Investigating the redox sensitivity of para-toluenesulfonamide (p-TSA) in groundwater     

Raffaella Meffe  Gudrun Massmann  Claus Kohfahl  Thomas Taute  Doreen Richter  Uwe Dünnbier  Asaf Pekdeger 《Environmental Earth Sciences》2012,65(3):861-870

The groundwater downstream of a former sewage irrigation farm in Berlin is contaminated with ammonium (NH₄ ⁺) and para-toluenesulfonamide (p-TSA), besides other anthropogenic pollutants. In the field, in situ removal of NH₄ ⁺ by gaseous oxygen (O₂) and air injection is currently being tested. A laboratory column experiment using aquifer material and groundwater from the site was performed to determine whether this remediation technology is also feasible to reduce high p-TSA concentrations in the anoxic groundwater. First, the column was operated under anoxic conditions. Later, compressed air was introduced into the system to simulate oxic conditions. Samples were collected from the column outlet before and after the addition of compressed air. The experiment revealed that whereas p-TSA was not removed under anoxic conditions, it was almost fully eliminated under oxic conditions. Results were modelled using a transient one-dimensional solute transport model. The degradation rate constants for p-TSA increased from 2.8E−06 to 7.5E−05 s^–1 as a result of microbial adaption to the change of redox conditions. Results show that O₂ injection into an anoxic aquifer is a successful strategy for p-TSA remediation.  相似文献   

Upper-atmosphere zonal winds from satellite orbit analysis     

D.G. King-hele  Doreen M.C. Walker 《Planetary and Space Science》1983,31(5):509-535

In this paper we review and interpret the values of upper-atmosphere rotation rate (zonal winds) obtained by analysing satellite orbits determined from observations. The history of the method is briefly reviewed, the basic principles are explained, objections to the method are answered, and three examples are given. Existing analyses of the atmospheric rotation rate A are critically reviewed, and, after rejecting some and revising others, we are left with 85 values. These are divided according to local time and season, to give the variation of A with height in nine situations—namely morning, evening and average local time, for summer, winter and average season. These observational results indicate that the value of Λ (in rev/day), averaged over both local time and season, increases from 1.0 at 125 km to 1.22 at 325 km and then decreases to 1.0 at 430 km and 0.82 at 600 km. The value of Λ is higher in the evening (18–24 h), with a maximum value (near 1.4) corresponding to a West-to-East wind of 150 m s^?1 at heights near 300 km. The value of Λ is lower in the morning (06–12 h), with East-to-West winds of order 50 m s^?1 at heights of 200–400 km. There is also a consistent seasonal variation, the values of Λ being on average 0.15 higher in winter and 0.1 lower in summer than the average seasonal value. No significant variation with solar activity is found, but there is a slight tendency for a greater rotation rate at lower latitudes for heights above 300 km. Unexpectedly, the values for the 1960s are found to be significantly higher than those for the 1970s. Finally, these observational values are compared with the theoretical global model of Fuller-Rowell and Rees: there is complete agreement on the trends, though there are some differences in the mean values.  相似文献   

Analyses of the US Navy orbits of 1963-24B and 1974-34A at 15th-order resonance     

Doreen M. C. Walker 《Geophysical Journal International》1981,67(1):1-18

Summary. The Upper Mesozoic section from Northern Tunisia provided an Upper Jurassic palaeomagnetic pole of 65.2°S 20.3°E α₉₅= 6.1 calculated from the means of normal and reversely magnetized samples from the uppermost Callovian, Oxfordian, Kimmeridgian and Portlandian rocks. In general the only Cretaceous rocks to yield acceptable results were the few samples collected from fresh outcrops.
A polarity sequence can be established for the Upper Jurassic which can be correlated with the oceanic Keathley anomaly sequence. One consequence of the proposed correlation of the oceanic anomaly with the terrestrial palaeomagnetic sequence is to suggest a slightly different age for the Oxfordian-Kimmeridgian boundary. One interpretation of the frequent intermediate directions of magnetization in the Cretaceous sequence is that there may be a number of unrecognized short period reversals within the Cretaceous and, more particularly, during the so-called Cretaceous normal period.  相似文献   

Geopotential harmonics of order 29, 30 and 31 from analysis of resonant orbits     

D.G. King-Hele  Doreen M.C. Walker 《Planetary and Space Science》1982,30(4):411-425

The Earth's gravitational potential is usually expressed as an infinite series of tesseral harmonics, and it is possible to evaluate “lumped harmonics” of a particular order m by analyses of resonant satellite orbits—orbits with tracks over the Earth that repeat after m revolutions. In this paper we review results on 30th-order harmonics from analyses of 15th-order resonance, and results on 29th- and 31st-order harmonics from 29:2 and 31:2 resonance.The values available for 30th-order lumped harmonics of even degree are numerous enough to allow a solution for individual coefficients of degree up to 40. The best-determined coefficients are those of degree 30, namely The standard deviations here are equivalent to 1 cm in geoid height.For the 29th- and 31st-order harmonics, and for the 30th-order harmonics of odd degree, there are not enough values to determine individual coefficients, but the lumped values from particular satellites can be used for “resonance testing” of gravity field models, particularly the Goddard Earth Model 10B (up to degree 36) and 10C (for degree greater than 36). The results of applying these tests are mixed. GEM 10B/C emerges well for order 30, with s.d. about 3×10^?9; for order 31, the GEM 10B values are probably good but the GEM 10C values are probably not; for order 29, the test is indecisive.  相似文献   

Multi-stage hydrothermal processes involved in “low-sulfide” Cu(–Ni)–PGE mineralization in the footwall of the Sudbury Igneous Complex (Canada): Amy Lake PGE zone, East Range     

Györgyi Tuba  Ferenc Molnár  Doreen E. Ames  Attila Péntek  David H. Watkinson  Peter C. Jones 《Mineralium Deposita》2014,49(1):7-47

The Amy Lake PGE zone is a “low-sulfide-type” Cu-(Ni-)PGE mineralization in the East Range footwall of the 1.85 Ga Sudbury Igneous Complex occurring in a 100-m-wide Sudbury Breccia belt that coincides with an impact-related major fracture zone (Bay Fault zone). Detailed hydrothermal alteration mapping, fluid inclusion, trace element, and stable isotope studies revealed a complex alteration and mineralization history in a multi-source, multi-stage Sudbury-related hydrothermal system. The two major stages of syn-Sudbury hydrothermal activity are characterized by similarly high-salinity, high-temperature fluids that are (1) locally derived from footwall granophyre bodies, and typified with high Ni/Cu and PGE/S ratios and high REE contents (magmatic–hydrothermal stage), and (2) a more voluminous Cu–Ni–PGE-rich fluid flux probably originated from the Sudbury Igneous Complex/footwall contact (hydrothermal stage). The second hydrothermal flux was introduced by brittle fractures in the area and resulted in a complex zonation of alteration assemblages and mineralization governed by local footwall composition. The Sudbury-related hydrothermal event was overprinted by shear-related epidote veining and calcite–chlorite replacement, both regionally present in the Sudbury structure. Based on analogies, the most important factors involved in the formation of hydrothermal low-sulfide mineralization are proposed to be (1) accumulation of PGE-enriched fluids, (2) large-scale brittle structures as conduits to these fluids, and (3) adequate host rock composition as a chemical trap resulting in sulfide and PGM precipitation. In environments meeting these criteria, hydrothermal PGE mineralization is known to have formed not only in the Sudbury footwall but also from mafic–ultramafic intrusions associated with primary magmatic PGE from several locations around the world.  相似文献   

Deformation,metamorphism, and mobilization of Ni–Cu–PGE sulfide ores at Garson Mine,Sudbury     

Joshua Mukwakwami  Bruno Lafrance  C. Michael Lesher  Douglas K. Tinkham  Nicole M. Rayner  Doreen E. Ames 《Mineralium Deposita》2014,49(2):175-198

The Garson Ni–Cu–platinum group element deposit is a deformed, overturned, low Ni tenor contact-type deposit along the contact between the Sudbury Igneous Complex (SIC) and stratigraphically underlying rocks of the Huronian Supergroup in the South Range of the 1.85-Ga Sudbury structure. The ore bodies are coincident with steeply south-dipping, north-over-south D₁ shear zones, which imbricated the SIC, its ore zones, and underlying Huronian rocks during mid-amphibolite facies metamorphism. The shear zones were reactivated as south-over-north, reverse shear zones during D₂ at mid-greenschist facies metamorphism. Syn-D₂ metamorphic titanite yields an age of 1,849?±?6 Ma, suggesting that D₁ and D₂ occurred immediately after crystallization of the SIC during the Penokean Orogeny. The ore bodies plunge steeply to the south parallel to colinear L₁ and L₂ mineral lineations, indicating that the geometry of the ore bodies are strongly controlled by D₁ and D₂. Sulfide mineralization consists of breccia ores, with minor disseminated sulfides hosted in norite, and syn-D₂ quartz–calcite–sulfide veins. Mobilization by ductile plastic flow was the dominant mechanism of sulfide/metal mobilization during D₁ and D₂, with additional minor hydrothermal mobilization of Cu, Fe, and Ni by hydrothermal fluids during D₂. Metamorphic pentlandite overgrows a S₁ ferrotschermakite foliation in D₁ deformed ore zones. Pentlandite was exsolved from recrystallized polygonal pyrrhotite grains after cessation of D₁, which resulted in randomly distributed large pentlandite grains and randomly oriented pentlandite loops along the grain boundaries of polygonal pyrrhotite within the breccia ore. It also overgrows a S₂ chlorite foliation in D₂ shear zones. Pyrrhotite recrystallized and was flattened during D₂ deformation of breccia ore along narrow shear zones. Exsolution of pentlandite loops along the grain boundaries of these flattened grains produced a pyrrhotite–pentlandite layering that is not observed in D₁ deformed ore zones. The overprinting of the two foliations by pentlandite and exsolution of pentlandite along the grain boundaries of flattened pyrrhotite grains suggest that the Garson ores reverted to a metamorphic monosulfide solid solution at temperatures ranging between 550 and 600 °C during D₁ and continued to deform as a monosulfide solid solution during D₂.  相似文献   

The evolution of the Onaping Formation at the Sudbury impact structure     

Richard A. F. GRIEVE  Doreen E. AMES  Joanna V. MORGAN  Natalia ARTEMIEVA 《Meteoritics & planetary science》2010,45(5):759-782

Abstract– The 1.4–1.6 km thick Onaping Formation consists of a complex series of breccias and “melt bodies” lying above the Sudbury Igneous Complex (SIC) at the Sudbury impact structure. Based on the presence of shocked lithic clasts and various “glassy” phases, the Onaping has been described as a “suevitic” breccia, with an origin, at least in part, as fallback material. Recent mapping and a redefined stratigraphy have emphasized similarities and differences in its various vitric phases, both as clast types and discrete intrusive bodies. The nature of the Onaping and that of other “suevitic” breccias overlying impact melt sheets is reviewed. The relative thickness, internal stratigraphic and lithological character, and the relative chronology of depositional units indicate multiple processes were involved over some time in the formation of the Onaping. The Sudbury structure formed in a foreland basin and water played an essential role in the evolution of the Onaping, as indicated by a major hydrothermal system generated during its formation. Taken together, observations and interpretations of the Onaping suggest a working hypothesis for the origin of the Onaping that includes not only impact but also the interaction of sea water with the impact melt, resulting in repeated explosive interactions involving proto‐SIC materials and mixing with pre‐existing lithologies. This is complicated by additional brecciation events due to the intrusion of proto‐SIC materials into the evolving and thickening Onaping. Fragmentation mechanisms changed as the system evolved and involved vesiculation in the formation of the upper two‐thirds of the Onaping.  相似文献   

Variation in the photochemical lability of dissolved organic matter in a large boreal watershed     

Doreen Franke  Michael W. Hamilton  Susan E. Ziegler 《Aquatic Sciences - Research Across Boundaries》2012,74(4):751-768

Boreal watersheds contain a vast quantity of terrestrially derived dissolved organic matter (DOM) originating from wetland and forest soils, yet variation in the potential for photochemical transformation of boreal aquatic DOM sources remains poorly understood. Laboratory solar radiation exposure experiments were conducted on DOM samples collected in three seasons, across nine sites, representing contrasting catchment composition and watershed position to assess variation in the photochemical lability of boreal DOM source and stable carbon isotopic signature (δ¹³C) of photomineralized DOM. Dissolved organic carbon (DOC) loss rates during laboratory exposure were lowest in summer, suggesting that DOM may have been more photo-degraded during summer. DOM from upstream portions of forested stream sites and wetland-influenced sites was more photolabile relative to downstream portions and the river DOM, suggesting potential losses in photolabile DOM downstream and in the lower reaches of the watershed. Increased a₂₅₄:a₃₅₀ and spectral slope following sample exposure suggest photoproduction of low molecular weight (LMW) CDOM and/or a higher photoreactivity of high molecular weight versus LMW compounds. Photomineralization of nitrogen was regulated by organic nitrogen concentration and resulted in NH₄ ⁺-photoproduction rates between 0.01 and 0.3?μM N?h^?1 and ecologically significant increases in NH₄ ⁺ for these waters. The δ¹³C of the photomineralized DOM was positively correlated to initial DOC concentration and generally lower when initial DOC concentrations were lower, suggesting variation in photomineralized DOM δ¹³C may be a result of kinetic isotope fractionation. Results from this study demonstrate significant variation in the photochemical lability of boreal watershed sources of DOM. Such variation suggests landscape and environmental change has the potential to alter the biogeochemical role photochemical transformations play in downstream portions of boreal watersheds.  相似文献   

The Use of a Standpipe to Evaluate Ground Water Samplers     

Doreen Y. Tai  Kenneth S. Turner  Lisa A. Garcia 《Ground Water Monitoring & Remediation》1991,11(1):125-132

A standpipe system was developed for testing the reliability of ground water samplers. The unit consists of a stainless steel pipe 5 inches (13 centimeters) in diameter and 100 feet (30.5 meters) in height. It has 14 sampling ports from which control samples can be withdrawn at the same time and position as the samples are collected by a sampler lowered to that position. Test solutions were made in two mixing tanks, totaling 260 gallons (980 liters), by diluting the concentrate of five volatile chlorohydrocarbons in water at two levels of concentration: 10-to-30 and 100-to-200 parts per billion (micrograms per liter).
A gas chromatograph interfaced with a purge-and-trap system was used to perform the analyses. Comparisons of the control samples with the sampler-collected samples have indicated that the three non-pumping samplers had recoveries in the range of 92.4 to 103.5 percent and the three pumping samplers had recoveries ranging from 97.7 to 101.5 percent.  相似文献   

Seasonality and abundance of ichthyoplankton in great South Bay,New York   总被引：1，自引：0，他引：1  

Doreen M. Monteleone 《Estuaries and Coasts》1992,15(2):230-238

The seasonality and abundance patterns of ichthyoplankton were investigated during 1985–1986 in Great South Bay, New York, USA. Eggs representing 17 species and larvae representing 23 species of fish were identified. Bay anchovy, Anchoa mitchilli, was the most abundant ichthyoplankter, comprising >96% of the eggs and >69% of the larvae collected. Bay anchovy spawned throughout the bay from late May through August, with peak baywide densities of >200 eggs and 6 larvae m^?3. Eggs of windowpane flounder (Scophthalmus aquosus) ranked second in abundance and were present in both spring and fall. Other dominant larvae were winter flounder (Pleuronectes americanus) and American sand lance (Ammodytes americanus). Their combined density reached 8 m^?3 and accounted for the winter peak in larvae. The seasonality of abundance of larval fish was strongly correlated with reported densities of copepod nauplii prey.  相似文献