Thermoelastic properties of chromium oxide Cr<Subscript>2</Subscript>O<Subscript>3</Subscript> (eskolaite) at high pressures and temperatures     

Anna M. Dymshits  Peter I. Dorogokupets  Igor S. Sharygin  Konstantin D. Litasov  Anton Shatskiy  Sergey V. Rashchenko  Eiji Ohtani  Akio Suzuki  Yuji Higo 《Physics and Chemistry of Minerals》2016,43(6):447-458

A new synchrotron X-ray diffraction study of chromium oxide Cr₂O₃ (eskolaite) with the corundum-type structure has been carried out in a Kawai-type multi-anvil apparatus to pressure of 15 GPa and temperatures of 1873 K. Fitting the Birch–Murnaghan equation of state (EoS) with the present data up to 15 GPa yielded: bulk modulus (K _0,T0), 206 ± 4 GPa; its pressure derivative K′_0,T , 4.4 ± 0.8; (?K _0,T /?T) = ?0.037 ± 0.006 GPa K^?1; a = 2.98 ± 0.14 × 10^?5 K^?1 and b = 0.47 ± 0.28 × 10^?8 K^?2, where α _0,T  = a + bT is the volumetric thermal expansion coefficient. The thermal expansion of Cr₂O₃ was additionally measured at the high-temperature powder diffraction experiment at ambient pressure and α _0,T0 was determined to be 2.95 × 10^?5 K^?1. The results indicate that coefficient of the thermal expansion calculated from the EoS appeared to be high-precision because it is consistent with the data obtained at 1 atm. However, our results contradict α ₀ value suggested by Rigby et al. (Brit Ceram Trans J 45:137–148, 1946) widely used in many physical and geological databases. Fitting the Mie–Grüneisen–Debye EoS with the present ambient and high-pressure data yielded the following parameters: K _0,T0 = 205 ± 3 GPa, K′_0,T  = 4.0, Grüneisen parameter (γ ₀) = 1.42 ± 0.80, q = 1.82 ± 0.56. The thermoelastic parameters indicate that Cr₂O₃ undergoes near isotropic compression at room and high temperatures up to 15 GPa. Cr₂O₃ is shown to be stable in this pressure range and adopts the corundum-type structure. Using obtained thermoelastic parameters, we calculated the reaction boundary of knorringite formation from enstatite and eskolaite. The Clapeyron slope (with \({\text{d}}P/{\text{d}}T = - 0.014\) GPa/K) was found to be consistent with experimental data.  相似文献   

Observations of some oxygen-containing and sulfur-containing organic molecules in cold dark clouds     

Irvine WM  Friberg P  Kaifu N  Kawaguchi K  Kitamura Y  Matthews HE  Minh Y  Saito S  Ukita N  Yamamoto S 《The Astrophysical journal》1989,342(2):871-875

Observations of nine oxygen- and sulfur-containing organic molecules have been made toward the cold dark clouds TMC-1 and L134N. We have confirmed the presence of para-ketene (H2C2O) in TMC-1, have for the first time observed ortho-ketene, and find a total ketene column density approximately 1 x 10(13) cm-2. Thioformaldehyde (H2CS) is easily detectable in both TMC-1 and L134N, with a column density about 5 times larger in the former source (approximately 3 x 10(13) cm-2). The fractional abundance of ketene is comparable to the predictions of ion-molecule chemistry, while that of thioformaldehyde in TMC-1 is one to two orders of magnitude greater than that expected from such models at steady state. Interstellar sulfur chemistry thus continues to be poorly understood. We set upper limits for the column densities of formic acid (HCOOH), vinyl alcohol (CH2CHOH), methyl formate (HCO2CH3), formamide (NH2CHO), methyl mercaptan (CH3SH), isothiocyanic acid (HNCS), and thioketene (H2C2S) in both sources.  相似文献   

Effects of mass sedimentation events after the 2011 off the Pacific coast of Tohoku Earthquake on benthic prokaryotes and meiofauna inhabiting the upper bathyal sediments     

Hidetaka Nomaki  Tomohiro Mochizuki  Tomo Kitahashi  Takuro Nunoura  Kazuno Arai  Takashi Toyofuku  Gengo Tanaka  Shuichi Shigeno  Eiji Tasumi  Katsunori Fujikura  Shuichi Watanabe 《Journal of Oceanography》2016,72(1):113-128

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Decreasing precipitation extremes at higher temperatures in tropical regions     

Eduardo Eiji Maeda  Nobuyuki Utsumi  Taikan Oki 《Natural Hazards》2012,64(1):935-941

It has been often accepted that rising troposphere temperatures will lead to higher precipitation intensities. This argument is based on the Clausius?CClapeyron (C?CC) relation, which indicates an increase in atmospheric moisture storage capacity of approximately 7?% K^?1. However, recent studies carried out in mid-latitude regions indicate that changes in precipitation intensity as a function of temperature do not necessarily follow the C?CC relation. This study aimed to evaluate the correlation between precipitation extremes and temperature in tropical regions, using measured data obtained at low latitude ranges over Brazil. The results indicate that, at daily timescale, the C?CC relation alone is unlikely to explain the relation between precipitation extremes and temperatures in tropical regions. Additional aspects, such as moisture availability and the duration of precipitation events, should be further analyzed to allow a comprehensive understanding of the relationship between temperature and precipitation intensity. Moreover, we show that in tropical regions, higher temperatures may reduce the magnitude of extreme precipitation events at daily timescales, independent of the season of the year.  相似文献   

The high-pressure phase relation of the MgSO₄-H₂O system and its implication for the internal structure of Ganymede     

Ryo Nakamura  Eiji Ohtani 《Icarus》2011,211(1):648-654

We have determined the phase relation of the MgSO₄-H₂O binary system using an externally heated diamond anvil cell in the compositional range of 0-30 wt.% MgSO₄, and under temperature and pressure conditions from 298 to 500 K and up to 4.5 GPa. Using our experimental results, we were able to estimate the composition of the ice mantle of the large icy satellites of Jupiter, such as Ganymede.In our experiments, we identified the following phases in the MgSO₄-H₂O system up to 4 GPa at 298 K: Ices VI and VII, magnesium heptahydrate, MgSO₄·7H₂O, and a liquid phase. The present phase relations suggest that there may be a deep internal ocean down to a depth about 800 km in the interior of Ganymede.  相似文献   

Microstructural records of multiple retrograde local H2O supplement in the pelitic gneiss,Lützow-Holm Complex at Akarui Point,East Antarctica     

Aya Nakamura  Masao Kitamura  Tetsuo Kawakami 《Mineralogy and Petrology》2014,108(2):177-186

The alkali-feldspar and biotite in the sillimanite-biotite-garnet gneiss from East Antarctica preserves characteristic microstructural evidence of multi-stage H₂O supplement during the retrograde metamorphism. The first microstructural evidence is the “zoned feldspar,” in which the mesoperthitic zone, the anti-perthitic zone, and lamella-free plagioclase zone coexist within a single crystal. They are occasionally found next to biotite, and are always depleted in orthoclase (Or) component toward the biotite. The formation process of this microstructure could be explained by the diffusion that oversteps the solvus. The second microstructural evidence is the serrate boundary between alkali-feldspar and biotite. The projections of biotite are selectively developed next to Or lamellae of alkali-feldspar every 3–5 μm. These two microstructures would have formed as the biotite grew by consuming potash in alkali-feldspar when H₂O-bearing fluid locally passed through the grain boundaries. The former microstructure was formed at 825–900 °C before lamella formation, and the latter microstructure was formed after the lamella formation. These microstructures are the indicators of fluid pathways formed under two different temperature conditions. The common coexistence of these microstructures implies that the fluid used similar pathways during the retrograde metamorphism.  相似文献   

Pc3-4 geomagnetic pulsations at very low latitude in Brazil     

Ademilson Zanandrea  J.M. Da Costa  S.L.G. Dutra  T. Kitamura  H. Tachihara  O. Saotome 《Planetary and Space Science》2004,52(13):1209-1215

In order to investigate Pc3-4 geomagnetic pulsations at very low and equatorial latitudes, L=1.0 to 1.2, we analyzed simultaneous geomagnetic data from Brazilian stations for 26 days during October-November 1994. The multitaper spectral method based on Fourier transform and singular value decomposition was used to obtain pulsation power spectra, polarization parameters and phase. Eighty-one (81) simultaneous highly polarized Pc3-4 events occurring mainly during daytime were selected for the study. The diurnal events showed enhancement in the polarized power density of about 3.2 times for pulsations observed at stations close to the magnetic equator in comparison to the more distant ones. The phase of pulsation observed at stations near the magnetic equator showed a delay of 48-62° in relation to the most distant one. The peculiarities shown by these Pc3-4 pulsations close to the dip equator are attributed to the increase of the ionospheric conductivity and the intensification of the equatorial electrojet during daytime that regulates the propagation of compressional waves generated in the foreshock region and transmitted to the magnetosphere and ionosphere at low latitudes. The source mechanism of these compressional Pc3-4 modes may be the compressional global mode or the trapped fast mode in the plasmasphere driving forced field line oscillations at very low and equatorial latitudes.  相似文献   

Song Hong (Red River) delta evolution related to millennium-scale Holocene sea-level changes   总被引：2，自引：0，他引：2  

Susumu Tanabe  Kazuaki Hori  Yoshiki Saito  Shigeko Haruyama  Van Phai Vu  Akihisa Kitamura 《Quaternary Science Reviews》2003,22(21-22):2345-2361

The Song Hong (Red River) delta occurs on the northwest coast of the South China Sea. Its evolution in response to Holocene sea-level changes was clarified on the basis of sedimentary facies and 14 radiocarbon dates from the 40 m long Duy Tien core from the delta plain, and using previously reported geological, geomorphological, and archaeological data. The delta prograded into the drowned valley as a result of early Holocene inundation from 9 to 6 cal. kyr BP, as sea-level rise decelerated. The sea-level highstand at +2–3 m from 6 to 4 cal. kyr BP allowed widespread mangrove development on the delta plain and the formation of marine notches in the Ha Long Bay and Ninh Binh areas. During sea-level lowering after 4 cal. kyr BP, the former delta plain emerged as a marine terrace, and the delta changed into the present tide- and wave-influenced delta with accompanying beach ridges. Delta morphology, depositional pattern, and sedimentary facies are closely related to Holocene sea-level changes. In particular, falling sea level at 4 cal. kyr BP had a major impact on the evolution of the Song Hong delta, and is considered to be linked to climate changes.  相似文献   

Heavy oil exposure induces high moralities in virus carrier Japanese flounder Paralichthys olivaceus     

Song JY  Nakayama K  Murakami Y  Kitamura S 《Marine pollution bulletin》2011,63(5-12):362-365

The relationship between chemical exposure and disease outbreak in fish has not been fully defined due to the limitations of experimental systems (model fish and pathogens). Therefore, we constructed a system using the Japanese flounder, Paralichthys olivaceus, and viral haemorrhagic septicemia virus (VHSV), and evaluated it by heavy oil (HO) exposure. The fish were exposed to HO at 0.3, 0.03, 0.003, and 0 g/L following VHSV infection at doses of 10(2.5) or 10(3.5) tissue culture infectious dose (TCID)50/fish. As a result, groups given the dual stressors showed more than 90% mortality. Although VHSV infection at 10(2.5) and 10(3.5) TCID50/fish without HO exposure also induced high mortality, at 68.8% and 81.3%, respectively, HO exposure induced faster and higher mortality in the virus carrier fish, indicating that chemical stressors raise the risk of disease outbreak in fish. The experimental system established in this study could be useful for chemical risk assessment.  相似文献   

Density measurements of liquid Fe–Si alloys at high pressure using the sink–float method     

Ryuji Tateyama  Eiji Ohtani  Hidenori Terasaki  Keisuke Nishida  Yuki Shibazaki  Akio Suzuki  Takumi Kikegawa 《Physics and Chemistry of Minerals》2011,38(10):801-807

The compositional dependence on the density of liquid Fe alloys under high pressure is important for estimating the amount of light elements in the Earth’s outer core. Here, we report on the density of liquid Fe–Si at 4 GPa and 1,923 K measured using the sink–float method and our investigation on the effect of the Si content on the density of the liquid. Our experiments show that the density of liquid Fe–Si decreases from 7.43 to 2.71 g/cm³ non-linearly with increasing Si content (0–100 at%). The molar volume of liquid Fe–Si calculated from the measured density gradually decreases in the compositional range 0–50 at% Si, and increases in the range 50–100 at% Si. It should be noted that the estimated molar volume of the alloys shows a negative volume of mixing between Fe and Si. This behaviour is similar to Fe–S liquid (Nishida et al. in Phys Chem Miner 35:417–423, 2008). However, the excess molar volume of mixing for the liquid Fe–Si is smaller than that of liquid Fe–S. The light element contents in the outer core estimated previously may be an underestimation if we take into account the possible negative value of the excess mixing volume of iron–light element alloys in the outer core.  相似文献