Reliable Determination of Ge in Solid Environmental Samples Using a Chemical Preparation Procedure Developed for Si Isotopes and ICP‐MS Analysis          下载免费PDF全文

Camille Delvigne  Bernard Angeletti  Abel Guihou  Isabelle Basile‐Doelsch  Jean‐Dominique Meunier 《Geostandards and Geoanalytical Research》2018,42(1):139-149

Germanium (Ge) exists at trace levels in the Earth's crust and is a powerful geochemical tracer of the silicon (Si) cycle. This study proposes a simple and reliable method for determining Ge contents in environmental samples using ICP‐MS. As Si and Ge have very similar chemical properties, we investigated the applicability of the chemical preparation procedure developed for Si isotopes for the determination of Ge in environmental samples. Advantages of this procedure are as follows: (a) efficient removal of the matrix and main interferences affecting Ge determinations by ICP‐MS, (b) a low limit of detection (6 ng l^?1), (c) relative repeatability of approximately 3% obtained on ⁷⁴Ge and (d) robustness and accuracy based on agreement within errors with the published Ge values for rock reference materials (BHVO‐2, AGV‐2 and BCR‐2). This procedure allowed revision of the Ge values of three soil reference materials (1.67 ± 0.09 μg g^?1, 2.41 ± 0.18 μg g^?1, 1.89 ± 0.10 μg g^?1 for GBW 07401, GBW 07404 and GBW 07407, respectively) and proposal of a value for the plant reference material ERM‐CD281 (70 ± 3 μg g^?1). This method provides a convenient procedure for determining Ge mass fractions in environmental samples and opens the possibility of coupling two tracers of the Si biogeochemical cycle with a single measurement procedure.  相似文献   

Significant Li isotope fractionation in geochemically evolved rare element-bearing pegmatites from the Little Nahanni Pegmatite Group,NWT, Canada     

Elspeth M. Barnes  Dominique Weis  Lee A. Groat 《Lithos》2012

Lithium isotope signatures of whole rock pegmatite samples and mineral separates from the rare element-bearing Little Nahanni Pegmatite Group, NWT, and whole rock samples from nearby granitic intrusions were measured. Correlation of the Li isotopic values from the pegmatite dikes with whole rock trace element geochemistry, mineralogy and primary textural evidence reflect mechanisms of Li isotopic fractionation during pegmatite formation. The heavier δ⁷Li signatures within the broad range measured from whole rock LNPG samples (? 0.94‰ to + 11.36‰) are related to the consolidation of the final ~ 15% melt fraction of a volatile-rich peraluminous magma in the late stages of magmatic fractionation. Rock-forming minerals (quartz, albite, spodumene and mica) display δ⁷Li signatures that indicate consolidation of the dikes under variable, non-equilibrium conditions. Lithium isotope signatures of relatively cool, highly evolved peraluminous magmas reflect the build-up of fluxes (e.g., H₂O and F) and provide a qualitative assessment of the state of mineral/melt chemical equilibrium.  相似文献   

From oblique accretion to transpression in the evolution of the Altaid collage: New insights from West Junggar,northwestern China     

Flavien Choulet  Michel Faure  Dominique Cluzel  Yan Chen  Wei Lin  Bo Wang 《Gondwana Research》2012,21(2-3):530-547

Along active margins, tectonic features that develop in response to plate convergence are strongly controlled by subduction zone geometry. In West Junggar, a segment of the giant Palaeozoic collage of Central Asia, the West Karamay Unit represents a Carboniferous accretionary complex composed of fore-arc sedimentary rocks and ophiolitic mélanges. The occurrence of quasi-synchronous upright folds and folds with vertical axes suggests that transpression plays a significant role in the tectonic evolution of the West Junggar. Latest Carboniferous (ca. 300 Ma) alkaline plutons postdate this early phase of folding, which was synchronous with accretion of the Carboniferous complex. The Permian Dalabute sinistral fault overprints Carboniferous ductile shearing and split the West Karamay Unit ca. 100 km apart. Oblique convergence may have been provoked by the buckling of the Kazakh orocline and relative rotations between its segments. Depending upon the shape of the convergence zone, either upright folds and fold with vertical axes, or alternatively, strike–slip brittle faults developed in response to strain partitioning. Sinistral brittle faulting may account for the lateral imbrication of units in the West Junggar accretionary complex.  相似文献   

The Late Eocene and Late Miocene fronts of the Atlas Belt in eastern Maghreb: integration in the geodynamic evolution of the Mediterranean Domain     

Sami Khomsi  Dominique Frizon de Lamotte  Mourad Bédir  Oussema Echihi 《Arabian Journal of Geosciences》2016,9(15):650

Regional cross sections at the scale of the eastern Maghreb based on subsurface and field data allow presenting the structural styles related to the Middle-Late Eocene compressional events. The structural cross sections depict that the Late Eocene front of the Atlas Belt extends far through the Northern Africa plate margin comparatively to the Late Miocene front cropping out in the Eastern Tunisian Atlas. The sections allow proposing a new subsurface front for the Atlas belt encompassing a large part of the Pelagian-Sirt basins. The consequences of this particular configuration are discussed at the scale of the south Tethys margin and replaced in the frame of the geodynamic evolution of the Mediterranean Domain.  相似文献   

Exploring the past through lynchet landscapes in the Vosges Mountains and the Lorraine Plateau (France)     

Benjamin Keller  Robin Vincent  Dominique Schwartz  Damien Ertlen 《Geoarchaeology》2024,39(3):300-319

Lynchets are ridges formed by erosion and sediment accumulation downstream of agricultural plots and offer valuable insights into past agricultural activity. These microtopographies cover vast areas and serve as indicators of historical changes in land use. As a result, their ubiquity across Europe makes them particularly interesting. In this study, we propose a geoarchaeological approach to analyze six lynchets, four in the Vosges Mountains and two on the Lorraine Plateau (France). The lynchets can be considered soil archives with no stratigraphic organization or chronological sequence from bottom to top, making it difficult to determine the age of the lynchets and identify changes in land use over time. To this end, we propose the analysis of historical and geo-historical archives combined with the “pedosedimentary” archives of lynchets through charcoal identification and dating combined with near-infrared spectroscopy to determine the age, vegetation, and past land use changes associated with lynchet landscapes. By combining these multiple data sources, we are better able to show the chronological development of these ancient agricultural systems and uncover valuable information on landscape history. Charcoal dating suggests a higher frequency of fires from the Middle Ages. The dating aligns with the regional dynamics of anthropogenic fires, indicating a potential use of fire for cultural purposes. We also demonstrate the difficulty of extrapolating the dating of a lynchet to the entire lynchet system. Our results highlight the difficulties of interpreting the formation and dating of lynchets and the lynchet system on the sole basis of charcoal analysis. However, we highlight the value of applying pedoanthracology to lynchets to determine the dynamics of land use change in former fields.  相似文献   

Sub-Micrometre Resolution FIB-SEM-based ToF-SIMS Used to Map Geochemical Zoning in Four Zircon Reference Materials     

Ryan North  Lloyd T. White  Mitchell Nancarrow  Anthony Dosseto  Dominique Tanner 《Geostandards and Geoanalytical Research》2023,47(1):125-142

Zircon geochemistry can vary over micrometre scales; therefore, natural reference materials need to be well characterised before being used to calculate trace element mass fractions in unmeasured samples. Moreover, reference material homogeneity needs to be ensured with the accelerating rate of geoanalytical developments to map mineral chemistry at increasingly finer scales. Here, we investigate trace element zoning in four widely used zircon reference materials: 91500, Mud Tank, Temora and Plešovice, as well as zircon crystals from the Mount Dromedary/Gulaga Igneous Complex, Australia. Sub-micrometre resolution focused ion beam scanning electron microscope (FIB-SEM) based time-of-flight secondary ion mass spectrometry (ToF-SIMS) and 5 μm resolution LA-ICP-MS mapping show that trace elements are zoned in all reference materials, though 91500 exhibited the least zonation. We demonstrate that FIB-SEM-based ToF-SIMS can rapidly resolve variations in trace elements (e.g., U, Th, Sc, Y, Gd, Dy, Yb and Li) at sensitivities down to the μg g^-1 level with a spatial resolution of 195 nm for areas 100 × 85 μm to 959 × 828 μm. Zircon 91500 is recommended for future quantitative analyses provided that (1) the spatial distribution of elements is imaged before analysis of unknown samples and (2) it is used in conjunction with a doped glass as the primary reference material.  相似文献