The feasibility of isolation and detection of fullerenes and carbon nanotubes using the benzene polycarboxylic acid method     

Lori A. Ziolkowski  Ellen R.M. Druffel 《Marine pollution bulletin》2009,59(4-7):213

The incorporation of fullerenes and carbon nanotubes into electronic, optical and consumer products will inevitably lead to the presence of these anthropogenic compounds in the environment. To date, there have been few studies isolating these materials from environmental matrices. Here we report a method commonly used to quantify black carbon (BC) in soils, the benzene polycarboxylic acid (BPCA) method, for measurement of two types of single walled carbon nanotubes (SWCNTs), two types of fullerenes and two forms of soot. The distribution of BC products (BPCAs) from the high pressure and high temperature oxidation illustrates the condensed nature of these compounds because they form predominantly fully substituted mellitic acid (B6CA). The conversion of carbon nanoparticles to BPCAs was highest for fullerenes (average of 23.2 ± 4.0% C recovered for both C₆₀ and C₇₀) and lowest for non-functionalized SWCNTs (0.5 ± 0.1% C). The recovery of SWCNTs was 10 times higher when processed through a cation-exchange column, indicating the presence of metals in SWCNTs compromises the oxidation chemistry. While mixtures of SWCNTs, soot and sediment revealed small losses of black carbon during sample processing, the method is suitable for quantifying total BC. The BPCA distribution of mixtures did not agree with theoretical mixtures using model polyaromatic hydrocarbons, suggesting the presence of a matrix effect. Future work is required to quantify different types of black carbon within the same sample.  相似文献   

The lower mass function of young open clusters: clues to (sub)stellar formation     

E. Moraux  J. Bouvier  C. Clarke 《Astronomische Nachrichten》2005,326(10):985-990

We report the present day mass functions (PDMFs) of 4 young open clusters over a mass range from 30 Jupiter masses to 3M_ . Three of these clusters have been chosen to have a similar age of ∼100 Myr. Their PDMFs are remarkably similar and are comparable to the field mass function. This suggests little impact of initial conditions (stellar density, metallicity) on the mass distribution and raises some issues concerning the currently debated star and brown dwarf formation theories. The fourth cluster is older (600 Myr) which allow us to investigate the effect of the cluster dynamical evolution on the shape of the mass function. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

Guest Editorial: Selected Papers from the Fourth International Conference on Integrating Geographic Information Systems and Environmental Modeling (GIS/EM4)     

Keith Clarke  Brad Parks  & Michael Crane 《Transactions in GIS》2000,4(3):177-180

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A Study of DMS Oxidation in the Tropics: Comparison of Christmas Island Field Observations of DMS, SO2, and DMSO with Model Simulations   总被引：2，自引：0，他引：2  

G. Chen  D. D. Davis  P. Kasibhatla  A. R. Bandy  D. C. Thornton  B. J. Huebert  A. D. Clarke  B. W. Blomquist 《Journal of Atmospheric Chemistry》2000,37(2):137-160

This study reports comparisonsbetween model simulations, based on current sulfurmechanisms, with the DMS, SO₂ and DMSOobservational data reported by Bandy et al.(1996) in their 1994 Christmas Island field study. For both DMS and SO₂, the model results werefound to be in excellent agreement with theobservations when the observations were filtered so asto establish a common meteorological environment. Thisfiltered DMS and SO₂ data encompassedapproximately half of the total sampled days. Basedon these composite profiles, it was shown thatoxidation of DMS via OH was the dominant pathway withno more than 5 to 15% proceeding through Cl atoms andless than 3% through NO₃. This analysis wasbased on an estimated DMS sea-to-air flux of 3.4 ×10⁹ molecs cm^-2 s^-1. The dominant sourceof BL SO₂ was oxidation of DMS, the overallconversion efficiency being evaluated at 0.65 ± 0.15. The major loss of SO₂ was deposition to theocean's surface and scavenging by aerosol. Theresulting combined first order k value was estimated at 1.6 × 10^-5 s^-1. In contrast to the DMSand SO₂ simulations, the model under-predictedthe observed DMSO levels by nearly a factor of 50. Although DMSO instrument measurement problems can notbe totally ruled out, the possibility of DMSO sourcesother than gas phase oxidation of DMS must beseriously considered and should be explored in futurestudies.  相似文献   

Watson: A new link in the HE iron chain     

Edward Olsen  Andrew Davis  Roy S. Clarke  Ludolf Schultz  Hartwig W. Weber  Robert Clayton  Toshiko Mayeda  Eugene Jarosewich  Paul Sylvester  Lawrence Grossman  Ming-Sheng Wang  Michael E. Lipschutz  Ian M. Steele  James Schwade 《Meteoritics & planetary science》1994,29(2):200-213

Abstract— Watson, which was found in 1972 in South Australia, contains the largest single silicate rock mass seen in any known iron meteorite. A comprehensive study has been completed on this unusual meteorite: petrography, metallography, analyses of the silicate inclusion (whole rock chemical analysis, INAA, RNAA, noble gases, and oxygen isotope analysis) and mineral compositions (by electron microprobe and ion microprobe). The whole rock has a composition of an H-chondrite minus the normal H-group metal and troilite content. The oxygen isotope composition is that of the silicates in the HE iron meteorites and lies along an oxygen isotope fractionation line with the H-group chondrites. Trace elements in the metal confirm Watson is a new HE iron. Whole rock Watson silicate shows an enrichment in K and P (each ～2X H-chondrites). The silicate inclusion has a highly equilibrated igneous (peridotite-like) texture with olivine largely poikilitic within low-Ca pyroxene: olivine (Fa₂₀), opx (Fs₁₇Wo₃), capx (Fs₉Wo₄₁) (with very fine exsolution lamellae), antiperthite feldspar (An_1–Or₅) with <1 μm exsolution lamellae (An_1–3Or_>40), shocked feldspar with altered stoichiometry, minor whitlockite (also a poorly characterized interstitial phosphate-rich phase) and chromite, and only traces of metal and troilite. The individual silicate minerals have normal chondritic REE patterns, but whitlockite has a remarkable REE pattern. It is very enriched in light REE (La is 720X C1, and Lu is 90X C1, as opposed to usual chonditic values of ～300X and 100–150X, respectively) with a negative Eu anomaly. The enrichment of whole rock K is expressed both in an unusually high mean modal Or content of the feldspar, Or₁₃, and in the presence of antiperthite. Whole rock trace element data for the silicate mass support the petrography. Watson silicate was an H-chondrite engulfed by metal and melted at > 1550 °C. A flat refractory lithophile and flat REE pattern (at ～1x average H-chondrites) indicate that melting took place in a relatively closed system. Immiscible metal and sulfide were occluded into the surrounding metal host. Below 1100 °C, the average cooling rate is estimated to have been ～1000 °C/Ma; Widmanstätten structure formed, any igneous zoning in the silicates was equilibrated, and feldspar and pyroxene exsolution took place. Cooling to below 300 °C was completed by 3.5 Ga B. P. At 8 Ma, a shock event took place causing some severe metal deformation and forming local melt pockets of schreibersite/metal. This event likely caused the release of Watson into interplanetary space. The time of this event, 8Ma, corresponds to the peak frequency of exposure ages of the H-chondrites. This further confirms the link between HE irons and the H-chondrites, a relationship already indicated by their common oxygen isotope source. Watson metal structures are very similar to those in Kodaikanal. Watson, Kodaikanal and Netschaëvo form the young group of HE meteorites (ages 3.7 ± 0.2 Ga). They appear to represent steps in a chain of events that must have taken place repeatedly on the HE parent body or bodies from which they came: chondrite engulfed in metal (Netschaëvo); chondrite melted within metal (Watson); and finally melted silicate undergoing strong fractionation with the fractionated material emplaced as globules within metal (Kodaikanal). Watson fills an important gap in understanding the sequence of events that took place in the evolution of the IIE-H parent body(ies). This association of H-chondrite with HE metal suggests a surface, or near surface process-a suggestion made by several other researchers.  相似文献   

Observations on seismic wave equation and reflection coefficient symmetries in stratified media     

C. Thomson  T. Clarke  J. Garmany 《Geophysical Journal International》1986,86(2):675-686

Summary. The equations describing seismic waves in a stratified earth have a number of symmetry properties, one of which has recently been used by Garmany to derive a simple expression for the inverse of the matrix of eigenvectors appearing in the solution of the equations. We review these symmetries of the wave equation in several notations to demonstrate that the property used by Garmany is distinct from the usual symmetries found in the seismological literature. Like the others, the new symmetry has implications for the reflection and transmission properties of a medium. These implications are briefly reviewed in order to show how the new symmetry is placed relative to the others. A limited discussion of the physical origins of the symmetries is given and, though the overall picture is incomplete, it is noted that the new symmetry yields conservation of energy for reflection/transmission at a single interface in all types of media (anisotropic, lossy, etc.).  相似文献   

Full reconstruction of a layered elastic medium from P-SV slant-stack data     

T. J. Clarke 《Geophysical Journal International》1984,78(3):775-793

Summary. We develop a méthod of reconstructing the elastic paraméters as functions of depth, for a horizontally stratified, isotropic elastic half-space. Unlike previous schemes, which have been able to retrieve the shear wave speed and density from SH seismograms slant stacked at two angles, our méthod makes use of P - SV data at a single stacking paraméter to obtain all three elastic constants. The data required are the elements of the full reflection matrix at the surface, corresponding to measurements of two separate components of the response to two independent sources, one explosive, the other generating shear waves.
In developing this inverse scheme fundamental differences emerge between the acoustic or SH problem, and the coupled P - SV case, the most important being in the nature of the interfacial scattering matrix. We show that it is not possible to make use of the downward reflection data for an interface to determine directly the remaining reflection and transmission coefficients, but that the scattering data may be completed by applying a simple iterative procedure at each interface.
We show the result of applying our inverse scheme to seismograms generated for a six-layered model, including a low-velocity layer. We are able to reconstruct both wave speeds and the density as functions of depth, all quantities being in close agreement with the original model.  相似文献   

THE VERKHNE DNIEPROVSK IRON METEORITE SPECIMENS IN THE VIENNA COLLECTION AND THE CONFUSION OF VERKHNE DNIEPROVSK WITH AUGUSTINOVKA     

V.F. Buchwald  Roy S. Clarke 《Meteoritics & planetary science》1987,22(2):121-135

It is now a hundred years since a small amount of meteoritic material labelled Verkhne Dnieprovsk was first described. Since then the material has been controversial, due to the corroded character and the very limited amount of material known. Authentic samples, totalling 8 g, have been identified in the Vienna collection, which confirm that Verkhne Dnieprovsk is a unique meteorite, both in its composition, belonging to group II E, and in its heavily shocked and distorted structure. The shock-produced structures include micromelts with a phosphorus gradient, suggesting that the melts originated in situ from mm-sized schreibersite crystals. Unfortunately, no additional information as to location and circumstances of find was discovered at this late date. Further work will probably require field work and interviews on the site and/or studies of Russian archives.  相似文献   

Community Recovery Following the Deepwater Horizon Oil Spill: Toward a Theory of Cultural Resilience     

Hannah E. Clarke 《社会与自然资源》2017,30(2):129-144

Culture plays an important role in communities’ abilities to adapt to environmental change and crises. The emerging field of resilience thinking has made several efforts to better integrate social and cultural factors into the systems-level approach to understanding social–ecological resilience. However, attempts to integrate culture into structural models often fail to account for the agentic processes that influence recovery at the individual and community levels, overshadowing the potential for agency and variation in community response. Using empirical data on the 2010 BP oil spill’s impact on a small, natural-resource-dependent community, we propose an alternative approach emphasizing culture’s ability to operate as a resource that contributes to social, or community, resilience. We refer to this more explicit articulation of culture’s role in resilience as cultural resilience. Our findings reveal that not all cultural resources that define resilience in reference to certain disasters provided successful mitigation, adaptation, or recovery from the BP spill.  相似文献   

An Assessment of HOx Chemistry in the Tropical Pacific Boundary Layer: Comparison of Model Simulations with Observations Recorded during PEM Tropics A     

G. Chen  D. Davis  J. Crawford  B. Heikes  D. O'Sullivan  M. Lee  F. Eisele  L. Mauldin  D. Tanner  J. Collins  J. Barrick  B. Anderson  D. Blake  J. Bradshaw  S. Sandholm  M. Carroll  G. Albercook  A. Clarke 《Journal of Atmospheric Chemistry》2001,38(3):317-344

Reported are the results from a comparison of OH,H₂O₂CH₃OOH, and O₃ observationswithmodel predictions based on current HO_x–CH₄reaction mechanisms. The field observations are thoserecorded during the NASA GTE field program, PEM-Tropics A. The major focus ofthis paper is on thosedata generated on the NASA P-3B aircraft during a mission flown in the marineboundary layer (MBL) nearChristmas Island, a site located in the central equatorial Pacific (i.e.,2° N, 157° W). Taking advantage of thestability of the southeastern trade-winds, an air parcel was sampled in aLagrangian mode over a significantfraction of a solar day. Analyses of these data revealed excellent agreementbetween model simulated andobserved OH. In addition, the model simulations reproduced the major featuresin the observed diurnalprofiles of H₂O₂ and CH₃OOH. In the case ofO₃, the model captured the key observational feature whichinvolved an early morning maximum. An examination of the MBL HO_xbudget indicated that the O(¹D) + H₂Oreaction is the major source of HO_x while the major sinks involveboth physical and chemical processes involving the peroxide species,H₂O₂ and CH₃OOH. Overall, the generally goodagreement between modeland observations suggests that our current understanding ofHO_x–CH₄ chemistry in the tropical MBL isquite good; however, there remains a need to critically examine this chemistrywhen both CH₂O and HO₂are added to the species measured.  相似文献