d'une puissante couche de Schistes de Raibler en-dessous du Wettersteinkalk, agissant comme lubrifiant.Puis les blocaux entraînés (des plaques de 100 à 200 m. d'épaisseur, jusqu'à 2000 m. de long), venaient s'intercaler en concordance dans les sédiments clastiques grossiers de l'avant-pays. Les deux phénomènes, séparation et glissement de ces plaques dans l'avantpays, indiquent un soulèvement rapide des Karawanken. Le soulèvement ultérieur ne délivra que de gros cailloux carbonatiques qui forment la partie supérieure du Miocène clastique (Bärentalkonglomerat).Dans la suite, ces sédiments furent chevauchés sur une courte distance par les Karawanken et impliqués aussi dans le soulèvement encore en cours (partie orientale).

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Determination of Antibiotic Residues in Manure,Soil, and Surface Waters     

Thorsten Christian  Rudolf J. Schneider  Harald A. Frber  Dirk Skutlarek  Michael T. Meyer  Heiner E. Goldbach 《洁净——土壤、空气、水》2003,31(1):36-44

In the last years more and more often detections of antimicrobially active compounds (“antibiotics”) in surface waters have been reported. As a possible input pathway in most cases municipal sewage has been discussed. But as an input from the realm of agriculture is conceivable as well, in this study it should be investigated if an input can occur via the pathway application of liquid manure on fields with the subsequent mechanisms surface run‐off/interflow, leaching, and drift. For this purpose a series of surface waters, soils, and liquid manures from North Rhine‐Westphalia (Northwestern Germany) were sampled and analyzed for up to 29 compounds by HPLC‐MS/MS. In each of the surface waters antibiotics could be detected. The highest concentrations were found in samples from spring (300 ng/L of erythromycin). Some of the substances detected (e.g., tylosin), as well as characteristics in the landscape suggest an input from agriculture in some particular cases. In the investigation of different liquid manure samples by a fast immunoassay method sulfadimidine could be detected in the range of 1…2 mg/kg. Soil that had been fertilized with this liquid manure showed a content of sulfadimidine extractable by accelerated solvent extraction (ASE) of 15 μg/kg dry weight even 7 months after the application. This indicates the high stability of some antibiotics in manure and soil.  相似文献   

Neotectonics and extension direction of the Southern Kenya Rift, Lake Magadi area     

Nassima Atmaoui  Dirk Hollnack   《Tectonophysics》2003,364(1-2):71-83

The Magadi area, located in the southern part of the Kenya Rift, is a seismically active region where rifting is still in progress. The recent tectonic activity has been investigated through a seismological survey and the study of neotectonic joints found in Lake Magadi sediments, which were deposited some 5000 years ago. The structural analysis of these open fractures was combined with a quantitative analysis of the orientation and size characteristics of imagery faults. The gathered data demonstrate (1) that the majority of the systematic joints have straight and parallel trajectories with a common en echelon mode of propagation displayed through a rich variety of patterns, and (2) that there is a self-similarity in fault and joint principal directions recognised at the different telescopic scales. SPOT image (1:125,000), aerial photos (1:76,000), and outcrop fieldwork reveal two important structural orientations which are N015°E and N015°W. The N015°E regional direction is consistent with the orientation of the southern segment of the Kenya Rift. Structural analysis is supported by results of a joint microseismic investigation in the Lake Magadi area. Obtained focal mechanism solutions indicate an E–W to ESE–WNW normal faulting extension direction.  相似文献   

An Inter-Laboratory Assessment of the Thorium Isotopic Composition of Synthetic and Rock Reference Materials   总被引：2，自引：0，他引：2  

Kenneth W.W. Sims  James B. Gill  Anthony Dosseto  Dirk L. Hoffmann  Craig C. Lundstrom  Ross W. Williams  Lary Ball  Darren Tollstrup  Simon Turner  Julie Prytulak  Justin J.G. Glessner  J.J. Standish  Tim Elliott 《Geostandards and Geoanalytical Research》2008,32(1):65-91

We present a concerted international effort to cross-calibrate five synthetic Th isotope reference materials (UCSC Th "A", OU Th "U", WUN, IRMM-35 and IRMM-36), and six rock reference materials (UCSC TML, Icelandic ATHO, USGS BCR-2, USGS W-2, USGS BHVO-2, LV18) using multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). We then compare our new values with a compilation of literature mass spectrometric data for these reference materials and derive recommended "consensus"²³⁰Th/²³²Th values for each. We also present isotope dilution U and Th concentration data for four rock reference materials (UCSC TML, Icelandic ATHO, USGS BCR-2, USGS W-2).  相似文献   

Analytical 3D views and virtual globes — scientific results in a familiar spatial context     

Dirk Tiede  Stefan Lang 《ISPRS Journal of Photogrammetry and Remote Sensing》2010,65(3):300-307

In this paper we introduce analytical three-dimensional (3D) views as a means for effective and comprehensible information delivery, using virtual globes and the third dimension as an additional information carrier. Four case studies are presented, in which information extraction results from very high spatial resolution (VHSR) satellite images were conditioned and aggregated or disaggregated to regular spatial units. The case studies were embedded in the context of: (1) urban life quality assessment (Salzburg/Austria); (2) post-disaster assessment (Harare/Zimbabwe); (3) emergency response (Lukole/Tanzania); and (4) contingency planning (faked crisis scenario/Germany). The results are made available in different virtual globe environments, using the implemented contextual data (such as satellite imagery, aerial photographs, and auxiliary geodata) as valuable additional context information. Both day-to-day users and high-level decision makers are addressees of this tailored information product. The degree of abstraction required for understanding a complex analytical content is balanced with the ease and appeal by which the context is conveyed.  相似文献   

A wind-driven model of the ocean surface layer with wave radiation physics     

Olbers  Dirk  Jurgenowski  Philipp  Eden  Carsten 《Ocean Dynamics》2020,70(8):1067-1088

Ocean Dynamics - Surface windstress transfers energy to the surface mixed layer of the ocean, and this energy partly radiates as internal gravity waves with near-inertial frequencies into the...  相似文献   

On the role of diffractions in velocity model building: a full-waveform inversion example     

Dell  Sergius  Abakumov  Ivan  Znak  Pavel  Gajewski  Dirk  Kashtan  Boris  Ponomarenko  Andrey 《Studia Geophysica et Geodaetica》2019,63(4):538-553

Studia Geophysica et Geodaetica - Imaging of small-scale heterogeneities is important for the geological exploration in complex environments. It requires a processing sequence tuned to...  相似文献