Polyatomic Interferences Produced by Macroelements During Direct Multi-Elemental ICP-MS Hydrochemical Analysis     

Vladimir N. Epov  Dominic Lariviere  Ekaterina N. Epova  R. Douglas Evans 《Geostandards and Geoanalytical Research》2004,28(2):213-224

An experimental study of the interferences produced by macroelements (Na, K, Ca, Mg, Sr, S, Cl, Si, N and C) contained in natural waters during inductively coupled plasma-mass spectrometry (ICP-MS) is presented. The most significant interferences created by these elements were found to be SO, CO, CAr, SiH, SiO, NaH, NaAr, MgAr, CaO, KO and KAr, the magnitude of which was dependant on the concentration of each macroelement. To reduce these interferences, different approaches, for example, desolvating nebulisation, high resolution and dynamic reaction cell ICP-MS were applied and compared. All three approaches were found to be useful tools for significantly reducing various polyatomic interferences. Advantages and disadvantages for each approach are discussed.  相似文献   

Field Survey and Geological Effects of the 15 November 2006 Kuril Tsunami in the Middle Kuril Islands     

Breanyn T. MacInnes  Tatiana K. Pinegina  Joanne Bourgeois  Nadezhda G. Razhigaeva  Victor M. Kaistrenko  Ekaterina A. Kravchunovskaya 《Pure and Applied Geophysics》2009,166(1-2):9-36

The near-field expression of the tsunami produced by the 15 November 2006 Kuril earthquake (M_w 8.1–8.4) in the middle Kuril Islands, Russia, including runup of up to 20 m, remained unknown until we conducted a post-tsunami survey in the summer of 2007. Because the earthquake occurred between summer field expeditions in 2006 and 2007, we have observations, topographic profiles, and photographs from three months before and nine months after the tsunami. We thoroughly surveyed portions of the islands of Simushir and Matua, and also did surveys on parts of Ketoi, Yankicha, Ryponkicha, and Rasshua. Tsunami runup in the near-field of the middle Kuril Islands, over a distance of about 200 km, averaged 10 m over 130 locations surveyed and was typically between 5 and 15 m. Local topography strongly affected inundation and somewhat affected runup. Higher runup generally occurred along steep, protruding headlands, whereas longer inundation distances occurred on lower, flatter coastal plains. Sediment transport was ubiquitous where sediment was available—deposit grain size was typically sand, but ranged from mud to large boulders. Wherever there were sandy beaches, a more or less continuous sand sheet was present on the coastal plain. Erosion was extensive, often more extensive than deposition in both space and volume, especially in areas with runup of more than 10 m. The tsunami eroded the beach landward, stripped vegetation, created scours and trim lines, cut through ridges, and plucked rocks out of the coastal plain.  相似文献   

Cyclonic circulation and upwelling in Lake Baikal   总被引：1，自引：0，他引：1  

Elena Troitskaya  Vadim Blinov  Vyacheslav Ivanov  Andrey Zhdanov  Ruslan Gnatovsky  Ekaterina Sutyrina  Mikhail Shimaraev 《Aquatic Sciences - Research Across Boundaries》2015,77(2):171-182

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Atmospheric boundary layer over steep surface waves     

Yuliya Troitskaya  Daniil A. Sergeev  Oleg Druzhinin  Alexander A. Kandaurov  Olga S. Ermakova  Ekaterina V. Ezhova  Igor Esau  Sergej Zilitinkevich 《Ocean Dynamics》2014,64(8):1153-1161

Turbulent air-sea interactions coupled with the surface wave dynamics remain a challenging problem. The needs to include this kind of interaction into the coupled environmental, weather and climate models motivate the development of a simplified approximation of the complex and strongly nonlinear interaction processes. This study proposes a quasi-linear model of wind-wave coupling. It formulates the approach and derives the model equations. The model is verified through a set of laboratory (direct measurements of an airflow by the particle image velocimetry (PIV) technique) and numerical (a direct numerical simulation (DNS) technique) experiments. The experiments support the central model assumption that the flow velocity field averaged over an ensemble of turbulent fluctuations is smooth and does not demonstrate flow separation from the crests of the waves. The proposed quasi-linear model correctly recovers the measured characteristics of the turbulent boundary layer over the waved water surface.  相似文献   

Structure and modeling of disorder in miserite from the Murun (Russia) and Dara-i-Pioz (Tajikistan) massifs     

Ekaterina Kaneva  Maria Lacalamita  Ernesto Mesto  Emanuela Schingaro  Fernando Scordari  Nikolay Vladykin 《Physics and Chemistry of Minerals》2014,41(1):49-63

The structure, structural disorder and chemistry of miserite from the charoite-bearing rocks of the Murun massif (Russia) and from alkaline-syenite pegmatitic rocks of the Dara-i-Pioz massif (Tajikistan) were investigated employing a combination of electron microprobe, single crystal diffraction and micro-Fourier transform infrared spectroscopy analysis. Chemical analysis of the sample investigated by X-ray diffraction evidenced that Dara-i-Pioz miserite has a greater REE concentration than Murun miserite (~0.22 vs. 0.05 apfu, respectively) and also contains Y (0.14 apfu), which is absent in Murun miserite. The occurrence of a band at about 1,600 cm^?1 testified to the presence of H₂O in miserite at hand. Structural analyses yielded average cell parameters of a = 10.092, b = 16.016, c = 7.356 Å, α = 96.60°, β = 111.27° and γ = 76.34°. Anisotropic structural refinement in space group P $\bar{1}$ converged at similar values for the analyzed samples (R ~3.4, R _w ~3.8 %). An interesting feature shown by both the miserite specimen is the presence, revealed by difference Fourier analysis, of a disordered part of the structure. This turned out to be due to the flipping of the tetrahedra belonging to the isolated [Si₂O₇]^6? diorthogroups, one of the two radicals (the other is [Si₁₂O₃₀]^12?) characterizing the miserite structure. The sixfold and seven-vertex Ca polyhedra linked to the inverted diorthogroups show variation in coordination number with respect to those of the ordered structure.  相似文献   

Assessing the extent of induced leakage to an urban aquifer using environmental tracers: an example from Bishkek, capital of Kyrgyzstan, Central Asia   总被引：2，自引：1，他引：1  

Brian L. Morris  W. George Darling  Daren C. Gooddy  Rafael G. Litvak  Ilka Neumann  Ekaterina J. Nemaltseva  Inna Poddubnaia 《Hydrogeology Journal》2006,14(1-2):225-243

A groundwater residence time study of the deep fluvioglacial aquifer supplying Bishkek, capital of Kyrgyzstan, has found evidence of deep infiltration of recent recharge both in the main periurban wellfield and below the city. Commonly-employed hydrochemical markers detected urban influence in the city-centre to depths of 65–100 m, but gave no indication of the important role of induced river/canal bed leakage, either upgradient in the periurban wellfield or within the city. This was revealed by O and H stable isotope measurements, which showed that local rainfall/snowfall play little part in the aquifer water balance. More remarkably, the universal detection of CFCs and SF₆, including in boreholes with 140–220 m deep upper screens, demonstrated that induced leakage of water just a few decades old had penetrated much deeper into the aquifer system than other hydrochemical markers indicated. A two-dimensional flow model set up to test whether such deep pumping-induced leakage could occur below the periurban wellfield confirmed its feasibility. The results imply vertical infiltration rates of 5–10 m/year and demonstrate that in this not-uncommon intergranular aquifer setting, deep boreholes with deep screen settings do not necessarily abstract old water. Hence, there are major implications for urban groundwater management and protection in such settings.

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Resumen Un estudio sobre el tiempo de residencia del agua subterránea, en un acuífero fluvioglacial profundo que abastece a Bishkek, capital de Kyrgyzstan, ha encontrado evidencias de infiltración profunda a partir de recarga reciente, tanto en el campo de pozos de las afueras de la ciudad, como también por debajo de la ciudad. Los indicadores hidroquímicos comúnmente usados, detectaron influencia urbana en el centro de la ciudad hasta profundidades de 65–100 m, pero no dieron indicación del papel importante del goteo inducido en el lecho del canal/río, tanto aguas arriba en el campo de pozos de los suburbios, como también dentro de la ciudad. Esto se reveló mediante mediciones de isótopos estables de O y H, las cuales mostraron que las precipitaciones/nevadas de tipo local, tienen una pequeña contribución en el balance de agua del acuífero. De manera más notoria, la detección universal de CFCs y SF6, incluidos en las rejillas superiores de pozos profundos con 140–220 m de profundidad, demostraron que un goteo inducido de agua, de solo unas pocas décadas de antigüedad, ha penetrado mucho más profundo dentro del sistema acuífero, de lo que los otros marcadores hidroquímicos indicaban. Un modelo bidimensional de flujo, realizado para probar si el goteo inducido—bombeo profundo podía suceder debajo del campo de pozos suburbano, confirmó su factibilidad. Los resultados implican tasas de infiltración vertical de 5 a 10 m/año, y demuestran que los pozos profundos con tramos de rejilla también profundos, no necesariamente extraen aguas antiguas, en estos ambientes acuíferos con porosidad intergranular. Por lo tanto, hay implicaciones importantes para la gestión y protección en zonas urbanas, y para esos ambientes de las aguas subterráneas.

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Résumé Lanalyse du temps de résidence des eaux souterraines dans un aquifère fluvial profond, dorigine glaciaire, qui alimente en eau Bishek, la capitale de Kyrgyzstan a mis en évidence une recharge récente tant dans le captage en eau que sous la ville même. Les traceurs chimiques ont indiqué linfluence urbaine dans le centre de la ville, à une profondeur de 65–100 m, mais ils nont pas mis en évidence le rôle important de lalimentation induite par la couche du fleuve, tant en amont, dans le captage que en aval, dans la ville. Ces effets ont été relevés par des isotopes stables, comme O et h qui ont montré linfluence récente des précipitations dans le bilan hydrique de laquifère. De plus, la détection universelle de CFC et de SF6, y compris dans les forages ayant une profondeur de 140–220 m, montre que lalimentation en eau induite de plusieurs décennies a pénétré à des profondeurs plus grandes que celles indiqués par des traceurs chimiques. Les possibilités dune drainance verticale induite par les pompages dans le puits profonds du captage ont été vérifiées par un modèle bidimensionnel découlement. Les résultats de la modélisation ont conduit à une infiltration verticale de 5–10 m/an et ont démontré aussi que leau extraite par des puits profonds dans un aquifère granulaire nest pas nécessairement dage ancienne. Il sagit donc des implications majeures concernant la gestion et la protection des captages urbaines en eaux souterraines

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A simple method to model the reduced environment of lake bottom sapropel formation     

Gaskova  Olga L.  Strakhovenko  Vera D.  Ermolaeva  Nadezhda I.  Zarubina  Eugene Yu.  Ovdina  Ekaterina A. 《中国海洋湖沼学报》2017,35(4):956-966

The Kambala and Barchin brackish lakes(Baraba steppe,southern West Siberia) contain an organic-rich sapropel layer that was formed in oxygen-depleted waters.We measured the bulk sediment elemental composition,the water chemistry and determined the mineralogical composition and predominant biota species(Diatoms and Cyanobacteria in phytoplankton community respectively) in the lakes.The result indicates that the first lake has a siliceous type of sapropel and the second a carbonaceous one.A computer thermodynamic model was developed for chemical interaction in water-bottom sediment systems of the Kambala and Barchin Lakes.The surface sodium bicarbonate waters are supersaturated with respect to calcite,magnesite(or low Mg-calcite),quartz and chlorite with minor strontianite,apatite and goethite(pH8.9-9.3,Eh 0.3 V).Nevertheless,it is shown that during sapropel deposition,deep silt waters should be anoxic(Eh0 V).The virtual component CH_2O has been used to create an anoxic environment suitable for pyrite formation due to the biotic community impact and abiotic reduction.Thermodynamic calculation has shown that silt water is not necessarily euxinic(anoxic and sulfidic).Depending on Eh,sulfate sulfur can dominate in solution,causing the formation of gypsum together with pyrite.An attempt was made to find a reason for solution supersaturation with respect to Ca and Mg ions due to their complexation with humic acids.  相似文献   

Surface manifestations of internal waves investigated by a subsurface buoyant jet: Part 2. Internal wave field     

V. G. Bondur  Yu. V. Grebenyuk  E. V. Ezhova  V. I. Kazakov  D. A. Sergeev  I. A. Soustova  Yu. I. Troitskaya 《Izvestiya Atmospheric and Oceanic Physics》2010,46(3):347-359

In a large test reservoir with artificial temperature stratification at the Institute of Applied Physics, Russian Academy of Sciences, a major simulation of internal wave actuation by buoyant turbulent jets generated by wastewater flows from underwater collector diffusers in conditions of temperature stratification with deep and shallow thermocline has been performed. Using a modification of the particle tracing velocimetry (PTV) method in the stratification mode with shallow thermocline, the velocities of currents generated by internal waves at the surface of the water area are measured. A theoretical model is developed describing the fields of internal waves in the presence of jet stream. Dispersion relations and structures of lower (first and second) modes of internal waves in the stratified basin for different rates of liquid outflow from the collector model are obtained. The experimentally measured field of isothermal shifts with respect to the system of characteristic modes of internal waves is decomposed. A mixed regime of internal wave actuation with the simultaneous existence of the first and second modes is observed. The characteristics of perturbations in the liquid column and on its surface are compared. This analysis allows us to prove that the velocity fields on the surface are indeed surface manifestations of internal waves.  相似文献   

‘Holocene history of the eastern side of Novaya Zemlya from glaciomarine sediment records in the Tsivol’ki Fjord’: Comments     

Ekaterina Taldenkova 《Boreas: An International Journal of Quaternary Research》2023,52(1):139-144

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