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31.
Environmental chemicals may modulate the endocrine system through interaction with plasma sex steroid-binding proteins (SBP) and SBP-regulated processes. Some of these chemicals, which are known to interact with the estrogen receptor (ER), were found to bind competitively to the Atlantic salmon (Salmo salar) SBP and potentially disrupt the endocrine function of these proteins. Furthermore, both weakly acting (di-n-butyl phthalate) and potent estrogen mimics (ethynylestradiol), were able to induce a substantial up-regulation of circulating levels of SBP in vivo. Interestingly, modulation of SBP-levels was found to be a more sensitive endpoint than chemically induced interference with classical ER-mediated mechanisms for weakly acting estrogen mimics like di-(n-butyl) phthalate. Interference with the endocrine function of SBPs may thus introduce a novel mechanism for endocrine disruption. and give additional answers to the question why some weakly acting xenoestrogens are causing "estrogen-like" reproductive disturbances in developing males. 相似文献
32.
E.?RantaEmail author G.?Stockmann T.?Wagner T.?Fusswinkel E.?Sturkell E.?Tollefsen A.?Skelton 《Contributions to Mineralogy and Petrology》2018,173(10):78
Petrogenetic studies of carbonatites are challenging, because carbonatite mineral assemblages and mineral chemistry typically reflect both variable pressure–temperature conditions during crystallization and fluid–rock interaction caused by magmatic–hydrothermal fluids. However, this complexity results in recognizable alteration textures and trace-element signatures in the mineral archive that can be used to reconstruct the magmatic evolution and fluid–rock interaction history of carbonatites. We present new LA–ICP–MS trace-element data for magnetite, calcite, siderite, and ankerite–dolomite–kutnohorite from the iron-rich carbonatites of the 1.3 Ga Grønnedal–Íka alkaline complex, Southwest Greenland. We use these data, in combination with detailed cathodoluminescence imaging, to identify magmatic and secondary geochemical fingerprints preserved in these minerals. The chemical and textural gradients show that a 55 m-thick basaltic dike that crosscuts the carbonatite intrusion has acted as the pathway for hydrothermal fluids enriched in F and CO2, which have caused mobilization of the LREEs, Nb, Ta, Ba, Sr, Mn, and P. These fluids reacted with and altered the composition of the surrounding carbonatites up to a distance of 40 m from the dike contact and caused formation of magnetite through oxidation of siderite. Our results can be used for discrimination between primary magmatic minerals and later alteration-related assemblages in carbonatites in general, which can lead to a better understanding of how these rare rocks are formed. Our data provide evidence that siderite-bearing ferrocarbonatites can form during late stages of calciocarbonatitic magma evolution. 相似文献
33.
The flow of dense water in a V-shaped laboratory-scale canyon is investigated by using a non-hydrostatic numerical ocean model with focus on the effects of rotation. By using a high-resolution model, a more detailed analysis of plumes investigated in the laboratory (Deep-Sea Res I 55:1021–1034 2008) for laminar flow is facilitated. The inflow rates are also increased to investigate plume structure for higher Reynolds numbers. With rotation, the plumes will lean to the side of the canyon, and there will be cross-canyon geostrophic currents and Ekman transports. In the present study, it is found that the cross-canyon velocities are approximately 5 % of the down-canyon velocities over the main body of the plume for the rotational case. With rotation, the flow of dense water through the body of the plume and into the plume head is reduced. The plume head becomes less developed, and the speed of advance of the head is reduced. Fluid parcels near the top of the plume will to a larger extent be left behind the faster flowing dense core of the plume in a rotating system. Near the top of the plume, the cross-canyon velocities change direction. Inside the plume, the cross-flow is up the side of the canyon, and above the interface to the ambient there is a compensating cross-flow down the side of the canyon. This means that parcels of fluid around the interface become separated. Parcels of fluid around the interface with small down-canyon velocity components and relative large cross-canyon components will follow a long helix-like path down the canyon. It is found that the entrainment coefficients often are larger in the rotational experiments than in corresponding experiments without rotation. The effects of rotation and higher inflow rates on the areal patterns of entrainment velocities are demonstrated. In particular, there are bands of higher entrainment velocities along the lateral edges of the plumes in the rotational cases. 相似文献
34.
Binyam L. Alemu Per Aagaard Ingrid Anne Munz Elin Skurtveit 《Applied Geochemistry》2011,26(12):1975-1989
Crushed rock from two caprock samples, a carbonate-rich shale and a clay-rich shale, were reacted with a mixture of brine and supercritical CO2 (CO2–brine) in a laboratory batch reactor, at different temperature and pressure conditions. The samples were cored from a proposed underground CO2 storage site near the town of Longyearbyen in Svalbard. The reacting fluid was a mixture of 1 M NaCl solution and CO2 (110 bar) and the water/rock ratio was 20:1. Carbon dioxide was injected into the reactors after the solution had been bubbled with N2, in order to mimic O2-depleted natural storage conditions. A control reaction was also run on the clay-rich shale sample, where the crushed rock was reacted with brine (CO2-free brine) at the same experimental conditions. A total of 8 batch reaction experiments were run at temperatures ranging from 80 to 250 °C and total pressures of 110 bar (∼40 bar for the control experiment). The experiments lasted 1–5 weeks.Fluid analysis showed that the aqueous concentration of major elements (i.e. Ca, Mg, Fe, K, Al) and SiO2 increased in all experiments. Release rates of Fe and SiO2 were more pronounced in solutions reacted with CO2–brine as compared to those reacted with CO2-free brine. For samples reacted with the CO2–brine, lower temperature reactions (80 °C) released much more Fe and SiO2 than higher temperature reactions (150–250 °C). Analysis by SEM and XRD of reacted solids also revealed changes in mineralogical compositions. The carbonate-rich shale was more reactive at 250 °C, as revealed by the dissolution of plagioclase and clay minerals (illite and chlorite), dissolution and re-precipitation of carbonates, and the formation of smectite. Carbon dioxide was also permanently sequestered as calcite in the same sample. The clay-rich shale reacted with CO2–brine did not show major mineralogical alteration. However, a significant amount of analcime was formed in the clay-rich shale reacted with CO2-free brine; while no trace of analcime was observed in either of the samples reacted with CO2–brine. 相似文献
35.
Counterstreaming in a Large Polar Crown Filament 总被引：1，自引：0，他引：1
The motion of small-scale structures is well resolved in high-resolution filament images that were observed on 19 June 1998
with the Swedish Vacuum Solar Telescope, La Palma. The filament was between 80 000 and 100 000 km high. The study is based
on two hours of narrow-band observations at three wavelength positions in Hα. Velocities along the line of sight and in the
transverse direction, respectively, V
los and V
tr, were measured for a large number of individual small-scale filament structures. Small features are all moving along nearly
parallel threads, some in one direction along the threads and the remainder in the other direction, a pattern of motion known
as counterstreaming. The net flow velocities in the two directions are about 8 km s−1 and both are tilted by an angle δ≃16° relative to the plane of the sky. This angle is less than expected, by factors between
2.0 and 2.5, relative to the local horizontal plane. We believe that V
los is underestimated by these factors due to a line-shift reducing effect by the underlying Hα absorption line of the chromosphere.
Supplementary material to this paper is available in electronic form at http://dx.doi.org/10.1023/A:1026150809598 相似文献
36.
Produced water (PW) discharged from offshore oil industry contains chemicals known to contribute to different mechanisms of toxicity. The present study aimed to investigate oxidative stress and cytotoxicity in rainbow trout primary hepatocytes exposed to the water soluble and particulate organic fraction of PW from 10 different North Sea oil production platforms. The PW fractions caused a concentration-dependent increase in reactive oxygen species (ROS) after 1 h exposure, as well as changes in levels of total glutathione (tGSH) and cytotoxicity after 96 h. Interestingly, the water soluble organic compounds of PW were major contributors to oxidative stress and cytotoxicity, and effects was not correlated to the content of total oil in PW. Bioassay effects were only observed at high PW concentrations (3-fold concentrated), indicating that bioaccumulation needs to occur to cause similar short term toxic effects in wild fish. 相似文献
37.
Thin Threads of Solar Filaments 总被引：1，自引：0，他引：1
Yong?LinEmail author Oddbj?rn?Engvold Luc?Rouppe?van?der?Voort Jun?Elin?Wiik Thomas?E.?Berger 《Solar physics》2005,226(2):239-254
High-resolution images obtained in H with the new Swedish Solar Telescope at La Palma, Spain, have been used for studies of fine-scale threads in solar filaments. The widths of the thin threads are 0.3 arcsec. The fact that the width of the thinnest threads is comparable to the diffraction limit of the telescope of about 0.14 arcsec, at the wavelength of H, suggests that even thinner threads may exist. Assuming that the threads represent thin magnetic strings, we conclude that only a small fraction of these are filled with observable absorbing plasma, at a given time. The absorbing plasma is continuously flowing along the thread structures at velocities 15± 10 kms–1, which suggests that the flows must be field-aligned. In one case where a bundle of thin threads appears to be rooted in the nearby photosphere, we find that the individual threads connects with intergranular, dark lanes in the photosphere. We do not find signs of typical network fields at the roots of the fine threads, as normally evidenced by bright points in associated G-band images. It is suggested that filament threads are rooted in relatively weak magnetic fields. 相似文献
38.
Elin Langsholt 《水文研究》1992,6(1):11-27
The water balance of a 600 m2 field site on a lateritic hillslope in Kerala, southwest India, has been studied during two southwest monsoon seasons. Surface runoff was of minor importance while infiltration and evapotranspiration were the major components amounting to approximately 2/3 and 1/3 of the rainfall, respectively. Groundwater response was rapid, involving fluctuations of several metres. Recharge mechanisms hypothesized are water movement via preferred pathways from the ground surface to the capillary fringe where rapid rise in groundwater level is brought about by a transmitted pressure pulse. Groundwater recharge was found normally to take place during the southwest monsoon season only. the field study demonstrates that seasonal shallow groundwater recharge representing the major portion of the rainfall May, be observed in this lateritic terrain in the humid tropics. It indicates a good potential for further groundwater development. Moreover, conditions are conducive to a considerable contribution to possible recharge to deeper aquifers. the observed groundwater recharge is the result of a complex process on which further research will throw more light. 相似文献
39.
Elin Kalleson Henning Dypvik Fridtjof Riis Odd Nilsen 《Meteoritics & planetary science》2013,48(9):1678-1701
A melt‐bearing impactite unit is preserved in the 2.7 km diameter shallow marine Ritland impact structure. The main exposure of the melt‐bearing unit is in an approximately 100 m long cliff about 700 m southwest of the center of the structure. The melt and clast content vary through this maximum 2 m thick unit, so that lithology ranges from impact melt rock to suevite. Stratigraphic variations with respect to the melt content, texture, mineralogy, and geochemistry have been studied in the field, and by laboratory analysis, including thin section microscopy. The base of the melt‐bearing unit marks the transition from the underlying lithic basement breccia, and the unit may have been emplaced by an outward flow during the excavation stage. There is an upward development from a melt matrix‐dominated lower part, that commonly shows flow structures, to an upper part characterized by more particulate matrix with patchy melt matrix domains, commonly as deformed melt slivers intermingled with small lithic clasts. Melt and lithic fragments in the upper part display a variety of shapes and compositions, some of which possibly represent fallback material from the ejecta cloud. The upper boundary of the melt‐bearing impactite unit has been placed where the deposits are mainly clastic, probably representing slump and avalanche deposits from the modification stage. These deposits are therefore considered sedimentary and not impactites, despite the component of small melt fragments and shocked minerals within the lowermost part, which was probably incorporated as the debris moved down the steep crater walls. 相似文献