Origin of iodine in volcanic fluids: I results from the Central American Volcanic Arc     

Glen T Snyder  Udo Fehn 《Geochimica et cosmochimica acta》2002,66(21):3827-3838

The largest reservoir of crustal iodine is found in marine sediments, where it is closely associated with organic material. This presence, together with the existence of a long-lived, cosmogenic radioisotope ¹²⁹I (t_1/2 = 15.7 Ma), make this isotopic system well suited for the study of sediment recycling in subduction zones. Reported here are the results of ¹²⁹I/I ratios in volcanic fluids, collected during a comprehensive study of fluids and gases in the Central American Volcanic Arc. ¹²⁹I/I ratios, together with I, Br, and Cl concentrations, were determined in 79 samples from four geothermal centers and a number of crater lakes, fumaroles, hot springs, and surface waters in Costa Rica, Nicaragua, and El Salvador. Geothermal and volcanic fluids were found to have iodine concentrations substantially higher than values in seawater or meteoric waters. ¹²⁹I/I ratios in most of the geothermal fluids are below the preanthropogenic input ratio of 1500 × 10⁻¹⁵, demonstrating that recent anthropogenic additions are largely absent from the volcanic systems. The majority of the ¹²⁹I/I ratios are between 500 and 800 × 10⁻¹⁵. These ratios indicate minimum iodine ages between 25 and 15 Ma, in good agreement with the age of subducted sediments in this region. In all four geothermal systems, however, a few samples were found with iodine ages older than 40 Ma—that is, considerably below the expected age range for subducted sediments from the Cocos Plate. These samples probably reflect the presence of iodine derived from sediments in older accreted oceanic terraines. The iodine ages indicate that the magmatic end member for the volcanic fluids originates in the deeper parts of the subducted sediment column, with small additions from older iodine mobilized from the overlying crust. The high concentrations of iodine in geothermal fluids, combined with the observed iodine ages, demonstrate that remobilization in the main volcanic zone (and probably also in the forearc area) is an important part in the overall marine cycle of iodine and similar elements.  相似文献   

Melting of β-quartz up to 2.0 GPa and thermodynamic optimization of the silica liquidus up to 6.0 GPa     

Pierre Hudon  In-Ho Jung  Don R. Baker 《Physics of the Earth and Planetary Interiors》2002,130(3-4):159-174

Melting relations of β-quartz were experimentally determined at 1.0 GPa (1900±20 °C), 1.5 GPa (2033±20 °C), and 2.0 GPa (2145±20 °C) using a new high-pressure assembly in a piston–cylinder apparatus and substantial differences were found with data previously reported. The new melting data of β-quartz were combined and optimized with all available thermodynamic, volumetric, and phase equilibria data for β-cristobalite, β-quartz and coesite to produce a P–T liquidus diagram for silica valid up to 6.0 GPa. Using the new optimized thermodynamic parameters, the invariant point β-cristobalite+β-quartz+liquid and β-quartz+coesite+liquid were determined to lie at 1687±17 °C and 0.457 GPa, and 2425±25 °C and 5.00 GPa, respectively.  相似文献   

Daily geomagnetic variations on the Iberian Peninsula   总被引：2，自引：0，他引：2  

Marta Cueto  Don McKnight  Miguel Herraiz 《Geophysical Journal International》2003,152(1):113-123

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Three-dimensional structure of the African superplume from waveform modelling   总被引：1，自引：0，他引：1  

Sidao Ni  Don V. Helmberger  Jeroen Tromp 《Geophysical Journal International》2005,161(2):283-294

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Environmental significance of C/C and O/O ratios of modern land-snail shells from the southern great plains of North America     

Meena Balakrishnan  James L. Theler  Don G. Wyckoff 《Quaternary Research》2005,63(1):15-30

¹³C/¹²C and ¹⁸O/¹⁶O ratios of aragonite shells of modern land snails from the southern Great Plains of North America were measured for samples from twelve localities in a narrow east-west corridor that extended from the Flint Hills in North Central Oklahoma to the foothills of the Sangre de Cristo Mountains in Northern New Mexico, USA. Across the study area, shell δ¹⁸O values (PDB scale) ranged from −4.1‰ to 1.2‰, while δ¹³C values ranged from −13.2‰ to 0.0‰. δ¹⁸O values of the shell aragonite were predicted with a published, steady state, evaporative flux balance model. The predicted values differed (with one exception) by less than 1‰ from locality averages of measured δ¹⁸O values. This similarity suggests that relative humidity at the time of snail activity is an important control on the δ¹⁸O values of the aragonite and emphasizes the seasonal nature of the climatic information preserved in the shells. Correlated δ¹³C values of coexisting Vallonia and Gastrocopta suggest similar feeding habits and imply that these genera can provide information on variations in southern Great Plains plant ecology. Although there is considerable scatter, multispecies, transect average δ¹³C values of the modern aragonite shells are related to variations in the type of photosynthesis (i.e., C₃, C₄) in the local plant communities. The results of this study emphasize the desirability of obtaining isotope ratios representing averages of many shells in a locale to reduce possible biases associated with local variations among individuals, species, etc., and thus better represent the “neighborhood” scale temporal and/or spatial environmental variations of interest in studies of modern and ancient systems.  相似文献   

Jet instability and the stabilizing effect of topography on jets in two-layer rotating systems     

Don L. Boyer  Rui-Rong Chen 《地球物理与天体物理流体动力学》2013,107(1-3):45-70

Abstract

Laboratory experiments concerning azimuthal jets in two-layer rotating systems in the absence and presence of bottom topography aligned along the jets have been conducted. The jets were forced by the selective withdrawal of fluid from the upper layer of a two-fluid system contained in a circular dishpan geometry. The principal parameters measured in the experiments were the jet Rossby number, Ro, and a stratification parameter F = r ₁/(λ₁λ₂)^1/2 where r ₁ is the radius of the circular disc used for the selective withdrawal (i.e., r ₁ is the approximate radius of curvature of the jet) and λ₁,λ₂ are the internal Rossby radii of deformation in the upper and lower fluids, respectively.

The no-topography experiments show that for a sufficiently small F, the particular value depending on Ro, the jet is stable for the duration of the experiment. For sufficiently large F, again as a function of Ro, the jet becomes unstable, exhibiting horizontal wave disturbances from modes three to seven. An Ro against F flow regime diagram is presented.

Experiments are then conducted in the presence of a bottom topography having constant cross-section and extending around a mid-radius of the dishpan. The axis of the topography is in the vicinity of the jet axis forced in the no-topography experiments and the crest of the topography is in the vicinity of the interface between the two fluids (i.e., the front associated with the jet). The experiments show that in all cases investigated the jet tends to be stabilized by the bottom topography. Experiments with the topography in place, but with the interface between the fluids being above the topography crest, are shown to be unstable but more irregular than their no-topography counterparts.

Various quantitative measurements of the jet are presented. It is shown, for example, that the jet Rossby number defined in terms of the fluid withdrawal rate from the tank. Q, can be well correlated with a dimensionless vorticity gradient, V_G , across the upper layer jet. This allows for an assessment of the stability characteristics of a jet based on a knowledge of V_G (which can be estimated given a jet profile) and F.  相似文献   

Testing the suitability of geologic frameworks for extrapolating hydraulic properties across regional scales     

Benjamin B Mirus  Keith Halford  Don Sweetkind  Joe Fenelon 《Hydrogeology Journal》2016,24(5):1133-1146

The suitability of geologic frameworks for extrapolating hydraulic conductivity (K) to length scales commensurate with hydraulic data is difficult to assess. A novel method is presented for evaluating assumed relations between K and geologic interpretations for regional-scale groundwater modeling. The approach relies on simultaneous interpretation of multiple aquifer tests using alternative geologic frameworks of variable complexity, where each framework is incorporated as prior information that assumes homogeneous K within each model unit. This approach is tested at Pahute Mesa within the Nevada National Security Site (USA), where observed drawdowns from eight aquifer tests in complex, highly faulted volcanic rocks provide the necessary hydraulic constraints. The investigated volume encompasses 40 mi³ (167 km³) where drawdowns traversed major fault structures and were detected more than 2 mi (3.2 km) from pumping wells. Complexity of the five frameworks assessed ranges from an undifferentiated mass of rock with a single unit to 14 distinct geologic units. Results show that only four geologic units can be justified as hydraulically unique for this location. The approach qualitatively evaluates the consistency of hydraulic property estimates within extents of investigation and effects of geologic frameworks on extrapolation. Distributions of transmissivity are similar within the investigated extents irrespective of the geologic framework. In contrast, the extrapolation of hydraulic properties beyond the volume investigated with interfering aquifer tests is strongly affected by the complexity of a given framework. Testing at Pahute Mesa illustrates how this method can be employed to determine the appropriate level of geologic complexity for large-scale groundwater modeling.  相似文献   

Landslide detection and susceptibility mapping using LiDAR and an artificial neural network approach: a case study in the Cuyahoga Valley National Park,Ohio     

Pece V. Gorsevski  M. Kenneth Brown  Kurt Panter  Charles M. Onasch  Anita Simic  Jeffrey Snyder 《Landslides》2016,13(3):467-484

The purpose of this study was to detect shallow landslides using hillshade maps derived from light detection and ranging (LiDAR)-based digital elevation model (DEM) derivatives. The landslide susceptibility mapping used an artificial neural network (ANN) approach and backpropagation method that was tested in the northern portion of the Cuyahoga Valley National Park (CVNP) located in northeast Ohio. The relationship between landslides and predictor attributes, which describe landform classes using slope, profile and plan curvatures, upslope drainage area, annual solar radiation, and wetness index, was extracted from LiDAR-based DEM using geographic information system (GIS). The approach presented in this paper required a training study area for the development of the susceptibility model and a validation study area to test the model. The results from the validation showed that within the very high susceptibility class, a total of 42.6 % of known landslides that were associated with 1.56 % of total area were correctly predicted. In contrast, the very low susceptibility class that represented 82.68 % of the total area was associated with 1.20 % of known landslides. The results suggest that the majority of the known landslides occur within a small portion of the study area, consistent with field investigation and other studies. Sample probabilistic maps of landslide susceptibility potential and other products from this approach are summarized and presented for visualization to help park officials in effective management and planning.  相似文献   

Increase in Dissolved Silica of Rivers Due to a Volcanic Eruption in an Estuarine Bay (Sorsogon Bay,Philippines)     

Fernando P. Siringan  Erwin Don R. Racasa  Carlos Primo C. David  Rhodelyn C. Saban 《Estuaries and Coasts》2018,41(8):2277-2288

Mount Bulusan, the Philippines’ fourth most active volcano, erupted in February 21, 2011, sending volcanic ash and pyroclastic materials to its surrounding rivers. The waters drained into the estuary of harmful algal blooms plagued Sorsogon Bay. We aim to determine the impact of the 2011 volcanic eruption and the preceding volcanic ash emissions to the dissolved silica concentration of rivers draining the flanks of Mt. Bulusan and its possible implications to the phytoplankton assemblage of the bay. Six river water sampling periods from August 2010 to October 2012 overlapped with Mt. Bulusan’s active phase of volcanism. Our data shows that mean river silica from pre-eruption levels of ~?500 μM increased by more than 200% during and post-eruption. Highest Si concentration of 2270 μM was measured from Cadacan River in August 2011. Here, we argue that the sustained general increase of dissolved silica is due to the silica-containing materials from Mt. Bulusan’s eruption and that their concentration in river waters is also a function of watershed lithology and precipitation. Increase in dissolved silica and other nutrients caused a shift to diatom domination and, possibly, termination of Pyrodinium bahamense var. compressum blooms. Silica load increase in embayments is a natural process that controls the dominance of algae. Our study also highlights the importance of Philippine rivers to the global ocean silica budget as a function of high precipitation, tectonics in general, and volcanism in particular.  相似文献   

Impact of Reservoir Permeability,Permeability Anisotropy and Designed Injection Rate on CO2 Gas Behavior in the Shallow Saline Aquifer at the CaMI Field Research Station,Brooks, Alberta     

Yu  Xinran  Ahmadinia  Masoud  Shariatipour  Seyed M.  Lawton  Don  Osadetz  Kirk  Saeedfar  Amin 《Natural Resources Research》2020,29(4):2735-2752

Natural Resources Research - Carbon capture and storage is part of Canada’s climate change action plan to reduce greenhouse gas emissions. The Containment and Monitoring Institute Field...  相似文献