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41.
Seasonal monitoring was carried out to investigate the influence of extracellular enzymatic activity (EEA) on metal speciation and organic matter cycling in the rhizosediment of Spartina maritima . Heavy metal speciation was achieved by the Tessier scheme, and showed a similar pattern of variation of the organic-bound fraction, indicating a decomposition process in progress. Both humic acid and organic matter showed the same seasonal pattern. The basal respiration of the rhizosediments also presented a similar seasonal pattern, indicating a microbial degradation of organic matter. The high organic-bound fraction found in the summer gradually decreased towards the winter. This decrease was found to be related to the increase of activity of peroxidase, β- N -acetylglucosaminidase and protease. Also the activity of sulphatase was found to be related to the depletion on the exchangeable fraction, probably due to sulphide formation and consequent mobilization. The results show an interaction between several microbial activities, affecting metal speciation.  相似文献   
42.
Larvae of various coastal fish undergo immigration from spawning grounds towards estuarine nurseries. Several environmental factors can have an important impact on survival at this stage making it crucial for recruitment. Generalized linear models were applied in order to investigate the relation between river drainage, sea surface temperature (SST), NAO index and the North-South wind component intensity, over the two months prior to the estuarine colonization peak, and the densities of Platichthys flesus, Dicentrarchus labrax, Diplodus vulgaris and Diplodus bellottii in the nursery grounds based on a discontinuous historical dataset (from 1978 to 2006), for the Tagus estuary. The relation between SST over the 12 months prior to the estuarine colonization peak and fish densities in the nurseries was also investigated, as it integrates the periods of spawning stock maturation, spawning and larval immigration. While SST over the prior 12 months was negatively correlated with the abundance of P. flesus, it was positively correlated with the abundance of D. bellottii. Abundance of D. vulgaris was positively correlated with SST in the two months prior to the estuarine colonization peak, while the abundance of D. labrax was positively correlated with river drainage. The relations between SST and the abundance of P. flesus, a cold-water species with declining densities, and the subtropical species D. bellottii and D. vulgaris, which are increasing in abundance, are indicative of species abundance alterations related to climate warming. Dicentrarchus labrax will probably also be affected by climate change because of lowered precipitation and consequently river drainage.  相似文献   
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The power of equations predicting seagrass depth limit (Zc) from light extinction (K z) was tested on data on seagrass depth limits collected from the literature. The test data set comprised 424 reports of seagrass colonization depth and water transparency, including data for 10 seagrass species. This data set confirmed the strong negative relationship betweenZ c andK z. The regression equation in Duarte (1991) overestimated the realized seagrass colonization depths at colonization depths < 5 m, while there was no prediction bias above this threshold. These results indicated that seagrass colonizing turbid waters (K z 0.27 m-1) have higher apparent light requirements than those growing in clearer waters. The relationship between seagrass colonization depth and light attenuation shifts at a threshold of light attenuation of 0.27 m-1, requiring separate equations to predictZ c for seagrass growing in more turbid waters and clearer waters, and to set targets for seagrass restoration and conservation efforts.  相似文献   
45.
The gold–tourmaline quartz–vein deposit of Passagem de Mariana, in the southeastern part of the Quadrilátero Ferrífero, produced more than 60 tonne of gold, from the end of the 17th Century until 1954. The mine has not operated since 1985. Orebodies are veins composed of white quartz (> 60 vol.%), carbonate (ankerite), tourmaline, sericite and sulfides. Tourmaline (dravite), up to 10 vol.% of the vein, occurs as subhedral, coarse, commonly zoned crystals, and is concentrated along vein boundaries and on the edges of host rock inclusions in the veins. Tourmaline is present in all rock types in the mine, but the chemical composition of the host rocks determinates the intensity of tourmalinization, with the alteration being greater in sericitic phyllites, graphite–sericite phyllites, and calcareous rocks. The most abundant sulfide is arsenopyrite, which is normally associated with pyrite and pyrrhotite. Minor amounts of chalcopyrite, galena, löllingite, berthierite, and maldonite are present throughout the deposit. Sulfides are concentrated at veins boundary or are dispersed in the veins. Arsenopyrite is associated, most commonly, with calcareous rocks, and graphite–sericite phyllite. Pyrrhotite is usually found at the base of itabirites. Gold abundance is directly proportional to sulfide concentration. Hydrothermal alteration associated with the veins includes silicification, tourmalinization, and sulfidation. The mineralized zone is a shear zone associated with a bedding-parallel thrust fault that juxtaposes the itabirite (Lower Proterozoic Minas Supergroup) over other units. This shear zone/thrust fault extends for tens of km beyond the Passagem mine and hosts numerous gold deposits. The richest orebodies are along the itabirite footwall contact and within the graphite–sericite phyllite (Main orebody). Although many lithologic units were mineralized the graphite–sericite phyllite appears to have been most favorable for gold deposition.The area underwent three phases of deformation, D1, D2 and D3. Mineral assemblages indicate upper-greenschist to lower-amphibolite conditions of regional metamorphism. Retrograde metamorphism, characterized by chloritization of biotite and chloritization and biotitization of garnet, developed locally. The gold-bearing veins crosscut the main foliation and lithologic contacts at low angle and occur within, or are in contact with, all lithotypes. Field and laboratory data indicate that gold mineralization at Passagem de Mariana is epigenetic. Gold deposition occurred after the peak of metamorphism, within the late- to post-D2 period of deformation, which is correlated with second set of structures of Trasamazonian age of Alkmim and Marshak [Alkmim, F.F., Marshak, S., 1998. Transamazonian Orogeny in the Southern São Francisco Craton Region, Minas Gerais, Brazil: evidence for Paleoproterozoic collision and collapse in the Quadrilátero Ferrífero. Precambrian Research 90, 29-58.], indicating that the gold mineralization occurred between 2.124 and 2.04 Ga. We choose to regard Passagem de Marina as an orogenic gold deposit as defined by Groves et al. [Groves, D. I., Goldfarb, R.J., Gebre-Mariam, M., Hagemann, S.G., Robert, F., 1998. Orogenic gold deposits: A proposed classification in the context of their crustal distribution and relationship to other gold deposit types. Ore Geology Reviews 13, 7-27.], i.e., an epigenetic, structurally-hosted lode–gold vein system in a deformed metamorphic terrane.  相似文献   
46.
Concentrations of chloride and sulfate and pH in the hot crater lake (Laguna Caliente) at Poás volcano and in acid rain varied over the period 1993–1997. These parameters are related to changes in lake volume and temperature, and changes in summit seismicity and fumarole activity beneath the active crater. During this period, lake level increased from near zero to its highest level since 1953, lake temperature declined from a maximum value of 70°C to a minimum value of 25°C, and pH of the lake water increased from near zero to 1.8. In May 1993 when the lake was nearly dry, chloride and sulfate concentrations in the lake water reached 85,400 and 91,000 mg l−1, respectively. Minimum concentrations of chloride and sulfate after the lake refilled to its maximum volume were 2630 and 4060 mg l−1, respectively. Between January 1993 and May 1995, most fumarolic activity was focused through the bottom of the lake. After May 1995, fumarolic discharge through the bottom of the lake declined and reappeared outside the lake within the main crater area. The appearance of new fumaroles on the composite pyroclastic cone coincided with a dramatic decrease in type B seismicity after January 1996. Between May 1995 and December 1997, enhanced periods of type A seismicity and episodes of harmonic tremor were associated with an increase in the number of fumaroles and the intensity of degassing on the composite pyroclastic cone adjacent to the crater lake. Increases in summit seismic activity (type A, B and harmonic tremor) and in the height of eruption plumes through the lake bottom are associated with a period of enhanced volcanic activity during April–September 1994. At this time, visual observations and remote fumarole temperature measurements suggest an increase in the flux of heat and gases discharged through the bottom of the crater lake, possibly related to renewed magma ascent beneath the active crater. A similar period of enhanced seismic activity that occurred between August 1995 and January 1996, apparently caused fracturing of sealed fumarole conduits beneath the composite pyroclastic cone allowing the focus of fumarolic degassing to migrate from beneath the lake back to the 1953–1955 cone. Changes in the chemistry of summit acid rain are correlated changes in volcanic activity regardless of whether fumaroles are discharging into the lake or are discharging directly into the atmosphere.  相似文献   
47.
In 1996, after 150 years of relative calm, Turrialba Volcano was reawakening. A visible plume and serious damage to surrounding vegetation due to acid rain are the most obvious signals. As part of the Network for Observation of Volcanic and Atmospheric Change project, four gas-monitoring stations were initially installed on the west flank of the volcano with the purpose of measuring sulphur dioxide emissions during this period of increased activity using the scanning-differential optical absorption spectroscopy technique. We present here the results of semicontinuous gas flux measurements over a period of 5 years (from 2008 to 2012), providing a novel data set that documents a relatively rapid increase in SO2 fluxes from around 350 t day?1 to around 4,000 t day?1 leading up to an eruptive period, followed by a gradual return to the former baseline values. Gas flux data were also compared with seismic data for selected periods of interest, providing insights into the link between degassing and seismicity. The most important result from this comparison is the identification of an inflexion point in the gas emissions followed by a clearly increasing trend in seismic activity, distinguishable 6 months prior to a phreatic eruptive event that occurred on 5 January 2010. This signal can be interpreted as a possible indicator of future eruptive events. Monitoring of SO2 thus complements seismic monitoring as a forecasting tool for eruptive events. Such monitoring is critical considering the proximity of Turrialba to the Central Valley, an area inhabited by more than 50 % of Costa Rica’s population.  相似文献   
48.
Theoretical and Applied Climatology - The climate change endangers many species of the Amazon Forest. An example, in the endangered medicinal species Pilocarpus microphyllus (popularly known as...  相似文献   
49.
The Mediterranean Sea has been identified as one of the hotspots for climate change. Intense warming in the Mediterranean Sea may have strong implications for biological activity and ecosystem functioning. To elucidate the effects of warming on planktonic and benthic metabolism, we performed experiments under different increasing temperature regimes, ranging from three to six different temperatures. The lowest range of temperatures assessed was of 2.6 °C and the maximum was 7.5 °C. Our results suggest that a 6 °C warming of the Mediterranean waters may yield a mean increment in planktonic respiration rates of coastal communities of 24 %, higher than the mean increase expected for planktonic gross primary production (9 %). These results confirm earlier theories, and agree with previous experiments, of a higher increase in respiration rates than in primary production with warming, with the subsequent consequences for the carbon cycle, resulting in a negative feedback to climate warming, as ocean communities will capture less CO2.  相似文献   
50.
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