Book reviews     

C. F. D’Elia  Douglas E. Ritchie 《Estuaries and Coasts》1980,3(2):152-153

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The influence of minerals on the pyrolysis of kerogens     

B. Horsfield  A.G. Douglas 《Geochimica et cosmochimica acta》1980,44(8):1119-1131

The effect of mineral matter on the laboratory pyrolysis of sediments, kerogens and coals, and of coal macerals mixed with either alumina, bentonite, kaolinite, or calcium carbonate has been investigated. Some minerals are more active than others in effecting changes in the composition of the pyrolysate. The relative content of low molecular weight pyrolysis products is higher for kerogens pyrolyzed in a mineral matrix than for isolated kerogens. Our limited data suggests that this is due to both condensation and gasification of higher molecular weight constituents in the ‘primary’ pyrolysate. Differences in the content of aromatic versus aliphatic compounds have been noted when pyrograms from coal macerals are compared with pyrograms from coal maceral-mineral mixtures. We conclude that mineralogy is important in controlling the composition of kerogen pyrolysis products.  相似文献   

The Global Carbon Cycle (Scope 13): B. Bolin,E.T. Degens,S. Kempe and P. Ketner (Editors). Wiley,New York, 1979, 491 pp., U.K. £ 17.50, ISBN 0-471-99710-2     

A.G. Douglas 《Physics of the Earth and Planetary Interiors》1981,26(3):230-231

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Geometric similarity for the temperature field in the unstable atmospheric surface layer     

Douglas S. Davison 《Boundary-Layer Meteorology》1976,10(2):167-180

Davenport's geometric similarity is applied to the temperature field in the unstable atmospheric surface layer for displacements in all three orthogonal directions. The decay constants for lateral displacements are over 50 times as large as for vertical displacements. Such large lateral decay constants mean that the measurement of longitudinal constants will be very difficult.Some of the assumptions inherent in geometric similarity were not satisfied. Two regimes, plume scales and larger scales, having different decay constants, were observed. The possibility of a similar scale dependency of the decay constants for the wind field is discussed.  相似文献   

Hemispheric simulation of the Asian summer monsoon     

Douglas A. Abbott 《Pure and Applied Geophysics》1977,115(5-6):1111-1130

A three-level, -plane, filtered model is used to simulate the Northern Hemisphere summer monsoon. A time-averaged initial state, devoid of sub-planetary scale waves, is integrated through 30 days on a 5° latitude-longitude grid. Day 25 through day 30 integrations are then repeated on a 2.5° grid. The planetary-scale waves are forced by time-independent, spatially varying diabatic heating. Energy is extracted via internal and surface frictional processes. Orography is excluded to simplify synoptic-scale energy sources.During integration the model energy first increases, but stabilizes near day 10. Subsequent flow patterns closely resemble the hemisphere summer monsoon. Climatological features remain quasi-stationary. At 200 mb high pressure dominates the land area, large-scale troughs are found over the Atlantic and Pacific Oceans, the easterly jet forms south of Asia, and subtropical jets develop in the westerlies. At 800 mb subtropical highs dominate the oceans and the monsoon trough develops over the Asian land mass. The planetary scales at all levels develop a realistic cellular structure from the passage of transient synoptic-scale features, e.g., a baroclinic cyclone track develops near 55°N and westward propagating waves form in the easterlies.Barotropic redistribution of kinetic energy is examined over a low-latitude zonal strip using a Fourier wave-space. In contrast to higher latitudes where the zonal flow and both longer and shorter waves are fed by barotropic energy redistribution from the baroclinically unstable wavelengths, the low-latitude waves have a planetary-scale kinetic energy source. Wave numbers 1 and 2 maintain both the zonal flow and all shorter scales via barotropic transfers. Transient and standing wave processes are examined individually and in combination.Wave energy accumulates at wave numbers 7 and 8 at 200 mb and at wave number 11 in the lower troposphere. The 800-mb waves are thermally indirect and in the mean they give energy to the zonal flow. These characteristics agree with atmospheric observation. The energy source for these waves is the three wave barotropic transfer. The implications of examining barotropic processes in a Fourier wave-space, vice the more common approach of separating the flow into a mean plus a deviation are discussed.  相似文献   

Stress in the lithosphere: Inferences from steady state flow of rocks   总被引：9，自引：0，他引：9  

Jean-Claude C. Mercier  Douglas A. Anderson  Neville L. Carter 《Pure and Applied Geophysics》1977,115(1-2):199-226

Mechanical data and flow processes from steady state deformation experiments may be used to infer the state of stress in the lithosphere and asthenosphere. Extrapolations of flow equations to a representative geologic strain rate of 10^–14/sec. for halite, marble, quartzite, dolomite, dunite and enstatolite are now warranted because the steady state flow processes in the experiments are identical to those in rocks and because the geotherms are reasonably well established. More direct estimates are obtained from free dislocation densities, subgrain sizes and recrystallized grain sizes all of which are functions only of stress. Using the last of these techniques, we have estimated stress profiles as a function of depth from xenoliths in basalts and kimberlites, whose depths of equilibration were determined by pyroxene techniques, from four different areas of subcontinental and suboceanic upper mantle. The results are similar and indicate stress differences of about 200 to 300 bars at 40 to 50 km, decaying to a few tens of bars at depths betow 100 km. These stresses are reasonable and are in accord with extrapolations of the mechanical data provided that allowance is made for a general increase in strain rate and decrease in viscosity with depth.  相似文献   

Variations in the content and distribution of n-alkanes in a series of carboniferous vitrinites and sporinites of bituminous rank     

J. Allan  A.G. Douglas 《Geochimica et cosmochimica acta》1977,41(9):1223-1230

n-Alkanes in the soluble organic matter extracted from a series of vitrinite and sporinite concentrates have been analysed by gas chromatography. The macerals were isolated from coals ranging in rank from 77.1% to 86.6% carbon (vitrinite: dry, ash-free), and yields of n-alkanes ranged from 10 to 580 ppm for vitrinites and from 20 to 970 ppm for sporinites. The maximum yields were found at a rank of 85.4% C from vitrinites and 86.6% C from sporinites.Distribution maxima of the n-alkanes, as shown by gas chromatography, range from C₂₇ and C₂₉ at lower ranks to as low as C₁₆ at higher ranks. The distributions also show a progressive decrease in the preference of odd-carbon-number homologues with increasing rank. Virtually smooth distributions were attained in high-volatile bituminous A coals. Quantitative data show that the loss of the odd-carbon-number preference occurred, for the most part, while individual long-chain homologues increased in concentration.There is a progressive increase in the amounts of shorter-chain n-alkanes with increasing rank. It is suggested that sequential processes may have occurred whereby the rate of formation of long-chain n-alkanes in high-volatile bituminous A rank macerals becomes slower than their rate of subsequent fragmentation to shorter chain lengths. Consequently, assuming derivation from the insoluble maceral matrices, the chain-length distributions of parent n-alkyl structures within the insoluble material may retain characteristics pertaining more to the nature of the source organic matter at the time of deposition than do the extractable n-alkane patterns, especially at higher ranks.  相似文献   

Trace element distribution in mineral separates of the Allende inclusions and their genetic implications     

Hiroshi Nagasawa  Douglas P Blanchard  Jeffrey W Jacobs  Joyce C Brannon  John A Philpotts  Naoki Onuma 《Geochimica et cosmochimica acta》1977,41(11):1587-1600

Concentrations of the REE, Sc, Co, Fe, Zn, Ir, Na and Cr were determined by instrumental neutron activation and mass spectrometric isotope dilution analysis for mineral separates of the coarseand fine-grained types (group I and II of Martin and Mason's classification) of the Allende inclusions.These data, combined with data on mineral/liquid partition coefficients, oxygen isotope distributions and diffusion calculations, suggest the following: (1) Minerals in the coarse-grained inclusions (group I) crystallized in a closed system with respect to refractory elements. On the other hand, differences in oxygen isotope distributions among minerals preclude a totally molten stage in the history of the inclusion. Group I inclusions were formed by rapid condensation (either to liquid or solid) in a supercooled solar nebula; extrasolar pyroxene and spinel dust were included but not melted in the condensing inclusions, thus preserving their extrasolar oxygen isotope composition. REE were distributed by diffusion during the subsequent heating at subsolidus temperatures; because oxygen diffuses much more slowly at these temperatures, the oxygen isotope anomalies were preserved. (2) The fine-grained (group II) inclusions were also formed by condensation from a super-cooled nebular gas; however, REE-rich clinopyroxene and spinel were formed early and REE-poor sodalite and nepheline were formed later and mechanically mixed with clinopyroxene and spinel to form the inclusions. The REE patterns of the bulk inclusions and the mineral separates are fractionated, indicating that REE abundances in the gaseous phase were already fractionated at the time of condensation of the minerals. (3) Pre-existing Mg isotope anomalies in the coarse-grained inclusions must have been erased during the heating stage thus resetting the ²⁶Al-²⁶Mg chronometer.  相似文献   

Reviews     

A. T. Miesch  A. C. Cook  John W. Harbaugh  H. Colin  P. H. A. Sneath  Douglas M. Hawkins  Martin A. Buzas  D. F. Merriam 《Mathematical Geosciences》1974,6(2):207-217

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Occurrence of a regular C₂₅ isoprenoid hydrocarbon in tertiary sediments representing a lagoonal-type,saline environment     

Douglas W Waples  Pat Haug  Dietrich H Welte 《Geochimica et cosmochimica acta》1974,38(3):381-387

A regular C₂₅ isoprenoid alkane (2,6,10,14,18-pentamethyleicosane) has been isolated from highly saline Tertiary sediments. The isolation utilized elution chromatography, urea adduction and gas chromatography; identification was based on the mass spectrum. This C₂₅ isoprenoid may represent a biological marker, possibly typical for a lagoonal-type, saline environment.  相似文献