A Raman spectroscopic study of arsenite and thioarsenite species in aqueous solution at 25°C     

Scott A Wood  C Drew Tait  David R Janecky 《Geochemical transactions》2002,3(1):31-9

The Raman spectra of thioarsenite and arsenite species in aqueous solution were obtained at room temperature. Solutions at constant ΣAs + ΣS of 0.1 and 0.5 mol kg^-1 were prepared with various ΣS/ΣAs ratios (0.1–9.0) and pH values (~7–13.2). Our data suggest that the speciation of As under the conditions investigated is more complicated than previously thought. The Raman measurements offer evidence for at least six separate S-bearing As species whose principal bands are centered near 365, 385, 390, 400, 415 and 420 cm^-1. The data suggest that at least two different species may give rise to bands at 385 cm^-1, bringing the probable minimum number of species to seven. Several additional species are possible but could not be resolved definitively. In general, the relative proportions of these species are dependent on total As concentration, ΣS/ΣAs ratio and pH. At very low ΣS/ΣAs ratios we also observe Raman bands attributable to the dissociation products of H₃AsO₃(aq). Although we were unable to assign precise stoichiometries for the various thioarsenite species, we were able to map out general pH and ΣS/ΣAs conditions under which the various thioarsenite and arsenite species are predominant. This study provides a basis for more detailed Raman spectroscopic and other types of investigations of the nature of thioarsenite species.  相似文献   

Memorial to John C. Griffiths 1912–1992     

Lawrence J. Drew 《Mathematical Geosciences》1993,25(3):421-424

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Directions     

Lawrence J. Drew 《Natural Resources Research》1995,4(4):291-295

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An interview with James MacKenzie     

Lawrence J. Drew 《Natural Resources Research》1994,3(1):1-5

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A procedure to estimate the parent population of the size of oil and gas fields as revealed by a study of economic truncation     

John H. Schuenemeyer  Lawrence J. Drew 《Mathematical Geosciences》1983,15(1):145-161

An estimation technique has been derived to predict the number of small fields in a geologic play or basin. Historically, many small oil and gas fields went unreported because they were not economical. This led to an underestimation of the number of undiscovered small fields. A study of the distributions of reported oil and gas fields in well-explored areas suggests that the large fields when grouped into log base 2 size classes are geometrically distributed. Further, the number of small fields reported is a function of the cost of exploration and development. Thus, the population field-size distribution is conjectured to be log geometric in form.  相似文献   

Debris flow initiation and sediment recharge in gullies   总被引：2，自引：0，他引：2  

Drew Brayshaw  Marwan A. Hassan   《Geomorphology》2009,109(3-4):122-131

Landslides that enter gullied low-order drainages can either initiate debris flow or stop, depositing sediment in the channel. This process is one of the most common ways that debris flows initiate, but little attention to date has been paid to evaluating the factors that affect whether or not the initial landslide will become a debris flow or deposit sediment in the channel. Statistically significant parameters that determine whether slope failures become debris flows or act to recharge in-channel sediment are channel gradient, angle of entry of failure into the channel, initial failure volume, and the amount of in-channel stored sediment. Steeper channels, low angles of entry, lower volumes of in-channel sediment, and larger initial failures were more likely to result in debris flows. This study found that as the volume of in-channel stored sediment increased, the volume of initial failure required to initiate a debris flow also increased. This result calls into question the simple supply-limited model of cyclical debris recharge and debris flow in low-order gullied drainages and suggests a negative feedback mechanism between debris accumulation and debris flow susceptibility.  相似文献   

CuNi-VTiFe复合型矿化镁铁-超镁铁杂岩体岩相学及岩石地球化学特征:以新疆北部为例   总被引：7，自引：4，他引：3  

王玉往  王京彬  王莉娟  龙灵利  唐萍芝  廖震  张会琼 《岩石学报》2010,26(2):401-412

铜镍硫化物矿床和钒钛磁铁矿矿床是镁铁-超镁铁杂岩重要的矿床类型,但二者共生的情况在国内还不多见。新疆北部这类铜镍-钒钛铁复合型矿化岩体较为发育,目前已发现有香山、牛毛泉、土墩南和哈拉达拉等4个岩体属于此类。它们的成岩时代多集中在早二叠世,出露面积在2.8～22km~2,介于通道型铜镍矿化小岩体和大型层状岩体之间,韵律构造发育;岩石组合为超基性-基性-中性岩类,以出现浅色的闪长岩或淡色辉长岩为特点,岩石中金属矿物氧化物(钛铁矿、磁铁矿)和硫化物(黄铁矿、磁黄铁矿、黄铜矿,有时有镍黄铁矿)共存和共生;含矿岩石组合和岩石化学特征与典型铜镍硫化物矿床和钒钛磁铁矿矿床相比,具有重叠和过渡特征;稀土和微量元素特征反映出杂岩体不同岩石类型可能具有相同或相似岩浆来源,是经过强烈分异和演化的产物。新疆北部这类复合型矿化,与北疆地区典型铜镍矿床和典型钒钛磁铁矿矿床,共同构成了新疆北部后碰撞幔源岩浆矿床成矿谱系。  相似文献   

IPHAS discoveries of young stars towards Cyg OB2 and its southern periphery     

Jorick S. Vink  Janet E. Drew  Danny Steeghs  Nick J. Wright  Eduardo L. Martin  Boris T. Gänsicke  Robert Greimel  Jeremy Drake 《Monthly notices of the Royal Astronomical Society》2008,387(1):308-318

We report on the discovery of over 50 strong Hα emitting objects towards the large OB association Cyg OB2 and the H  ii region DR 15 on its southern periphery. This was achieved using the INT Photometric Hα Survey of the Northern Galactic Plane (IPHAS), combined with follow-up spectroscopy using the MMT multi-object spectrometer HectoSpec. We present optical spectra, supplemented with optical r ',  i ' and H α photometry from IPHAS, and near-infrared J ,  H and K photometry from Two Micron All Sky Survey. The position of the objects in the ( J − H ) versus ( H − K ) diagram strongly suggests most of them are young. Many show Ca  ii infrared triplet emission indicating that they are in a pre-main-sequence phase of evolution of T Tauri and Herbig Ae nature. Among these, we have uncovered pronounced clustering of T Tauri stars roughly a degree south of the centre of Cyg OB2, in an arc close to the H  ii region DR 15, and the radio ring nebula G79.29+0.46, for which we discuss its candidacy as a luminous blue variable. The emission-line objects towards Cyg OB2 itself could be the brightest most prominent component of a population of lower mass pre-main-sequence stars that has yet to be uncovered. Finally, we discuss the nature of the ongoing star formation in Cyg OB2 and the possibility that the central OB stars have triggered star formation in the periphery.  相似文献   

Early-A stars from IPHAS, and their distribution in and around the Cyg OB2 association     

Janet E. Drew  R. Greimel  M. J. Irwin  S. E. Sale 《Monthly notices of the Royal Astronomical Society》2008,386(4):1761-1773

Stellar photometry derived from the INT/WFC Photometric Hα Survey (IPHAS) of the Northern Galactic plane can be used to identify large, reliable samples of A0–A5 stars. For every A-type star, so identified, it is also possible to derive individual reddening and distance estimates, under the assumption that most selected objects are on or near the main sequence, at a mean absolute r ' magnitude of 1.5–1.6. This study presents the method for obtaining such samples and shows that the known reddenings and distances to the open clusters NGC 7510 and NGC 7790 are successfully recovered. A sample of over 1000 A-type stars is then obtained from IPHAS data in the magnitude range  13.5 < r ' < 20  from the region of sky including the massive northern OB association Cyg OB2. An analysis of these data reveals a concentration of ∼200 A stars over an area about a degree across, offset mainly to the south of the known 1–3 Myr old OB stars in Cyg OB2: their dereddened r ' magnitudes fall in the range 11.8–12.5. These are consistent with a ∼7 Myr old stellar population at distance modulus DM = 10.8, or with an age of ∼5 Myr at DM = 11.2. The number of A-type stars found in this clustering alone is consistent with a lower limit to the cluster mass of  ∼10⁴ M_⊙  .  相似文献   

Wicked but worth it: student perspectives on socio‐hydrology          下载免费PDF全文

Morgan C. Levy  Margaret Garcia  Peter Blair  Xi Chen  Sharlene L. Gomes  Drew B. Gower  Johanna Grames  Linda Kuil  Ye Liu  Landon Marston  Paul F. McCord  Mahendran Roobavannan  Ruijie Zeng 《水文研究》2016,30(9):1467-1472

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