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481.
Eleonora S. Carol Eduardo E. Kruse Patricia C. Laurencena Adolfo Rojo Marta H. Deluchi 《Environmental Earth Sciences》2012,65(2):421-428
The phreatic aquifer beneath the Pampean plain, in eastern central Argentina, constitutes a relevant source of water supply
in the area. The objective of this work was to assess the significance of the cation exchange processes in the hydrochemical
evolution of this aquifer, based on a study case located in the middle and upper basin of the El Pescado creek. Results indicate
that Ca2+/Na+ exchange is the main process determining the evolution of groundwater from the recharge areas (Ca–HCO3) towards the local discharge areas (Na–HCO3), as well as representing a source of Na+ contribution to the water in the aquifer. This hydrochemical characteristic is central to the identification of local discharge
areas within a plain environment which extends regionally. The ion exchange capacity of these discharge areas has environmental
importance, due to its influence on groundwater quality and potential groundwater uses. These results may be applied to any
aquifer sharing similar hydrogeological characteristics. 相似文献
482.
Nitrate concentrations in multi-aquifer systems are heavily affected by the presence of wellbores (active or abandoned) that
are screened in several aquifers. The spatial variability of hydraulic conductivity in the confining layers has also an important
impact on the concentrations. A synthetic three-dimensional flow and transport exercise was carried in a multi-aquifer system
consisting of two aquifers separated by an aquitard in which 100 vertical wellbores had been drilled. To model the wellbores
and the flow and transport connection between aquifers that they may induce, we assign a high vertical hydraulic conductivity
and a low effective porosity to the cell blocks including the wells. With these parameters, a solute will travel quickly from
one aquifer to the other without being stored in the well itself. The wellbores will act as preferential pathways, and the
solute will move quickly between aquifers according to the hydrodynamic conditions. Not considering these preferential pathways
could induce erroneous interpretations of the solute distribution in an aquifer. We also noted that when there are vertical
wellbores that connect aquifers in a multi-aquifer system, low conductivity in the aquitard enhances the flow of solute through
the wellbores. Time-varying pumping rates induce important fluctuations in nitrate concentrations; therefore, any estimate
of the water quality of the aquifer will depend on the moment when the data has been recorded. Consequently, concentration
maps obtained by interpolation of point samples are seldom a good indicator of the chemical status of groundwater bodies;
alternatively, we recommend complementing the usual interpolated maps with numerical models to gain a true understanding of
the spatial distribution of the solute concentration. 相似文献
483.
484.
Paula C.S. Carvalho Ana M.R. Neiva Maria M.V.G. Silva Eduardo A. Ferreira da Silva 《Chemie der Erde / Geochemistry》2014
Waters from abandoned Sb-Au mining areas have higher Sb (up to 2138 μg L−1), As (up to 1252 μg L−1) and lower Al, Zn, Li, Ni and Co concentrations than those of waters from the As-Au mining area of Banjas, which only contain up to 64 μg L−1 As. In general, Sb occurs mainly as SbO3− and As H2AsO4−. In general, waters from old Sb-Au mining areas are contaminated in Sb, As, Al, Fe, Cd, Mn, Ni and NO2−, whereas those from the abandoned As-Au mining area are contaminated in Al, Fe, Mn, Ni, Cd and rarely in NO2−. Waters from the latter area, immediately downstream of mine dumps are also contaminated in As. In stream sediments from Sb-Au and As-Au mining areas, Sb (up to 5488 mg kg−1) and As (up to 235 mg kg−1) show a similar behaviour and are mainly associated with the residual fraction. In most stream sediments, the As and Sb are not associated with the oxidizable fraction, while Fe is associated with organic matter, indicating that sulphides (mainly arsenopyrite and pyrite) and sulphosalts containing those metalloids and metal are weathered. Arsenic and Sb are mainly associated with clay minerals (chlorite and mica; vermiculite in stream sediments from old Sb-Au mining areas) and probably also with insoluble Sb phases of stream sediments. In the most contaminated stream sediments, metalloids are also associated with Fe phases (hematite and goethite, and also lepidocrocite in stream sediments from Banjas). Moreover, the most contaminated stream sediments correspond to the most contaminated waters, reflecting the limited capacity of stream sediments to retain metals and metalloids. 相似文献
485.
486.
David Völker Jacob Geersen Eduardo Contreras-Reyes Javier Sellanes Silvio Pantoja Wolfgang Rabbel Martin Thorwart Christian Reichert Martin Block Wilhelm Reimer Weinrebe 《International Journal of Earth Sciences》2014,103(7):1765-1787
The continental shelf and slope of southern Central Chile have been subject to a number of international as well as Chilean research campaigns over the last 30 years. This work summarizes the geologic setting of the southern Central Chilean Continental shelf (33°S–43°S) using recently published geophysical, seismological, sedimentological and bio-geochemical data. Additionally, unpublished data such as reflection seismic profiles, swath bathymetry and observations on biota that allow further insights into the evolution of this continental platform are integrated. The outcome is an overview of the current knowledge about the geology of the southern Central Chilean shelf and upper slope. We observe both patches of reduced as well as high recent sedimentation on the shelf and upper slope, due to local redistribution of fluvial input, mainly governed by bottom currents and submarine canyons and highly productive upwelling zones. Shelf basins show highly variable thickness of Oligocene-Quaternary sedimentary units that are dissected by the marine continuations of upper plate faults known from land. Seismic velocity studies indicate that a paleo-accretionary complex that is sandwiched between the present, relatively small active accretionary prism and the continental crust forms the bulk of the continental margin of southern Central Chile. 相似文献
487.
Jos I Saiz Nuria Anadn Javier Cristobo Oscar Garca-Alvarez Gerardo Garca-Castrillo Eduardo Lpez Cruz Palacn Jess S Troncoso Ana Ramos 《海洋学报(英文版)》2013,32(6):47-55
Insular marine biotas are often richer in faunal diversity than those from the open sea in the same geographical region. The existence of particular island effects were tested under polar conditions by comparing infaunal benthic assemblages on Peter I Island with those of similar latitudes in the open ocean at the Bellingshausen Sea and also from the coast of the Antarctic Peninsula. Sampling was carried out aboard the R/V Hespérides during the expedition named BENTART-2003 from 24 January to 3 March 2003. Benthic samples were collected at 18 stations ranging from 90 to 2 044 m depth, using an USNEL-type box corer (BC) dredge. Representatives of 32 higher taxa of invertebrates were found. Univariate and multivariate analyses revealed various patterns in the data. First, significant differences in polychaete abundance were detected between the stations located in the open sea and the remaining sites (island plus mainland sites). Bivalve abundances were also distinct between island and mainland sampling sites. Sediment columns taken from the island seafloor exhibited the highest rate of bioturbation by the infauna. These findings confirm the model that islands develop distinct assemblages characterized by the enhancement of the benthic communities even in cold waters. Several abiotic factors were measured simultaneously at the seafloor and along the water column to investigate faunal distribution patterns. Significant correlations were found between the benthic assemblages and a combination of two environmental variables: "island effect" (measured as a categorical variable) and the redox state of sediments. Richer and more complex benthic assemblages were found in Peter I Island’s sea bottom, whereas the more depauperate bottoms remained in the open sea. 相似文献
488.
Ricardo Arevalo Jr Jeremy Bellucci William F. McDonough 《Geostandards and Geoanalytical Research》2010,34(4):327-341
Recent developments from 2008 to 2009 in ICP-MS engineering, methods and applications are reviewed here. Of particular emphasis are advances in: (a) maximising sensitivity and reducing elemental/isotopic fractionation during laser ablation processing; (b) developing new analytical techniques to measure major, minor and trace element abundances without depending on matrix-matched calibrating materials, pre-determined internal standard concentrations and/or multiple analytical methods; (c) applying in situ and solution-based ICP-MS techniques to the analysis of forensic materials for criminal and/or nuclear investigations; and (d) improving precision and limits of detection of laser ablation multi-collector ICP-MS measurements of (ultra) trace elemental and isotopic abundances. 相似文献
489.
Eleonora S. Carol Eduardo Emilio Kruse Jorge L. Pousa 《Environmental Earth Sciences》2010,60(4):749-756
Although not well known, the eco-hydrological functions of deep aquifers (those having no contact with surface hydrological
events) play an important role in the hydrological regime because they can affect the type of habitats, the availability of
water and nutrients and the salinity of the medium, among other environmental features. This work aims at characterizing the
deep Tertiary hydrogeological units of the Salado sedimentary basin in the Province of Buenos Aires, Argentina, at a regional
scale, and to determine their environmental importance in the hydrological cycle. The geological characterization of the study
area is based on the drilling profiles from oil exploration wells bored by different oil companies between 1948 and 1994,
and also from the existing literature. The conclusion is that water exchange between quaternary surface aquifers in contact
with atmospheric events and deep tertiary aquifers is one of the main processes that keep the hydrologic balance of the region.
Not only is this crucial for the conservation of the numerous and well-developed ecosystems in the basin wetlands, but also
significant for the agricultural and cattle-raising activities of the region. 相似文献
490.